X-ray Absorption Spectroscopy (XAS) is a powerful technique with which to probe the properties of matter, equally applicable to the solid, liquid and gas phases. Semiconductors are arguably our most technologically-relevant group of materials given they form the basis of the electronic and photonic devices that now so widely permeate almost every aspect of our society. The most effective utilisation of these materials today and tomorrow necessitates a detailed knowledge of their structural and vibrational properties. Through a series of comprehensive reviews, this book demonstrates the versatility of XAS for semiconductor materials analysis and presents important research activities in this ever growing field. A short introduction of the technique, aimed primarily at XAS newcomers, is followed by twenty independent chapters dedicated to distinct groups of materials. Topics span dopants in crystalline semiconductors and disorder in amorphous semiconductors to alloys and nanometric material as well as in-situ measurements of the effects of temperature and pressure. Summarizing research in their respective fields, the authors highlight important experimental findings and demonstrate the capabilities and applications of the XAS technique. This book provides a comprehensive review and valuable reference guide for both XAS newcomers and experts involved in semiconductor materials research.

This handbook presents electronic structure data and tabulations of Slater-Koster parameters for the whole periodic table. This second edition presents data sets for all elements up to Z = 112, Copernicium, whereas the first edition contained only 53 elements.

In this new edition, results are given for the equation of state of the elements together with the parameters of a Birch fit, so that the reader can regenerate the results and derive additional information, such as Pressure-Volume relations and variation of Bulk Modulus with Pressure. For each element, in addition to the equation of state, the energy bands, densities of states and a set of tight-binding parameters is provided.

For a majority of elements, the tight-binding parameters are presented for both a two- and three-center approximation. For the hcp structure, new three-center tight-binding results are given. Other new material in this edition include: energy bands and densities of states of all rare-earth metals, a discussion of the McMillan-Gaspari-Gyorffy theories and a tabulation of the electron-ion interaction matrix elements. The evaluation of the Stoner criterion for ferromagnetism is examined and results are tabulated. This edition also contains two new appendices discussing the effects of spin-orbit interaction and a modified version of Harrison's tight-binding theory for metals which puts the theory on a quantitative basis.

This book presents an Ultrafast Low-Energy Electron Diffraction (ULEED) system that reveals ultrafast structural changes on the atomic scale. The achievable temporal resolution in the low-energy regime is improved by several orders of magnitude and has enabled the melting of a highly-sensitive, molecularly thin layer of a polymer crystal to be resolved for the first time. This new experimental approach permits time-resolved structural investigations of systems that were previously partially or totally inaccessible, including surfaces, interfaces and atomically thin films. It will be of fundamental importance for understanding the properties of nanomaterials so as to tailor their properties.

This book represents volume 2 of a 3-volume monograph on Particle Penetration and Radiation Effects. While volume 1 addressed the basic theory of scattering and stopping of swift point charges, i.e., protons, antiprotons and alpha particles, the present volume focuses on ions heavier than helium as well as molecules and clusters over an energy range from a few keV/u to a few hundred MeV/u. The book addresses the foundations in atomic-collision physics of a wide variety of application areas within materials and surface science and engineering, micro and nano science and technology, radiation medicine and biology as well as nuclear and particle physics. Problems have been added to all chapters. This should make the book useful for both self-study and advanced university courses. An effort has been made to establish a unified notation throughout the monograph.

Many and ever more mobile users wish to enjoy a variety of multimedia services, in very diverse geographical environments. The growing number of communication options within and across wireless standards is accommodating the growing volume and heterogeneity in wireless wishes. On the other hand, advancement in radio technologies opening much more flexibility, a.o. through Software Defined Radios, opens up the possibility to realize mobile devices featuring multi-mode options at low cost and interesting form factors.

It is crucial to manage the new degrees of freedom opened up in radios and standards in a smart way, such that the required service is offered at satisfactory quality as efficiently as possible. Efficiency in energy consumption is clearly primordial for battery powered mobile terminals specifically, and in the context of growing ecological concerns in a broader context. Moreover, efficient usage of the spectrum is a growing prerequisite for wireless systems, and coexistence of different standards puts overall throughput at risk.

The management of flexibility risks bringing about intolerable complexity and hamper the desired agility. A systematic approach, consisting of anticipative preparing for smooth operation, allows mastering this challenge. Case studies show that already today, this approach enables smart operation of radios realizing impressive efficiency gains without hampering Quality-of-Service. In the future wireless communication scenes will be able to profit form the opening of the spectrum. Even smarter and cognitive behavior will become possible and essential.

This book mainly focuses on the study of the high-temperature superconductor Bi2Sr2CaCu2O8 by vacuum, ultra-violet, laser-based, angle-resolved photoemission spectroscopy (ARPES). A new form of electron coupling has been identified in Bi2212, which occurs in the superconducting state. For the first time, the Bogoliubov quasiparticle dispersion with a clear band back-bending has been observed with two peaks in the momentum distribution curve in the superconducting state at a low temperature. Readers will find useful information about the technique of angle-resolved photoemission and the study of high-temperature superconductors using this technique. Dr. Wentao Zhang received his PhD from the Institute of Physics at the Chinese Academy of Sciences.

Nuclear Magnetic Resonance Spectroscopy (NMR) is now widely regarded as having evolved into a subscience. The field has become immensely diverse, ranging from medical use through solid state NMR to liquid state applications, with countless books and scientific journals devoted to these topics. Theoretical as well as experimental advance continues to be rapid, and has in fact accelerated by many novel innovations. This multi-authored book focuses on the latest developments in the rapidly evolving field of high resolution NMR, specifically with a view to applications on the structure elucidation of organic molecules of moderate molecular weight. Conceptually it differs from basic educational texts, hard-core scientific papers and regular review articles in that each chapter may be regarded as the authors' personal account of their special insights and results that crystallised after several years of research into a given topic. The book revolves around several themes and offers a handful of scientific "gems" of various colors, reflecting the great diversity of NMR. It contains 16 loosely connected chapters written by some of today's most accomplished NMR scientists in the world. Each chapter is a unique synthesis of the authors' previous research results in the given field, and thus projects special insights. Much emphasis has been given to the latest developments in NMR, in particular to selective pulses and pulsed field gradients. As a part of the series "Analytical Spectroscopy Library," with subsequent editions coming along this book should provide a platform for future research accounts of similar flavor. The material is presented in a mostly non-mathematical fashion, and is intended mainly for chemists, application NMR scientists and students with already some background in NMR. Some of the chapters slightly overlap in the discussed topics, which is particularly exciting in terms of gaining insight into the same area from different angles.

This thesis describes a proof-of-principle experiment demonstrating a technique for stable isotope enrichment called Magnetically Activated and Guided Isotope Separation (MAGIS). Over the past century many enriched isotopes have become available, thanks largely to electromagnetic separators called calutrons. Due to substantial maintenance and operating costs, the United States decommissioned the last of its calutrons in 1998, leading to demand for alternative methods of isotope separation. The work presented here suggests the promise for MAGIS as a viable alternative to the calutrons.The MAGIS technique combines optical pumping with a scalable magnetic field gradient to enrich atoms of a specific isotope in an atomic beam. Benchmarking this work against the calutron using lithium as a test case, the author demonstrated comparable enrichment in a manner that should scale to the production of similar quantities, while requiring vastly less energy input.

Structure and Dynamics of Macromolecules: Absorption and Fluorescence Studies is clearly written and contains invaluable examples, coupled with illustrations that demonstrate a comprehensible analysis and presentation of the data. This book offers practical information on the fundamentals of absorption and fluorescence, showing that it is possible to interpret the same result in different ways. It is an asset to students, professors and researchers wishing to discover or use absorption and fluorescence spectroscopy, and to scientists working on the structure and dynamics of macromolecules.
* Offers concise information on the fundamentals of absorption and fluorescence
* Critically reviews examples taken from previously published literature
* Highly illustrated, it is suitable for academic and institutional libraries and government laboratories

This thesis combines quantum electrical engineering with electron spin resonance, with an emphasis on unraveling emerging collective spin phenomena. The presented experiments, with first demonstrations of the cavity protection effect, spectral hole burning and bistability in microwave photonics, cover new ground in the field of hybrid quantum systems. The thesis starts at a basic level, explaining the nature of collective effects in great detail. It develops the concept of Dicke states spin-by-spin, and introduces it to circuit quantum electrodynamics (QED), applying it to a strongly coupled hybrid quantum system studied in a broad regime of several different scenarios. It also provides experimental demonstrations including strong coupling, Rabi oscillations, nonlinear dynamics, the cavity protection effect, spectral hole burning, amplitude bistability and spin echo spectroscopy.

Laser induced breakdown spectroscopy (LIBS) is basically an emission spectroscopy technique where atoms and ions are primarily formed in their excited states as a result of interaction between a tightly focused laser beam and the material sample. The interaction between matter and high-density photons generates a plasma plume, which evolves with time and may eventually acquire thermodynamic equilibrium. One of the important features of this technique is that it does not require any sample preparation, unlike conventional spectroscopic analytical techniques. Samples in the form of solids, liquids, gels, gases, plasmas and biological materials (like teeth, leaf or blood) can be studied with almost equal ease. LIBS has rapidly developed into a major analytical technology with the capability of detecting all chemical elements in a sample, of real- time response, and of close-contact or stand-off analysis of targets. The present book has been written by active specialists in this field, it includes the basic principles, the latest developments in instrumentation and the applications of LIBS . It will be useful to analytical chemists and spectroscopists as an important source of information and also to graduate students and researchers engaged in the fields of combustion, environmental science, and planetary and space exploration.
* Recent research work
* Possible future applications
* LIBS Principles

Solid-State spectroscopy is a burgeoning field with applications in many branches of science, including physics, chemistry, biosciences, surface science, and materials science. Handbook of Applied Solid-State Spectroscopy brings together in one volume information about various spectroscopic techniques that is currently scattered in the literature of these disciplines. This concise yet comprehensive volume covers theory and applications of a broad range of spectroscopies, including NMR, NQR, EPR/ESR, ENDOR, scanning tunneling, acoustic resonance, FTIR, auger electron emission, x-ray photoelectron emission, luminescence, and optical polarization, and more. Emphasis is placed on fundamentals and current methods and procedures, together with the latest applications and developments in the field.

This edition contains carefully selected contributions by leading scientists in high-resolution laser spectroscopy, quantum optics and laser physics. Emphasis is given to ultrafast laser phenomena, implementations of frequency combs, precision spectroscopy and high resolution metrology. Furthermore, applications of the fundamentals of quantum mechanics are widely covered. This book is dedicated to Nobel prize winner Theodor W. Hansch on the occasion of his 75th birthday. The contributions are reprinted from a topical collection published in Applied Physics B, 2016. Selected contributions are available open access under a CC BY 4.0 license via link.springer.com. Please see the copyright page for further details.

The detection of hidden explosives has become an issue of utmost importance in recent years. While terrorism is not new to the international community, recent terrorist attacks have raised the issue of detection of explosives and have generated a great demand for rapid, sensitive and reliable methods for detecting hidden explosives. Counterterrorist Detection Techniques of Explosives covers recent advances in this area of research including vapor and trace detection techniques (chemiluminescence, mass spectrometry, ion mobility spectrometry, electrochemical methods and micromechanical sensors, such as microcantilevers) and bulk detection techniques (neutron techniques, nuclear quadrupole resonance, x-ray diffraction imaging, millimeter-wave imaging, terahertz imaging and laser techniques). This book will be of interest to any scientists involved in the design and application of security screening technologies including new sensors and detecting devices which will prevent the smuggling of bombs and explosives.
* Covers latest advances in vapor and trace detection techniques and bulk detection techniques
* Reviews both current techniques and those in advanced stages of development
* Techniques that are described in detail, including its principles of operation, as well as its applications in the detection of explosives

This series provides an unequalled source of information on an area of chemistry that continues to grow in importance. Divided into sections mainly according to the particular spectroscopic technique used, coverage in each volume includes: NMR (with reference to stereochemistry, dynamic systems, paramagnetic complexes, solid state NMR and Groups 13-18); nuclear quadrupole resonance spectroscopy; vibrational spectroscopy of main group and transition element compounds and coordinated ligands; and electron diffraction. Reflecting the growing volume of published work in the field, researchers will find this an invaluable source of information on current methods and applications. Volume 39 provides a critical review of the literature published up to late 2004.

In-Situ Spectroscopic Studies of Adsorption at the Electrode and Electrocatalysis is a new reference on in-situ spectroscopic techniques/applications, fundamentals of electrocatalysis at molecule level, and progresses within electrochemical surface science. Presenting both essential background knowledge at graduate level and original research within the fields of spectroscopy, electrochemistry, and surface science.
Featuring 15 chapters by prominent worldwide scholars, based on their recent progress in different aspects of in-situ spectroscopy studies, this book will appeal to a wide audience of scientists. In summary this book is highly suitable for graduates learning basic concepts and advanced applications of in-situ spectroscopy, electrocatalysis and electrode adsorptions.
* Written by the most active scientists in the fields of spectroscopy, electrochemistry and surface science
* Essential background knowledge for graduate students
* A modern reference of cutting-edge scientific research

Detection of concealed explosives is a notoriously difficult problem, and many different approaches have been proposed to solve this problem. Nuclear quadrupole resonance (NQR) is unique in many ways. It operates in a safe AM radio frequency range, and it can remotely detect unique fingerprint (NQR spectrum) of many explosives, such as TNT or RDX. As such, the detection of target does not depend on the shape or material of the container, or the presence of metallic object such as triggers etc. Spectra of chemically similar compounds differ enough that their presence never causes interference or false alarms. Unfortunately, widespread use is prevented due to low sensitivity, radiofrequency interference from the noisy environment, and inability to detect liquid explosives. This book presents current state of the art of the attempts to overcome NQR sensitivity problem, either by increasing the strengths of signals generated, or by increasing the specificity of the technique through a better understanding of the factors that affect the quadrupolar parameters of specific explosives. The use of these specific quadrupolar parameters is demonstrated on signal processing techniques that can detect weak signals, which are hidden in a noisy background. The problem of differentiation of liquid explosives and benign liquids in closed containers is approached by measurements of different nuclear magnetic resonance (NMR) parameters. As shown, a couple of solutions has reached a prototype stage and could find their use in a near future."

Biosensors are making a large impact in environmental, food, biomedical, and other applications. In comparison to standard analytical detection methods, such as minimal sample preparation and handling, they offer advantages including real time detection, rapid detection of the analytes of concern, use of non-skilled personnel, and portability. The aim of this book is to focus on research related to the rapid detection of agents and weapons of bioterrorism and provide a comprehensive review of the research topics most pertinent to advancing devices applicable to the rapid real-time detection of toxicants such as microbes, pathogens, toxins, or nerve gases. The ongoing war on terrorism and the rising security concerns are driving the need for newer faster biosensors against bio-warfare agents for both military and civil defence applications. The volume brings together contributions from the most eminent international researchers in the field, covering various aspects of work not so far published in any scientific journal and often going beyond the "state of art" . Readers of these review articles will learn new technological schemes that can lead to the construction of devices that will minimize the risk of bio-terrorism."

The Hydrogen Bond and the Water Molecule offers a synthesis of what is known and currently being researched on the topic of hydrogen bonds and water molecules. The most simple water molecular, H2O, is a fascinating but poorly understood molecule. Its unique ability to attract an exceptionally large number of hydrogen bonds induces the formation of a dense "hydrogen bond network" that has the potential to modify the properties of the surrounding molecules and their reactivities. The crucial role that water molecules play is described in this book. The author begins by providing an overview of the thermodynamical and structural properties of H-bonds before examining their much less known dynamical properties, which makes them appear as centres of reactivity. Methods used to observe these components are also reviewed. In the second part of the book the role played by the dense H-bond network developed by H2O molecules is examined. First in ice, where it has important atmospheric consequences, then in liquid water, and finally in macromolecules where it sheds some original light on the fundamental question "How is it that without water and hydrogen bonds life would not exist?."
This book will be of interest to researchers in the fields of physics, chemistry, biochemistry and molecular biology. It can also serve as a teaching aid for students attending course in chemical physics, chemistry or molecular biology. Engineers involved the water industry would benefit from reading this book, as would scientists working in pharmaceutics, cosmetics and materials.
* overview of what is known and being researched on the topic of hydrogen bonds and water molecules
* reviews methods used to observe interactions between water molecules and hydrogen bonds
* examines role of H-bond network developed by H2O molecules

MALDI-ToF Mass Spectrometry for Studying Noncovalent Complexes of Biomolecules, by Stefanie Madler, Elisabetta Boeri Erba, Renato Zenobi Application of MALDI-TOF-Mass Spectrometry to Proteome Analysis Using Stain-Free Gel Electrophoresis, by Iuliana Susnea, Bogdan Bernevic, Michael Wicke, Li Ma, Shuying Liu, Karl Schellander, Michael Przybylski MALDI Mass Spectrometry for Nucleic Acid Analysis, by Xiang Gao, Boon-Huan Tan, Richard J. Sugrue, Kai Tang Determination of Peptide and Protein Disulfide Linkages by MALDI Mass Spectrometry, by Hongmei Yang, Ning Liu, Shuying Liu MALDI In-Source Decay, from Sequencing to Imaging, by Delphine Debois, Nicolas Smargiasso, Kevin Demeure, Daiki Asakawa, Tyler A. Zimmerman, Loic Quinton, Edwin De Pauw Advances of MALDI-TOF MS in the Analysis of Traditional Chinese Medicines, by Minghua Lu, Zongwei Cai Chemical and Biochemical Applications of MALDI TOF-MS Based on Analyzing the Small Organic Compounds, by Haoyang Wang, Zhixiong Zhao, Yinlong Guo Bioinformatic Analysis of Data Generated from MALDI Mass Spectrometry for Biomarker Discovery, by Zengyou He, Robert Z. Qi, Weichuan Yu

Specialist Periodical Reports provide systematic and critical review coverage in major areas of chemical research. Compiled by teams of leading authorities in the relevant subject, the series creates a unique service for the active research chemist with regular critical in-depth accounts of progress in particular areas of chemistry. Subject coverage of all volumes is very similar and publication is on an annual or biennial basis. As EPR continues to find new applications in virtually all areas of modern science, including physics, chemistry, biology and materials science, this series caters not only for experts in the field, but also those wishing to gain a general overview of EPR applications in a given area.

This series provides an unequalled source of information on an area of chemistry that continues to grow in importance. Divided into sections mainly according to the particular spectroscopic technique used, coverage in each volume includes: NMR (with reference to stereochemistry, dynamic systems, paramagnetic complexes, solid state NMR and Groups 13-18); nuclear quadrupole resonance spectroscopy; vibrational spectroscopy of main group and transition element compounds and coordinated ligands; and electron diffraction. Reflecting the growing volume of published work in the field, researchers will find this an invaluable source of information on current methods and applications. Volume 39 provides a critical review of the literature published up to late 2004.

The book starts with a detailed description of ICP-MS, including quadruple-based, sector-based and time-of-flight instruments. Instrumentation from existing manufacturers is described and compared to show their similarities and differences. Also, a review of the ICP-MS literature is carried out to outline both the strengths and limitations of the technique, whatever its brand, as well as what it can currently accomplish in terms of applications. Then, the book demonstrates how these limitations can be reduced and/or eliminated by combining various techniques with ICP-MS. Great detail is provided on each technique so that the reader can get a good understanding of it before carrying on to the instrumental requirements for its hyphenation to ICP-MS, and the resulting impact on the operation of the hyphenated instrument. Since this book is concerned with the ICP side only, which is fairly similar in all the instruments from the different manufacturers, the information should be useful to all ICP-MS users. The features and limitations of each technique are thoroughly discussed and illustrated with a review of the ICP-MS literature. Approaches which could be used but have not yet been tried with ICP-MS are also suggested. This is particularly true of flow injection techniques which are extremely flexible and have been used extensively in atomic spectroscopy and spectrophotometry. Many of the features of the technique have not yet been combined to ICP-MS, and one purpose of the book will be to point out potentially beneficial combinations.

As a spectroscopic method, nuclear magnetic resonance (NMR) has seen spectacular growth, both as a technique and in its applications. Today's applications of NMR span a wide range of scientific disciplines, from physics to biology to medicine. Each volume of Nuclear Magnetic Resonance comprises a combination of annual and biennial reports which together provide comprehensive coverage of the literature on this topic. This Specialist Periodical Report reflects the growing volume of published work involving NMR techniques and applications, in particular NMR of natural macromolecules, which is covered in two reports: NMR of Proteins and Nucleic Acids; and NMR of Carbohydrates, Lipids and Membranes. For those wanting to become rapidly acquainted with specific areas of NMR, Nuclear Magnetic Resonance provides unrivalled scope of coverage. Seasoned practitioners of NMR will find this an invaluable source of current methods and applications. Specialist Periodical Reports provide systematic and detailed review coverage in major areas of chemical research. Compiled by teams of leading experts in their specialist fields, this series is designed to help the chemistry community keep current with the latest developments in their field. Each volume in the series is published either annually or biennially and is a superb reference point for researchers. www.rsc.org/spr

This book gathers 12 outstanding contributions that reflect state-of-the-art industrial applications of fluorescence, ranging from the pharmaceutical and cosmetics industries to explosives detection, aeronautics, instrumentation development, lighting, photovoltaics, water treatment and much more. In the field of fluorescence, the translation of research into important applications has expanded significantly over the past few decades. The 18th volume in the Springer Series on Fluorescence fills an important gap by focusing on selected industrial applications of fluorescence, described in contributions by both industry-based researchers and academics engaged in collaborations with industrial partners.