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Books > Science & Mathematics > Chemistry > Physical chemistry > Nuclear chemistry, photochemistry & radiation
This book, the third in the series Behavior of Radionuclides in the
Environment, is dedicated to Fukushima. Major findings from
research since 2011 are reviewed concerning the behavior of
radionuclides released into the environment due to the Fukushima
Dai-ichi Nuclear Power Plant accident, including atmospheric
transport and fallout of radionuclides, their fate, and transport
in the soil-water environment, behavior in freshwater, coastal and
marine environment, transfer in the terrestrial and agricultural
environment. Volume III discusses not only radionuclides dynamics
in the environment in the short- and mid-term, but also modeling
and prediction of long-term time changes. Along with reviews, the
book contains original data and results not published previously.
It was spearheaded by the authors from the Institute of
Environmental Radioactivity at Fukushima University, established
two years after the Fukushima accident, with their collaborators
from Japan, Russia, and Ukraine. The knowledge emerging from the
studies of the environmental behavior of Fukushima-derived
radionuclides enables us to move forward in understanding
mechanisms of environmental contamination and leads to better
modeling and prediction of long-term pollution effects in general.
Pertaining to homeland security, this title is a comprehensive
guide to radiation protection caused by accidents or terrorism
Provides essential strategies and guidance for protecting ports and
examines the latest nuclear detection devices that can be deployed
Explains the procedures in FEMA's "National Incident Management
System" Gives specific details for first responders and emergency
workers on how to prepare for and handle radiological incidents
The 2011 disaster at the Fukushima Daiichi Nuclear Power Station
led to serious radioactive contamination of the environment. Due to
transportation by seasonal wind and ocean currents, these
radioactive materials have now been observed in many places in the
Northern Hemisphere. This book provides a unique summary of the
environmental impact of the unprecedented accident. It covers how
radioactive materials were transported through the atmosphere,
oceans and land. The techniques used to investigate the deposition
and migration processes are also discussed including atmospheric
observation, soil mapping, forest and ecosystem investigations, and
numerical simulations. With chapters written by international
experts, this is a crucial resource for researchers working on the
dispersion and impact of radionuclides in the environment. It also
provides essential knowledge for nuclear engineers, social
scientists and policymakers to help develop suitable mitigation
measures to prepare for similar large-scale natural hazards in the
future.
Photochemistry is the study of the interaction of light with
matter. This Primer describes the chemistry that follows the
absorption of light, and explains the extraordinary influence of
visible or ultraviolet light on chemical behaviour. After the
absorption of light, a molecule may acquire completely different
properties from those of its parent. The authors explain the role
of light initiating this metamorphosis, the dependence of natural
processes such as photosynthesis on photochemistry, the emission of
radiation as fluorescence and phosphoresence, and current
applications of photochemistry, which include photography,
photopolymerization, photodegradable polymers, and the synthesis of
organic chemicals. This book is an essential introduction to the
intriguing field of photochemistry.
Vorliegendes Buch gibt den Inhalt unserer zweisemestrigen Vor-
lesung in Kernchemie und Radiochemie an der hiesigen Technischen
Hochschule wieder. Der entsprechende Unterricht galt ursprunglich
Horern der Fachabteilungen Chemie, Elektrizitatslehre und Mechanik
sowie Medizinern der hiesigen Universitat, hat sich aber in den
letzten Jahren hauptsachlich auf Chemiker und Technische Physiker
be- schrankt. Der Mangel an zusammenfassenden Darstellungen des
umfangreichen Gebietes in einer Schrift fuhrte zunachst zu einem
Manuskript in schwe- discher Sprache, dann zur Dbersetzung ins
Deutsche. Seit der Fertig- stellung des ursprunglichen Manuskriptes
hat sich der Mangel an deutsch- sprachiger Literatur auf unserem
Arbeitsgebiet verringert [so sind u. a. inzwischen Bucher uber die
kernchemischen Grundlagen, uber die Ana- lyse des zu
radiochemischen Trennungen so oft verwendeten Ionenaus-
tauschverfahrens, uber Einzelheiten der Kernbrennstoffaufbereitung
und uber die Berucksichtigung des Strahlenschutzes bei Arbeiten mit
hochradioaktiven Stoffen erschienen, vgl. Literaturhinweise Kap.
1-3: 4, Kap. 7: 20 und Kap. 9: 9 und 14]. Dennoch haben wir von dem
ursprunglichen Plan einer zusammen- fassenden Darstellung nicht
Abstand genommen, da wir es fur wesent- lich halten, den
Studierenden eine im Umfang noch einigermaBen leicht zu
bewaltigende Einfiihrung in das gesamte Fachgebiet in die Hande zu
geben. Die Form einer Einfuhrung fuhrt mit sich, daB wir von dem
ublichen System der Literaturhinweise in Form von Zitaten Abstand
nehmen. Jedoch erwies es sich als zweckmaBig, zumindest die Namen
einiger Verfasser an den entsprechenden Textstellen zu erwahnen.
(Bei der gedrangten Auswahl sind moglicherweise fiihrende Forscher
un- genugend oder uberhaupt nicht erwahnt worden.
This 1958 book sets out the elementary precautions to be taken by
anyone handling radioactive isotopes in laboratories. The
introductory sections explain the types of radiation encountered,
and enumerate the possible dangers from external sources,
accidental ingestion and contamination of the body. The safety
techniques for various laboratory experiments and the proper
methods of disposal of radioactive waste are described in some
detail. A final section on laboratory administration is followed by
a convenient summary of 'dos' and do nots' for safe working. The
appendices include a classified table of isotopes and their
toxicity, diagrams of protective equipment, and details of the
shielding necessary for emissions of given energy. Dr Boursnell
confines his discussion to the common essentials of all laboratory
techniques; his book will be of value to anyone with an interest in
the active materials.
More than ever before, radiation is a part of our modern daily
lives. We own radiation-emitting phones, regularly get diagnostic
x-rays, such as mammograms, and submit to full-body security scans
at airports. We worry and debate about the proliferation of nuclear
weapons and the safety of nuclear power plants. But how much do we
really know about radiation? And what are its actual dangers? An
accessible blend of narrative history and science, Strange Glow
describes mankind's extraordinary, thorny relationship with
radiation, including the hard-won lessons of how radiation helps
and harms our health. Timothy Jorgensen explores how our knowledge
of and experiences with radiation in the last century can lead us
to smarter personal decisions about radiation exposures today.
Jorgensen introduces key figures in the story of radiation--from
Wilhelm Roentgen, the discoverer of x-rays, and pioneering
radioactivity researchers Marie and Pierre Curie, to Thomas Edison
and the victims of the recent Fukushima Daiichi nuclear power plant
accident. Tracing the most important events in the evolution of
radiation, Jorgensen explains exactly what radiation is, how it
produces certain health consequences, and how we can protect
ourselves from harm. He also considers a range of practical
scenarios such as the risks of radon in our basements, radiation
levels in the fish we eat, questions about cell-phone use, and
radiation's link to cancer. Jorgensen empowers us to make informed
choices while offering a clearer understanding of broader societal
issues. Investigating radiation's benefits and risks, Strange Glow
takes a remarkable look at how, for better or worse, radiation has
transformed our society.
There has been a resurgence of interest in light-induced water
splitting as the search for storable carbon neutral energy becomes
more urgent. Although the history of the basic idea dates back more
than four decades, efficient, economical and stable integrated
devices have yet to be realized. In the continuing quest for such
devices, the field of photoelectrochemistry is entering a new phase
where the extraordinary interdisciplinary of the research and
development efforts are opening new avenues. This aspect of current
research effort is reflected in the chapters of this book, which
encompass present thinking in the various disciplines such as
materials science, photo-electrochemistry and interfaces that can
contribute to realization of viable solar fuel generators. This
book presents a blend of the background science and recent advances
in the field of photoelectrochemical water splitting, and includes
aspects that point towards medium to long term future realization.
The content of the book goes beyond the more traditional approaches
to the subject by including topics such as novel excitation energy
processes that have only been realized so far in advanced
photonics. The comprehensive overview of current activities and
development horizons provided by the impressive collection of
internationally renowned authors therefore represents a unique
reflection of current thinking regarding water splitting by light.
The Globally Harmonized System of Classification and Labelling of
Chemicals (GHS) addresses classification and labelling of chemicals
by types of hazards. It provides the basis for worldwide
harmonization of rules and regulations on chemicals and aims at
enhancing the protection of human health and the environment during
their handling, transport and use by ensuring that the information
about their physical, health and environmental hazards is
available. The sixth revised edition includes, inter alia, a new
hazard class for desensitized explosives and a new hazard category
for pyrophoric gases; miscellaneous amendments intended to further
clarify the criteria for some hazard classes (explosives, specific
target organ toxicity following single exposure, aspiration hazard,
and hazardous to the aquatic environment) and to complement the
information to be included in section 9 of the Safety Data Sheet;
revised and further rationalized precautionary statements; and an
example of labelling of a small packaging in Annex 7.
The world made new is a biography of one of the most original and
widely significant, yet largely forgotten, British scientists.
Frederick Soddy was born in 1877 and was one of the first
generation of English atomic scientists, who stood out from his
colleagues from the start. He worked with Rutherford on the initial
discoveries about atomic disintegration, for which Rutherford
received the Nobel Prize. Soddy himself received the Nobel Prize in
1921 for his research on isotopes. Soddy's worry about the
responsibility of science and scientists to society began with his
fear that the atomic energy he and Rutherford had discovered could
be disastrous if suitable political controls were not enforced, and
led to him abandoning scientific research. He lived to see his
worst fears realized with the bombing of Hiroshima and Nagasaki.
Soddy was also concerned with economics and ecology and was a
pioneer in the field of energy conservation and environmental
ethics. Throughout his life, Soddy was also committed to social
reform. Frederick Soddy was a remarkable and talented man who was
not recognized as such in his own life-time, largely because his
ideas and attitudes did not fit in with the times in which he
lived. However he has become more appreciated since his death, not
only because his scientific work has gained its rightful
recognition, but also because of the increased awareness today of
the environment and the role of science in it.
Artificial photosynthesis is the process of converting solar energy
into useful fuels and represents a significant achievement in the
production of clean energy for the planet. In the process, energy
is generated from water and CO2 reduction using solar-powered
photocatalysis. This book provides a comprehensive overview of
recently developed, multifunctional materials as visible
light-driven catalysts, their mechanisms and applications in solar
energy utilisation and conversion. Chapters highlight the use of
different approaches such as molecular catalysis, nanomaterials
systems, as well as thin-films for solar-driven evolution of
renewable fuels, such as hydrogen. This is the first book to give
an overview of this area, with chapters specifically interesting
for those looking towards industrial applications. With in-depth
discussions ranging from understanding, to engineering of materials
and applied devices, it will be suitable for industry
professionals, researchers and students interested in understanding
of the current state of photocatalysis research and its possible
applications in the energy domain.
Photoinitiating systems play a key role in the starting point of a
polymerization reaction under exposure to a UV or a visible light.
The number of publications discussing photoinitiating systems for
polymerization has seen a significant growth in recent years and
this book provides an update on their latest research developments.
The book covers different types of photoinitiating systems
including UV radical photoinitiators, long wavelength sensitive
radical photoinitiators, cationic photoinitiators and water soluble
photoinitiators as well as a chapter on how to design novel
photoinitiators. The book then focusses on the applications of the
photoinitiators from nanoparticles and materials to ionic liquids
and solar cells. Edited by leading names in the field, the book is
suitable for postgraduate students and researchers in academia and
industry interested in polymer chemistry, organic chemistry,
materials science and the applications of the materials.
To assure the safe, technically optimal and cost effective
management of spent fuel and radioactive waste, appropriate
policies and strategies are required. This publication clarifies
the differences between a policy and a strategy, and provides
principal advice to Member States on the typical composition,
mutual links and the process of compilation of such documents. It
also offers options for and indicates approaches to the management
of spent fuel and radioactive waste, thus enabling an effective
spent fuel and radioactive waste management infrastructure to be
developed.
Setting the pace for progress and innovation . . .
ADVANCES IN PHOTOCHEMISTRY
More than a simple survey of the current literature, Advances in
Photochemistry offers critical evaluations written by
internationally recognized experts. These pioneering scientists
offer unique and varied points of view of the existing data. Their
articles are challenging as well as provocative and are intended to
stimulate discussion, promote further research, and encourage new
developments in the field.
In this volume
Spectroscopy and Photochemistry of Polyatomic Alkaline
Earth-Containing Molecules
PETER F. BERNATH
Photochemically Induced Dynamic Nuclear Polarization
MARTIN GOEZ
Photophysics of Gaseous Aromatic Molecules: Excess Vibrational
Energy Dependence of Radiationless Processes
EDWARD C. LIM
Lanthanide Complexes of Encapsulating Ligands as Luminescent
Devices
NANDA SABBATINI, MASSIMO GUARDIGLI, AND ILSE MANET
Advances in the Measurement of Correlation in Photoproduct Motion
CHRISTOPHER G. MORGAN, MARCEL DRABBELS, AND ALEC M. WODTKE
Das Aachener Steinkohlengebiet zeichnet sich im Vergleich zu den
Steinkohlen lagerstiitten des niederrheinisch-westfiilischen
Gebietes durch eine groBe tek tonische und stratigraphische
Mannigfaltigkeit aus. Trotz jahrelanger Forschungen auf dies em
Gebiet ist es auch heute noch in der Praxis nicht moglich, eine
sichere Identifizierung der FlOze an Hand einfacher
Untersuchungsmethoden vorzuneh men. Eine gleichmiiBige Ausbildung
der Gesteinsschichten ist nur flir regional eng begrenzte Riiume zu
erwarten, und die Aufstellung eines fiir das gesamte Gebiet
giiltigen Normalprofils ist nicht moglich. Selbst die fiir einzelne
Gruben angefertig ten Schichtenprofile lassen nur anniiherungsweise
Schliisse auf die Ablagerungsfol ge in diesem beschriinkten Gebiet
zu. In der Hoffnung, weitere, bisher nicht beriicksichtigte,
charakteristische Merk male der Gesteine aufzuspiiren, die
moglicherweise zur Identifizierung der FlOze herangezogen werden
konnten, wurden die Untersuchungen der Radioaktivitiit der
Sedimente im Aachener Raum begonnen. In den letzten Jahren wurden
eine Reihe von Arbeiten, die sich mit Radioaktivitiits messungen
befassen, veroffentlicht. So beschrieb KOHL in seiner Monographie
iiber das Vorkommen von Uran ( 17], 1954) und anderen Aufsiitzen (
19], 1951) die Bemiihungen franzosicher Wissenschaftler urn die
Auffindung mariner Hori zonte mittels Radioaktivitiitsmessungen.
Marine Schichten weisen im Gebiet von Valenciennes eine bis zu
zehnfach hoheren Radiumgehalt als nichtmarine Sedi mente auf. Als
Grund fiir diese Erscheinungen werden sekundiire Absorptions
effekte von Uran an Tonmineralien bzw. die Ausfiillung von Radium
aus dem Meerwasser wiihrend der Sedimentation ( 18], 1951)
angenommen."
Photovoltaic systems enable the sun's energy to be converted
directly into electricity using semiconductor solar cells. The
ultimate goal of photovoltaic research and development is to reduce
the cost of solar power to reach or even become lower than the cost
of electricity generated from fossil and nuclear fuels. The power
conversion efficiency and the cost per unit area of the
phototvoltaic system are critical factors that determine the cost
of photovoltaic electricity. Until recently, the power conversion
efficiency of single-junction photovoltaic cells has been limited
to approximately 33% - the socalled Shockley-Queisser limit. This
book presents the latest developments in photovoltaics which seek
to either reach or surpass the Shockley-Queisser limit, and to
lower the cell cost per unit area. Progress toward this ultimate
goal is presented for the three generations of photovoltaic cells:
the 1st generation based on crystalline silicon semiconductors; the
2nd generation based on thin film silicon, compound semiconductors,
amorphous silicon, and various mesoscopic structures; and the 3rd
generation based on the unique properties of nanoscale materials,
new inorganic and organic photoconversion materials, highly
efficient multi-junction cells with low cost solar concentration,
and novel photovoltaic processes. The extent to which photovoltaic
materials and processes can meet the expectations of efficient and
cost effective solar energy conversion to electricity is discussed.
Written by an international team of expert contributors, and with
researchers in academia, national research laboratories, and
industry in mind, this book is a comprehensive guide to recent
progress in photovoltaics and essential for any library or
laboratory in the field.
This publication presents a review of technical solutions providing
both corrective actions and preventive measures to reduce the
ingress of radon indoors. A description of methods, design and
implementation of measures to reduce ingress of radon into
buildings, and of the materials and equipment used in these
solutions are included. The publication also presents methods for
measuring gamma radiation from radionuclides in building and
construction materials and for methods of reducing exposure due to
this gamma radiation. Aimed primarily at building and construction
professionals designing and installing radon preventive and
mitigation measures, this publication will also be a useful
resource for national authorities responsible for the development
of national building codes and implementation of national radon
action plans.
Dieser Buchtitel ist Teil des Digitalisierungsprojekts Springer
Book Archives mit Publikationen, die seit den Anfangen des Verlags
von 1842 erschienen sind. Der Verlag stellt mit diesem Archiv
Quellen fur die historische wie auch die disziplingeschichtliche
Forschung zur Verfugung, die jeweils im historischen Kontext
betrachtet werden mussen. Dieser Titel erschien in der Zeit vor
1945 und wird daher in seiner zeittypischen politisch-ideologischen
Ausrichtung vom Verlag nicht beworben.
3 der Spannung durchdringender, harter werden, ist also ebenfalls
eine Folge der Quantengleichung (vgI. ds. Handb., 2. Auf I., Bd.
XXIII/2, Kap. 2). Der lichtelektrische Effekt im Rontgengebiet, d.
h. die Auslosung sekundarer Elektronen durch monochromatische
Rontgenstrahlen, ist bisher noch nicht zur genauen Bestimmung von h
verwertet worden. Zwar ist die beim lichtelektrischen Effekt im
optischen Gebiet wesentliche "Austrittsarbeit" P von wenigen Volt
gegeniiber der nach vielen tausend Volt zahlenden Geschwindigkeit
der Elek tronen, die die Rontgenstrahlen erzeugen, nur eine
unbedeutende Korrektions groBe; dafiir tritt aber die Ablosearbeit
der fest ans Atom gebundenen, inneren Atomelektronen in
Wirksamkeit, die von ahnlicher GroBe wie die Quanten energie h. y
der aus16senden Rontgenstrahlen ist. Die groBte Intensitat der
sekundaren Elektronen besitzen gerade die festgebundenen
Elektronen, fiir deren Abtrennung die wirksame Quantenenergie eben
hinreicht; zugleich treten aber auch Elektronen aus dem bestrahlten
Korper aus, die aus anderen Energie stufen des Atoms stammen, und
es ist bisher noch nicht gelungen, die Geschwindig keit der
entstehenden, verschieden schnellen Elektronen so genau zu messen,
daB die hieraus abgeleitete h-Bestimmung an die Genauigkeit der
anderen Me 1 thoden heranreichte Auch die ElektronenstoBmethode ist
im Rontgengebiet prinzipiell anwendbar. Es ist niimlich, ahnlich
wie im optischen Gebiet, eine durch die Quantengleichung scharf
bestimmte Geschwindigkeit der Elektronen erforderlich, urn die
Rontgen spektrallinien zu erzeugen, allerdings entstehen alle
Linien einer "Serie" (z. B. der K-Serie) auf einmal, wenn die
kiirzestwellige Linie dieser Serie erregt wird."
Das vorliegende Buch ist als Fortsetzung der "Probleme der
Zellteilung" gedacht, deren Inhalt daher als bekannt vorausgesetzt
wird. Ich habe jede Wiederholung des im ersten Bande Ent haltenen
vermieden und fuhre den Leser sofort in medias res ein. Es wird
sicher auffallen, dass im Gegensatz zum ersten Bande das Problem
der Zellteilung als solches ganz in den Hintergrund tritt und gar
nicht diskutiert wird. Es zeigte sich namlich in den letzten Jahren
immer mehr, dass hier ein weiteres Vordringen auf dem von uns
eingeschlagenen Wege eine gewaltige Vorarbeit auf anderen Gebieten
der mitogenetischen Strahlungsforschung voraussetzte, die uns in
den verflossenen Jahren vollstandig in Anspruch nahm, aber jetzt zu
einem gewissen, partiellen Ab schlusse gelangte, da die
wesentlichen Vorbedingungen des Zu standekommens des
mitogenetischen Effektes gegenwartig als einigermassen geklart
gelten durften. Das Buch ist im ubrigen in viel geringerem Masse
eine Zu sammenfassung des bisher Veroffentlichten, als eine
abgerundete Darstellung und theoretische Verwertung einer sehr
grossen Anzahl neuerer Ergebnisse, sowohl aus unserem Laboratorium,
wie auch von fremden Forschern, die mir ihre Ergebnisse in
freundlicher Weise zur Verfugung stellten. Die ganze Lehre von der
mito genetischen Strahlung erhalt nunmehr ein in manchen Zugen
vollig neues Gewand, welches hoffentlich zur Klarung der noch
bestehenden Missverstandnisse fuhren wird. Denn anders als mit
diesem Namen kann ich die vereinzelten skeptischen Ausserungen der
allerletzten Zeit nicht bezeichnen."
In vorliegender Arbeit werden die Resultate von Untersuchungen zum
ersten mal ausfiihrlich niedergelegt, die wir in den letzten;P 2
Jahren ausgeflihrt haben, angcregt durch die Veroffentlichungen A.
G u I' \y its c h S libel' die von ihm entdeckte biologische
Strahlung und ihrem Einflu13 auf die Zellteilung. ""il' z()gerten
lange mit diesel' Verciffentlichung, weil sich das Bilel des hiel'
behandeIten Gegcnstandes, wie es sich uns anf Grund immer neuer
Versuchsreihcn darbot, standig wechseIte. Dies hat sich auch hcute
noch nicht geandert. Es liegt uns ferne unserc heutigen
Anschanungen als endgliltig anzusehen. 'Vir hoffen abel', da13
unsere Versuehsergeb nisse sich als gesichert erweisen werden,
nnabhangig von unserer Deutung. 'Vir gebcn anch nnsere Anschauungen
wiedel', einmal, weil sic ein einigermaBen geschlos senes Bild der
Erscheinungen ergeben, vor aHem abel', wei I sie uns die Richtung
unserer Versuche vorgeschricben haben. 'Vir nehmen an, da13 unsere
Deutung sich aueh Hir weitere Untersuehungen als fruchtbar erweisen
wird. Ganz gesichert scheint nns dagegen auf jeden Fall die
Existenz del' Strahlen, be wiesen durch das Vorhandensein cineI'
unzweifelhaft feststellbaren 'Yirkung. Nun ist gerade die Existenz
dieser 'Virkung in del' letzten Zeit Gegenstand einer heftigen
Diskussion geworden, und diese Diskussion veranla13t uns, mit
unseren Ergebnissen in aller Ausfiihrlichkeit hervorzutreten. Das
ganze Problem, so eng es auch mit den Grundfragen del' Biologie und
mit allen ihren Theorien verlmupft ist, bleibt letzten Endes ein
rein expel'imenteHes. ur die Ergebnisse del' Experimente und ihl'e
moglichst vorul'teilsfl'eie Deutung konnen uns weiterbringen."
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