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Books > Science & Mathematics > Chemistry > Physical chemistry > Nuclear chemistry, photochemistry & radiation
Written by Glenn T. Seaborg, Nobel Laureate and pre-eminent figure
in the field, with the assistance of Walter D. Loveland, it covers
all aspects of transuranium elements, including their discovery,
chemical properties, nuclear properties, nuclear synthesis
reactions, experimental techniques, natural occurrence, superheavy
elements, and predictions for the future. Published on the fiftieth
anniversary of the discovery of transuranium elements, it conveys
the essence of the ideas and distinctive blend of theory and
experiment that has marked their study.
With the resurgence of nuclear power around the world, and the
increasingly important role of hydrogen as a clean energy carrier,
the utilization of nuclear energy for large-scale hydrogen
production will have a key role in a sustainable energy future.
Co-generation of both electricity and hydrogen from nuclear plants
will become increasingly attractive. It enables load leveling
together with renewable energy and storage of electricity in the
form of hydrogen, when electricity prices and demand are lowest at
off-peak hours of nuclear plants, such as overnight. Hydrogen
Production from Nuclear Energy provides an overview of the latest
developments and methods of nuclear based hydrogen production,
including electrolysis and thermochemical cycles. Particular focus
is given to thermochemical water splitting by the copper-chlorine
and sulphur-based cycles. Cycle configurations, equipment design,
modeling and implementation issues are presented and discussed. The
book provides the reader with an overview of the key enabling
technologies towards the design and industrialization of hydrogen
plants that are co-located and linked with nuclear plants in the
future. The book includes illustrations of technology developments,
tables that summarize key features and results, overviews of recent
advances and new methods of nuclear hydrogen production. The latest
results from leading authorities in the fields will be presented,
including efficiencies, costs, equipment design, and modeling.
Super Light Water Reactors and Super Fast Reactors provides an
overview of the design and analysis of nuclear power reactors.
Readers will gain the understanding of the conceptual design
elements and specific analysis methods of supercritical-pressure
light water cooled reactors. Nuclear fuel, reactor core, plant
control, plant stand-up and stability are among the topics
discussed, in addition to safety system and safety analysis
parameters. Providing the fundamentals of reactor design criteria
and analysis, this volume is a useful reference to engineers,
industry professionals, and graduate students involved with nuclear
engineering and energy technology.
Unravelling the Mystery of the Atomic Nucleus is a history of
atomic and nuclear physics. It begins in 1896 with the discovery of
radioactivity, which leads to the discovery of the nucleus at the
center of the atom. It follows the experimental discoveries and the
theoretical developments up to the end of the Fifties. Unlike
previous books regarding on history of nuclear physics, this book
methodically describes how advances in technology enabled
physicists to probe the physical properties of nuclei as well as
how the physical laws which govern these microscopic systems were
progressively discovered. The reader will gain a clear
understanding of how theory is inextricably intertwined with the
progress of technology. Unravelling the Mystery of the Atomic
Nucleus will be of interest to physicists and to historians of
physics, as well as those interested development of science.
This book combines theoretical explanations of the reactions of
light and polymeric materials with development of light responsive
polymeric materials for various practical applications. Photo
associated reactions and light responsive materials have great
potential to improve existing industrial processes, including
capturing solar energy. This book presents a range of reactions and
materials with some of the most exciting current and future
applications.
This is the first book to cover actinide nano research. It is of
interest both for fundamental research into the chemistry and
physics of f-block elements as well as for applied researchers such
as those studying the long-term safety of nuclear waste disposal
and developing remediation strategies. The authors cover important
issues of the formation of actinide nano-particles, their
properties and structure, environmental behavior of colloids and
nanoparticles related to the safe disposal of nuclear wastes,
modeling and advanced methods of characterization at the
nano-scale.
As the title suggests, Isotope Effects in the Chemical, Geological
and Bio Sciences deals with differences in the properties of
isotopically substituted molecules, such as differences in the
chemical and physical properties of water and the heavy waters.
Since the various fields in which isotope effects are applied do
not only share fundamental principles but also experimental
techniques, this book includes a discussion of experimental
apparatus and experimental techniques. Isotope Effects in the
Chemical, Geological and Bio Sciences is an educational monograph
addressed to graduate students and others undertaking isotope
effect research. The fundamental principles needed to understand
isotope effects are presented in appropriate detail. While it is
true that these principles are more familiar to students of
physical chemistry and some background in physical chemistry is
recommended, the text provides enough detail to make the book an
asset to students in organic and biochemistry, and geochemistry.
THE EURATOM WORKING GROUP ON REACTOR DOSIMETRY AND THE ASTM-EURATOM
SYMPOSIA The Euratom Working Group on Reactor Dosimetry (EWGRD)
started around 1960 with members having been nominated by the
governments, from each European la boratory working in reactor
physics and technology. The goal was to exchange di rectly
experience and know-how in reactor dosimetry and related
programmes. A need for normalisation was felt in order to guarantee
that: the same nuclear data is used; measurements in different
laboratories give the same results (need for in tercalibration
experiments and standards); results are expressed such that a com
parison with results from other laboratories is possible. In
sub-groups, specific arguments were discussed resulting in final
recommenda tions. These final recommendations were then discussed
in a plenary meeting and accepted as a recommendation for European
usage. Several of these recommenda tions were published, e.g.
radiation damage dosimetry guidebooks, and a nuclear data
guidebook. Also a programme, executed by the BCMN GEEL, for the
produc tion and selling of Reference Materials for Neutron
Dosimetry is sponsored by the EWGRD. Workshops in the field of
radiation damage and on the pressure vessel steels programme in
Europe were successfully organised. The group works in close
contact with ASTM (American Society for Testing of Mate rials).
Altogether seven symposia were jointly organized, and held,
alternatively in Europe and USA. The next symposium, the eighth,
will be organized by ASTM in 1993 in the USA.
Personalized medicine employing patient-based tailor-made
therapeutic drugs is taking over treatment paradigms in a variety
of ?elds in oncology and the central nervous system. The success of
such therapies is mainly dependent on ef?cacious therapeutic drugs
and a selective imaging probe for identi?cation of potential
responders as well as therapy monitoring for an early bene?t
assessment. Molecular imaging (MI) is based on the selective and
speci?c interaction of a molecular probe with a biological target
which is visualized through nuclear, magnetic resonance, near
infrared or other methods. Therefore it is the method of choice for
patient selection and therapy monitoring as well as for speci?c e-
point monitoring in modern drug development. PET (positron emitting
tomography), a nuclear medical imaging modality, is ideally suited
to produce three-dimensional images of various targets or
processes. The rapidly increasing demand for highly selective
probes for MI strongly pushes the development of new PET tracers
and PET chemistry. 'PET chemistry' can be de?ned as the study of
positron-emitting compounds regarding their synthesis, structure,
composition, reactivity, nuclear properties and processes and their
properties in natural and - natural environments. In practice PET
chemistry is strongly in?uenced by the unique properties of the
radioisotopes used (e. g. , half-life, che- cal reactivity, etc. )
and integrates scienti?c aspects of nuclear-, organic-, inorganic-
and biochemistry.
How did life begin on the Earth? The units of life are cells, which
can be defined as bounded systems of molecules that capture energy
and nutrients from the environment -- systems that expand,
reproduce, and evolve over time, often into more complex systems.
This book is the proceedings of a unique meeting, sponsored by NATO
and held in Maratea, Italy, that brought together for the first
time an international group of investigators who share an interest
in how molecules self-assemble into supramolecular structures, and
how those structures may have contributed to the origin of life.
The book is written at a moderately technical level, appropriate
for use by researchers and by students in upper-level undergraduate
and graduate courses in biochemistry and molecular biology. The
overall interest of its subject matter provides an excellent
introduction for students who wish to understand how the
foundational knowledge of chemistry and physics can be applied to
one of the most fundamental questions now facing the scientific
community. The editors are pioneers in defining what we mean by the
living state, particularly the manner in which simple molecular
systems can assume complex associations and functions, including
the ability to reproduce. Each chapter of the book presents an
up-to-date report of highly significant research. Two of the
authors received medals from the National Academy of Science USA in
1994, and other research reported in the book has been featured in
internationally recognized journals such Scientific American, Time,
and Discover.
The 1982 summer school on nuclear physics, organized by the Nuclear
Physics Division of the Netherlands' Physical Society, was the
fifth in a series that started in 1963. The number of students
attending has always been about one hundred, coming from about
thirty countries. The theme of this year's school was symmetry in
nuclear physics. This book covers the material presented by the
enthusi astic speakers, who were invited to lecture on this
subject. We think they have succeeded in presenting us with clear
and thorough introductory talks at graduate or higher level. The
time schedule of the school and the location allowed the
participants to make many informal contacts during many social
activities, ranging from billiards to surf board sailing. We hope
and expect that the combination of a relaxed atmosphere during part
of the time and hard work during most of the time, has furthered
the interest in, and understanding of, nuclear physics. The
organization of the summer school was made possible by substantial
support from the Scientific Affairs Division of the North Atlantic
Treaty Organization, the Netherlands' Ministry of Education and
Science, the Foundation Physica and the Nether lands' Physical
Society."
The present volume in our annual review series reviews a wide range
of developments, giving a broad interpretation to the "technology"
of our title. Starting at the beginning, Science, we have the
review of basic nuclear physics data of Walker and Weaver for
reactor kinetics, particularly, there fore, delayed neutron data.
In the search for better and better accuracy, it is being realized
that this involves the closest scrutiny of fundamental data, given
to us here from the Birmingham school. Associated with this review
of data is the review from Italy by Professor Pacilio and his co
workers of the theory of reactor kinetics in the stochastic form,
and a valuable compilation of the theory underlying a wide range of
practical techniques. Tending more to technology come the papers by
Jervis, reviewing the application of digital computers to the
control of large nuclear power stations as developed in both the
united Kingdom and Canada, Pickman's review of the design of fuels
for heavy water reactors, and the account by Ishi kawa and Inabe of
the new Japanese Research Reactor Program, itself initially
directed largely to fuel element studies. The balance of the volume
is made up of more philoso phical contributions to the
practicalities of nuclear power."
Dr J. Landi Dessy, Director of the Astronomical Observatory,
Cordoba, Argentina, invited the International Astronomical Union to
hold a Symposium in Cordoba in connection with the celebration of
the Centennial of the Cordoba Observatory; the date of foundation
is October 24, 1871. He proposed that the Symposium should deal
with Spectral Classification and Multicolour Photometry as seven
years had elapsed since the Symposium No. 24 in Saltsj6baden, and
much development had occurred in the field. The invitation and the
proposal were accepted by the IAU, and the Symposium was held in
Villa Carlos Paz, near Cordoba, between October 18 and October 24,
1971. It was attended by about 50 scientists representing
Argentina, Canada, Chile, Den mark, France, Germany, Italy, Mexico,
Sweden, Switzerland, U.K., U.S.A., Vatican City State and
Venezuela. The Symposium was divided into four sessions: 1.
Classification of slit spectra, 2. Classification of
objective-prism spectra, 3. Photometric classification, 4.
Catalogues and documentation. It was decided not to include
problems of calibration of absolute magnitudes and temperatures of
stars but to refer this to a separate symposium. The contents of
the present volume follow closely the programmes of the individual
sessions of the Symposium. All the participants at the Symposium
appreciated the excellent hospitality of their Argentinian hosts
and the efficient help given by the staff ofthe Cordoba
Observatory."
This book attempts to build a bridge between two sciences:
chemistry and electronics. The inside of the black boxes the
nuclear chemist uses daily is explained in simple electronic terms.
Knowledge of the inside not only satisfies curiosity but helps one
"get the most out of the available equipment." Likewise, this book
tries to give sufficient understanding for not "over buying," that
is to say, for buying the equipment which just serves the purpose,
instead of buying the best so at least it will serve the purpose.
The first three chapters give a concise understanding of what the
area of applied nuclear chemistry is concerned with and what kind
of equipment is generally used. Chapter 1 gives a theoretical
background, while Chapter 3 deals with the practical
implementations. Thus, these chapters provide the background to
determine what one can expect from the experiments. The remainder
of the book is devoted to the practical instrumentation of the
experiments. Each chapter deals with specific types of instruments
and devices, discusses briefly the electronics involved, considers
the limitations, and investigates how and to what extent they can
be circumvented. The advantage of having different contributors,
each with his own practical experience, shows clearly in this
latter aspect. Detailed practical knowledge and experience can be
explained best by the person who has long been con cerned with the
subject theoretically and practically."
Significant amounts of liquid and solid radioactive waste have been
generated in Russia during the production of nuclear weapons, and
there is an urgent need to find suitable ways to manage these
wastes in a way that protects both the current population and
future generations. This book contains contributions from pure and
applied scientists and other representatives from Europe, North
America, and Russia, who are, or have been, actively involved in
the field of radioactive waste management and disposal. First-hand
experience of specific problems associated with defence-related
wastes in the USA and the Russian Federation is presented, and
current plans are described for the disposal of solid wastes
arising from civilian nuclear power production programmes in other
countries, including Belgium, Bulgaria, Canada, Germany and the UK.
The book provides a good insight into ongoing research at local and
national level within Russia, devoted to the safe disposal of
defence-related radioactive waste. It also demonstrates how
existing expertise and technology from civilian nuclear waste
management programmes can be applied to solving the problems
created by nuclear defence programmes. Contributions address
methods of immobilisation, site selection methodology, site
characterisation techniques and data interpretation, the key
elements of safety/performance assessments of planned deep
(geological) repositories for radioactive waste, and radionuclide
transport modelling. Concerns associated with certain specific
nuclear waste disposal concepts and repository sites are also
presented.
Prompt gamma activation analysis (PGAA) is a unique,
non-destructive nuclear analytical method with multi-element
capabilities. It is most effective if intense neutron beams
(especially cold beams) of nuclear reactors are used to induce the
prompt gamma radiation. Based largely on the authors' pioneering
research in cold neutron PGAA, the handbook describes the
methodology in self-contained manner and reviews recent
applications. The library of prompt gamma ray data and spectra for
all natural elements is a unique aid to the practitioner. The level
is understandable by a broad audience, which facilitates teaching
and training. The Handbook of Prompt Gamma Activation Analysis is a
comprehensive handbook written for those practising the method,
wanting to implement it at a reactor facility, or just looking for
a powerful non-destructive method of element analysis. The book is
also useful for nuclear physics, chemistry and engineering
scientists, scholars and graduate students interested in
neutron-induced gamma ray spectroscopy and nuclear analytical
methods.
After the success of the previous summer schools organized by the
Nuclear Physics Division of the Netherlands' Physical Society in
1975 and 1977, we thought it worthwhile to continue this tradition.
The immediate very positive reactions received from all invited
speakers encouraged us to proceed with the orgaization. Although
the number of students had to be restricted to about one hundred,
the international character of the School was evident from about
thirty nationalities which were represented. The material contained
in this book covers the talks given by all speakers invited to
lecture on the subject of nuclear structure research. These
proceedings should therefore serve as an excellent introduction to
many topics of current interest in this exciting field. We hope
that the lectures and discussions as well as the many informal
contacts made during the various social activities will greatly
stimulate interest in nuclear structure investigations among all
the participants. The organization of the summer school has been
made possible by substantial support given by the Scientific
Affairs Division of the North Atlantic Treaty Organization, the
Netherlands' Ministry of Education and Science and the Netherlands'
Physical Society. The invaluable help of the "Bureau Congressen" of
the Ministry of Education and Science and the friendly assistance
of the manage ment of the College of Agriculture in Dronten
contributed greatly to the pleasant atmosphere during the summer
school."
The increased demand on fossil fuels for energy production has
resulted in expanded research and development efforts on direct use
of fossil fuels and conversion of fossil fuels into synthetic
fuels. These efforts have focused on the efficiency of the energy
production and/or conversion processes, and of the emission control
technology, as well as delineation of the health and environmental
impacts of those processes and their by-products. A key ingredient
of these studies is the analytical capability necessary to identify
and quan- tify those chemicals of interest in the process and
by-produce streams from coal combustion, oil shale retorting,
petroleum refin- ing, coal l1quifaction and gasification. These
capabilities are needed to analyze a formidable range of materials
including liquids, solids, gases and aerosols containing large
numbers of criteria and pollutants including potentially hazardous
polynuclear aromatic hy- drocarbons, organo-sulfur and
organo-nitrogen species, trace elements and heavy metals, among
others. Taking notice of these developments we sought to provide a
forum to discuss the latest information on new and novel applica-
tions of a subset of those necessary analytical capabilities,
namely atomic and nuclear techniques. Consequently, we organized
the con- ference on Atomic and Nuclear Methods in Fossil Fuel
Energy Research, which was held in Mayaguez, Puerto Rico from
December 1 to December 4, 1980.
Stability is one of the most important performances required for
silver halide photographic materials. In 1935, Dr. E. 1. Birr
introduced the concept of the stabilization ofphotographic
emulsions for the first time by inventing a most effective
stabilizer, 4-oxo-6-methyl-l,3,3a,7-tetraazaindene (TAl). Dr.
Birr's monograph Stabilization ofPhotographic Silver Halide
Emulsions was published in 1974,and accepted as a reliable
reference book by many photographic scientists and engineers. Since
then, silver halide photographic materials have been greatly
improved and expanded through active and continual development of
various kinds of technologies. Especially, extensive efforts have
been made to develop photographic materials with high sensitivity
and rapid processing, which rely upon the stability ofphotographic
emulsions under various conditions. Thus, the concept and
technologies of stabilization ofphotographic silver halide
materials have been expanded so extensively that many photographic
scientists and engineers eagerly want a reliable, new reference
book on the stabilization of photographic emulsions. Dr. Gunther
Fischer is one of the most experienced and eminent scientists and
engineers in the field of the stabilization of photographic
materials with expanded concept. He has been involved in research
on the stabilization of pho tographic emulsions since 1964 when he
joined the Technical Scientific Laboratory in the Research and
Development Department of the Photo Film Company Agfa Wolfen
formerly headed by Dr. Birr, whom he succeeded in that position. I
was deeply impressed by his fruitful and elaborate achievements in
these fields.
Microdosimetry and Its Applications is an advanced textbook
presenting the fundamental concepts and numerical aspects of the
absorption of energy by matter exposed to ionizing radiation. It is
the only comprehensive work on the subject that can be considered
definitive. It provides a deeper understanding of the initial phase
of the interaction of ionizing radiation with matter, especially
biological matter, and its consequences.
The papers included in this volume were presented at the symposium
on "Americium and Curium Chemistry and Technology" at the
International Chemical Congress of Pacific Basin Societies in
Honolulu, Hawaii, December 16-21, 1984. This symposium commemorated
forty years of research on americium and curium. Accordingly, the
papers included in this volume begin with historical perspectives
on the discovery of americium and curium and the early
characterization of their chemical properties, and then cover a
wide range of subjects, such as thermodynamic properties,
electronic structure, nuclear reactions, analytic chemistry, high
pressure phase transitions, and technological aspects. Thus, this
volume is a review of the chemistry of americium and curium, and
provides a perspective on the current research on these elements
forty years after their discovery. The editors would like to thank
the participants in this symposium for their contributions. It is a
pleasure to acknowledge the assistance of Ms. Barbara Moriguchi in
handling the administrative aspects of the symposium and of the
production of this volume. April 2, 1985 Norman M. Edelstein
Materials and Molecular Research Division Lawrence Berkeley
Laboratory University of California Berkeley, California 94720,
U.S.A. James D. Navratil Rockwell International Rocky Flats Plant
P.O. Box 464 Golden, Colorado 80402-0464, U.S.A. Wallace W. Schulz
Rockwell Hanford P.O. Box 800 Richland, Washington 99352, U.S.A.
Risk assessment has come to assume acute importance in the former
Soviet Union since money is so scarce, yet the needs for cleanup
are so huge. Other factors contribute to this situation, too: New
leaders are still emerging, and governmental structures are still
evolving. This creates a particular difficulty for
environmentalists who attempt to become involved in the risk
assessment process. New information continues to surface on the
fallout from Chernobyl and its consequences for human health.
Scientists are still debating the effects of low doses of radiation
delivered over a long period of time. This type of contamination is
especially prevalent in the Russian North, for example, as a result
of the dumping of nuclear submarine reactors into the Kara and
Barents Seas. This book examines the complexities of risk
assessment in the FSU at this unique time in history.
A stone carving from the 14th century B.C. records that the
Egyptian pharaoh Akhenaten (born Amenhoteph IV) and his wife,
Nefertiti, recognized the importance of sunlight to life. In fact,
Akhenaten initiated a monotheistic religion, with Aton, the sun, as
God. One of his daughters be came the wife of King Tut Ankamon, the
spelling of whose name indicates a return to the old religion and
an eclipse of interest in photobiology among the pharaohs. A
renewal of interest in photobiology in modern times was climaxed in
1928 by the establishment of an international organization for
photobiology under the title Comite International de la Lumiere
(C.I.L.). Its present title, Comite International de Photobiologie
(C.I.P.), was adopted at a meeting in Paris in 1951. The first of a
series of international congresses on photobiology was held in 1954
and probably represents the beginning of modern day photobiology.
Medical men were prominent in the activities of the old C.I.L., for
the importance of natural sunlight in human health and disease was
obvious though not well understood. The bringing together of
physicians with physicists, chemists, and biologists from the pure
and applied branches of their subjects was the aim of the older
C.I.L. and continues to the present day through the C.I.P."
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