This thesis investigates the behavior of two candidate materials (a-SiO2 and MgO) for applications in fusion (e.g., the International Thermonuclear Experimental Reactor ITER) and Generation IV fission reactors. Both parts of the thesis - the development of the ionoluminescence technique and the study of the ion-irradiation effects on both materials - are highly relevant for the fields of the ion-beam analysis techniques and irradiation damage in materials. The research presented determines the microstructural changes at different length scales in these materials under ion irradiation. In particular, it studies the effect of the irradiation temperature using several advanced characterization techniques. It also provides much-needed insights into the use of these materials at elevated temperatures. Further, it discusses the development of the ion-beam-induced luminescence technique in different research facilities around the globe, a powerful in situ spectroscopic characterization method that until now was little known. Thanks to its relevance, rigorosity and quality, this thesis has received twoprestigious awards in Spain and France.

With current moves towards international harmonization, there is a need for rationalization and standardization of test procedures and interpretation of test results in many fields. Testing of metals for use in structures, particularly steel and aluminium, is a subject where information on these aspects is generally lacking. In response to this, RILEM (The International Union of Testing and Research Laboratories for Materials and Structures) organized an international workshop to identify "need in testing metals". Invited experts from Europe, Japan and the USA have contributed papers not only on experimental procedures for testing metallic materials, joints and structural components, but also on analytical models for interpreting their behaviour and for use in calculations. The papers brought together in this book provide reviews of the current situation and signposts for future research and development needs. In response to the recommendations of the workshop, RILEM is setting up new international committees and initiatives on the behaviour of joints, high cycle fatigue, non-destructive testing, structural imperfections, composite and thin-walled structures. This book should be va

This work reviews methods for the experimental determination of concrete toughness and presents theories and models suitable for describing cracking and fracturing phenomena in plain and reinforced concrete. Test methods based on classsical linear fracture mechanics cannot be applied to laboratory sized concrete specimens. The book compares the currently used methods and presents recommended test procedures for mode I fracture/toughness using notched beam and other specimens. Crack propagation under mixed-mode loading (Mode II) is discussed and current test methods are extensively reviewed. Effects of loading rate, temperature and humidity effects are treated in a separate chapter. The book concludes with descriptions and recommendations of techniques for detecting the fracture process zone in concrete, in particular, pulse velocity and laser interferometry techniques. The introduction of the concepts of fracture toughness and fracture energy into structural concrete design codes means that the experimental determination of fracture porperties is ceasing to be an academic exercise and is becoming a technical need. This book has been prepared by RILEM Technical committee 89-FMT and

As a follow up to these meetings the Fourth International Symposium has the purpose of emphasizing the role of mechanical tests in the characterization, design and quality control of bituminous mixes. Its basic objectives are to evaluate all information enabling the assessment of methods, their advantages and drawbacks and also the manner in which problems can be solved, to establish a better understanding and a documentation of results of research and practical engineering in order to establish a common ground between research, road authorities and contractors. Traditional test methods help avoid large errors, but the significance of the results is very restricted. Fundamental methods are more complex; they yield better, more significant paremeters but the application of these methods is limited to experts and special laboratories. Consequently, every effort should be made to develop tests having the advantages of both the traditional as well as modern methods and avoiding the restrictions of both. The particular aim of this symposium is to promote tests for the characterization, design and control of bituminous mixes, considering the needs of practice and science and the connecti

Growth of Crystals, Volume 21 presents a survey, with detailed analysis, of the scientific and technological approaches, and results obtained, by leading Russian crystal growth specialists from the late 1990's to date.

The volume contains 16 reviewed chapters on various aspects of crystal and crystalline film growth from various phases (vapour, solution, liquid and solid). Both fundamental aspects, e.g. growth kinetics and mechanisms, and applied aspects, e.g. preparation of technically important materials in single-crystalline forms, are covered.

A large portion of the volume is devoted to film growth, including film growth from eutectic melt, from amorphous solid state, kinetics of lateral epitaxy and film growth on specially structured substrates. An important chapter in this section covers heteroepitaxy of non-isovalent A3B5 semiconductor compounds, which have important applications in the field of photonics.

The volume also includes a detailed analysis of the structural aspects of a broad range of laser crystals, information that is invaluable for successfully growing perfect, laser-effective, single crystals.

The results in this dissertation set the ground to answer a fundamental question in data-driven polymer material science: "Why don't prepared composites show less fatigue than the pure plastics?" A simultaneous analysis of mechanical testing and small angle X-Ray scattering from the DESY source in Hamburg has been applied to approach this question, which is also central to the European research project "Nanotough", and the results are clearly presented in this book. The evolution of the materials structure is visualized and quantitatively analyzed from exhaustive sequences of scattering images. Three different classes of polymer composites are presented as typical and illustrative examples. The obtained results illustrate that the interactions of their components can cause unpredictable structural effects, ultimaltely leading to a weakening of the material, where a reinforcement was expected.

During the last decade we have been witness to several exciting achievements in electron crystallography. This includes structural and charge density studies on organic molecules complicated inorganic and metallic materials in the amorphous, nano-, meso- and quasi-crystalline state and also development of new software, tailor-made for the special needs of electron crystallography. Moreover, these developments have been accompanied by a now available new generation of computer controlled electron microscopes equipped with high-coherent field-emission sources, cryo-specimen holders, ultra-fast CCD cameras, imaging plates, energy filters and even correctors for electron optical distortions. Thus, a fast and semi-automatic data acquisition from small sample areas, similar to what we today know from imaging plates diffraction systems in X-ray crystallography, can be envisioned for the very near future. This progress clearly shows that the contribution of electron crystallography is quite unique, as it enables to reveal the intimate structure of samples with high accuracy but on much smaller samples than have ever been investigated by X-ray diffraction. As a tribute to these tremendous recent achievements, this NATO Advanced Study Institute was devoted to the novel approaches of electron crystallography for structure determination of nanosized materials.

Following my graduation in physical organic chemistry at the University of Amst- dam, I started to work at the Royal Dutch Shell Laboratories in Amsterdam. My first assignment was research in the field of detergents and industrial chemicals. It was followed by development work on thermal wax cracking for production of C - C 2 14 olefins and on acid-catalyzed synthesis of carboxylic acids from C - C olefins. 3 6 Then, I made a significant change to analytical chemistry, first at Shell's process development department and later in the chemical engineering department of Delft University of Technology. In both departments, there was a large variety of analy- cal techniques and development of new methods for automated analysis of small process streams. It was the time that gas chromatography conquered the world. In this field, a firm basis was given by Henk Boer, Arie Kwantes and Frits Zuiderweg at Shell Research Laboratories in Amsterdam, both for packed and for capillary c- umns. The potential of gas chromatography was huge and, therefore, also in Delft, its use increased enormously. Moreover, the growth of this technique was facilitated significantly by the rapidly developing electronics industry. It not only led to digital peak integrators and personal computers but also enabled complex measurement techniques. In addition, I became involved in surface area and porosity characteri- tion of catalysts and adsorbents, on which topic the research had been initiated by Prof. J. H. de Boer.

This thesis presents a novel ultrasonic instrument for non-invasive and in-situ characterization of journal bearing lubricant viscosity. In particular, the application to journal bearings is described by non-invasively measuring the viscosity and localized power losses throughout operation. This ultrasonic viscometer is based on the reflection of polarized shear waves from a thin resonating coating layer to increase the measurement sensitivity, in comparison to conventional ultrasonic methods. This instrument allows for a full engine oil viscoelastic characterization in-situ. The book investigates the effects of temperature, pressure and shear rate, and describes in detail the ultrasonic setup and method. Further, it demonstrates that the same technique can be applied similarly to monitor the lubrication of other engine components. As such, it offers a unique instrument that can drive the research of oil formulations to improve engine performance and fulfill the requirements of international fuel economy regulations.

This book presents a comprehensive review of the most important methods used in the characterisation of piezoelectric, ferroelectric and pyroelectric materials. It covers techniques for the analysis of bulk materials and thick and thin film materials and devices.

There is a growing demand by industry to adapt and integrate piezoelectric materials into ever smaller devices and structures. Such applications development requires the joint development of reliable, robust, accurate and - most importantly - relevant and applicable measurement and characterisation methods and models. In the past few years there has been a rapid development of new techniques to model and measure the variety of properties that are deemed important for applications development engineers and scientists.

The book has been written by the leaders in the field and many chapters represent established measurement best practice, with a strong emphasis on application of the methods via worked examples and detailed experimental procedural descriptions. Each chapter contains numerous diagrams, images, and measurement data, all of which are fully referenced and indexed.

The book is intended to occupy space in the research or technical lab, and will be a valuable and practical resource for students, materials scientists, engineers, and lab technicians.

This book presents the practical aspects of mass measurements. Concepts of gravitational, inertial and conventional mass and details of the variation of acceleration of gravity are described. The Metric Convention and International Prototype Kilogram and BIPM standards are described. The effect of change of gravity on the indication of electronic balances is derived with respect of latitude, altitude and earth topography. The classification of weights by OIML is discussed. Maximum permissible errors in different categories of weights prescribed by national and international organizations are presented. Starting with the necessity of redefining the unit kilogram in terms of physical constants, various methods of defining the kilogram in terms of physical constants are described. The kilogram can be defined by Avogadro's constant, ion collection of some heavy elements, levitation, voltage and Watt Balance. The detection of very small mass of the order of zeptogram through Nanotechnolgy is also discussed. Latest recommendations of CIPM are given.

This thesis presents an in-depth study on the effect of colloidal particle shape and formation mechanism on self-organization and the final crystal symmetries that can be achieved. It demonstrates how state-of-the-art X-ray diffraction techniques can be used to produce detailed characterizations of colloidal crystal structures prepared using different self-assembly techniques, and how smart systems can be used to investigate defect formation and diffusion in-situ. One of the most remarkable phenomena exhibited by concentrated suspensions of colloidal particles is the spontaneous self-organization into structures with long-range spatial and/or orientational orders. The study also reveals the subtle structural variations that arise by changing the particle shape from spherical to that of a rounded cube. In particular, the roundness of the cube corners, when combined with the self-organization pathway, convective assembly or sedimentation, was shown to influence the final crystal symmetries.

The papers in this volume cover a broad spectrum of topics that represent the truly diverse nature of the field of composite materials. In recent years, composite materials have grown in strength, stature, and significance to become a key material of enhanced scientific interest and resultant research into understanding their behavior for selection and safe use in a wide spectrum of technology-related applications. This collection presents research and findings relevant to the latest advances in composites materials, specifically their use in aerospace, maritime, and even land applications. The editors have made every effort to bring together authors who put forth recent advances in their research while concurrently both elaborating on and thereby enhancing our prevailing understanding of the salient aspects related to the science, engineering, and far-reaching technological applications of composite materials.

The discovery of high temperature superconductors (HTS) in 1986 by two IBM scientists led to an unprecedented explosion of research and development efforts world-wide because of the significant potential for practical applications offered by these materials. However, the early euphoria created by the exciting prospects was dampened by the daunting task of fabricating these materials into useful forms with acceptable superconducting properties. Progress towards this goal has been hindered by many intrinsic materials problems, such as weak-links, flux-creep, and poor mechanical properties.

The above problems led to the development of the Second-Generation of HTS wires. Three methods were invented to produce flexible metallic substrates, which were also crystallographically biaxially textured, and resembled a long, mosaic single crystal. The first method invented is the Ion-Beam-Assisted-Deposition (IBAD). The second method developed was the Inclined-Substrate-Deposition (ISD). The third method invented is called the Rolling-assisted-biaxially-textured-substrates (RABiTS).

The book is divided into four sections. The first section discusses the three methods to fabricate biaxially textured substrates, upon which, epitaxial YBCO or other HTS materials can be deposited to realize a single-crystal-like HTS wire. The second section includes chapters on various methods of HTS deposition such as pulsed laser ablation (PLD), thermal co-evaporation, sputtering, pulsed electron beam deposition, ex-situ BaF2 by co-evaporation flowed by annealing, chemical solution based ex-situ processes, jet vapor deposition, metal organic chemical vapor deposition (MOCVD), and liquid phase epitaxy (LPE).The third section includes detailed chapters on other HTS materials such as the various Tl-based and Hg-based conductors.

These Second-Generation HTS conductors, also referred to as "Coated conductors" represent one of the most exciting developments in HTS technology. HTS wires based on this technology have the potential to carry 100-1000 times the current without resistance losses of comparable copper wire. HTS power equipment based on these HTS conductors has a potential to be half the size of conventional alternatives with the same or higher power rating and less than one half the energy losses. Upgrading of the world-wide electric power transmission and distribution with HTS based devices can significantly help in meeting the growing demand for electricity world-wide. There is little question that superconducting technology based on the Next-Generation HTS Superconducting Wires will make a substantial impact on the way we generate, transmit, distribute and use electric power. Of course the question is - how soon?

The dielectric properties especially of glassy materials are nowadays explored at widely varying temperatures and pressures without any gap in the spectral range from Hz up to the Infrared, thus covering typically 20 decades or more. This extraordinary span enables to trace the scaling and the mutual interactions of relaxation processes in detail, e.g. the dynamic glass transition and secondary relaxations, but as well far infrared vibrations, like the Boson peak. Additionally the evolution of intra-molecular interactions in the course of the dynamic glass transition is also well explored by (Fourier Transform) Infrared Spectroscopy. This volume within 'Advances in Dielectrics' summarizes this knowledge and discusses it with respect to the existing and often competing theoretical concepts.

This volume represents the current knowledge on the effect of SCMs (slag, fly ash, silica fume, limestone powder, metakaolin, natural pozzolans, rice husk ash, special SCMs, ternary blends) on the properties of fresh and hardened concrete (e.g. early strength development, workability, shrinkage) and curing requirements. Other topics treated in the book are postblending vs preblending, implications of SCM variability, interaction between SCM and commonly used admixtures (e.g. superplasticizers, air entrainers).

The measurement and characterisation of surface topography is crucial to modern manufacturing industry. The control of areal surface structure allows a manufacturer to radically alter the functionality of a part. Examples include structuring to effect fluidics, optics, tribology, aerodynamics and biology. To control such manu-facturing methods requires measurement strategies. There is now a large range of new optical techniques on the market, or being developed in academia, that can measure areal surface topography. Each method has its strong points and limitations. The book starts with introductory chapters on optical instruments, their common language, generic features and limitations, and their calibration. Each type of modern optical instrument is described (in a common format) by an expert in the field. The book is intended for both industrial and academic scientists and engineers, and will be useful for undergraduate and postgraduate studies.

This collection presents the papers from a symposium on extraction of rare metals as well as rare extraction processing techniques used in metal production. Paper topics include the extraction and processing of elements like antimony, arsenic, calcium, chromium, hafnium, gold, indium, lithium, molybdenum, niobium, rare earth metals, rhenium, scandium, selenium, silver, strontium, tantalum, tellurium, tin, tungsten, vanadium, and zirconium. Rare processing techniques presented include bio leaching, molecular recognition technology, recovery of valuable components of commodity metals such as magnesium from laterite process wastes, titanium from ilmenites, and rare metals from wastes such as phosphors and LCD monitors.

This book focuses on the modern development of techniques for analysis of the hierarchical structure of polymers from both the experimental and theoretical points of view. Starting with molecular and crystal symmetry, the author explains fundamental and professional methods, such as wide- and small-angle X-ray scattering, neutron diffraction, electron diffraction, FTIR and Raman spectroscopy, NMR, and synchrotron radiation. In addition, the author explains another indispensable method, computer simulation, which includes energy calculation, lattice dynamics, molecular dynamics, and quantum chemistry. These various methods are described in a systematic way so that the reader can utilize them for the purpose of 3D structure analysis of polymers. Not only such analytical knowledge but also the preparation techniques of samples necessary for these measurements and the methods of analyzing the experimental data collected in this way are given in a concrete manner. Examples are offered to help master the principles of how to clarify the static structures and dynamic structural changes in the phase transitions of various kinds of crystalline polymers that are revealed by these novel methods. The examples are quite useful for readers who want to apply these techniques in finding practical solutions to concrete problems that are encountered in their own research. The principal audience for this book is made up of young professional researchers including those working in industry, but it can also be used as an excellent reference for graduate-level students. This book is the first volume of a two-volume set with Structural Science of Crystalline Polymers: A Microscopically Viewed Structure-Property Relationship being the second volume by the same author.

This book presents physical units and widely used physical formulas, which are given together with conversion factors in various units. It includes frequently used atomic spectra and data for atoms, ions and molecules, as well as potential curves for diatomic molecules, and provides numerical parameters for transport phenomena in gases and plasmas. Further, the rate constants of a number of processes in atmospheric ionized air have been added to this second edition of the book. The numerical data has been selected from the information on atoms, atomic systems, atomic processes and models for atomic physics in this area, and the numerical parameters of atoms, ions and atom systems are included in periodical tables of elements.

This book is devoted to the development of the shape memory materials and their applications. It covers many aspects of smart materials. It also describes the method on how we can obtain not only large recovery strains but also high recovery stress, energy storage and energy dissipation in applications. This volume treats the mechanical properties of shape memory alloys, shape memory polymers and the constitutive equations of the materials which are necessary to design the shape memory elements in applications. It also deals with the fatigue properties of materials, the method to design the shape memory elements, and the shape memory composites. The authors are international experts on shape memory alloys and shape memory polymers in the metallurgical, chemical, mechanical and engineering fields. The book will be of interest to graduate students, engineers, scientists and designers who are working in the field of electric and mechanical engineering, industries, medical engineering, aerospace engineering, robots, automatic machines, clothes and recycling for research, design and manufacturing.

The subject of this book is to study the porous media and the transport processes occur there. As a first step, the authors discuss several techniques for artificial representation of porous. Afterwards, they describe the single and multi phase flows in simplistic and complex porous structures in terms of macroscopic and microscopic equations as well as of their analytical and numerical solutions. Furthermore, macroscopic quantities such as permeability are introduced and reviewed. The book also discusses with mass transport processes in the porous media which are further strengthen by experimental validation and specific technological applications. This book makes use of state-of-the-art techniques for the modeling of transport processes in porous structures, and considers of realistic sorption mechanisms. It the applies advanced mathematical techniques for upscaling of the major quantities, and presents the experimental investigation and application, namely, experimental methods for the measurement of relevant transport properties. The main benefit of the book is that it discusses all the topics related to transport in porous media (including state-of-the-art applications) and presents some of the most important theoretical, numerical and experimental developments in porous media domain, providing a self-contained major reference that is appealing to both the scientists and the engineers. At the same time, these topics encounter a variety of scientific and engineering disciplines, such as chemical, civil, agricultural, mechanical engineering. The book is divided in several chapters that intend to be a resume of the current state of knowledge for benefit of related professionals and scientists.

This book provides insight into the underlying basic theories and concepts in X-ray, light, and neutron scattering. The three scattering principles are systematically presented, together with a unified description based on elastic scattering of electromagnetic waves and the Schroedinger wave from matter. These explanations are presented with an introduction of their common Born approximation using a consistent set of symbols and terminology and with step-by-step derivations of equations. This book emphasizes the combined applications of these three scattering methods, wherever and whenever possible, as a very powerful methodology for characterization of internal structures of soft matters in the length scale ranging from subnanometers to a few 10 micron meters. These applications include explorations for evolution of hierarchically self-organized internal structures of a variety of soft matters, including cells, under diverse environmental conditions. This book will not only be an excellent resource for graduate students and academic researchers who analyze structures of soft matters and polymers, but it will also be useful for researchers in industries.

All living things contain carbon in some form, as it is the primary component of macromolecules including proteins, lipids, nucleic acids (RNA and DNA), and carbohydrates. As a matter of fact, it is the backbone of all organic (chemistry) compounds forming different kinds of bonds. Carbon: The Black, the Gray and the Transparent is not a complete scientific history of the material, but a book that describes key discoveries about this old faithful element while encouraging broader perspectives and approaches to its research due to its vast applications. All allotropes of carbon are described in this book, along with their properties, uses, and methods of procurement or manufacturing. Black carbon is represented by coal, gray carbon is represented by graphite, and transparent carbon is represented by diamond.