Offering thorough coverage of atomic layer deposition (ALD), this book moves from basic chemistry of ALD and modeling of processes to examine ALD in memory, logic devices and machines. Reviews history, operating principles and ALD processes for each device.

This book surveys state-of-the-art research on and developments in lithium-ion batteries for hybrid and electric vehicles. It summarizes their features in terms of performance, cost, service life, management, charging facilities, and safety. Vehicle electrification is now commonly accepted as a means of reducing fossil-fuels consumption and air pollution. At present, every electric vehicle on the road is powered by a lithium-ion battery. Currently, batteries based on lithium-ion technology are ranked first in terms of performance, reliability and safety. Though other systems, e.g., metal-air, lithium-sulphur, solid state, and aluminium-ion, are now being investigated, the lithium-ion system is likely to dominate for at least the next decade - which is why several manufacturers, e.g., Toyota, Nissan and Tesla, are chiefly focusing on this technology. Providing comprehensive information on lithium-ion batteries, the book includes contributions by the world's leading experts on Li-ion batteries and vehicles.

This book discusses the merging of nanoscale electronics and electrochemistry and how this can potentially modernize the way electronic devices are currently engineered or constructed. It introduces the electrochemical capacitance as a fundamental missing concept that solves the puzzle between molecular electronics and electrochemistry at the nanoscale. The electrochemical capacitance, as a fundamental principle, is deduced from first principles quantum mechanics. The text also confirmed that faradaic and non-faradaic processes are only different physical approximations of the same sort of energetic phenomenon.The book comprises three chapters. Chapter one introduces the concepts of chemical capacitance, relaxation resistance, and the quantum resistive-capacitive circuit and demonstrates how these elements are translated to the electrochemistry context. In chapter two, the chemical capacitance, the fundamental concept and missing part of the puzzle that unity electronics and electrochemistry, is deduced from first principles of quantum mechanics. In chapter three, the concepts are practically used in different contexts that include molecular diagnostics, molecular conductance and super-capacitive phenomena is explained using the introduced basic principles.

This book reviews the latest advances in the bioelectrochemical degradation of recalcitrant environmental contaminants. The first part introduces readers to the basic principles and methodologies of bioelectrochemical systems, electron-respiring microorganisms, the electron transfer mechanism and functional electrode materials. In turn, the second part addresses the bioelectrochemical remediation/treatment of various environmental pollutants (including highly toxic refractory organics, heavy metals, and nitrates) in wastewater, sediment and wetlands. Reactor configuration optimization, hybrid technology amplification and enhanced removal principles and techniques are also discussed. The book offers a valuable resource for all researchers and professionals working in environmental science and engineering, bioelectrochemistry, environmental microbiology and biotechnology.

Electrogenerated chemiluminescence (ECL) is a powerful and versatile analytical technique, which is widely applied for biosensing and successfully commercialized in the healthcare diagnostic market. After introducing the fundamental concepts, this book will highlight the recent analytical applications with a special focus on immunoassays, genotoxicity, imaging, DNA and enzymatic assays. The topic is clearly at the frontier between several scientific domains involving analytical chemistry, electrochemistry, photochemistry, materials science, nanoscience and biology. This book is ideal for graduate students, academics and researchers in industry looking for a comprehensive guide to the different aspects of electrogenerated chemiluminescence.

This book offers a survey of the historic development of selected areas of chemistry and chemical physics, discussing in detail the European, American and Russian approaches to the development of chemistry. Other key topics include the kinetics and non-linear thermodynamics of chemical reactions and mathematical modeling, which have found new applications in the theory of dynamical systems. The first observations of the periodicity of chemical reactions were lost in the mist of time. In the second half of the 19th century, the phenomenon of chemical periodicity was studied in relation to electrochemistry, solutions and colloids. Discovered in the late 19th century, Liesegang rings are still enigmatic and remain attractive for researchers. However, the discovery of the Belousov-Zhabotinsky reaction marked the successful culmination of the efforts to find a true chemical oscillatory reaction. The book investigates chemical phenomena that were neglected in the past, but have been rediscovered, placing them into a new conceptual framework. For example, it notes that William Bray, who discovered the first oscillatory homogeneous reaction in 1921, was influenced by the first bio-mathematicians who predicted chemical oscillations in homogeneous systems.

This book reviews the structure and composition of Prussian Blue materials. It presents the state-of-the-art of their application to metal-ion batteries, highlighting the benefits derived from the integration of electrochemical energy storage with clean energies. It concludes with future perspectives including prototyping and large-scale production.

This book focuses on nanocarbons (carbon nanotubes, graphene, nanoporous carbon, and carbon black) and related materials for energy conversion, including fuel cells (predominately proton exchange membrane fuel cells [PEMFC]), Li-ion batteries, and supercapacitors. Written by a group of internationally recognized researchers, it offers an in-depth review of the structure, properties, and functions of nanocarbons, and summarizes recent advances in the design, fabrication and characterization of nanocarbon-based catalysts for energy applications. As such, it is an invaluable resource for graduate students, academics and industrial scientists interested in the areas of nanocarbons, energy materials for fuel cells, batteries and supercapacitors as well as materials design, and supramolecular science.

The brief gives a comprehensive overview of the polysaccharide applications in the field of battery materials. Included is a historic overview as well as recent developments in the field including new battery types and chemistries. Written in an accessible style by academics, it is aimed at those new to the field as well as individuals who have interest in novel polysaccharide applications. Aimed at advanced undergraduates, academic and industrial researchers and professionals studying or using biobased polymers.

This brief reviews the fundamentals, recent developments, challenges and prospects of Li-S and Li-O2 batteries, including fundamental research and potential applications. It starts with a brief overview encompassing the current state of Li-S and Li-O2 battery technology. It then provides general information on Li-S and Li-O2 batteries, including the electrochemical processes and battery components. The following sections focus on the historical and recent development of Li-S and Li-O2 batteries respectively, offering detailed insights into the key material development, cell assembly, diagnostic test and mechanism of electrolyte decomposition. Lastly, it focuses on the main promising applications of Li-S and Li-O2 batteries together with their challenges and potential

This book describes various carbon nanomaterials and their unique properties, and offers a detailed introduction to graphene-carbon nanotube (CNT) hybrids. It demonstrates strategies for the hybridization of CNTs with graphene, which fully utilize the synergistic effect between graphene and CNTs. It also presents a wide range of applications of graphene-CNT hybrids as novel materials for energy storage and environmental remediation. Further, it discusses the preparation, structures and properties of graphene-CNT hybrids, providing interesting examples of three types of graphene-CNT hybrids with different nanostructures. This book is of interest to a wide readership in various fields of materials science and engineering.

This book introduces the reader to the quantum theories needed to describe the interactions of diatomic molecules with electromagnetic fields and systematically discusses the effects of static and dynamic electric and magnetic fields on the rotational, fine, and hyperfine structure of molecules. It illustrates how the concepts developed in ultracold physics research have lead to what may be the beginning of controlled chemistry in the fully quantum regime. The theories described are applied to discuss examples from research on trapping molecules in electromagnetic fields, laser control of molecular rotations and external field control of microscopic intermolecular interactions. The book presents the description of scattering theory for molecules in electromagnetic fields and is written to be a practical guide for students working on various aspects of molecular interactions.

This book provides a comprehensive overview of contemporary research and emerging measurement technologies associated with gas transport in solid oxide fuel cells. Within these pages, an introduction to the concept of gas diffusion in solid oxide fuel cells is presented. This book also discusses the history and underlying fundamental mechanisms of gas diffusion in solid oxide fuel cells, general theoretical mathematical models for gas diffusion, and traditional and advanced techniques for gas diffusivity measurement.

Given that thermodynamics books are not a rarity on the market, why would an additional one be useful? The answer is simple: at any level, thermodynamics is usually taught as a somewhat abstruse discipline where many students get lost in a maze of difficult concepts. However, thermodynamics is not as intricate a subject as most people feel. This book fills a niche between elementary textbooks and mathematically oriented treatises, and provides readers with a distinct approach to the subject. As indicated by the title, this book explains thermodynamic phenomena and concepts in physical terms before proceeding to focus on the requisite mathematical aspects. It focuses on the effects of pressure, temperature and chemical composition on thermodynamic properties and places emphasis on rapidly evolving fields such as amorphous materials, metastable phases, numerical simulations of microsystems and high-pressure thermodynamics. Topics like redox reactions are dealt with in less depth, due to the fact that there is already much literature available. Without requiring a background in quantum mechanics, this book also illustrates the main practical applications of statistical thermodynamics and gives a microscopic interpretation of temperature, pressure and entropy. This book is perfect for undergraduate and graduate students who already have a basic knowledge of thermodynamics and who wish to truly understand the subject and put it in a broader physical perspective. The book is aimed not at theoretical physicists, but rather at practitioners with a variety of backgrounds from physics to biochemistry for whom thermodynamics is a tool which would be better used if better understood.

Mimicking nature's efficiency and sustainability in organic chemistry is a major goal for future chemists; redox reactions are a key element in a variety of fields ranging from synthesis and catalysis to materials chemistry and analytical applications. Sustainability is increasingly becoming a consideration in synthesis and functional chemistry and an essential element for the next generation of chemistry in academia and industry. This book represents a compilation of the latest advancements in functional redox chemistry and demonstrates its importance in achieving a more sustainable future. This book is an ideal companion for any postgraduate students or researchers interested in sustainability in academia and industry.

Battery Management Systems - Design by Modelling describes the design of Battery Management Systems (BMS) with the aid of simulation methods. The basic tasks of BMS are to ensure optimum use of the energy stored in the battery (pack) that powers a portable device and to prevent damage inflicted on the battery (pack). This becomes increasingly important due to the larger power consumption associated with added features to portable devices on the one hand and the demand for longer run times on the other hand. In addition to explaining the general principles of BMS tasks such as charging algorithms and State-of-Charge (SoC) indication methods, the book also covers real-life examples of BMS functionality of practical portable devices such as shavers and cellular phones.

Simulations offer the advantage over measurements that less time is needed to gain knowledge of a battery's behaviour in interaction with other parts in a portable device under a wide variety of conditions. This knowledge can be used to improve the design of a BMS, even before a prototype of the portable device has been built. The battery is the central part of a BMS and good simulation models that can be used to improve the BMS design were previously unavailable. Therefore, a large part of the book is devoted to the construction of simulation models for rechargeable batteries. With the aid of several illustrations it is shown that design improvements can indeed be realized with the presented battery models. Examples include an improved charging algorithm that was elaborated in simulations and verified in practice and a new SoC indication system that was developed showing promising results.

The contents of Battery Management Systems - Design by Modelling is based on years of research performed at the Philips Research Laboratories. The combination of basic and detailed descriptions of battery behaviour both in chemical and electrical terms makes this book truly multidisciplinary. It can therefore be read both by people with an (electro)chemical and an electrical engineering background.

The quest for efficient and durable battery technologies is one of the key challenges for enabling the transition to renewable energy economies. Magnesium batteries, and in particular rechargeable non-aqueous systems, are an area of extensive opportunity and intense research. Rechargeable magnesium batteries hold numerous advantages over current lithium-ion batteries, namely the relative abundance of magnesium to lithium and the potential for magnesium batteries to greatly outperform their Li-ion counterparts. Magnesium Batteries comprehensively outlines the scientific and technical challenges in the field, covering anodes, cathodes, electrolytes and particularly promising systems such as the Mg-S cell. Edited by a leading figure in the field of electrochemical energy storage, with contributions from global experts, this book is a vital resource for students and researchers at all levels. Whether entering into the subject for the first time or extending their knowledge of battery materials across chemistry, physics, energy, engineering and materials science this book provides an ideal reference for anyone interested in the state-of-the-art and future of magnesium batteries.

This concise sourcebook of the electrochemical, engineering and economic principles involved in the development and commercialization of fuel cells offers a thorough review of applications and techno-economic assessment of fuel cell technologies, plus in-depth discussion of conventional and novel approaches for generating energy. Parts I and II explain basic and applied electrochemistry relevant to an understanding of fuel cells. Part III covers engineering and technology aspects. The book is useful for undergraduate and graduate students and scientists interested in fuel cells. Unlike any other current book on fuel cells, each chapter includes problems based on the discussions in the text.

A systematic analysis of electrochemical processes involving metal complexes. Starting with general considerations on equilibria in solutions and at interfaces as well as on mass transport, the text acquaints readers with the theory and common experimental practice for studying electrochemical reactions of metals complexes. The core part of the book deals with all important aspects of electroplating, including a systematic discussion of co-deposition of metals and formation of alloys. It also discusses such related subjects as oxide layer formation and hydrogen evolution as a side reaction.

Disposable electrodes have been widely used as a sensing platform in electrical and electrochemical sensors owing to the possibility of quantitative detection using clinical biomarkers with high precision, sensitivity and reproducibility, which are necessary for accurate diagnosis of the health condition of an individual. This book focusses on the emerging disposable electrochemical sensors in the health sector and the advancement of analytical devices to monitor diabetic, cancer and cardiovascular patients using different nanomaterials. It discusses the upcoming strategies, advantages and the limitations of the existing devices using disposable electrodes. Uniquely, it covers in-depth knowledge of mechanistic features of various designs of screen-printing electrodes and the material aspects required of sensors developed for the healthcare field. It also looks at the portable devices using a variety of materials and the future directions for research in this area. Appealing to the health care industry, this book is aimed at academic and research institutes at both the graduate and postgraduate level. The contributors are leading experts in the field and they are providing guidance for the next decade of research in the field of disposable electrochemical biosensors.

Broad in scope, this book describes the general theory and practice of using the Electron Capture Detector (ECD) to study reactions of thermal electrons with molecules. It reviews electron affinities and thermodynamic and kinetic parameters of atoms, small molecules, and large organic molecules obtained by using various methods.
* Summarizes other methods for studying reactions of thermal electrons with molecules
* Discusses applications in analytical chemistry, physical chemistry, and biochemistry
* Provides a data table of electron affinities

Stereoelectronic Effects illustrates the utility of stereoelectronic concepts using structure and reactivity of organic molecules An advanced textbook that provides an up-to-date overview of the field, starting from the fundamental principles Presents a large selection of modern examples of stereoelectronic effects in organic reactivity Shows practical applications of stereoelectronic effects in asymmetric catalysis, photochemical processes, bioorganic chemistry and biochemistry, inorganic and organometallic reactivity, supramolecular chemistry and materials science

This long awaited and thoroughly updated version of the classic text (Plenum Press, 1970) explains the subject of electrochemistry in clear, straightforward language for undergraduates and mature scientists who want to understand solutions. Like its predecessor, the new text presents the electrochemistry of solutions at the molecular level. The Second Edition takes full advantage of the advances in microscopy, computing power, and industrial applications in the quarter century since the publication of the First Edition. Such new techniques include scanning-tunneling microscopy, which enables us to see atoms on electrodes; and new computers capable of molecular dynamics calculations that are used in arriving at experimental values. Chapter 10 starts with a detailed description of what happens when light strikes semi-conductor electrodes and splits water, thus providing in hydrogen a clean fuel. There have of course been revolutionary advances here since the First Edition was written. The book also discusses electrochemical methods that may provide the most economical path to many new syntheses - for example, the synthesis of the textile, nylon. The broad area of the breakdown of material in moist air, and its electrochemistry is taken up in the substantial Chapter 12. Another exciting topic covered is the evolution of energy conversion and storage which lie at the cutting edge of clean automobile development. Chapter 14 presents from a fresh perspective a discussion of electrochemical mechanisms in Biology, and Chapter 15 shows how new electrochemical approaches may potentially alleviate many environmental problems.

This book presents the latest research in electrochemical properties and applications of ionic liquids. While there is no universally agreed upon definition, an ionic liquid may be conveniently described as a compound composed entirely of ions that is a liquid at temperatures less than 100 DegreesC. However, this is an arbitrary definition employed to distinguish ionic liquids from classically well-known molten salts. This book addresses a comprehensive overview of the area, because it is obvious that ionic liquids have the ability to offer many advantages, but also some disadvantages, over traditional molecular solvent (electrolyte) media in the field of electrochemistry.

This book describes, for the first time in a modern text, the fundamental principles on which solid state electrochemistry is based. In this sense it is in contrast to other books in the field which concentrate on a description of materials. Topics include solid (ceramic) electrolytes, glasses, polymer electrolytes, intercalation electrodes, interfaces and applications. The different nature of ionic conductivity in ceramic, glassy and polymer electrolytes is described as are the thermodynamics and kinetics of intercalation reactions. The interface between solid electrolytes and electrodes is discussed and contrasted with the more conventional liquid state electrochemistry. The text provides an essential foundation of understanding for postgraduates or others entering the field for the first time and will also be of value in advanced undergraduate courses.