One of the major challenges in current chemistry is to ?nd molecules able to move charges rapidly and ef?ciently from, for example, one terminus to another one under the control of an external electrical, electrochemical or photochemical stimulus. Nature has provided impressive examples of how these goals are achieved. The photosynthetic reaction center protein, for instance, rapidly moves electrons with near unity quantum ef?ciency across a lipid bilayer membrane using several redox cofactors, and thus, serves as a model for developing biomimetic analogues for applications in ?elds such as photovoltaic devices, molecular electronics and photonic materials. In this context, p-conjugated oligomeric molecular assemblies are of particular interest because they provide ef?cient electronic couplings between electroactive units - donor and acceptor termini - and display wire-like behavior. In order to make a molecule able to behave as an ideal molecular wire different requirements need to be ful?lled: i) matching between the donor (acceptor) and bridge energy levels, ii) a good electronic coupling between the electron donor and acceptor units via the bridge orbitals, and iii) a small attenuation factor. Among the many different p-conjugated oligomers, oligo(p-phenylenevin- enes) (oPPV), have emerged as a particularly promising model system that helps to comprehend/rationalize the basic features of polymeric poly(p-phenyle- vinylenes) and also as a versatile building block for novel materials with che- cally tailored properties.

What determines how cities move on? The ever-increasing challenges to urban mobility come in many forms, and approaches to address them range from the technically ingenious to attempts to change travel behaviour. Key amongst factors essential to the success of any such approach is whether the urban environment proves to be fertile ground for the desired progress. Another vital determinant of success is how well individual measures to engineer the transport system interact with other developments. This leads to the principal subject of Megacity Mobility Culture: the basic principles that determine the paths along which cities move. This book demonstrates that the concept of 'mobility culture' provides a framework for understanding the development of urban transport which transcends the boundaries between academic disciplines. Based on a discussion of the diversity of megacities worldwide, it provides help in navigating the complexity of megacity mobility culture. Experts from megacities around the world each take the reader on a journey to their own city and its mobility culture, giving a deeper insight into the unique evolutionary paths of mobility that these places have taken, and what lies before them. Whilst acknowledging the overwhelming diversity of cities worldwide, the authors also identify common denominators behind the evolution of urban transport systems - seven temperaments which are found in a unique mix in any given city, defining the character of its mobility culture. The Institute for Mobility Research is a research facility of the BMW Group. It deals with future developments and challenges relating to mobility across all modes of transport, with automobility being only one aspect among many. Taking on an international perspective, ifmo's activities focus on social science and sociopolitical, economic and ecological issues, but also extend to cultural questions related to the key challenges facing the future of mobility. The work of the Institute is supported by an interdisciplinary board of renowned scientists and scholars, and by representatives of BMW, Deutsche Bahn, Lufthansa, MAN, Siemens and The World Bank.

Sustainable energy services to customers - a balanced choice and coordination of energy generated by traditional and alternative sources - are the subject of this new innovative book. The myriad factors involved in modeling an effective sustainable power system are overwhelming. The Green Islands project represents a decade of work by over a dozen researchers who have developed a model designed to utilize the potential of distributed clean resources. The key is the proper use of Information Technology (IT).Sited on two islands in the Azores, the project developed the model of careful forecasting of demand and supply, down to the minute, coordinating the output of conventional power plants, wind energy, fly wheels, hydroelectricity, demand reduction, and even plug-in electric vehicles to take full advantage of the clean resources available. The energy contingencies of the remote islands are not unique. The issues of integrating promising clean technologies, such as wind, into a complex power grid are challenging in geographically far-flung, island-scale, power systems.
Model-based sensing, communications, and decision-making algorithms to coordinate adaptive load management (ALM) could enable customers to utilize just-in-time (JIT), just-in-place (JIP), and just-in-context (JIC) energy resources. The distribution of flexible and efficient energy to customers is the goal. The model the authors have developed could change the way power portfolios are built. A new perspective for optimization of green energy is presented in this book. Additional data provided online via Springer represents a repository of real-world electric energy systems and its IT-enabled smarts."

1. 1. Greenhouse gas emissions and climate change . . . . . . . . . . . . . . 3 1. 1. 1. Emissions and concentrations of greenhouse gases 3 1. 1. 2. Impact of increasing greenhouse gases concentration 4 1. 2. Options to reduce carbon dioxide emissions 5 1. 2. 1. Carbon dioxide removal 8 1. 3. Scope of the thesis 10 1. 4. Outline of the thesis. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 11 1. 4. 1. General evaluation method. . . . . . . . . . . . . . . . . . . . . . . 12 1. 4. 2. Some notes . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 13 II. Simulation and optimization of carbon dioxide recovery from the flue gases of a coal-fired power plant using amines 14 Abstract 19 2. 1. Introduction . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 20 2. 2. The chemical absorption process. . . . . . . . . . . . . . . . . . . . . . . . 22 2. 2. 1. General process description. . . . . . . . . . . . . . . . . . . . . . . 22 2. 2. 2. Types of absorbent 23 2. 2. 3. Effects of flue gas contaminants 24 2. 3. Simulation of the scrubber in ASPEN PLUS . . . . . . . . . . . . . . . . . 25 2. 3. 1. ASPEN PLUS for flow sheet simulation 26 2. 3. 2. Simulation of the performance for the base-case design . . 26 the scrubber . . . . . . . . . . . . . . . . . . . . . . 29 2. 3. 3. Optimization of 2. 3. 4. Design and results 32 2. 3. 5. Discussion. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 34 2. 4. Integration of the scrubber in the power plant 35 2. 4. 1. Power loss caused by steam extraction 36 2. 4. 2. Power saved by avoiding preheating boiler feed water . . . 38 2. 4. 3. Power consumption by the carbon dioxide scrubber . . . . . 38 2. 4. 4. Power consumption for carbon dioxide compression . . . . . 38 2. 4. 5. Calculation of plant efficiency losses " . . . . . . . . . . . . . . 39 2. 5.

This edited monograph collects theoretical, empirical and political contributions from different fields, focusing on the commercial launch of electric mobility, and intending to shed more light on the complexity of supply and demand. It is an ongoing discussion, both in the public as well as in academia, whether or not electric mobility is capable of gaining a considerable market share in the near future. The target audience primarily comprises researchers and practitioners in the field, but the book may also be beneficial for graduate students.

In-depth and systemic examination of distribution automation with specific focus on fault location and service restoration Focuses on the detailed and systemic examination of fault location and service restoration in distribution grid Arms the readers with a complete picture of what fault location and service restoration is from both theoretical and practical perspectives Presents the authors research on fault location and restoration for distribution systems since 1995 Introduces the first-hand application experience obtained from over 30 DAS (Distribution Automation System) projects in China Examines the protection approaches of electrical distribution networks automation and on relevant mechanisms associated to electrical supply restoration after (local) blackouts

The functionalization of surfaces on the nanoscale is one of the most fascinating and at the same time challenging topics in science. It is the key to tailoring catalysts, sensors, or devices for solar energy conversion, whose functional principle is based on the interaction of an active solid surface with another (liquid or gaseous) phase. As an example, planar transition metal complexes adsorbed on solid supports are promising candidates for novel heterogeneous catalysts. An important feature of these catalysts, compared to supported metal clusters, is the fact that the active sites, i. e. , the coordinated metal centers with their vacant axial coordination sites, are well de?ned and uniform. Metalloporphyrinoids are particularly suitable in this respect because they combine a structure forming element-the rigid molecular frame, which often induces long range order-with an active site, the coordinated metal ion. Its planar coordination environment leaves two axial coordination sites available for additional ligands. If adsorbed on a surface, one of these axial sites is occupied by the underlying substrate. The resulting electronic interaction with the surface can be used to tailor the electronic structure and thereby the reactivity of the metal center. The remaining site is free for the attachment of molecules (sensor functionality) and/or operates as a reaction center (single-site catalysis). Prototype examples are omnipresent in nature, where in particular metallo-tetrapyrrols play a decisive role in important biological processes, with the most prominent examples being iron porphyrins in heme, magnesium porphyrins in chlorophyll, and cobalt corrin in vitamin B12.

The liberalization of U.S. and European electric power markets presents a critical challenge for renewable sources of energy. Edinger and Kaul survey the technological state-of-the-art and economic aspects of renewable electricity generation, and outline the role of other renewable sources, such as solar, wind, and micro-hydroelectric technologies. Offering an empirical and theoretical assessment of these technologies and their assets and liabilities, the book shows how it is possible to restructure our electric power systems and reorient them toward sustainable and environmentally friendly alternatives.

International climate conferences such as those in Rio de Janeiro and Kyoto have proclaimed the need for environmentally hospitable technologies. A new electricity system, based on renewable resources and small-scale power technologies, is needed badly; their economics and other efficiencies over conventional central power generation with fossil fuels is clear. Edinger and Kaul assess the rewards and risks associated with renewable technologies and outline a feasible path toward a more environmentally friendly, and reasonable, use of limited natural resources and the global ecosystem. One promising approach for industrialized countries is the decentralization of our current public grid systems. This offers an opportunity for developing countries to leapfrog the stage of fossil fuel, held responsible now for environmental pollution, resource depletion and possibly global climate change. The authors present theoretical analyses and empirical evidence to buttress their contentions, mainly, that electric power systems founded on renewable resources are vital prerequisites if we are to achieve the United Nations' target of globally sustained development.

Formal verification has become one of the most important steps in circuit design. Since circuits can contain several million transistors, verification of such large designs becomes more and more difficult. Pure simulation cannot guarantee the correct behavior and exhaustive simulation is often impossible. However, many designs, like ALUs, have very regular structures that can be easily described at a higher level of abstraction. For example, describing (and verifying) an integer multiplier at the bit-level is very difficult, while the verification becomes easy when the outputs are grouped to build a bit-string. Recently, several approaches for formal circuit verification have been proposed that make use of these regularities. These approaches are based on Word-Level Decision Diagrams (WLDDs) which are graph-based representations of functions (similar to BDDs) that allow for the representation of functions with a Boolean range and an integer domain. Formal Verification of Circuits is devoted to the discussion of recent developments in the field of decision diagram-based formal verification. Firstly, different types of decision diagrams (including WLDDs) are introduced and theoretical properties are discussed that give further insight into the data structure. Secondly, implementation and minimization concepts are presented. Applications to arithmetic circuit verification and verification of designs specified by hardware description languages are described to show how WLDDs work in practice. Formal Verification of Circuits is intended for CAD developers and researchers as well as designers using modern verification tools. It will help people working with formal verification (in industry or academia) to keep informed about recent developments in this area.

In this book, first published in 1965, the authors identify the technological opportunities and costs of water recirculation and water quality adjustment in thermal plants, relating them to the possibilities for minimal expenditure and maximum efficiency in the use of water for servicing an entire region with thermal power. Water Demand for Steam Electric Generation will be of interest to students of environmental studies.

This book covers smart polymer nanocomposites with perspectives for application in energy harvesting, as self-healing materials, or shape memory materials. The book is application-oriented and describes different types of polymer nanocomposites, such as elastomeric composites, thermoplastic composites, or conductive polymer composites. It outlines their potential for applications, which would meet some of the most important challenges nowadays: for harvesting energy, as materials with the capacity to self-heal, or as materials memorizing a given shape.The book brings together these different applications for the first time in one single platform. Chapters are ordered both by the type of composites and by the target applications. Readers will thus find a good overview, facilitating a comparison of the different smart materials and their applications. The book will appeal to scientists in the fields of chemistry, material science and engineering, but also to technologists and physicists, from graduate student level to researcher and professional.

This book thoroughly examines the technical parameters of photovoltaic systems, and appraises their net energy balance from production, operation and maintenance, to recycling. Similar performance and yield analysis is applied to optical, thermal, and electrical parameters and interfaces. Professor Krauter demonstrates how accurate yield calculations, optimal system performance, and new prototypes aid in cost reduction. Examples, tables and figures are included.

The rapidly growing photovoltaic industry is expanding the need for education and training worldwide, particularly at the system level. Modelling Photovoltaic Systems using PSpice provides expert help in understanding photovoltaic systems engineering and system design. Working with PSpice, the most popular standard for analogue and mixed signal simulation, the book allows detailed and quantitative analysis of design concepts, criteria and results.

Featuring:

• Both topological and behavioural models for the key components helping short- and long-term simulation.

• A model to compute the Loss of Load probability, considering year long daily radiation data.

• Sizing procedures for stand-alone and grid connected systems, based on energy balance and long-term simulations.

• Models for PV generators, batteries, converters and inverters.

• Coverage of numerous topics related to small PV systems, such as artificial light response, random irradiance and illuminance conditions

• A comprehensive range of solved examples

This monograph focuses on the dynamical research work on crank-piston mechanisms considering basic and additional motions. In order to have full dynamical analyses of piston machines and their mechanisms, the book studies the crank-piston mechanisms with clearances in kinematic pairs. The tasks are carried out by focusing on friction, wear and impacts in mechanisms, as well as cracks formation in links and elasticity of details, with distributed and concentrated masses. Then, the reliability and durability of the mechanisms of piston machines is applied on oil and gas transportation. The monograph is meant for design specialists. It is also useful for specialists-manufacturers and designers of piston machines, scientists and lecturers, doctoral students.

Maximizing reader insights into the challenges facing maritime supply chains and container port logistics service providers in Asia, this book highlights their innovative responses to these challenges through real-world case studies. With a focus on mathematical modeling, simulation and heuristics approaches, this book provides academics, engineers, container terminal operators, students in logistics and supply chain management with the latest approaches that can be used to address the planning and scheduling problem in large container terminal yards. This book can be used on a self-contained basis as teaching cases in an undergraduate or specialist class setting, or on techniques applied to maritime container operations for port operations.

High quality electrical service is key to power systems around the world, particularly in utilities and industrial facilities. Both voltage and grid frequency must be kept within tight limits to maintain functioning of critical infrastructure. The growing use of renewable power of intermittent character is adding to that challenge. One of the keys to achieving quality service is the protection system, which needs to be reliable, fast and with a good cost/benefit ratio. It consists of various components, including relays, circuit breakers and fuses. An understanding of the different behaviours of these components in the face of malfunctions, and of countermeasures, is needed. This book has established itself as a classic work in its field, allowing the reader to easily follow the ideas explored. It provides an overview of most aspects of electrical protections, with emphasis on distribution systems; but protection of generation and transmission systems are also addressed. For this 4th edition, new topics have been added, such as protection of renewable power plants and transient stability analysis. It offers a thorough revision of the material, particularly the numerical type of relays, protective functions, control, measurement, communications and oscillography features. Most chapters have illustrative examples using MATLAB or PSAT (Power System Analysis Tools). This work remains essential reading for researchers, utility engineers, design, maintenance and consulting engineers as well as for instructors and senior students.

This volume contains papers presented at the International conference "The Aerodynamics of Heavy Vehicles III: Trucks, Buses and Trains" held in Potsdam, Germany, September 12-17, 2010 by Engineering Conferences International (ECI). Leading scientists and engineers from industry, universities and research laboratories, including truck and high-speed train manufacturers and operators were brought together to discuss computer simulation and experimental techniques to be applied for the design of more efficient trucks, buses and high-speed trains in the future. This conference was the third in the series after Monterey-Pacific Groove in 2002 and Lake Tahoe in 2007.The presentations address different aspects of train aerodynamics (cross wind effects, underbody flow, tunnel aerodynamics and aeroacoustics, experimental techniques), truck aerodynamics (drag reduction, flow control, experimental and computational techniques) as well as computational fluid dynamics and bluff body, wake and jet flows.

The accumulation of large amounts of ash from fossil fuel combustion for electric power plant generation is becoming a major environmental concern in the United States. Furthermore, stringent environmental regulations mandated by the Environmental Protection Agency through the Clean Air Act, Clean Water Act, Resource Conservation and Recovery Act, as well as state and local environmental regulations may result in even more ash production with subsequent contact with the environment. The concentrations of trace elements in coal residues are extremely variable and depend on the composition of the original coal, conditions during combustion, the efficiency of emission control devices, storage and handling ofbyproducts, and climate. The research papers in this book were presented as a part of the Sixth International Conference on the Biogeochemistry of Trace Elements held at the University of Guelph, Ontario, Canada, from July 29-August 2, 2001. The purpose of this corit'erence was to present current knowledge on the source, pathways, behavior and effects of trace elements in soils, waters, plants and animals. In addition, the book also includes invited research papers from scientists who have done significant research in the area of coal and coal combustion byproducts. All the research papers presented herein have been subjected to peer review.

This book deals in a basic and systematic manner with the fundamentals of random function theory and looks at some aspects related to arrival, vehicle headway and operational speed processes at the same time. The work serves as a useful practical and educational tool and aims at providing stimulus and motivation to investigate issues of such a strong applicative interest. It has a clearly discursive and concise structure, in which numerical examples are given to clarify the applications of the suggested theoretical model. Some statistical characterizations are fully developed in order to illustrate the peculiarities of specific modeling approaches; finally, there is a useful bibliography for in-depth thematic analysis.

An invaluable academic reference for the area of high-power converters, covering all the latest developments in the field High-power multilevel converters are well known in industry and academia as one of the preferred choices for efficient power conversion. Over the past decade, several power converters have been developed and commercialized in the form of standard and customized products that power a wide range of industrial applications. Currently, the modular multilevel converter is a fast-growing technology and has received wide acceptance from both industry and academia. Providing adequate technical background for graduate- and undergraduate-level teaching, this book includes a comprehensive analysis of the conventional and advanced modular multilevel converters employed in motor drives, HVDC systems, and power quality improvement. Modular Multilevel Converters: Analysis, Control, and Applications provides an overview of high-power converters, reference frame theory, classical control methods, pulse width modulation schemes, advanced model predictive control methods, modeling of ac drives, advanced drive control schemes, modeling and control of HVDC systems, active and reactive power control, power quality problems, reactive power, harmonics and unbalance compensation, modeling and control of static synchronous compensators (STATCOM) and unified power quality compensators. Furthermore, this book: Explores technical challenges, modeling, and control of various modular multilevel converters in a wide range of applications such as transformer and transformerless motor drives, high voltage direct current transmission systems, and power quality improvement Reflects the latest developments in high-power converters in medium-voltage motor drive systems Offers design guidance with tables, charts graphs, and MATLAB simulations Modular Multilevel Converters: Analysis, Control, and Applications is a valuable reference book for academic researchers, practicing engineers, and other professionals in the field of high power converters. It also serves well as a textbook for graduate-level students.

A comprehensive approach to Wind Turbine Generator Systems (WTGS) and their operation in dynamic electric power system analysis. The presented advanced models arose from the author's research. They describe the complicated dynamical system behavior of wind turbines much better than the over-simplified static models. In particular, the control structure is taken into account. This book provides advanced tools for design, projection and optimization of turbines and systems that have yet not been available.

Features * Offers a hands-on tutorial on interactive dynamic-system modeling and simulation * Includes examples from physics, aerospace engineering, population dynamics, and physiology * Contains hints for selecting integration rules and step size * Provides a complete, industrial-strength simulation program package on an accompanying CD-ROM New to This Edition * Introduces a new vectorizing compiler for fast vector operations and parameter-influence studies * Incorporates a new treatment of the difference equation programs for modeling sampled-data control systems with digital controllers * Presents improved versions of several classical simulation programs to illustrate useful programming tricks Summary Showing you how to use personal computers for modeling and simulation, Interactive Dynamic-System Simulation, Second Edition provides a practical tutorial on interactive dynamic-system modeling and simulation. It discusses how to effectively simulate dynamical systems, such as aerospace vehicles, power plants, chemical processes, control systems, and physiological systems. Written by a pioneer in simulation, the book introduces dynamic-system models and explains how software for solving differential equations works. After demonstrating real simulation programs with simple examples, the author integrates a new treatment of the difference equation programs needed to model sampled-data control systems with digital controllers. Subsequent chapters provide detailed programming know-how. These chapters cover library, table-lookup, user-definable, limiter, switching, and noise functions; an experiment-protocol scripting language; powerful vector and matrix operations; and classical simulation programs that illustrate a number of useful programming tricks. The final chapter shows how experiment-protocol scripts and compiled DYNAMIC program segments can quickly solve mathematical problems, including fast graph plotting, Fourier transforms

A COMPREHENSIVE REFERENCE TO THE MOST RECENT ADVANCEMENTS IN OFFSHORE WIND TECHNOLOGY Offshore Wind Energy Technology offers a reference based on the research material developed by the acclaimed Norwegian Research Centre for Offshore Wind Technology (NOWITECH) and material developed by the expert authors over the last 20 years. This comprehensive text covers critical topics such as wind energy conversion systems technology, control systems, grid connection and system integration, and novel structures including bottom-fixed and floating. The text also reviews the most current operation and maintenance strategies as well as technologies and design tools for novel offshore wind energy concepts. The text contains a wealth of mathematical derivations, tables, graphs, worked examples, and illustrative case studies. Authoritative and accessible, Offshore Wind Energy Technology: Contains coverage of electricity markets for offshore wind energy and then discusses the challenges posed by the cost and limited opportunities Discusses novel offshore wind turbine structures and floaters Features an analysis of the stochastic dynamics of offshore/marine structures Describes the logistics of planning, designing, building, and connecting an offshore wind farm Written for students and professionals in the field, Offshore Wind Energy Technology is a definitive resource that reviews all facets of offshore wind energy technology and grid connection.

This thesis proposes a new raft-type wave-powered desalination device that can convert wave power into hydraulic energy and use reverse osmosis (RO) to directly desalinate seawater. Both analytical and numerical methods are used to study the hydrodynamic characteristics of the device. Further, the thesis investigates the maximum power extraction and multiple parameter effects on power absorption and averaged permeate water flux. Lastly, it proposes and assesses two power extraction enhancing strategies. The thesis offers a valuable and important reference guide to ocean-wave-and-structure interaction and wave-powered seawater desalination for scientists and engineers alike.