Storage and conversion are critical components of important energy-related technologies. "Advanced Batteries: Materials Science Aspects" employs materials science concepts and tools to describe the critical features that control the behavior of advanced electrochemical storage systems.

This volume focuses on the basic phenomena that determine the properties of the components, i.e. electrodes and electrolytes, of advanced systems, as well as experimental methods used to study their critical parameters. This unique materials science approach utilizes concepts and methodologies different from those typical in electrochemical texts, offering a fresh, fundamental and tutorial perspective of advanced battery systems.

Graduate students, scientists and engineers interested in electrochemical energy storage and conversion will find "Advanced Batteries: Materials Science Aspects" a valuable reference.

This book is a systematic survey of the knowledge accumulated in this field in the last thirty years. It includes material on the thermodynamic aspects of the polymers, the theory of the mechanism of charge transport processes, and the chemical and physical properties of these compounds. Also covered are the techniques of characterization, the electrochemical methods of synthesis, and the application of these systems. Inzelt 's book is a must-read for electrochemists and others.

As world demand for electrical energy increases, it will be the ingenuity and skill of brilliant electrochemists that enables us to utilize the planet's mineral reserves responsibly. This biographical dictionary profiles 85 electrochemists from 19 nations who during the past 270 years have researched and developed ever more efficient batteries and energy cells. Each entry traces the subject's origin, education, discoveries and patents, as well as hobbies and family life. The breakthroughs of early innovators are cataloged and the work of living scientists and technicians is brought up to date. An appendix provides a cross-referenced timeline of innovation.

The development of solid state devices began a little more than a century ago, with the discovery of the electrical conductivity of ionic solids. Today, solid state technologies form the background of the society in which we live. The aim of this book is threefold: to present the background physical chemistry on which the technology of semiconductor devices is based; secondly, to describe specific issues such as the role of defects on the properties of solids, and the crucial influence of surface properties; and ultimately, to look at the physics and chemistry of semiconductor growth processes, both at the bulk and thin-film level, together with some issues relating to the properties of nano-devices. Divided into five chapters, it covers: Thermodynamics of solids, including phases and their properties and structural order Point defects in semiconductors Extended defects in semiconductors and their interactions with point defects and impurities Growth of semiconductor materials Physical chemistry of semiconductor materials processing With applications across all solid state technologies, the book is useful for advanced students and researchers in materials science, physics, chemistry, electrical and electronic engineering. It is also useful for those in the semiconductor industry.

Batteries are becoming increasingly important in today's world of portable electronic devices, along with the need to store electricity derived from solar and other renewable forms of energy, and the desire to introduce electric and hybrid electric vehicles to reduce emissions. Understanding Batteries is a must for all those seeking a straightforward explanation of how batteries are constructed, their operation, and the factors determining their performance and life. Beginning with a brief history of the development of batteries and a discussion of their applications and markets, the book goes on to outline the basic terminology and science of batteries. The different types of primary (non-rechargeable) and secondary (rechargeable) batteries are then described and emphasis is given to the importance of matching the battery to the intended application. Examples are given to demonstrate how to define and prioritise the various criteria which comprise the battery specification. Throughout, the chemistry is kept as simple as possible. Understanding Batteries will appeal to a wide range of readers, including electrical equipment manufacturers and users, engineers and technicians, chemistry and materials science students, teachers and the interested battery user.

Lithium Batteries: Science and Technology is an up-to-date and comprehensive compendium on advanced power sources and energy related topics. Each chapter is a detailed and thorough treatment of its subject. The volume includes several tutorials and contributes to an understanding of the many fields that impact the development of lithium batteries. Recent advances on various components are included and numerous examples of innovation are presented. Extensive references are given at the end of each chapter. All contributors are internationally recognized experts in their respective specialty. The fundamental knowledge necessary for designing new battery materials with desired physical and chemical properties including structural, electronic and reactivity are discussed. The molecular engineering of battery materials is treated by the most advanced theoretical and experimental methods.

Die nachhaltige Nutzung verfugbarer Energieressourcen, deren Moglichkeiten derzeit viel diskutiert werden, beinhaltet auch eine zukunftsfahige Hausenergieversorgung. Eine Option dafur stellen Brennstoffzellen in Minikraftwerken als Heizungsersatz dar, mit denen bei einer koordinierten Kopplung und Steuerung in sogenannten Virtuellen Kraftwerken durch bedarfsgerechte Fahrweise neben einer Grundversorgung auch Nachfragespitzen abgedeckt werden konnen.

Die vorliegende Studie zeigt Wege fur einen zukunftsfahigen Einsatz der Technologien Brennstoffzelle und Virtuelles Kraftwerk in der Hausenergieversorgung auf. Dazu werden zunachst Konkurrenztechnologien miteinander verglichen, Wettbewerbsverzerrungen aufgedeckt und Rahmenbedingungen analysiert. Darauf aufbauend werden Strategien zur Beseitigung von Innovationsbarrieren erarbeitet und Handlungsempfehlungen fur den (umwelt-, energie- und technologie-) politischen Umgang mit den neuen Technologien gegeben. Die Autorengruppe stellt u.a. Herausforderungen heraus, die sich bei der Gestaltung der Technologieforderung, der Erwirtschaftung moglicher zusatzlicher Erlose, der Vermeidung des Missbrauchs von Marktmacht und der Gestaltung der gesetzlichen Rahmenbedingungen fur den Einsatz dieser Technologien ergeben.

Die interdisziplinare Forschungsarbeit verknupft Aspekte aus Energietechnik, Technikfolgenanalyse, Politikwissenschaft, Okonomie und Rechtswissenschaft miteinander und richtet sich an Wissenschaft, Politik, Akteure in der Energiewirtschaft sowie an die interessierte Offentlichkeit.

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Fuel Cells have become a potentially highly efficient sustainable source of energy and electricity for an ever-demanding power hungry world. The two main types of fuel cells ripe for commercialisation are the high temperature solid oxide fuel cell (SOFC) and the low temperature polymer electrolyte membrane fuel cell (PEM). The commercial uses of which include, but are not limited to, military, stand-by power, commercial and industrial, and remoter power. However, all aspects of the electricity market are being considered.

This book has brought together a team of world-renowned experts in all aspects of fuel cell development for both SOFC and PEM in a workshop environment. The workshop held between June 6-10, 2004 was held in the capital city of the Ukraine, Kiev. The reason for the venue was that Ukraine is the third largest resource of zircon sands, a major source of material for the solid oxide fuel cell. Ukraine is looking at undertaking a very large effort in the solid oxide fuel cell arena, and hopes, one day, to be an international player in this market, and this book is an outcome from the workshop. The book focuses on the issues related to fuel cells, particularly the state-of-the-art internationally, the issues that were of particular interest for getting fuel cells fully commercialized, and advances in fuel cell materials and technology. The focus was on all types of fuel cells, but the emphasis was particularly on solid oxide fuel cells (SOFC), due to their importance to the host country. The book is an essential reference to researchers, academics and industrialists interested in up-to-date information on SOFC and PEM development.

The second edition of this practical text offers a broad introduction to the engineering principles of chemical energy conversion. Eugene L. Keating, Ph.D., P.E., a recognized authority within academia, government, and industry, examines combustion science and technology using fundamental principles. Thermochemical engineering data and design formulations of basic performance relationships appear in dual SI and English engineering dimensions and units, helping you save time and avoid conversion errors.
New in the Second Edition
Streamlined organization that progressively develops fundamental concepts
Extended section on fuel cells
New section on the nitrogen-oxygen reaction system
Additional coverage of environmental aspects of specific combustion characteristics
New chapter on thermal destruction
Furnishing examples that demonstrate a proper engineering analysis as well as important concepts relevant to the nature of combustion devices, Applied Combustion, Second Edition explores the ideal oxidation-reaction equation, fuel heat release rates, chemical equilibrium, incomplete combustion, chemical kinetics, and detonation, thermal explosion, and basic flame theories. The book treats the features of chemical energy resources and presents a thermochemical overview of current and potential solid, liquid, and gaseous natural and synthetic fuel resources. It also describes the fuel-engine interface characteristics of important external and internal combustion heat engines in terms of fuel compatibility, consumption rates, pollution characteristics, emission controls, and energy conversion efficiencies.

The book starts with an exposition of the relevant properties of ions and continues with a description of their solvation in the gas phase. The book contains a large amount of factual information in the form of extensive tables of critically examined data and illustrations of the points made throughout. It covers: * the relevant properties of prospective liquid solvents for the ions * the process of the transfer of ions from the gas phase into a liquid where they are solvated * various aspects of the solutions of the ions, such as structural and transport ones and the effects of the ions on the solvent dynamics and structure * what happens in cases where the solvent is a mixture selective solvation takes place * applications of the concepts expounded previously in fields such as electrochemistry, hydrometallurgy, separation chemistry, biophysics, and synthetic methods

Capillary Electrophoresis in Chiral Analysis Bezhan Chankvetadze Tbilisi State University, Republic of Georgia The application of capillary electrophoresis (CE) to the field of chiral analysis has exploded recently. The advantages of capillary electrophoresis - extremely high peak efficiency, excellent compatibility with biological samples, short analysis time, simplicity, versatility and low cost - are perfect for the accurate measurement of optical purity, increasingly important in the regulation-ruled pharmaceutical industry. Although there have been a number of books on capillary electrophoresis and chiral analysis separately, as yet there has been no dedicated monograph on the application of capillary electrophoresis to chiral analysis. This book bridges the gap. Capillary Electrophoresis in Chiral Analysis charts the evolution of chiral capillary electrophoresis and describes new types of chiral selectors and mechanistic aspects of chiral recognition. While on the one hand, it is an excellent introduction to newcomers, on the other, it is of practical use to experienced researchers in the field wishing to solve a particular separation problem. It includes an alphabetical list of chiral compounds resolved using CE with appropriate references, which any one working in the field will find invaluable.

This book is a comprehensive review of the chemistry of what are the simplest and most fundamental species present in aqueous solution for a chemical element - an ‘aqua’ ion. Understanding the chemistry of the aqua ion i.e. the species [M(OH₂)_n]^m+ is fundamental to an appreciation of not only a given elements aqueous solution chemistry, but also to the general chemical properties of that element. The Chemistry of Aqua Ions has been written at a time when environmental issues and the move towards ‘clean technology’ is driving synthetic chemists away from organic based solvent systems and towards water as the preferred medium of the future. The paints industry has already moved to aqueous based products. Metal aqua complexes are widely used in the areas of catalysis, dyes and pigments and in hydrometallurgy where a complete understanding of the metal ions in aqueous media is highly desirable. This is the first book to treat the chemistry of the aqua ions as a self-contained topic. It includes basic concepts relating to the structure of water and periodic trends concerning the state of hydration of metal ions in solution. It examines the significant role that spectroscopic techniques, e.g. NMR, Raman spectroscopy, EXAFS and diffraction techniques have played in establishing the structures of aqua metallic species. Element by element through the periodic table, the author reviews the preparative and separative techniques for aquated ions and their derivatives, physical techniques and their structure and reactivity with a strong emphasis on reaction mechanisms. The Chemistry of Aqua Ions -invaluable reading for all research students in the physical and natural sciences, chemistry, biochemistry, environmental, colloid and soil science, and practicing professional chemists and environmentalists in research and industry.

This book is an analytical treatment of the subject, that enables the reader to design successfully chemical methods (such as separations) and predict the required conditions for such methods. Part 1 describes the ways of obtaining selective effects through the use of competing reactions in aqueous media. Part 2 investigates how modifications of chemical reactivity of solutes are produced by using nonaqueous solvents. Particular consideration is given to ionized molten salts and molecular organic and inorganic solvents. This is a broad ranging study of the field. It demonstrates the theory and methodology behind practical problems in solution chemistry and enables the reader to solve them effectively, taking into account the chemistry of the system. The work is elucidated by numerous examples provided in context plus nearly 200 problems at the end of the book.

Providing the reader with an up to date digest of the most important research currently carried out in the field, Electrochemistry Volume 14 is compiled and written by leading experts from across the globe. Coverage includes chapters on the use of metal organic frameworks as a precursor for electrocatalytic centre supports to enhance the oxygen reduction process in low temperature fuel cell systems, electrocatalysis for ethanol electrooxidation in alkaline media, and new polymer electrolyte and electrocatalysts for direct alcohol fuel cells. This volume is a key reference for researchers providing a timely overview of this exciting and developing area.

The aim of this book is to provide the reader with a modern presentation of ionic solutions at interfaces, for physical chemists, chemists and theoretically oriented experimentalists in this field. The discussion is mainly on the structural and thermodynamic properties, in relation to presently available statistical mechanical models. Some dynamic properties are also presented, at a more phenomenological level. The initial chapters are devoted to the presentation of some basic concepts for bulk properties: hydrodynamic interactions, electrostatics, van der Waals forces and thermodynamics of ionic solutions in the framework of a particular model: the mean spherical approximation (MSA). Specific features of interfaces are then discussed: experimental techniques such as in-situ X-ray diffraction, STM and AFM microscopy are described. Ions at liquid/air, liquid/metal and liquid/liquid interfaces are considered from the experimental and theoretical viewpoint. Lastly some dynamic (transport) properties are included, namely the self-diffusion and conductance of small colloids (polyelectrolytes and micelles) and the kinetics of solute transfer at free liquid/liquid interfaces.

In recent interactions with industrial companies it became quite obvious, that the search for new materials with strong anisotropic properties are of paramount importance for the development of new advanced electronic and magnetic devices. The questions concerning the tailoring of materials with large anisotropic electrical and thermal conductivity were asked over and over again. It became also quite clear that the chance to answer these questions and to find new materials which have these desired properties would demand close collaborations between scientists from different fields. Modem techniques ofcontrolled materials synthesis and advances in measurement and modeling have made clear that multiscale complexity is intrinsic to complex electronic materials, both organic and inorganic. A unified approach to classes of these materials is urgently needed, requiring interdisciplinary input from chemistry, materials science, and solid state physics. Only in this way can they be controlled and exploited for increasingly stringent demands oftechnology. The spatial and temporal complexity is driven by strong, often competing couplings between spin, charge and lattice degrees offreedom, which determine structure-function relationships. The nature of these couplings is a sensitive function of electron-electron, electron-lattice, and spin-lattice interactions; noise and disorder, external fields (magnetic, optical, pressure, etc. ), and dimensionality. In particular, these physical influences control broken-symmetry ground states (charge and spin ordered, ferroelectric, superconducting), metal-insulator transitions, and excitations with respect to broken-symmetries created by chemical- or photo-doping, especially in the form of polaronic or excitonic self-trapping.

It has been always an incentive for students to find whether his/her efforts to solve exercises give correct results, or to find tips for problems that he/she finds more difficult. These are the main reasons for the appearance of the present book. As part of the textbook Modern Electrochemistry 1: Ionics, A Guide to Problems in Modern Electrochemistry: Part 1: Ionics compiles many of the solutions to the exercises and problems presented in the text, as well as many new problems.

This long-awaited and thoroughly updated version of the classic text (Plenum Press, 1970) explains the subject of electrochemistry in clear, straightforward language for undergraduates and mature scientists who want to understand solutions. Like its predecessor, the new text presents the electrochemistry of solutions at the molecular level. The Second Edition takes full advantage of the advances in microscopy, computing power, and industrial applications in the quarter century since the publication of the First Edition. Such new techniques include scanning-tunneling microscopy, which enables us to see atoms on electrodes; and new computers capable of molecular dynamics calculations that are used in arriving at experimental values. A description of the electrochemical stage - the high field region near the interface - is the topic of Chapter 6 and involves a complete rewrite of the corresponding chapter in the First Edition, particularly the various happenings which occur with organic molecules which approach surfaces in solution. The chapter on electrode kinetics retains material describing the Butler-Volmer equation from the First Edition, but then turns to many new areas, including electrochemical theories of potential-dependent gas catalysis. Chapter 8 is a new one devoted to explaining how electrochemists deal with the fast-changing nature of the electrode surface. Quantum Mechanics as the basis to electrode kinetics is given an entirely new look - up to and including considerations of bond-breaking reactions.

This volume is based on the lectures presented at the NATO Advanced Study Institute: (ASI) "Pollutants Formation from Combustion. Formation Mechanisms and Impact on th th Atmospheric Chemistry" held in Maratea, Italy, from 13 to 26 september 1998. Preservation of the environment is of increasing concern in individual countries but also at continental or world scales. The structure of a NATO ASI which involve lecturers and participants of different nationalities was thought as especially well suited to address environmental issues. As combustion is known to substantially contribute to the damaging of the atmosphere, it was natural to concentrate the ASI program on reviewing the currently available knowledge of the formation mechanisms of the main pollutants liberated by combustion systems. In most situations, pollutants are present as trace components and their formation and removal is strongly conditioned by the chemical reactions initiated by fuel consumption. Therefore specific lectures were aimed at defining precisely the general properties of combustion chemistry for gaseous, liquid and solid fuels. Physical factors can strongly affect the combustion chemistry and their influence was also considered. An interesting peculiarity of this specific ASI was to complement the program with a substantial part concerned with the impact of the main combustion pollutants: NOx, aromatics, soot, VOCs, sulphur and chlorinated compounds, on atmospheric chemistry.

This book had its nucleus in some lectures given by one of us (J. O'M. B. ) in a course on electrochemistry to students of energy conversion at the University of Pennsyl- nia. It was there that he met a number of people trained in chemistry, physics, biology, metallurgy, and materials science, all of whom wanted to know something about electrochemistry. The concept of writing a book about electrochemistry which could be understood by people with very varied backgrounds was thereby engendered. The lectures were recorded and written up by Dr. Klaus Muller as a 293-page manuscript. At a later stage, A. K. N. R. joined the effort; it was decided to make a fresh start and to write a much more comprehensive text. Of methods for direct energy conversion, the electrochemical one is the most advanced and seems the most likely to become of considerable practical importance. Thus, conversion to electrochemically powered transportation systems appears to be an important step by means of which the difficulties of air pollution and the effects of an increasing concentration in the atmosphere of carbon dioxide may be met. Cor- sion is recognized as having an electrochemical basis. The synthesis of nylon now contains an important electrochemical stage. Some central biological mechanisms have been shown to take place by means of electrochemical reactions. A number of American organizations have recently recommended greatly increased activity in training and research in electrochemistry at universities in the United States.

This textbook is an accessible overview of the broad field of organic electrochemistry, covering the fundamentals and applications of contemporary organic electrochemistry. The book begins with an introduction to the fundamental aspects of electrode electron transfer and methods for the electrochemical measurement of organic molecules. It then goes on to discuss organic electrosynthesis of molecules and macromolecules, including detailed experimental information for the electrochemical synthesis of organic compounds and conducting polymers. Later chapters highlight new methodology for organic electrochemical synthesis, for example electrolysis in ionic liquids, the application to organic electronic devices such as solar cells and LEDs, and examples of commercialized organic electrode processes. Appendices present useful supplementary information including experimental examples of organic electrosynthesis, and tables of physical data (redox potentials of various organic solvents and organic compounds and physical properties of various organic solvents).

The text Modern Electrochemistry (authored by J. O'M. Bockris and A. K. N. Reddy and published by Plenum Press in 1970) was written between 1967 and 1969. The concept for it arose in 1962 in the Energy Conversion Center at the University of Pennsylvania, and it was intended to act as a base for interdisciplinary students and mature scientists hemists, physicists, biologists, metallurgists, and engineers-who wanted to know about electrochemical energy conversion and storage. In writing the book, the stress, therefore, was placed above all on lucidity in teaching physical electrochemistry from the beginning. Although this fundamentally undergraduate text continues to find purchasers 20 years after its birth, it has long been clear that a modernized edition should be written, and the plans to do so were the origin of the present book. However, if a new Bockris and Reddy was to be prepared and include the advances of the last 20 years, with the same degree of lucidity as characterized the first one, the depth of the development would have to be well short of that needed by professional electrochemists.

This introduction to the principles and application of electrochemistry is presented in a manner designed for undergraduates in chemistry and related fields. The author covers the essential aspects of the subject and points the way to further study, his concern being with the overall shape of electrochemistry, its coherence and its wider application. This edition differs from its predecessors in having principles and applications separated, and greater prominence is given to areas such as electrochemical sensors and electroanalytical techniques, of which a number of modern methods were not included in previous editions. A range of numerical problems and outline solutions is provided for each chapter to cover most situations that a student might encounter.

"Bioelectrochemistry: Fundamentals, Experimental Techniques and Application," covers the fundamental aspects of the chemistry, physics and biology which underlie this subject area. It describes some of the different experimental techniques that can be used to study bioelectrochemical problems and it describes various applications of biolelectrochemisty including amperometric biosensors, immunoassays, electrochemistry of DNA, biofuel cells, whole cell biosensors, "in vivo" applications and bioelectrosynthesis.

By bringing together these different aspects, this work provides a unique source of information in this area, approaching the subject from a cross-disciplinary viewpoint.