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Books > Science & Mathematics > Chemistry > Analytical chemistry > General
Low Grade Heat Driven Multi-effect Distillation and Desalination describes the development of advanced multi-effect evaporation technologies that are driven by low grade sensible heat, including process waste heat in refineries, heat rejection from diesel generators or microturbines, and solar and geothermal energy. The technologies discussed can be applied to desalination in remote areas, purifying produced water in oil-and-gas industries, and to re-concentrate process liquor in refineries. This book is ideal for researchers, engineering scientists, graduate students, and industrial practitioners working in the desalination, petrochemical, and mineral refining sectors, helping them further understand the technologies and opportunities that relate to their respective industries. For researchers and graduate students, the core enabling ideas in the book will provide insights and open up new horizons in thermal engineering.
This book presents fundamental experimental data and experiment-based theoretical conclusions on, as well as physico-chemical models of, the natural hydrothermal, metasomatic, metamorphic, magmatic and ore-producing processes in the Earth's crust, upper mantle, transition zone and lower mantle. The topics discussed concern the interactions of oil and aqueous fluids as revealed by aqueous-hydrocarbonic inclusions in synthetic quartz and applied to the natural evolution of oil; determining the solubility and inter-phase partitioning of trace and strategic elements and their components; and experimentally validating physico-chemical mechanisms in the ultrabasic-basic evolution of deep-mantle magmatic and diamond-forming systems. In addition, the book presents experimental studies on the physico-chemical properties of supercritical water and hydrothermal fluids, viscosity of acidic ultramafic magmatic materials melts, peculiarities of metamorphism in basic rocks, kinetics of mineral nucleation in silicate melts and hydrothermal solutions, and influence of complex H2O-CO2-HCl fluids on melting relations in mantle-crust rocks, together with novel results and conclusions. Given its scope, the book will be of great interest to all Earth scientists, lecturers and students specialized in experimental and genetic mineralogy, petrology and geochemistry.
Nonlinear Optics and Collective Excitations; N. Bloembergen. Fundamentals of Spectroscopy of Collective Excitations in Solids; B. Di Bartolo. Light-Matter Interaction: Experimental Aspects; C. Klingshirn. Theoretical Description of Collective Excitations: Bloch Equations and Relaxation Mechanisms; R. Zimmerman. Linear and Nonlinear Optical Spectroscopy: Spectral, Temporal and Spatial Resolution; J.M. Hvam. The Study of Collective Excitations in Solids by Inelastic Neutron Scattering: T. Riste. Excitation Dynamics in Organic Molecules, Solids, Fullerenes, and Polymers; P. Prasad. The IR Vibrational Properties of Composite Solids and Particles: The Lyddane-Sachs-Teller Relation Revisited; A.J. Sievers. Intrinsic Localized Modes in Anharmonic Lattices; A.J. Sievers, et al. Plasmons and Surface Plasmons in Bulk Metals, Metallic Clusters, and Metallic Heterostructures; R.V. Baltz. Enlightenment of Luminescent Materials; C.R. Ronda. Spectroscopy and Development of Solid Sate Layers at NASA; N.P. Barnes. Optical Excitation and Relaxation of Solids with Defects; B. Baldacchini. Newly Developed Solid State Lasers; R. Reisfeld. Energy Transfer and Migration of Excitation in Solids and Confined Structures; F. Auzel. 45 Additional Articles. Index.
This 8-volume set provides a systematic description on 8,350 active marine natural products from 3,025 various kinds of marine organisms. The diversity of structures, biological resources and pharmacological activities are discussed in detail. Molecular structural classification system with 264 structural types are developed. The 4th volume continuously illustrates the molecular formula and structures of alkaloids.
This book aims to give state of the art in several domains of cultural heritage in which Nanosciences allow fundamental breakthrough. The first part of the book concerns nanostructured materials in ancient artifacts. Understanding their nature and formation processes bring new insight in the apprehension of technical level of ancient societies but can also inspire the design of new materials. The second part is dedicated to the understanding of materials. This crucial issue in material science today, for cultural heritage, needs to perform specific characterization techniques and technologies, but also to create tailored analytical strategies. Part three presents new methods, processes and materials at nano levels that can bring innovative solutions to conservation and restoration issues, linked with the understanding of the alteration processes involved at different scales.
This volume offers up-to-date and comprehensive information on various aspects of the Nile River, which is the main source of water in Egypt. The respective chapters examine the Nile journey; the Aswan High Dam Reservoir; morphology and sediment quality of the Nile; threats to biodiversity; fish and fisheries; rain-fed agriculture, rainfall data, and fluctuations in rainfall; the impact of climate change; and hydropolitics and legal aspects. The book closes with a concise summary of the conclusions and recommendations provided in the preceding chapters, and discusses the requirements for the sustainable development of the Nile River and potential ways to transform conflicts into cooperation. Accordingly, it offers an invaluable source of information for researchers, graduate students and policymakers alike.
The indiscriminate use of medications and their inadequate disposal have resulted in them being released into the environment via municipal, hospital and industrial discharges. This volume critically examines the presence of pharmaceuticals in aquatic ecosystems, the hazards they entail, and how to minimize their impact on the environment. The topics covered include: historical findings that have made the development of the discipline ecopharmacovigilance possible; the main exposure routes, fate and life cycle of pharmaceuticals in water; occurrence data and the impact on biodiversity; methods used for the detection, analysis and quantification of pharmaceuticals in water and for their removal; current legislation on the presence of emerging contaminants in water; biosensors for environmental analysis and monitoring; and the measures needed to reduce the existing problems. This book is aimed at students, academics and research workers in the fields of toxicology, ecology, microbiology and chemistry, as well as those in the pharmaceutical industry, health sector professionals, and members of government bodies involved in environmental protection and legislation. Industrial: Industrial Protein Xray Crystallography: An Overview (J.D. Oliver) Recent Advances in the Use of Synchrotron Radiation for Protein Crystallography (R. Sweet). The Crystal Structures of Some New Forms of Aluminum Fluoride as Determined from Their Synchrotron Powder Diffraction Patterns (R.L. Harlow et al.). Synchrotron Radiationbased Research at the Dow Chemical Company (R.A. Bubeck et al.). Chemical: The Chemical Dynamics Beamline at the Advanced Light Source (A.G. Suits et al.). High Resolution Photoionization and Excitation Using Third Generation Radiation Sources (N. Berrah et al.). Recent Advances toward a Structural Model for the Photosynthetic Oxygenevolving Manganes Cluster (M.J. Latimer et al.). Cesium XAFS Studies of Solution Phase Csionophore Complexation (K.M. Kemner et al.). Materials Science: Studies of Magnetic Material with Circular Polarized Soft Xrays (V. Chakarian et al.). Resonant Photoemission in Polymers (J. Kikuma et al.). Characterization of the Complexation of Uranyl Ions with Humic Acids by Xray Absorption Spectroscopy (T. Reich et al.). Spectroscopic Studies of Lanthanide Coordination in Crystalline and Amorphous Phosphates (L.R. Morss et al.). 5 additional articles. Index.
The fundamentals of the discipline, now complete with the latest experimental research and techniques Factor analysis is a mathematical tool for examining a wide range of data sets, with applications especially important to the design of experiments (DOE), spectroscopy, chromatography, and chemometrics. Whereas the first two editions concentrated on standardizing the fundamentals of this emerging discipline, the Third Edition of Factor Analysis in Chemistry, the "bible" of factor analysis, proves a comprehensive handbook at a level that is consistent with the research and design of experiments today. With the exception of updates, the introductory chapters remain unchanged. Chapter 6 has been edited to focus on evolutionary methods, including window factor analysis, transmutation, and DECRA. Selections on partial least squares and multimode analysis have been expanded and consolidated into two new chapters, 7 and 8. Some of the latest advances in a wide variety of fields, such as chromatography, NMR, biomedicine, environmental science, food, and fuels, are described in the applications chapters (chapters 9 through 12). Other features of the text include:
Factor Analysis in Chemistry, Third Edition remains the premier reference in its field.
This volume provides a comprehensive overview of advanced research in the field of efficient, clean and renewable energy production, conversion and storage. The ten chapters, written by internationally respected experts, address the following topics: (1) solar and wind energy; (2) energy storage in batteries; (3) biomass; and (4) socio-economic aspects of energy. Given its multidisciplinary approach, which combines environmental analysis and an engineering perspective, the book offers a valuable resource for all researchers and students interested in environmentally sustainable energy production, conversion, storage and its engineering.
High-pressure Molecular Spectroscopy describes examples of the applications of several spectroscopic methods to investigate the behavior of various chemical systems under high pressures, including guest-host interactions, chemical reactions, molecule-based multiferroics, lanthanide ion-doped glasses, and organic, inorganic and organometallic materials. The techniques involved include: Luminescence studies Inelastic neutron scattering Infrared and Raman studies Synchrotron X-ray diffraction
This thesis describes novel substrate embedded physical sensors that can be used to monitor different types of cell-based assays non-invasively and label-free. The sensors described provide integrative information of the cells under study with an adaptable time resolution (ranging from milliseconds to days). This information about the dynamic cell response to chemical, physical or biological stimuli defines a new paradigm in fundamental biomedical research. The author, Maximilian Oberleitner, describes approaches in which the cells are directly grown on different sensor surfaces (gold-film electrodes, shear wave resonators or dye-doped polymer films). This approach, with the reacting cells in particularly close proximity and contact with the sensor surface, is key to a remarkable sensitivity, opening the way for a variety of new applications. This thesis not only introduces the fundamentals of each approach, but it also describes in great detail the design principles and elucidates the boundary conditions of the new sensors.
The thesis provides the necessary experimental and analytical tools to unambiguously observe the atomically resolved chemical reactions. A great challenge of modern science has been to directly observe atomic motions during structural transitions, and while this was first achieved through a major advance in electron source brightness, the information content was still limited and new methods for image reconstruction using femtosecond electron diffraction methods were needed. One particular challenge lay in reconciling the innumerable possible nuclear configurations with the observation of chemical reaction mechanisms that reproducibly give the same kind of chemistry for large classes of molecules. The author shows that there is a simple solution that occurs during barrier crossing in which the highly anharmonic potential at that point in nuclear rearrangements couples high- and low-frequency vibrational modes to give highly localized nuclear motions, reducing hundreds of potential degrees of freedom to just a few key modes. Specific examples are given in this thesis, including two photoinduced phase transitions in an organic system, a ring closure reaction, and two direct observations of nuclear reorganization driven by spin transitions. The emerging field of structural dynamics promises to change the way we think about the physics of chemistry and this thesis provides tools to make it happen.
This volume summarises recent developments and highlights new techniques which will define possible future directions for small molecule X-ray crystallography. It provides an insight into how specific aspects of crystallography are developing and shows how they may interact or integrate with other areas of science. The development of more sophisticated equipment and the massive rise in computing power has made it possible to solve the three-dimensional structure of an organic molecule within hours if not minutes. This successful trajectory has resulted in the ability to study ever more complex molecules and use smaller and smaller crystals. The structural parameters for over a million organic and organometallic compounds are now archived in the most commonly used database and this wealth of information creates a new set of problems for future generations of scientists. The volume provides some insight into how users of crystallographic structural data banks can navigate their way through a world where "big data" has become the norm. The coupling of crystallography to quantum chemical calculations provides detailed information about electron distributions in crystals affording a much more detailed analysis of bonding than has been possible previously. In quantum crystallography, quantum mechanical wavefunctions are used to extract information about bonding and properties from the measured X-ray structure factors. The advent of quantum crystallography has resulted in form and structure factors derived from quantum mechanics which have been used in advanced refinement and wavefunction fitting. This volume describes how quantum mechanically derived atomic form factors and structure factors are constructed to allow the improved description of the diffraction experiment. It further discusses recent developments in this field and illustrates their applications with a wide range of examples. This volume will be of interest to chemists and crystallographers with an interest in the synthesis, characterisation and physical and catalytic properties of solid-state materials. It will also be relevant for the community of computational chemists who study chemical systems. Postgraduate students entering the field will benefit from a historical introduction to the way in which scientists have used the data derived from crystallography to develop new structural and bonding models.
A recipient of the PROSE 2017 Honorable Mention in Chemistry & Physics, Radioactivity: Introduction and History, From the Quantum to Quarks, Second Edition provides a greatly expanded overview of radioactivity from natural and artificial sources on earth, radiation of cosmic origins, and an introduction to the atom and its nucleus. The book also includes historical accounts of the lives, works, and major achievements of many famous pioneers and Nobel Laureates from 1895 to the present. These leaders in the field have contributed to our knowledge of the science of the atom, its nucleus, nuclear decay, and subatomic particles that are part of our current knowledge of the structure of matter, including the role of quarks, leptons, and the bosons (force carriers). Users will find a completely revised and greatly expanded text that includes all new material that further describes the significant historical events on the topic dating from the 1950s to the present.
In the recent past quantitative chemical analysis textbook writers included selected experiments to complete and complement the text and thus give instructors a choice to select the experiments to be performed by students in quantitative analysis course. On the other hand, this is not so for courses in instrumental analysis which is a sequential course to quantitative analysis. This is, perhaps, due to the numerous instrumental techniques that have been developed over the years for chemical analysis. In its stead, textbooks on experiments in instrumental analysis are common, and these are as diversified as the topics covered in lecture courses. Most of the experimental topics covered, especially, in quantitative analysis, lean heavily on determination of materials or compounds of inorganic chemistry origin. This seems to be the tradition with only a few exceptions. However, recently, textbooks on quantitative analysis have emerged and continue to emerge, without any experimental section. This is not quite surprising though, since many instructors nowadays, tend to design their own experiments to suit and complement their lecture materials. On the other hand, the trend in the production of books on instrumental analysis experiments has remained the same. The objective of this book is therefore two fold. One is to design a reasonably comprehensive laboratory text that embodies both areas of analytical chemistry. The other is to shy away from the tradition of making quantitative analysis experiments lean too heavily on inorganic materials. To this end, several topics ranging from inorganic to organic materials are included in this laboratory text book. A new element is also introduced inthis book. That is, students are exposed throughout the book to the analysis of compounds of pharmaceutical relevance.
This book explains how the partial differential equations (pdes) in electroanalytical chemistry can be solved numerically. It guides the reader through the topic in a very didactic way, by first introducing and discussing the basic equations along with some model systems as test cases systematically. Then it outlines basic numerical approximations for derivatives and techniques for the numerical solution of ordinary differential equations. Finally, more complicated methods for approaching the pdes are derived. The authors describe major implicit methods in detail and show how to handle homogeneous chemical reactions, even including coupled and nonlinear cases. On this basis, more advanced techniques are briefly sketched and some of the commercially available programs are discussed. In this way the reader is systematically guided and can learn the tools for approaching his own electrochemical simulation problems. This new fourth edition has been carefully revised, updated and extended compared to the previous edition (Lecture Notes in Physics Vol. 666). It contains new material describing migration effects, as well as arrays of ultramicroelectrodes. It is thus the most comprehensive and didactic introduction to the topic of electrochemical simulation.
This book focuses on scientific and technological aspects of groundwater-resources assessment and surveillance. It describes relevant risks and investigates selected techniques for the monitoring and mitigation of the individuated threats to groundwater quality. The authors discuss the concepts of groundwater-resources protection and offer examples of both geogenic and anthropogenic degradation of groundwater quality, such as heavy metals from mining activities and natural water-rock interactions, as well as risk of contamination due to geological CO2 storage practices etc. The volume also covers non-invasive monitoring techniques and briefly addresses innovative sensor technologies for the online assessment of water quality. Furthermore, the role played by geochemical techniques, the potential of environmental isotopes and the support provided by physical modelling are highlighted. The chapters guide the reader through various viewpoints, according to the diverse disciplines involved, without aiming to be exhaustive, but instead picking representative topics for their relevance in the context of groundwater protection and control. This book will be of interest to advanced students, researchers, policy-makers and stakeholders at various levels.
This book presents quality technical papers representing the recent developments in the field of hydrological modeling, water management and water governance including practical applications. The content covers multifarious aspects of hydrology and water resources. It includes an application of the Hydrologic Modelling System (HEC-HMS) which has been successfully demonstrated for assessment of floods. The authors suggest an approach for the mitigation of cyclone disaster through a case study of the Phailin cyclone, whilst considering mitigating pluvial flooding, developing suitable management strategies. The book includes chapters discussing the detrended fluctuation analysis which is carried out for multifractal description of droughts. Drought characteristics are analyzed, and drought indices evolved for drought preparedness/management. The use of science in community planning under changing climate is also studied and discussed. The authors present and experimental study wherein hydraulic coefficients are calibrated by using vertical orifice. A cross flow hybrid hydrokinetic turbine is also evaluated for performance, and high head regulating radial gate designed and studied its sensitivity. This book will appeal to researchers, field practitioners, NGO and other Governmental as well as private water practitioners
Interdisciplinary knowledge is becoming more and more important to the modern scientist. This invaluable textbook covers bioanalytical chemistry (mainly the analysis of proteins and DNA) and explains everything for the nonbiologist. Electrophoresis, mass spectrometry, biosensors, bioassays, DNA and protein sequencing are not necessarily all included in conventional analytical chemistry textbooks. The book describes the basic principles and the applications of instrumental and molecular methods. It is particularly useful to chemistry and engineering students who already have some basic knowledge about analytical chemistry.
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