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Books > Science & Mathematics > Chemistry > Physical chemistry > Nuclear chemistry, photochemistry & radiation
An introductory text on radiation heat transfer for undergraduate and postgraduate students with no prior knowledge of the subject. The text introduces the physical principles of radiation heat transfer and develops methods for the analysis of thermal radiation in a variety of engineering applications.
This book is designed to serve as a textbook for core courses offered to postgraduate students enrolled in chemistry. This book can also be used as a core or supplementary text for nuclear chemistry courses offered to students of chemical engineering. The book covers various topics of nuclear chemistry like Shell model, fission/fusion reaction, natural radioactive equilibrium series, nuclear reactions carried by various types of accelerators. In addition, it describes the law of decay of radioactivity, type of decay, and interaction of radiation with matter. It explains the difference between ionization counter, scintillation counter and solid state detector. This book also consists of end-of-book problems to help readers aid self-learning. The detailed coverage and pedagogical tools make this an ideal textbook for postgraduate students and researchers enrolled in various chemistry and engineering courses. This book will also be beneficial for industry professionals in the allied fields.
The development of nuclear weapons during the Manhattan Project is one of the most significant scientific events of the twentieth century. This revised and updated 4th edition explores the challenges that faced the scientists and engineers of the Manhattan Project. It gives a clear introduction to fission weapons at the level of an upper-year undergraduate physics student by examining the details of nuclear reactions, their energy release, analytic and numerical models of the fission process, how critical masses can be estimated, how fissile materials are produced, and what factors complicate bomb design. An extensive list of references and a number of exercises for self-study are included. Revisions to this fourth edition include many upgrades and new sections. Improvements are made to, among other things, the analysis of the physics of the fission barrier, the time-dependent simulation of the explosion of a nuclear weapon, and the discussion of tamped bomb cores. New sections cover, for example, composite bomb cores, approximate methods for various of the calculations presented, and the physics of the polonium-beryllium "neutron initiators" used to trigger the bombs. The author delivers in this book an unparalleled, clear and comprehensive treatment of the physics behind the Manhattan project.
Photobiology integrates a wide variety of scientific disciplines.
As more people become aware of the many ways light interacts with
chemical and biological systems, the need for a concise treatment
of photobiology has become more critical. Kohen "et al." Have
written just such a book, intended both as a textbook and as a
reference.
This textbook, intended for advanced undergraduate and graduate students, is an introduction to the physical and mathematical principles used in clinical medical imaging. The first two chapters introduce basic concepts and useful terms used in medical imaging and the tools implemented in image reconstruction, while the following chapters cover an array of topics such as physics of x-rays and their implementation in planar and computed tomography (CT) imaging; nuclear medicine imaging and the methods of forming functional planar and single photon emission computed tomography (SPECT) images and Clinical imaging using positron emitters as radiotracers. The book also discusses the principles of MRI pulse sequencing and signal generation, gradient fields, and the methodologies implemented for image formation, form flow imaging and magnetic resonance angiography and the basic physics of acoustic waves, the different acquisition modes used in medical ultrasound, and the methodologies implemented for image formation and flow imaging using the Doppler Effect. By the end of the book, readers will know what is expected from a medical image, will comprehend the issues involved in producing and assessing the quality of a medical image, will be able to conceptually implement this knowledge in the development of a new imaging modality, and will be able to write basic algorithms for image reconstruction. Knowledge of calculus, linear algebra, regular and partial differential equations, and a familiarity with the Fourier transform and it applications is expected, along with fluency with computer programming. The book contains exercises, homework problems, and sample exam questions that are exemplary of the main concepts and formulae students would encounter in a clinical setting.
Solar Energy Conversion and Storage: Photochemical Modes showcases the latest advances in solar cell technology while offering valuable insight into the future of solar energy conversion and storage. Focusing on photochemical methods of converting and/or storing light energy in the form of electrical or chemical energy, the book: Describes various types of solar cells, including photovoltaic cells, photogalvanic cells, photoelectrochemical cells, and dye-sensitized solar cells Covers the photogeneration of hydrogen, photoreduction of carbon dioxide, and artificial/mimicking photosynthesis Discusses the generation of electricity from solar cells, as well as methods for storing solar energy in the form of chemical energy Highlights existing photochemical methods of solar energy conversion and storage Explores emerging trends such as the use of nanoparticles Solar Energy Conversion and Storage: Photochemical Modes provides a comprehensive, state-of-the-art reference for graduate students, researchers, and engineers alike.
This book provides an authoritative review of the origin and extraction of strontium and its impact on the environment. It also presents the latest strontium decontamination and remediation strategies. Around the globe, nuclear power is being recognized as a major source of energy and is expected to play a crucial role in meeting the energy requirements of present day society. However, the pros and cons have to be considered, and the safe disposal of large amounts of radionuclide wastes is becoming a matter of great concern. These wastes encompass contaminants such as heavy metals and toxic substances, which may exist in solid, liquid or gaseous forms or a combination of these, and as such, their disposal requires particular attention. The book focuses on 90Sr, which is a predominant isotope of strontium and considered an intermediate level radioactive waste with a half-life of 28.8 years, average biological half-life of 18 years and 546 KeV decay energy. Written by expert contributors, it addresses occurrence, detection and extraction of strontium, the chemical and nuclear properties of strontium isotopes, the fate and migration of strontium in soil, its bioaccumulation, and its associated health impact, mechanistic toxicity response as well as related regulation and remediation. It appeals to scholars, scientists and environmental managers working with strontium contamination in the environment and its consequences.
Dynamic light scattering is a new method for investigating macromolecular systems. The importance of the technique lies in its non-invasive character. It can be employed on extremely small fluid volumes, the instrumentation is relatively inexpensive and allows the rapid determination of diffusion coefficients as well as providing information on relaxation time distributions for the macromolecular components of complex systems. This volume is directed in part to the philosophy and current practice in dynamic light scattering. Single photon correlation techniques are introduced; a discussion of noise on photon correlation functions is given and data analysis in dynamic light scattering to polymer structure analysis is presented; and a comprehensive introduction to diffusing wave spectroscopy is given. Theoretical developments relating dynamic light scattering to the viscoelasticity of polymers in solution and in the bulk are described. A secondary aim of the work is to illustrate the widely varying fields in which the technique finds application. Chapters address multicomponent mixtures, polyelectrolytes, dense polymer systems, gels, rigid rods, micellar systems and the application of dynamic light scattering to biological systems.
This open access book is a unique compilation of experimental benchmark analyses of the accelerator-driven system (ADS) at the Kyoto University Critical Assembly (KUCA) on the most recent advances in the development of computational methods. It is devoted especially to nuclear engineers and scientists. Readers will find a detailed description of advanced measurement techniques and calculation methodologies for the ADS with 14 MeV neutrons and high-energy neutrons (with combined use of 100 MeV protons and Pb-Bi target) at KUCA. Additionally, experimental results of nuclear transmutation of minor actinides by ADS and at a critical state are included. Readers also have access to benchmarks of specific ADS experiments with raw data in the Appendix. The book is a valuable resource for the ADS experiments at KUCA which are globally recognized as both static and kinetic studies from the point of view of fundamental research.
Though thousands of articles and books have been published on various aspects of the Manhattan Project, this book is the first comprehensive single-volume history prepared by a specialist for curious readers without a scientific background. This project, the United States Army's program to develop and deploy atomic weapons in World War II, was a pivotal event in human history. The author presents a wide-ranging survey that not only tells the story of how the project was organized and carried out, but also introduces the leading personalities involved and features simplified but accurate descriptions of the underlying science and the engineering challenges. The technical points are illustrated by reader-friendly graphics. .
This monograph describes the theory and practice of electron spectrometry using synchrotron radiation. The book is in three parts. After a short review of background theory, neon is used to elucidate the principles of the photoelectron and Auger spectra. The second part of the book looks at experimental aspects, including characteristic features of electrostatic analysers, detectors, lenses, disturbances, and optimisation, and then illustrates theory and experiment with details of recent experiments. The third part provides useful reference data, including wavefunctions, special theory, polarisation and special aspects of instrumentation. A detailed reference list completes the volume. The study of electron spectrometry using synchrotron radiation is a growing field of research driven by the increasing availability of advanced synchrotron radiation light sources and improved theoretical methods for solving the many-electron problem in atoms. This balanced account will be of value to both theorists and experimentalists working in this area.
This thesis presents two significant results in the field of precision measurements in low-energy nuclear physics. Firstly, it presents a precise half-life determination of 11C, leading to the most precise ft-value for a beta decay transition between mirror nuclides, an important advance in the testing of the electroweak sector of the Standard Model. Secondly, it describes a high-precision mass measurement of 56Cu, a critical nucleus for determining the path of the astrophysical rapid-proton capture process, performed by the author using the LEBIT Penning trap at the National Superconducting Cyclotron Laboratory. This new measurement resolves discrepancies in previously-reported calculated mass excesses. In addition, the thesis also presents the construction and testing of a radio-frequency quadrupole cooler and buncher that will be part of the future N = 126 factory at Argonne National Laboratory aimed at producing nuclei of interest for the astrophysical rapid-neutron capture process for the first time.
The story of superheavy elements - those at the very end of the periodic table - is not well known outside the community of heavy-ion physicists and nuclear chemists. But it is a most interesting story which deserves to be known also to historians, philosophers, and sociologists of science and indeed to the general public. This is what the present work aims at. It tells the story or rather parts of the story, of how physicists and chemists created elements heavier than uranium or searched for them in nature. And it does so with an emphasis on the frequent discovery and naming disputes concerning the synthesis of very heavy elements. Moreover, it calls attention to the criteria which scientists have adopted for what it means to have discovered a new element. In this branch of modern science it may be more appropriate to speak of creation instead of discovery. The work will be of interest to scientists as well as to scholars studying modern science from a meta-perspective.
These peer-reviewed NIC XV conference proceedings present the latest major advances in nuclear physics, astrophysics, astronomy, cosmochemistry and neutrino physics, which provide the necessary framework for a microscopic understanding of astrophysical processes. The book also discusses future directions and perspectives in the various fields of nuclear astrophysics research. In addition, it also includes a limited number of section of more general interest on double beta decay and dark matter.
A unique opportunity to learn about the most important developments in environmental applications of ionizing radiation This book makes it easy for scientists and engineers to acquaint themselves with the state of the art in ionizing radiation techniques for pollution control, environmental cleanup, and waste processing. With contributions by more than 100 researchers working in industry, academia, and government, it reports from around the world on the most important recent advances in the field. From the latest refinements in electron beam technology to new techniques for the purification of flue gases, and from radiation recycling of rubber wastes to radiation-induced cleanup of water and wastewater, this valuable resource covers all established and emerging environmental applications of ionizing radiation. The only book available in English to focus exclusively on the subject, Environmental Applications of Ionizing Radiation belongs in the working library of every aspiring or practicing scientist or engineer concerned with environmental pollution. Radiation has long been used in food processing, medical device sterilization, and polymer production, but only recently has it begun to be widely accepted as a valued component in environmental cleanup initiatives. The growing popularity of radiation as a means of neutralizing both natural and synthetic contaminants is due, in great part, to impressive results recently achieved by researchers worldwide using ionizing radiation methods, especially those involving electron beam techniques. Despite these many successes, there continues to be a conspicuous poverty of professional references on the subject. Environmental Applications of Ionizing Radiation fills that gap. Environmental Applications of Ionizing Radiation brings together contributions by more than 100 leading scientists from the Americas, Europe, and Asia. The first English-language text devoted exclusively to this exciting growth area, it affords readers a unique opportunity to acquaint themselves with state-of-the-art applications of ionizing radiation for solving environmental remediation problems. Featuring many fascinating and informative case studies from around the world, it brings scientists and engineers quickly in line with the latest advances in:
Environmental Applications of Ionizing Radiation is a valuable working resource for civil, chemical, and environmental engineers and scientists involved with pollution control, water treatment, and natural and industrial waste treatment. It also belongs on the syllabuses of all graduate-level engineering courses in air and water management.
The use of catalysts as a means of facilitating and expediting polymer synthesis has become an essential industrial tool over the past forty years. This book provides a comprehensive survey of the entire field of catalysis in polymer synthesis covering the majority of essential aspects from basic organic, organometallic and bio-chemistry to industrial production. Particular emphasis is placed on 'precision polymerization', where the catalyst plays a key role in the fabrication of innovative polymers. Precision polymerization enables the production of polymers with precisely controlled structures, molecular weight, distribution and stereochemistry, free from defects. New catalysis is now used in addition polymerization, polycondensation and polyadditions for various monomers of vinyl, diene, acetylene, hetero-multiple bond, ring-opening and enzyme-substrate types. By utilising precision polymerization, highly functional and high performance polymers for future demands will be created. Intended as a polymer synthesis text for advanced undergraduate and graduate courses, this book will also serve as a valuable reference source for polymer chemists researching catalytic functions with reaction mechanisms in academia and industry, stimulating the discovery of new catalysts and consequently, the design of innovative high performance materials.
Twenty--first century innovation today. Advances in Photochemistry A critical evaluation by internationally recognized experts of some of the most important work currently being done in photochemistry, Volume 22 of this respected series provides a glimpse into the possible shape of the science tomorrow. Each article is intended as a catalyst for further research and discussion, allowing chemists to widen their interests and broaden the boundaries of experimentation. In this volume Ultraviolet Photodissociation Studies of Organosulfur Molecules and Radicals: Energetics, Structure Identification, and Internal State Distribution C. Y. NG Photoreactive Organic Thin Films in the Light of Bound Electromagnetic Waves Z. Sekkat and W. Knoll Elementary Photoprocesses in Designed Chromophore Sequences on alpha--Helical Polypeptides M. Sisido The Photochemistry of Indoles A. Weedon
Radiochemistry or nuclear chemistry is the study of radiation from an atomic and molecular perspective, including elemental transformation and reaction effects, as well as physical, health and medical properties. This revised edition of one of the earliest and best-known books
on the subject has been updated to bring into teaching the latest
developments in research and the current hot topics in the field.
To further enhance the functionality of this text, the authors have
added numerous teaching aids, examples in MathCAD with variable
quantities and options, hotlinks to relevant text sections from the
book, and online self-grading tests.
A number of IAEA Member States generate relatively small quantities of radioactive waste and/or disused sealed sources in research or in the application of nuclear techniques in medicine and industry. This publication presents a modular approach to the design of waste processing and storage facilities to address the needs of such Member States with a cost effective and flexible solution that allows easy adjustment to changing needs in terms of capacity and variety of waste streams. The key feature of the publication is the provision of practical guidance to enable the users to determine their waste processing and storage requirements, specify those requirements to allow the procurement of the appropriate processing and storage modules and install and eventually operate those modules.
Since its infancy in the early 1960s, the use of radiation chemistry in commercial and industrial processes has been greeted with equal parts enthusiasm and controversy. Thirty years later, while much has changed in the technology of radiation chemistry, both the enthusiasm and the controversy have remained. Applied Radiation Chemistry takes a long hard look at the entire field of radiation processing: its history, the current state of technology, level of use, controversial applications, and promising developments. The only book of its kind, Applied Radiation Chemistry places as much emphasis on the chemical changes and principles that produce the observable results as it places on the techniques in question. This enables the reader to understand applications in chemical terms, rather than as a series of recipes. Full chapters are devoted to the processing of polymers and the sterilization of medical disposables, two applications currently in use worldwide. There is also an extensive discussion of the controversial subject of radiation treatment of food, including detailed tables of foods approved for irradiation, and a section on identification of irradiated foods. Applied Radiation Chemistry is the ultimate handbook for chemists, food scientists, polymer scientists, environmental scientists, chemical engineers, and others engaged in research on radiation-processing applications. This fully referenced text is also an ideal textbook for graduate-level courses in radiation applications because it gives basic information on the processes, covers radiation dosimetry, and introduces students to a wide range of actual and potential applications.
This annual review, the 50th volume in the series, provides critical analysis for anyone wanting to keep up to date with the literature on photochemistry and its applications. This essential volume combines reviews on the latest advances in photochemical research with specific topical highlights in the field. The volume starts with periodical reports of the recent literature on organic and computational aspects, including computational advances in photochemistry, chemiluminescence and dark photochemistry, organic aspects of photochemistry of alkenes, dienes and polyenes, aromatic compounds, oxygen-containing functions and those functions containing other heteroatoms, and finally a chapter on transition metal catalysis. Coverage continues in the second part with highlighted topics including photochemical tools for sensing and controlling biological processes, visible light driven enantioselective processes, photochemical formation of C-Chalcogen bonds, photoelectrocatalysis, photovoltaic techniques, photochemical activation of aryl chlorides, luminescent water-soluble systems and computational analyses of fluorescence absorption spectra. This volume will again include a third section entitled 'SPR Lectures on Photochemistry', providing examples for academic readers to introduce a photochemistry topic and precious help for students in photochemistry.
This proceedings volume results from the NATO Advanced Research Workshop on 'Biomarkers of Radiation in the Environment: Robust Tools for Risk Assessment (BRITE)'. The BRITE workshop discussed insights from cancer research, epigenetics, non-human and human risk assessment, since many of the state-of-the-art biomarkers being developed for humans deserve consideration for environmental applications and vice versa. Sessions were very wide-ranging covering methods, mechanisms, cross disciplinary application and regulation. The chapters in this book have been grouped into five major themes that were covered by the BRITE workshop: * Techniques for biomarker development * Low-dose effect mechanisms * Biomarkers for risk evaluation * Biomarkers in wildlife * Biomarker use and responses Each chapter has been written independently and reflects the views of the chapter author(s). Therefore, the readers can form their own balanced view of the different perspectives on biomarkers of radiation in the environment. Given the breadth of topics covered and the state-of-the-art perspectives shared by leading experts in their respective fields, this book should form a valuable resource for anyone with an interest in how biomarkers can be used to improve our understanding of radiation in the environment and its potential impacts.
A review of contemporary actinide research that focuses on new advances in experiment and theory, and the interplay between these two realms Experimental and Theoretical Approaches to Actinide Chemistry offers a comprehensive review of the key aspects of actinide research. Written by noted experts in the field, the text includes information on new advances in experiment and theory and reveals the interplay between these two realms. The authors offer a multidisciplinary and multimodal approach to the nature of actinide chemistry, and explore the interplay between multiple experiments and theory, as well as between basic and applied actinide chemistry. The text covers the basic science used in contemporary studies of the actinide systems, from basic synthesis to state-of-the-art spectroscopic and computational techniques. The authors provide contemporary overviews of each topic area presented and describe the current and anticipated experimental approaches for the field, as well as the current and future computational chemistry and materials techniques. In addition, the authors explore the combination of experiment and theory. This important resource: Provides an essential resource the reviews the key aspects of contemporary actinide research Includes information on new advances in experiment and theory, and the interplay between the two Covers the basic science used in contemporary studies of the actinide systems, from basic synthesis to state-of-the-art spectroscopic and computational techniques Focuses on the interplay between multiple experiments and theory, as well as between basic and applied actinide chemistry Written for academics, students, professionals and researchers, this vital text contains a thorough review of the key aspects of actinide research and explores the most recent advances in experiment and theory.
Based on an American Chemical Society Symposium organized by Professors Glenn Seaborg and Oliver Manuel, this volume provides a comprehensive record of different views on this important subject at the end of the 20th century. They have assembled a blend of highly respected experimentalists and theorists from astronomy, geology, meteoritics, planetology and nuclear chemistry and physics to discuss the origin of elements in the solar system. The intent was to include all points of view and let history judge their validity.
Fluorescent chemosensors have been widely applied in many diverse fields such as biology, physiology, pharmacology, and environmental sciences. The interdisciplinary nature of chemosensor research has continued to grow over the last 25 years to meet the increasing needs of monitoring our environment and health. More recently, a large range of fluorescent chemosensors have been established for the detection of biologically and/or environmentally important species, and are increasingly being used to solve biological problems. The use of these molecules as imaging probes to diagnose and treat disease is gaining momentum with clear future applications. This book will bring together world-leading experts to describe the current state of play in the field and introduce the cutting-edge research and possible future directions into fluorescent chemosensors design. Chapters focus on the basic principles involved in the design of chemosensors for specific analytes, problems, and challenges in the field. Concentrating on advanced techniques and methods, the book will be of use for academics and researchers across a number of disciplines, with international appeal. |
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