A stone carving from the 14th century B.C. records that the Egyptian pharaoh Akhenaten (born Amenhoteph IV) and his wife, Nefertiti, recognized the importance of sunlight to life. In fact, Akhenaten initiated a monotheistic religion, with Aton, the sun, as God. One of his daughters be came the wife of King Tut Ankamon, the spelling of whose name indicates a return to the old religion and an eclipse of interest in photobiology among the pharaohs. A renewal of interest in photobiology in modern times was climaxed in 1928 by the establishment of an international organization for photobiology under the title Comite International de la Lumiere (C.I.L.). Its present title, Comite International de Photobiologie (C.I.P.), was adopted at a meeting in Paris in 1951. The first of a series of international congresses on photobiology was held in 1954 and probably represents the beginning of modern day photobiology. Medical men were prominent in the activities of the old C.I.L., for the importance of natural sunlight in human health and disease was obvious though not well understood. The bringing together of physicians with physicists, chemists, and biologists from the pure and applied branches of their subjects was the aim of the older C.I.L. and continues to the present day through the C.I.P."

Preface by Sir Harold W. Kroto, FRS Although the discovery of C60 is now almost 15 years old and the extraction occurred 60 nearly ten years ago it is amazing that the range of spin-off research still seems to expand without limits. The birth of the Fullerenes has spawned fascinating research programmes in almost every area of chemistry and physics and this monograph explores a particularly interesting and important area - the behaviour of these pure carbon cages in the presence of high-energy radiation. The C molecules must also be in the space 60 between the stars (albeit in quantities too small to detect at this time) as the conditions in the atmospheres of some carbon stars appear to be almost identical to the plasmas generated in the Kratschmer-Huffman system for making C60. The conditions in space 60 are very varied as it is pervaded by a plethora of high-energy particles (photons, cosmic rays, etc.) and the chapters in this book discuss, among other things, the response of C60 and various derivatives to probing by a range of high-energy particles. Various fullerenes and fullerene salts have been examined by positron annihilation techniques, revealing details of their electronic and structural properties as well as phase transition behaviour. Muons have been implanted to enable mSR techniques to probe with high sensitivity the endohedral electronic structures of fullerenes including those in superconducting systems. Mossbauer spectroscopy can give valuable information about the interactions in certain types of organometallic complexes and in particular it can reveal the degree of charge transfer in endohedral species. Nuclear irradiation/radiochemical analytical techniques have been applied resulting in information ranging widely from the stability of the fullerene cage containing endohedral metal atoms in various oxidation states to pharmaceutical studies of the distribution of fullerenes in the internal organs of animals. Time resolved pulsed radio lysis provides information at high sensitivity enabling micromolar concentrations to be probed e.g. C60 in water in which it is almost insoluble! Redox and rate constant measurements have given useful information on photolytically generated radical ion pairs involving a variety of fullerenes. Interesting accounts of observations involving the production of rare gas endohedral species by nuclear recoil have revealed information about the recoil mechanism. From the first moment of its discovery the unique cage structure of C60 initiated thoughts about the interesting possibility of encapsulation of atoms and molecules. One possibility that immediately suggested itself was the isolation of chemically toxic radionuclides by encapsulation in the (supposedly chemically innocuous) cage for pharmaceutical purposes. The possibility of creating cages carrying a radioactive atom inside the cage and moieties outside with molecular recognition capabilities is a most exciting prospect and discussion is included of some important first steps aimed at achieving this fascinating breakthrough. Another problem dealt with in this monograph is the effect of elemental impurities which has, as our studies progress, become more and more a matter of concern and interest. Impurities can have important effects on the observed physical and chemical behaviour of fullerenes, especially when very sensitive probe techniques are applied. This valuable book reviews some detailed studies of fundamental properties of fullerenes, which are leading to a deeper understanding of their behaviour in the presence of high energy radiation. The information obtained already and that which will be garnered in future studies of the kind described here is an absolutely necessary prerequisite for success in applications.

Nuclear Analytical Methods in the Life Sciences 1994 is a forefront survey of key presentations from the 1993 International Conference on Nuclear Analytical Methods in the Life Sciences. Sponsored by the International Atomic Energy Agency (IAEA), this useful volume covers the spectrum of multidisciplinary research on both the methodological aspects and the development of nuclear analytical methods and their applications in the life sciences.
The book is divided into six sections covering related material. These sections are: Methodology of Nuclear Analytical Methods; Environmental Applications; Biomedical Applications; Analysis of Biological Samples; Quality Assurance and Comparison with Other Methods; and a section dealing with miscellaneous issues, such as programs offered by the IAEA."

This work is a comprehensive and much-needed tool for the teaching and practice of radioanalytical chemistry. It encompasses a concise theoretical background, laboratory work, and data interpretation. It also contains chapters on the most current and visible applications of radioanalytical techniques. Its emphasis on the practical aspects on laboratory setup and operation make it a valuable tool for training professionals and students alike.

The handling of actinides and actinide-based materials provides significant technological challenges due to the toxicity and radioactivity associated with these materials. These challenges are particularly apparent in the nuclear power industry. Under normal operation, a reactor can produce a significant amount of spent fuel requiring subsequent containment for geologic times, and under accident conditions it can release lethal doses of radioactive material to the environment. Inevitably, radioactive material will enter the environment, necessitating as complete an understanding as possible of its behavior. An understanding of the interaction between actinides and the environment must be based on a knowledge of their basic physical and chemical properties. To date, although there is general agreement on the principles for waste disposal, no facility has been built for the long term disposal of high level radioactive waste from either normal reactor operations or from accidental catastrophes. This makes it most important for the scientific and technical community to develop the necessary cross-disciplinary understanding that will help us implement safe and secure waste management, accident remediation and accident prevention systems.

Artificial sources of radiation are commonly used in the manufacturing and service industries, research institutions and universities, and the nuclear power industry. As a result, workers can be exposed to artificial sources of radiation. There are also a significant number of workers, such as underground miners and aircrew, who are exposed to naturally occurring sources of radiation. This publication, prepared in collaboration with the International Labour Organization, and with reference to IAEA Safety Standards Series No. GSR Part 3 provides guidance for individuals and organizations on the assessment of prospective cancer risks due to occupational exposure to ionizing radiation for prevention purposes. It describes cancer risk assessment theory, models and methodologies, and offers practical examples of carrying out these assessments.

A survey of recent research in the fields of condensed matter physics and chemistry based on novel NMR and ESR techniques. Applications include quantum computing, metal nanoparticles, low dimensional magnets, fullerenes as atomic cages, superconductors, porous media, and laser assisted studies. The book is dedicated to Professor Robert Blinc, on the occasion of his seventieth birthday, in appreciation of his remarkable scientific accomplishments in the NMR of condensed matter.

Written by one of the founders of gas-chromotagraphic methods in radiochemistry, this book attempts a genuine first. It is a discussion of the state of art of heavy element inorganic radiochemistry. It aims to be a real addition to the understanding of this crucial topic. Written as much for newcomers to the field as experts, its goal is also to stimulate wider use of the advantageous gas phase techniques for common elements.

ADRIANO DE MAIO IReR President This publication originated from the workshop on "Control and risk prevention of dangerous materials and crisis management" that took place in Sofia, Bulgaria, in March 2009. The basic idea is that international scientific cooperation can effectively contribute to security, stability and solidarity among nations, through increased collaboration, networking and capacity-building and supporting democratic growth and economic development in Partner Countries. We are all facing new needs and threats, deriving from a world changing constantly its social, political and economic dimension and, for this reason, the international dialogue through civil science represents a way forward to comm- ment to global common issues. In fact, the Lombardy Regional Institute for Research has developed some international activities aiming at establishing networks of scientists and experts in defined areas and subjects. Through one of these activities, the Institute entered in touch with the Science for Peace and Security Programme. In this framework, we decided to share the experience of Lombardy Region on transportation of dangerous materials (half of their total transport in Italy): research and studies in civil area conducted in Lombardy Region are considered the most innovative in Europe for the results obtained. Comparison with diverse international experiences is a great opportunity of implementing present results and applying them to different applications (from civil to anti-terrorism) and extending them to countries other than Italy.

With contributions from 24 international authorities, Synthetic Organic Photochemistry offers a leading-edge presentation of the most recent and in-demand applications of photochemical methodologies. Outlining a wide assortment of reaction types entailing cycloadditions, cyclizations, isomerizations, rearrangements, and other organic syntheses, this reference offers unmatched coverage of all reactions in the foreground of organic photochemistry and ties in critical considerations that overlap in modern photochemistry and organic chemistry, such as stereoselectivity. Select experimental procedures demonstrate the industrial and academic value of reactions presented in the text.

Atmospheric Chemistry provides readers with a basic knowledge of the chemistry of Earth's atmosphere, and an understanding of the role that chemical transformations play in this vital part of our environment. The composition of the 'natural' atmosphere (troposphere, stratosphere and mesosphere) is described in terms of the physical and chemical cycles that govern the behaviour of the major and the many minor species present, and of the atmospheric lifetimes of those species. An extension of these ideas leads to a discussion of the impacts of Man's activities on the atmosphere, and to an understanding of some of the most important environmental issues of our time. One thread of the book explains how living organisms alter the composition and pressures in the atmosphere, modify temperatures, and change the intensity and wavelength-distribution of light arriving from the Sun. Meanwhile, the living organisms on Earth have depended on these very same environmental conditions being satisfactory for the maintenance and evolution of life. There thus appear to be two-way interactions between life and the atmosphere. Man, just one species of living organism, has developed an unfortunate ability to interfere with the feedbacks that seem to have maintained the atmosphere to be supportive of surface life for more than 3.5 billion years. This book will help chemists to understand the background to the problems that arise from such interference. The structure of the book and the development of the subject deviate somewhat from those usually encountered. Important and recurring concepts are presented in outline first, before more detailed discussions of the atmospheric behaviour of specific chemical species. Examples of such themes are the sources and sinks of trace gases, and their budgets and lifetimes. That is, the emphasis is initially on the principles of the subject, with the finer points emerging at later points in the book, sometimes in several successive chapters. In this way, some of the core material gets repeated exposure, but in new ways and in new contexts. The book is written at a level that makes it accessible to undergraduate chemists, and in a manner that should make it interesting to them. However, the material presented forms a solid base for those who are extending their studies to a higher level, and it will also provide non-specialists with the background to an understanding of Man's several and varied threats to the atmosphere. Well-informed citizens can then better assess measures proposed to prevent or alleviate the potential damage, and policy makers more realistically formulate the necessary controls on a sound scientific foundation.

In this fascinating biography, Patricia Rife interprets both the life and times of Lise Meitner (1878 1968), providing a rich background of the scientific discoveries and social milieu that affected the research, events, personalities, and politics of 20th century quantum physics. Rife asks the central question of why, given the priority evidence of Meitner's role in the interpretation of nuclear fission, was she too not awarded the Nobel Prize?

The use of catalysts as a means of facilitating and expediting polymer synthesis has become an essential industrial tool over the past forty years. This book provides a comprehensive survey of the entire field of catalysis in polymer synthesis covering the majority of essential aspects from basic organic, organometallic and bio-chemistry to industrial production. Particular emphasis is placed on 'precision polymerization', where the catalyst plays a key role in the fabrication of innovative polymers. Precision polymerization enables the production of polymers with precisely controlled structures, molecular weight, distribution and stereochemistry, free from defects. New catalysis is now used in addition polymerization, polycondensation and polyadditions for various monomers of vinyl, diene, acetylene, hetero-multiple bond, ring-opening and enzyme-substrate types. By utilising precision polymerization, highly functional and high performance polymers for future demands will be created. Intended as a polymer synthesis text for advanced undergraduate and graduate courses, this book will also serve as a valuable reference source for polymer chemists researching catalytic functions with reaction mechanisms in academia and industry, stimulating the discovery of new catalysts and consequently, the design of innovative high performance materials.

This volume combines reviews on the latest advances in photochemical research with specific topical highlights in the field. Starting with periodical reports of the recent literature on organic and computational aspects including reports on computational photochemistry and chemiluminescence of biological and nanotechnological molecules, photochemistry of alkenes, dienes and polyenes, aromatic compounds and oxygen-containing functions. The final chapter of this section is a review of industrial application of photochemistry from 2014 to 2019. Coverage continues with highlighted topics, in the second part, from ruthenium-caged bioactive compounds, advances in logically and light induced systems, developments of metal-free photocatalysts, photoresponsive organophosphorus materials and applications of photo-fragmentation in synthesis, photo-click chemistry and azo-based molecular photoswitches. This volume will again include a section entitled 'SPR Lectures on Photochemistry', a collection of examples for academic readers to introduce a photochemistry topic and precious help for students in photochemistry. Providing critical analysis of the topics, this book is essential reading for anyone wanting to keep up to date with the literature on photochemistry and its applications. "A certain amount of energy destroys the same amount of CO2 according to the whether it is administered continuously or intermittently. In order to rationalize this result there are two possibilities, either the destruction of CO2 further occurred in the dark periods, which would lead to the same form of energy storing form, or in the illuminated period the reaction goes at twice the rate." O. Warburg, Biochem. Z., 1919, 100, 230-270.

This is a comprehensive account of the nature of the hazards presented by ionizing radiation and the methods of protection. It takes the reader through the general background of the subject, the underlying principles applied to the control of radiation hazards (including chapters on human physiology, the biological effects of radiation and radiation detection and measurement), before moving to specialized topics such as medical applications and waste disposal.;This edition has been revised and updated to reflect the significant changes that have occurred in this area in recent years. The most recent ICRP recommendations are included, the section on legislation has been expanded to emphasize the European and International requirements in addition to those of the UK, while the chapter on radiological emergencies has been rewritten to highlight international developments arising from the Chernobyl disaster.

In the last two decades it was demonstrated that, in addition to masses and charges, magnetic moments of nuclei are able to influence remarkably chemical reactions. This book presents the physical background (both theoretical and experimental) of the magnetic isotope effects in radical reactions in solutions. Special attention has been paid to the quantitative interpretation of the available experimental data. This book will be useful for physicists, chemists and biologists employing the isotope effect in their investigations as well as for those involved in isotope separation and isotope enrichment projects. Additionally, the magnetic isotope effect appears to be important in geochemistry and cosmochemistry. The book can be recommended for postgraduates and senior undergraduate students.

Traditionally, most synthetically developed materials are hardened by heating them to an elevated temperature, a process requiring large amounts of energy and space. Interest in photo cured materials using UV-light is growing due to simplifications in manufacturing and growing environmental concerns; it is expected photocuring could reduce electricity consumption by 90% compared to traditional curing. Photocured materials also reduce evaporation of volatile organic components, curing time and waste, thereby enhancing productivity and reducing work space. The materials technologies based on photocuring are gaining momentum, and this will be the first book to provide an in-depth focus on the subject. This book summarises the fundamentals required to understand the field, characterises the use of novel materials and the development of synthetic aspects, and discusses the future of the technology. The comprehensive review chapters are suitable for a broad readership from diverse backgrounds including chemistry, physics, materials science and engineering, medical science, pharmacy, biotechnology and biomedical engineering. Photocured Materials will be of interest to students, researchers, scientists, engineers and professors.

This topical book addresses the need for emerging economies in Central, Eastern and South-Eastern Europe to find a new, sustainable growth model that fosters continued convergence with the EU without leading to the build-up of new vulnerabilities.The expert contributions frame the discussion on balanced growth in Europe, deal with the legacy of the old growth model (such as managing disrupted capital flows and deleveraging), and provide insights from the growth strategies of Russia and Turkey as well as the adjustment process of successful small CESEE countries. They focus on providing a multi-disciplinary assessment, combining the views of policy-makers and academics with those of central and commercial bankers. This book will prove a thought-provoking read for academics, researchers and students in the fields of economics - particularly international economics - and finance, money and banking. Policy-makers and economists interested in European integration and emerging European economies will also find this book to be an invaluable resource. Contributors: A.F. Aysan, G. Bisagni, D. Bogov, M. Dabrowski, M. Ferrazzi, A. Filardo, M. Gachter, L. Gattini, M.H. Guler, A. Hansson, S. Honkapohja, R. Jela i , K. Knot, I. Korhonen, A. Krstevska, E. Liikanen, E. Nowotny, C. Orman, E. Plato, P. Pumberger, M. Randveer, D. Revoltella, A. Riedl, D. Ritzberger-Grunwald, K. Sonin, E. Tuomi, S. Verkaart

The biological action of radiation undoubtedly constitutes an issue of actual con cern, particularly after incidences like those in Harrisburg or Chernobyl. These considerations, however, were not the reason for writing this book although it is hoped that it will also be helpful in this respect. The interaction of radiation with biological systems is such an interesting research objective that to my mind no special justification is needed to pursue these problems. The combination of physics, chemistry and biology presents on one hand a fascinating challenge to the student, on the other, it may lead to insights which are not possible if the dif ferent subjects remain clearly separated. Special problems of radiation biology have quite often led to new approaches in physics (or vice versa), a recent example is "microdosimetry" (chapter 4). Biological radiation a9tion comprises all levels of biological organization. It starts with the absorption in essential atoms and molecules and ends with the development of cancer and genetic hazards to future generations. The structure of the book reflects this. Beginning with physical and chemical fundamentals, it then turns to a description of chemical and subcellular systems. Cellular effects form a large part since they are the basis for understanding all further responses. Reactions of the whole organism, concentrating on mammals and especially humans, are subsequently treated. The book concludes with a short discussion of problems in radiation protection and the application of radiation in medical therapy. These last points are necessarily short and somewhat superficial."

The project that finally led to this book, was originally started with Dr. Jean-Paul Desclaux. It is a pleasure to thank hirn for a fruitful collaboration stretching over more than a decade. While accepting the responsibility for any remaining errors and omissions, I wish to acknowledge in particular the comments by Teijo Aberg, Viktor Flambaum, Burkhard Fricke, Franz Mark and Arne Rosen. The Bibliography was compiled using a Fortran program, written for the DEC 20 at the University of Turku by Matti Hotokka, and adap ted to the University of Helsinki Burroughs 7800 by Dage Sundholm. Harriet Bjornstrom did most of the typing and Kathe Ramsay cross checked the text against the Bibliography. Readers, interested in obtaining a Wordstar-readable, IBM PC compatible diskette file (about 520 kb on a two-sided diskette) of the Bibliography should contact the author Helsinki, 20 August, 1986 Pekka Pyykko CONTENTS 1. Introduction ................................................. 1 Table 1.1. Managraphs and ather general references ........... 2 2. One-particle problems ........................................ 5 2.1. Special relativity and the ald quantum theary ........... 5 2.2. On the Klein-Gardon equation ............................ 5 2.3. The Dirac equation ...................................... 6 Table 2.l. The Dirac equation: interpretative studies, symmetry properties and non-relativistic limits ............ 7 Table 2.2. The Dirac equation: further transformations ...... 13 Table 2.3. The Dirac equation: solutions for hydrogen-like systems. . ........................................ 1 6 Table 2.4. The Dirac equations: solutions for various n- coulomb fields. . ................................. 21 Table 2.5. Relativistic virial theorems ..................... 26 3. Quantum electrodynamical effects ............................ 27 Table 3.1."

Drawing on the continued wealth of photochemical research, this volume combines reviews on the latest advances in the field with specific topical highlights. Starting with periodical reports of the recent literature on physical and inorganic aspects, light induced reactions in cryogenic matrices, properties of transition-metal compounds, time-resolved spectroscopy, the exploitation of solar energy and the molecules of colour. Coverage continues with highlighted topics, in the second part, from photoresponsive hydrogels, the tunable photoredox properties of organic dyes, light-driven asymmetric organocatalytic processes, dual gold-photoredox catalysis, the preparation and characterization of photosensitizers for triplet-triplet annihilation photon upconversion and the role of photochemistry on traditional synthetic processes. This volume will include for the first time a section entitled 'SPR Lectures on Photochemistry', providing examples for academic readers to introduce a photochemistry topic and precious help for students in photochemistry. Providing critical analysis of the topics, this book is essential reading for anyone wanting to keep up to date with the literature on photochemistry and its applications.

"Photochemistry of Organic Compounds: From Concepts to Practice" provides a hands-on guide demonstrating the underlying principles of photochemistry and, by reference to a range of organic reaction types, its effective use in the synthesis of new organic compounds and in various applications.

The book presents a complete and methodical approach to the topic, Working from basic principles, discussing key techniques and studies of reactive intermediates, and illustrating synthetic photochemical procedures.Incorporating special topics and case studies covering various applications of photochemistry in chemistry, environmental sciences, biochemistry, physics, medicine, and industry.Providing extensive references to the original literature and to review articles.Concluding with a chapter on retrosynthetic photochemistry, listing key reactions to aid the reader in designing their own synthetic pathways.

This book will be a valuable source of information and inspiration for postgraduates as well as professionals from a wide range of chemical and natural sciences.

The United Nations Scientific Committee on the Effects of Atomic Radiation (UNSCEAR) established by the General Assembly in 1955 assesses the levels and effects of exposure to ionizing radiation on human health and the environment. This is the third of four volumes of scientific annexes provide the supporting scientific deliberations for the UNSCEAR 2020/2021 report to the General Assembly. Annex C "Biological mechanisms relevant for the inference of cancer risks from low dose and low-dose rate radiation" synthesizes the current knowledge on biological mechanisms of radiation actions at low doses and low-dose-rates, and assesses the implications for understanding the processes of cancer development after exposure to ionizing radiation, and for dose-response relationships of radiation-induced cancers.

The world made new is a biography of one of the most original and widely significant, yet largely forgotten, British scientists. Frederick Soddy was born in 1877 and was one of the first generation of English atomic scientists, who stood out from his colleagues from the start. He worked with Rutherford on the initial discoveries about atomic disintegration, for which Rutherford received the Nobel Prize. Soddy himself received the Nobel Prize in 1921 for his research on isotopes. Soddy's worry about the responsibility of science and scientists to society began with his fear that the atomic energy he and Rutherford had discovered could be disastrous if suitable political controls were not enforced, and led to him abandoning scientific research. He lived to see his worst fears realized with the bombing of Hiroshima and Nagasaki. Soddy was also concerned with economics and ecology and was a pioneer in the field of energy conservation and environmental ethics. Throughout his life, Soddy was also committed to social reform. Frederick Soddy was a remarkable and talented man who was not recognized as such in his own life-time, largely because his ideas and attitudes did not fit in with the times in which he lived. However he has become more appreciated since his death, not only because his scientific work has gained its rightful recognition, but also because of the increased awareness today of the environment and the role of science in it.

This book highlights a comprehensive and detailed introduction to the fundamental principles related to nuclear engineering. As one of the most popular choices of future energy, nuclear energy is of increasing demand globally. Due to the complexity of nuclear engineering, its research and development as well as safe operation of its facility requires a wide scope of knowledge, ranging from basic disciplines such as mathematics, physics, chemistry, and thermodynamics to applied subjects such as reactor theory and radiation protection. The book covers all necessary knowledge in an illustrative and readable style, with a sufficient amount of examples and exercises. It is an easy-to-read textbook for graduate students in nuclear engineering and a valuable handbook for nuclear facility operators, maintenance personnel and technical staff.