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Books > Science & Mathematics > Chemistry > Physical chemistry > Nuclear chemistry, photochemistry & radiation
The question of "what to do with radioactive waste" has been raised frequently for both fission and fusion power plants. In recent years, fusion designers have become increasingly aware of the large amount of mildly radioactive materials that fusion generates. The search for a suitable solution has stimulated discussions about the origin and nature of fusion radioactive waste. This book discusses the perspectives of managing fusion radioactive materials. It also discusses the canister quandary, and the nuclear security system in Georgia.
Ultraviolent (UV) radiation represents a comparatively small part of the total electromagnetic spectrum, yet this portion of the spectrum is responsible for an extremely wide range of effects in many different settings. In biological systems, it can produce good and bad outcomes. We use UV radiation to drive chemical reactions that are desired, and we know that it also drives environmental reactions that are harmful to living organisms. We use UV radiation to interrogate molecules and to analyze cells. Some animals view our world in the UV radiation range, while astronomers use UV to study the universe; in both cases, what is observed is very different from that observed using other parts of the electromagnetic spectrum. This volume gives the reader just the very beginning of the broad range of properties, applications, and effects of UV radiation and is intended to stimulate the reader to explore more of this fascinating part of the electromagnetic spectrum.
Phosphors for Radiation Detector Phosphors for Radiation Detectors Discover a comprehensive overview of luminescence phosphors for radiation detection In Phosphors for Radiation Detection, accomplished researchers Takayuki Yanagida and Masanori Koshimizu deliver a state-of-the-art exploration of the use of phosphors in radiation detection. The internationally recognized contributors discuss the fundamental physics and detector functions associated with the technology with a focus on real-world applications. The book discusses all forms of luminescence phosphors for radiation detection used in a variety of fields, including medicine, security, resource exploration, environmental monitoring, and high energy physics. Readers will discover discussions of dosimeter materials, including thermally stimulated luminescent materials, optically stimulated luminescent materials, and radiophotoluminescence materials. The book also covers transparent ceramics and glasses and a broad range of devices used in this area. Phosphors for Radiation Detection also includes: Thorough introductions to ionizing radiation induced luminescence, organic scintillators, and inorganic oxide scintillators Comprehensive explorations of luminescent materials, including discussions of materials synthesis and their use in gamma-ray, neutron, and charged particle detection Practical discussions of semiconductor scintillators, including treatments of organic-inorganic layered perovskite materials for scintillation detectors In-depth examinations of thermally stimulated luminescent materials, including discussions of the dosimetric properties for photons, charged particles, and neutrons Relevant for research physicists, materials scientists, and electrical engineers, Phosphors for Radiation Detection is an also an indispensable resource for postgraduate and senior undergraduate students working in detection physics.
Little is known about lithium-7 production in China and Russia and whether their supplies can meet future domestic demand. According to industry representatives, China and Russia produce enough lithium-7 to meet demand from U.S. pressurised water reactors, a type of commercial nuclear power reactor that requires lithium-7 for safe operation. This book examines what is known about the supply and demand of lithium-7, what federal agencies are responsible for managing supply risks, and alternative options to mitigate a potential shortage. The authors of this book also discuss the management of helium-3 and the availability of tritium for the weapons stockpile to the National Nuclear Security Administration.
The Department of Energy is the only domestic supplier for many of the over 300 different isotopes it sells that are critical to medical, commercial, research, and national security applications. Previous shortages of some isotopes, such as helium-3, an isotope used to detect radiation at seaports and border crossings, highlight the importance of managing supplies of and demand for critical isotopes. Additionally, the U.S. neutron science effort continues to be world-class, with searches for the neutron electric dipole moment and measurements of the neutron lifetime, radiative decay, beta decay correlation coefficients, hadronic parity violation, and interferometry. This book provides an overview of select assessments of national science programs relating to both isotopes and neutrons.
Ionizing radiation is radiation composed of particles that individually can liberate an electron from an atom or molecule, producing ions, which are atoms or molecules with a net electric charge. These tend to be especially chemically reactive, and the reactivity produces the high biological damage caused per unit of energy of ionizing radiation. This new book examines the applications, sources and biological effects of ionizing radiation with a focus on the analytical methods for the identification of irradiated foods; protein kinases as fundamental participants in the response to DNA damage from ionizing radiation; radiative defects in nanocyrstals as compared with those in bulk crystals; mechanical and optical properties of ionic crystals; mtDNA as a marker of radiation damage; antioxidant prophylaxis of radiation stress; and dosimetry characterisation of a cobalt-60 y-irradiation facility for the radiation sterilization of insects.
Handbook of Radioactivity Analysis: Radiation Physics and Detectors, Volume One, and Radioanalytical Applications, Volume Two, Fourth Edition, constitute an authoritative reference on the principles, practical techniques and procedures for the accurate measurement of radioactivity - everything from the very low levels encountered in the environment, to higher levels measured in radioisotope research, clinical laboratories, biological sciences, radionuclide standardization, nuclear medicine, nuclear power, and fuel cycle facilities, and in the implementation of nuclear forensic analysis and nuclear safeguards. It includes sample preparation techniques for all types of matrices found in the environment, including soil, water, air, plant matter and animal tissue, and surface swipes. Users will find the latest advances in the applications of radioactivity analysis across various fields, including environmental monitoring, radiochemical standardization, high-resolution beta imaging, automated radiochemical separation, nuclear forensics, and more.
In our everyday imaginations we use the laws of nature with their tremendous possibilities of technical progress for the benefit of mankind. The three catastrophes of Chernobyl (26 April 1986), Fukushima Daichii (11 March 2011) and in the Gulf of Mexico, explosion of the drilling platform Deepwater Horizon (20 April 2010), have shaken this world view. Who directed this development? Is it a matter of human error or technical failure? For the answer, approaches from the natural sciences and the humanities are presented.
Das Buch deckt neben den Themen der Entstehung, der Eigenschaften sowie Detektion von R ntgenstrahlen, die Entwicklungshistorie der Computertomographie, die elementaren Methoden der Signalverarbeitung und insbesondere die Signalverarbeitungsverfahren der Computertomographie ab. Hierbei wird Wert auf die ausf hrliche Darstellung der Mathematik der zwei- und dreidimensionalen Rekonstruktionsverfahren gelegt. Neben der ausf hrlichen Erkl rung der theoretischen Konzepte wird auf die praktischen Randbedingungen der technischen Realisierung sowie auf die auftretenden Bildartefakte besonders eingegangen.
This book offers a comprehensive survey of basic elements of nuclear dynamics at low energies and discusses similarities to mesoscopic systems. It addresses systems with finite excitations of their internal degrees of freedom, so that their collective motion exhibits features typical for transport processes in small and isolated systems. The importance of quantum aspects is examined with respect to both the microscopic damping mechanism and the nature of the transport equations. The latter must account for the fact that the collective motion is self-sustained. This implies highly nonlinear couplings between internal and collective degrees of freedom --- different to assumptions made in treatments known in the literature. A critical discussion of the use of thermal concepts is presented. The book can be considered self-contained. It presents existing models, theories and theoretical tools, both from nuclear physics and other fields, which are relevant to an understanding of the observed physical phenomena.
This thesis explores two distinct applications of laser spectroscopy: the study of nuclear ground state properties, and element selective radioactive ion beam production. It also presents the methods and results of an investigation into isotope shifts in the mercury isotopic chain. These Resonance Ionization Laser Ion Source (RILIS) developments are detailed, together with an RILIS ionization scheme that allowed laser ionized ion beams of chromium, germanium, radium and tellurium to be generated at the Isotope Mass Separator On-Line (ISOLDE) facility. A combination of laser spectroscopy with decay spectroscopy and mass spectrometry unambiguously demonstrated a cessation of the extreme shape staggering first observed in the 1970s and revealed the characteristic kink at the crossing of the N=126 shell closure. A series of RILIS developments were required to facilitate this experiment, including mercury "ionization scheme" development and the coupling of the RILIS with an arc discharge ion source. Laser spectroscopy has since become a powerful tool for nuclear physics and the Resonance Ionization Laser Ion Source (RILIS), of the ISOLDE facility at CERN, is a prime example. Highlighting important advances in this field, the thesis offers a unique and revealing resource.
This textbook introduces the topic of special relativity, with a particular emphasis upon light-matter interaction and the production of light in plasma. The physics of special relativity is intuitively developed and related to the radiative processes of light. The book reviews the underlying theory of special relativity, before extending the discussion to applications frequently encountered by postgraduates and researchers in astrophysics, high power laser interactions and the users of specialized light sources, such as synchrotrons and free electron lasers. A highly pedagogical approach is adopted throughout, and numerous exercises are included within each chapter to reinforce the presentation of key concepts and applications of the material.
Principles of Molecular Photochemistry: An Introduction develops photochemical and photophysical concepts from a small set of familiar principles. Developed from Nick Turro's best-selling text for three decades - Modern Molecular Photochemistry - this updated primer introduces an initial paradigm that relates the photon and a reactant molecular structure to photochemistry through the structure and dynamics of electronically excited states, reactive intermediates and products. The same paradigm is readily adapted to incorporate the photon and a reactant molecular structure to photophysics. The book provides brilliantly clear descriptions in pictorial terms that can be readily understood by the student and applied to systems of interest. This text will be of interest to not only practicing photochemists and their students, but also to biological scientists, polymer scientists, material scientists and nanoscientists who use photochemistry and photophysics in their research and teaching.
An introductory text on radiation heat transfer for undergraduate and postgraduate students with no prior knowledge of the subject. The text introduces the physical principles of radiation heat transfer and develops methods for the analysis of thermal radiation in a variety of engineering applications.
This book is designed to serve as a textbook for core courses offered to postgraduate students enrolled in chemistry. This book can also be used as a core or supplementary text for nuclear chemistry courses offered to students of chemical engineering. The book covers various topics of nuclear chemistry like Shell model, fission/fusion reaction, natural radioactive equilibrium series, nuclear reactions carried by various types of accelerators. In addition, it describes the law of decay of radioactivity, type of decay, and interaction of radiation with matter. It explains the difference between ionization counter, scintillation counter and solid state detector. This book also consists of end-of-book problems to help readers aid self-learning. The detailed coverage and pedagogical tools make this an ideal textbook for postgraduate students and researchers enrolled in various chemistry and engineering courses. This book will also be beneficial for industry professionals in the allied fields.
The development of nuclear weapons during the Manhattan Project is one of the most significant scientific events of the twentieth century. This revised and updated 4th edition explores the challenges that faced the scientists and engineers of the Manhattan Project. It gives a clear introduction to fission weapons at the level of an upper-year undergraduate physics student by examining the details of nuclear reactions, their energy release, analytic and numerical models of the fission process, how critical masses can be estimated, how fissile materials are produced, and what factors complicate bomb design. An extensive list of references and a number of exercises for self-study are included. Revisions to this fourth edition include many upgrades and new sections. Improvements are made to, among other things, the analysis of the physics of the fission barrier, the time-dependent simulation of the explosion of a nuclear weapon, and the discussion of tamped bomb cores. New sections cover, for example, composite bomb cores, approximate methods for various of the calculations presented, and the physics of the polonium-beryllium "neutron initiators" used to trigger the bombs. The author delivers in this book an unparalleled, clear and comprehensive treatment of the physics behind the Manhattan project.
This textbook, intended for advanced undergraduate and graduate students, is an introduction to the physical and mathematical principles used in clinical medical imaging. The first two chapters introduce basic concepts and useful terms used in medical imaging and the tools implemented in image reconstruction, while the following chapters cover an array of topics such as physics of x-rays and their implementation in planar and computed tomography (CT) imaging; nuclear medicine imaging and the methods of forming functional planar and single photon emission computed tomography (SPECT) images and Clinical imaging using positron emitters as radiotracers. The book also discusses the principles of MRI pulse sequencing and signal generation, gradient fields, and the methodologies implemented for image formation, form flow imaging and magnetic resonance angiography and the basic physics of acoustic waves, the different acquisition modes used in medical ultrasound, and the methodologies implemented for image formation and flow imaging using the Doppler Effect. By the end of the book, readers will know what is expected from a medical image, will comprehend the issues involved in producing and assessing the quality of a medical image, will be able to conceptually implement this knowledge in the development of a new imaging modality, and will be able to write basic algorithms for image reconstruction. Knowledge of calculus, linear algebra, regular and partial differential equations, and a familiarity with the Fourier transform and it applications is expected, along with fluency with computer programming. The book contains exercises, homework problems, and sample exam questions that are exemplary of the main concepts and formulae students would encounter in a clinical setting.
Solar Energy Conversion and Storage: Photochemical Modes showcases the latest advances in solar cell technology while offering valuable insight into the future of solar energy conversion and storage. Focusing on photochemical methods of converting and/or storing light energy in the form of electrical or chemical energy, the book: Describes various types of solar cells, including photovoltaic cells, photogalvanic cells, photoelectrochemical cells, and dye-sensitized solar cells Covers the photogeneration of hydrogen, photoreduction of carbon dioxide, and artificial/mimicking photosynthesis Discusses the generation of electricity from solar cells, as well as methods for storing solar energy in the form of chemical energy Highlights existing photochemical methods of solar energy conversion and storage Explores emerging trends such as the use of nanoparticles Solar Energy Conversion and Storage: Photochemical Modes provides a comprehensive, state-of-the-art reference for graduate students, researchers, and engineers alike.
The chemical composition of any planetary atmosphere is of fundamental importance in determining its photochemistry and dynamics in addition to its thermal balance, climate, origin and evolution. Divided into two parts, this book begins with a set of introductory chapters, starting with a concise review of the Solar System and fundamental atmospheric physics. Chapters then describe the basic principles and methods of spectroscopy, the main tool for studying the chemical composition of planetary atmospheres, and of photochemical modeling and its use in the theoretical interpretation of observational data on chemical composition. The second part of the book provides a detailed review of the carbon dioxide atmospheres and ionospheres of Mars and Venus, and the nitrogen-methane atmospheres of Titan, Triton and Pluto. Written by an expert author, this comprehensive text will make a valuable reference for graduate students, researchers and professional scientists specializing in planetary atmospheres.
Dynamic light scattering is a new method for investigating macromolecular systems. The importance of the technique lies in its non-invasive character. It can be employed on extremely small fluid volumes, the instrumentation is relatively inexpensive and allows the rapid determination of diffusion coefficients as well as providing information on relaxation time distributions for the macromolecular components of complex systems. This volume is directed in part to the philosophy and current practice in dynamic light scattering. Single photon correlation techniques are introduced; a discussion of noise on photon correlation functions is given and data analysis in dynamic light scattering to polymer structure analysis is presented; and a comprehensive introduction to diffusing wave spectroscopy is given. Theoretical developments relating dynamic light scattering to the viscoelasticity of polymers in solution and in the bulk are described. A secondary aim of the work is to illustrate the widely varying fields in which the technique finds application. Chapters address multicomponent mixtures, polyelectrolytes, dense polymer systems, gels, rigid rods, micellar systems and the application of dynamic light scattering to biological systems.
This open access book is a unique compilation of experimental benchmark analyses of the accelerator-driven system (ADS) at the Kyoto University Critical Assembly (KUCA) on the most recent advances in the development of computational methods. It is devoted especially to nuclear engineers and scientists. Readers will find a detailed description of advanced measurement techniques and calculation methodologies for the ADS with 14 MeV neutrons and high-energy neutrons (with combined use of 100 MeV protons and Pb-Bi target) at KUCA. Additionally, experimental results of nuclear transmutation of minor actinides by ADS and at a critical state are included. Readers also have access to benchmarks of specific ADS experiments with raw data in the Appendix. The book is a valuable resource for the ADS experiments at KUCA which are globally recognized as both static and kinetic studies from the point of view of fundamental research.
Learn about the properties of synchrotron radiation and its wide range of applications in physics, materials science and chemistry with this invaluable reference. This thorough text describes the physical principles of the subject, its source and methods of delivery to the sample, as well as the different techniques that use synchrotron radiation to analyse the electronic properties and structure of crystalline and non-crystalline materials and surfaces. Explains applications to study the structure and electronic properties of materials on a microscopic, nanoscopic and atomic scale. An excellent resource for current and future users of these facilities, showing how the available techniques can complement information obtained in users' home laboratories. Perfect for graduate and senior undergraduate students taking specialist courses in synchrotron radiation, in addition to new and established researchers in the field.
This thesis presents two significant results in the field of precision measurements in low-energy nuclear physics. Firstly, it presents a precise half-life determination of 11C, leading to the most precise ft-value for a beta decay transition between mirror nuclides, an important advance in the testing of the electroweak sector of the Standard Model. Secondly, it describes a high-precision mass measurement of 56Cu, a critical nucleus for determining the path of the astrophysical rapid-proton capture process, performed by the author using the LEBIT Penning trap at the National Superconducting Cyclotron Laboratory. This new measurement resolves discrepancies in previously-reported calculated mass excesses. In addition, the thesis also presents the construction and testing of a radio-frequency quadrupole cooler and buncher that will be part of the future N = 126 factory at Argonne National Laboratory aimed at producing nuclei of interest for the astrophysical rapid-neutron capture process for the first time.
Though thousands of articles and books have been published on various aspects of the Manhattan Project, this book is the first comprehensive single-volume history prepared by a specialist for curious readers without a scientific background. This project, the United States Army's program to develop and deploy atomic weapons in World War II, was a pivotal event in human history. The author presents a wide-ranging survey that not only tells the story of how the project was organized and carried out, but also introduces the leading personalities involved and features simplified but accurate descriptions of the underlying science and the engineering challenges. The technical points are illustrated by reader-friendly graphics. .
The story of superheavy elementsĀ - those at the very end of the periodic tableĀ - is not well known outside the community of heavy-ion physicists and nuclear chemists. But it is a most interesting story which deserves to be known also to historians, philosophers, and sociologists of science and indeed to the general public. This is what the present work aims at. It tells the story or rather parts of the story, of how physicists and chemists created elements heavier than uranium or searched for them in nature. And it does so with an emphasis on the frequent discovery and naming disputes concerning the synthesis of very heavy elements. Moreover, it calls attention to the criteria which scientists have adopted for what it means to have discovered a new element. In this branch of modern science it may be more appropriate to speak of creation instead of discovery. The work will be of interest to scientists as well as to scholars studying modern science from a meta-perspective. |
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