This book provides comprehensive research findings related to the environmental monitoring of radiation, levels of radioactive nuclides in various environments and dose estimation in residents after the Fukushima nuclear power plant accident caused severe environmental contamination with radioactive nuclides. At the beginning of the book, a technical review written by a leading researcher of nuclear reactor technology explains what happened at the power plant. The review is followed by a commentary from a former member of the International Commission on Radiological Protection, providing the reader with easily understandable information about the concept of radiation dosage. In the main part of the book, a series of scientific reports presents valuable data on the radiation surveys of the environment, environmental radioactivity, transfer models and parameters of radioactive nuclides and dose assessment among residents. These reports present a wide range of findings from the research carried out in a variety of activities by large governmental organizations as well as by small private groups and individuals. The reader thus will find a large collection of valuable and interesting data related to the environmental contamination by radioactive nuclides after the Fukushima accident. Although earlier reports on this issue have been made public, this book is the only publication to fully depict the actual situation by providing comprehensive data obtained by diverse organizations and individuals.

The series Topics in Current Chemistry Collections presents critical reviews from the journal Topics in Current Chemistry organized in topical volumes. The scope of coverage is all areas of chemical science including the interfaces with related disciplines such as biology, medicine and materials science. The goal of each thematic volume is to give the non-specialist reader, whether in academia or industry, a comprehensive insight into an area where new research is emerging which is of interest to a larger scientific audience. Each review within the volume critically surveys one aspect of that topic and places it within the context of the volume as a whole. The most significant developments of the last 5 to 10 years are presented using selected examples to illustrate the principles discussed. The coverage is not intended to be an exhaustive summary of the field or include large quantities of data, but should rather be conceptual, concentrating on the methodological thinking that will allow the non-specialist reader to understand the information presented. Contributions also offer an outlook on potential future developments in the field.

Presents the state of the technology, from fundamentals to new materials and applications

Today's electronic devices, computers, solar cells, printing, imaging, copying, and recording technology, to name a few, all owe a debt to our growing understanding of the photophysics and photochemistry of polymeric materials. This book draws together, analyzes, and presents our current understanding of polymer photochemistry and photophysics. In addition to exploring materials, mechanisms, processes, and properties, the handbook also highlights the latest applications in the field and points to new developments on the horizon.

"Photochemistry and Photophysics of Polymer Materials" is divided into seventeen chapters, including:

Optical and luminescent properties and applications of metal complex-based polymers

Photoinitiators for free radical polymerization reactions

Photovoltaic polymer materials

Photoimaging and lithographic processes in polymers

Photostabilization of polymer materials

Photodegradation processes in polymeric materials

Each chapter, written by one or more leading experts and pioneers in the field, incorporates all the latest findings and developments as well as the authors' own personal insights and perspectives. References guide readers to the literature for further investigation of individual topics.

Together, the contributions represent a series of major developments in the polymer world in which light and its energy have been put to valuable use. Not only does this reference capture our current state of knowledge, but it also provides the foundation for new research and the development of new materials and new applications.

The first source on this expanding analytical science, this reference explores advances in the instrumentation, design, and application of techniques with electrogenerated chemiluminescence (ECL), examining the use and impact of ECL-based assays in clinical diagnostics, life science research, environmental testing, food and water evaluation, and the detection of biowarfare agents. Compiled by the pioneer of this highly innovative technology, this volume provides contributions from 16 leading authorities. They discuss the simulation of ECL behavior using commercial software, summarize key characteristics of organic ECL systems, and cover developments in metal chelate ECL.

This text discusses di-p-methane rearrangements via radical-cation intermediates, the photo-Fries rearrangement in organized media and of biologically active compounds, electron transfer leading to fragmentation, dimerization, and nucleophilic capture, and the characterization and reactivity of photochemically generated phenylene bis(diradical) species. The authors reveal experimental and computational techniques for the study of phenylene-linked carbenes and nitrenes. Brimming with over 900 references, Photochemistry of Organic Molecules in Isotropic and Anisotropic Media is crucial for professionals and students in photochemistry; chemical engineering; materials and semiconductor science; and organic, inorganic, and physical chemistry.

The observation of Nature is an inexhaustible source of inspiration to promote innovations in chemistry. The bioinspired approach is a revolution in our paradigms because it is not based on what we can take to nature, but on what we can learn from it. Enzymatic systems involved in solar energy conversion (photosystem), hydrogen production (hydrogenases), dioxygen activation (oxydases et oxygenases), CO2 reduction (CO dehydrogenase) use abundant and cheap starting material such as O2, H2O and CO2. Inspiration of these biological systems is a solution to make our chemical processes greener. These are some of the many challenges that bioinspired chemistry is able to take up.A number of the recent developments in bioinspired chemistry are discussed, including some descriptions on the biological systems that are the source of inspiration. This book is a guide to where bioinspired chemistry will be in the near future and provides a thoughtful perspective on how bioinspiration could change our world.

The 1989 International Conference on Nuclear Analytical Methods in theUfe Scienceswas a continuationofa seriesofconfer encesheldbytheInternationalAtomicEnergyAgency. Thefirsttook placeinAmsterdamin 1967, thesecondin Bledin 1972, andthethird inViennain 1978. Theaimoftheseconferenceshasbeentostimulate discussions between scientists who are working as biologists, envi ronmentalists, and physicians, and those who are working on the advancementofnuclear analytical techniques. The 1989 Conference was held at the National Institute of Standards and Technology (NIST, formerly the National Bureau of Standards)inGaithersburg, Maryland. ThefocalpointoftheConfer ence was the presentation of results from multidisciplinary research involvingnuclear analytical techniques and their applications to the life sciences. Wehave obtained contributions from life sciencefields thatrelatethenuclear analyticalmethods to abroad scopeofbiologi cal, medical, and environmental applications. Deliberately, our defi nition of nuclear analytical techniques was made flexible. Methods and applications were treated in a more comprehensive way than thoseatestablished meetings. Particularconsideration was given to contributions from developing countries. We are indebted to many people and organizations for their assistancein making this symposium possible. TheConference was organizedbytheUSDepartmentofCommerce'sNISTincooperation with the International Atomic Energy Agency, by supplying both financial support and scientific expertise. The meeting was cospon soredbytheAmericanNuclearSociety, theUSDepartmentofEnergy, andtheFoodandDrugAdministration, whoprovidedbothorganiza tional and financial support. We hope that the results of this Conference, presented here, will stimulatethe developmentofnew collaborativeresearch efforts betweenthe life sciencesand analytical fields. Acontinuationofthis series ofconferences willbe a measureofthe successofthis interdis ciplinary collaboration."

This book provides a first authoritative text on radiochromic film, covering the basic principles, technology advances, practical methods, and applications. It focuses on practical uses of radiochromic film in radiation dosimetry for diagnostic x-rays, brachytherapy, radiosurgery, external beam therapies (photon, electron, protons), stereotactic body radiotherapy, intensity-modulated radiotherapy, and other emerging radiation technologies. The expert authors address basic concepts, advantages, and the main applications including kilovoltage, brachytherapy, megavoltage, electron beam, proton beam, skin dose, in vivo dosimetry, postal and clinical trial dosimetry. The final chapters discuss the state of the art in microbeam, synchrotron radiation, and ultraviolet radiation dosimetry.

This book provides a first comprehensive summary of the basic principles, instrumentation, methods, and clinical applications of three-dimensional dosimetry in modern radiation therapy treatment. The presentation reflects the major growth in the field as a result of the widespread use of more sophisticated radiotherapy approaches such as intensity-modulated radiation therapy and proton therapy, which require new 3D dosimetric techniques to determine very accurately the dose distribution. It is intended as an essential guide for those involved in the design and implementation of new treatment technology and its application in advanced radiation therapy, and will enable these readers to select the most suitable equipment and methods for their application. Chapters include numerical data, examples, and case studies.

Continuous-flow photochemistry is an expanding field within chemistry. It unites the mass transfer enhancement of flow chemistry with the high energy field density of microscale geometries. Moreover, it provides means to scale photochemical reactions efficiently.This book gives an overview of both technological and chemical aspects associated with photochemical processes in microreactors. It provides analysis, the first of its kind, of these new technologies developed within the field of photochemical processes, with a description and case studies of practical implementation. It specifically looks at:By providing a deeper understanding of underlying concepts, coupled with numerous examples, this book is an essential reference for chemistry students, researchers and professionals working on photochemistry, photoredox catalysis, flow chemistry, process chemistry and reactor engineering.

Principles of Nuclear Chemistry is an introductory text in nuclear chemistry and radiochemistry, aimed at undergraduates with little or no knowledge of physics. It covers the key aspects of modern nuclear chemistry and includes worked solutions to end of chapter questions.The text begins with basic theories in contemporary physics and uses these to introduce some fundamental mathematical techniques. It relates nuclear phenomena to key divisions of chemistry such as atomic structure, spectroscopy, equilibria and kinetics. It also gives an introduction to f-block chemistry and the nuclear power industry.This book is essential reading for those taking a first course in nuclear chemistry and is a useful companion to other volumes in physical and analytical chemistry. It will also be of use to those new to working in nuclear chemistry or radiochemistry.

Nuclear Analytical Methods in the Life Sciences -1994 is a forefront survey of key presentations from the 1993 International Conference on Nuclear Analytical Methods in the Life Sciences. Sponsored by the International Atomic Energy Agency (IAEA), this useful volume covers the spectrum of multidisciplinary research on both the methodological aspects and the development of nuclear analytical methods and their applications in the life sciences.
The book is divided into six sections covering related material. These sections are: Methodology of Nuclear Analytical Methods; Environmental Applications; Biomedical Applications; Analysis of Biological Samples; Quality Assurance and Comparison with Other Methods; and a section dealing with miscellaneous issues, such as programs offered by the IAEA.

'Radiation Effects on Embedded Systems' provides the reader with the major guidelines for coping with radiation effects on components supposed to be included in today's application devoted to operate in space, but also in atmosphere at high altitude or at ground level. It contains a set of chapters based on the tutorials presented at the International School on Effects of Radiation on Embedded Systems for Space Applications (SERESSA) that was held in Manaus, Brazil, from 20 to 25 November 2005.

This book is a treatment on the foundational knowledge of Nuclear Science and Engineering. It is an outgrowth of a first-year graduate-level course which the author has taught over the years in the Department of Nuclear Science and Engineering at MIT. The emphasis of the book is on concepts in nuclear science and engineering in contrast to the traditional nuclear physics in a nuclear engineering curriculum. The essential difference lies in the importance we give to the understanding of nuclear radiation and their interactions with matter. We see our students as nuclear engineers who work with all kinds of nuclear devices, from fission and fusion reactors to accelerators and detection systems. In all these complex systems nuclear radiation play a central role. In generating nuclear radiation and using them for beneficial purposes, scientists and engineers must understand the properties of the radiation and how they interact with their surroundings. It is through the control of radiation interactions that we can develop new devices or optimize existing ones to make them more safe, powerful, durable, or economical. This is why radiation interaction is the essence of this book.

Traditionally, most synthetically developed materials are hardened by heating them to an elevated temperature, a process requiring large amounts of energy and space. Interest in photo cured materials using UV-light is growing due to simplifications in manufacturing and growing environmental concerns; it is expected photocuring could reduce electricity consumption by 90% compared to traditional curing. Photocured materials also reduce evaporation of volatile organic components, curing time and waste, thereby enhancing productivity and reducing work space. The materials technologies based on photocuring are gaining momentum, and this will be the first book to provide an in-depth focus on the subject. This book summarises the fundamentals required to understand the field, characterises the use of novel materials and the development of synthetic aspects, and discusses the future of the technology. The comprehensive review chapters are suitable for a broad readership from diverse backgrounds including chemistry, physics, materials science and engineering, medical science, pharmacy, biotechnology and biomedical engineering. Photocured Materials will be of interest to students, researchers, scientists, engineers and professors.

Photodynamic therapy (PDT) was discovered over one hundred years ago after observing the death of microorganisms upon exposure to dyes and light. It is the combination of non-toxic dyes and harmless visible light that, in the presence of oxygen, produce highly toxic reactive species. The principal medical application during the last century was in cancer therapy but, in these days of rising antibiotic resistance, PDT shows increasing promise as an alternative approach to treating infections. PDT has also been used in blood product sterilization, peridontology, acne reduction, and the treatment of viral lesions such as those caused by human papilloma virus. It may also have potential as an environmentally friendly pesticide. This is the first and only book to comprehensively cover the use of light and photosensitising agents for controlling microbial pathogens. It provides a comprehensive and up-to-date coverage of an emerging field. There are several chapters on the design of antimicrobial photosensitizers, their use to kill pathogenic organisms and their success in treating infections in animal models. It has long been known that gram-positive bacteria are highly susceptible to photoinactivation but the book also discusses means of widening the range of microorganisms that can be tackled by PDT. Edited by two pioneers in the application of PDT to medical and environmental issues, this book covers the basic science, translational research in animals, and the clinical applications in various medical specialities. It represents an indispensable resource for microbiologists and infectious disease doctors as well as dentists, dermatologists, gastroenterologists and transfusion specialists.

Incidents in the past have made scientists aware of the need for accurate methods of radionuclide analyses in order to estimate the risk to the public from released radioactivity .This book is an authoritative, up-to-date collection of research contributions presented at the 11th International Symposium on Environmental Radiochemical Analysis. Representing the work of leading scientists from across the globe it presents information on analytical radiochemistry, the behaviour of radionuclides in the environment, radioactively contaminated land, fate of radionuclides in natural and engineered environments and behaviour of radionuclides in radioactive wastes. This essential work will be a key reference for graduates and professionals who work across fields involving analytical chemistry, environmental science and technology, and hazards and waste research and disposal.

The book deals with the environmentally friendly cleaning materials functionalized with TiO2, a widely known semiconductor giving rise to redox reactions under artificial or solar irradiation. The role of Titanium dioxide in the worldwide community is introduced first. The fundamental working principles of heterogeneous photocatalysis follow and a critical section on the semiconductor bulk and surface properties open the way to the differences between TiO2 blend features with respect to analogous thin film layouts. Then follows the main section of the book which deals with the techniques applied to manufactured commercial devices, ranging from glasses to textiles and from concrete and other construction materials to paintings. Also road asphalt and other devices, such as photocatalytic air conditioning machines are outlined. Last generation materials, not yet commercialized, and the deposition techniques applied to prepare them are also widely discussed. The final part of the book covers the difficult and modern topic of standardization and comparison of performance of photocatalytic processes and in particular the guidelines proposed by various worldwide organizations for standardization are discussed. The book covers the general matters as well as the practical applications with the supporting methods discussed in detail. This book brings together a team of highly experienced and well-published experts in the field, providing a comprehensive view of the applications of supported titanium dioxide.

Nuclear power currently contributes some 20% of the electricity needs of the UK and is rising rapidly on the political agenda due to environmental and economic factors, and yet all but one of the UK's existing nuclear reactors is expected to close by 2023. The increasing emphasis towards nuclear power rests on security of supply and reducing carbon emissions. This comprehensive book provides an account of the recent advances in securing safe performance of graphite-moderated nuclear reactors both within the UK and abroad which underpin life extension whilst maintaining high levels of plant performance. These reactors rely on graphite as a moderator in the form of layers of interlocked graphite bricks which undergo complex changes when exposed over long periods to the effects of neutron irradiation and radiolytic oxidation. The objective of this book is to outline the current approaches in terms of assessment methodologies, surveillance and test methods, performance prediction, graphite reactor decommissioning, regulatory requirements and the relevance to future reactor designs. The book is a sequel to the successful RSC publication "Managing of Ageing Processes in Graphite Reactor Cores," but with the emphasis on the challenges for the future safe performance. It is hoped that the contributed papers will also help in the design, construction, operation and eventual decommissioning of the new generation of graphite-moderated reactors. Papers presented in the book represent contributions from the most eminent specialists in the field and reflect the UK's contribution over the past 50 years to graphite reactor technology that will remain significant for years to come, especially in the development of Generation IV designs. This seminal book is written in a way that takes the reader from fundamental knowledge to reactor operation in a straight forward and understandable manner - ideal for non-specialist as well as a unique reference for the specialist. It is fully illustrated to aid understanding and is relevant to a wide range of readers from policy makers to reactor operators.

Recent Trends in Radiation Chemistry is a state-of-the-art review of the present status and future trends in the field of radiation chemistry research. It covers a broad spectrum of topics, ranging from the historical perspective, instrumentation of accelerators in the nanosecond to femtosecond region, through the use of radiation chemical methods in the study of antioxidants and nanomaterials, radiation-induced DNA damage by ionizing radiation involving both direct and indirect effects, to ultrafast events in free electron transfer, radiation-induced processes at solid-liquid interfaces and the recent work on infrared spectroscopy and radiation chemistry.The contributors to the book are world-renowned specialists. The book is unique in that it covers a wide spectrum of topics that will be of great interest to beginners as well as experts. Recent data on ultrafast phenomena from the recently established world-class laser-driven accelerators facilities in the US, France and Japan are reviewed.There has not been a significant book covering the important field of radiation chemistry for the last 5 years. This timely book, which includes highlights of recent work, will appeal not only to the specialists working in the area but also to other researchers involved in related specialties. remove remove

Vibrationally Mediated Photodissociation (VMP) deals with the influence of vibrational excitation of the ground electronic state of a molecule on its dissociation following excitation of this state to a higher electronic state. Aimed at students and academics, this is the first book devoted to the effect of vibrational pre-excitation on molecular dynamics in the gas phase. In particular, it deals with the influence of this excitation on the dissociation of molecules (ie: on the branching ratio between the dissociation products and its dependence on the vibrational state being excited). The effect in the gas phase has been extensively studied, both theoretically and experimentally and encompasses diverse areas of chemical physics. This monograph presents the methodology of VMP, using state-of-the-art specific examples. Overviews of earlier works are included as well, to serve as a background for current research. Wherever appropriate, original works are quoted, including the original drawings. The contents include a brief review of theoretical and experimental methods relevant to VMP and specific examples. Also included are a bibliography, author and subject index. From the description of the motivation, the approach, the execution of the experiment and the analysis of the results of the specific examples, the reader will get a comprehensive understanding of the field. The book is aimed at senior undergraduate and graduate students of chemistry and physics. It serves as an introduction to VMP for beginners and as a literature guide to those acquainted with the subject but not necessarily working on VMP.

The analysis of radionuclides in the environment became extremely important after the accident at Chernobyl in1986. The accident made scientists aware that accurate methods of radionuclide analyses are essential in order to estimate the risk to the public from released radioactivity. Methods are still being developed today because of the ongoing requirement to monitor environmental radioactivity and, to assess the radionuclide waste inventory for the recently proposed intermediate radioactive waste repository. This book brings together current developments in radioactive analyses. Environmental Radiochemical Analysis III is an authoritative, up to date review of research contributions presented at the 10th International Symposium on Environmental Radiochemical Analysis. Representing the work of leading scientists across the globe this edition provides information on: * new methods of radioanalyses * waste steams during decommissioning * radioactivity measurements in the environment * hazard assessment in decommissioning * improvements in measurement instrumentation * application of software to measurements * current IAEA activities for the ALMERA network * proficiency testing and research and development in the NDA. This exceptional work offers an insight into topical areas of research and is a key point of reference for graduates and professionals alike who work across fields involving analytical chemistry, environmental science and technology, and hazards and waste research and disposal.

Nuclear power currently contributes nearly a quarter of the electricity needs of the UK. Much of this is from nuclear reactor plants developed some fifty years ago. Consequently, in the next few decades, many of these reactors and components are coming to the end of their 'useful' life and strategies for the effective management of these decommissioned parts are paramount. Management of Ageing Processes in Graphite Reactor Cores discusses in detail both the scientific challenges and the issues involved in this subject. It begins with an introductory section on the fundamentals of reactor design and goes on to discuss graphite core behaviour under irradiation; graphite-component behaviour and its assessment; and whole core behaviour. The book concludes with a section on the lessons learned from decades of experience. Written by leading experts in the field, this high level book is ideal for both academia and industry, and would also be of relevance to policy makers and governments.

Flavins and flavoproteins are a widely investigated and highly versatile group of compounds. Participation of these compounds in photochemistry and photobiology processes are of particular importance in the fields of biology, chemistry and medicine. Written by leading experts in the field each section of the book includes a historical overview of the subject, state of the art developments and future perspectives. Flavins: Photochemistry and Photobiology begins with the properties and applications of flavins, including their photochemistry in aqueous and organic solutions. Subsequent sections discuss riboflavin as a visible light sensitizer in the photo degradation of drugs, antiviral and antibacterial effects, the role of flavins in light induced toxicity and blue light initiated DNA repair by photolyase. Finally there are sections on the flavin based photoreceptors in plants, bacteria and eukaryotic photosynthetic flagelettes. This book brings together leading experts with a unique interdisciplinary emphasis, to provide an authoritative resource on flavins and their role in photochemistry and photobiology.

Cleavage of water to its constituents (i.e., hydrogen and oxygen) for production of hydrogen energy at an industrial scale is one of the "holy grails" of materials science. That can be done by utilizing the renewable energy resource i.e. sunlight and photocatalytic material. The sunlight and water are abundant and free of cost available at this planet. But the development of a stable, efficient and cost-effective photocatalytic material to split water is still a great challenge. To develop the effective materials for photocatalytic water splitting, various type of materials with different sizes and structures from nano to giant have been explored that includes metal oxides, metal chalcogenides, carbides, nitrides, phosphides, and so on. Fundamental concepts and state of art materials for the water splitting are also discussed to understand the phenomenon/mechanism behind the photoelectrochemical water splitting. This book gives a comprehensive overview and description of the manufacturing of photocatalytic materials and devices for water splitting by controlling the chemical composition, particle size, morphology, orientation and aspect ratios of the materials. The real technological breakthroughs in the development of the photoactive materials with considerable efficiency, are well conversed to bring out the practical aspects of the technique and its commercialization.