This thesis details the significant progress made in improving the performance of organic transistors and the network conductivity of carbon nanotubes. The first section investigates organic semiconductor nucleation and growth on the most common dielectric surface used to fabricate organic thin film transistors. The nucleation and growth of the semiconductor was determined to be a critical factor affecting the device performance. Excellent dielectric modification layers, which promote desirable semiconductor growth leading to high conductivity were identified, and a technologically relevant deposition technique was developed to fabricate high quality dielectric modification layers over large areas. This may represent an important step towards the realization of large area organic circuity. In the final section, lessons learned from studying organic semiconductor nucleation and growth were utilized to improve the conductivity of carbon nanotube networks. Selective nucleation of materials at the junctions between nanotubes in the network significantly decreased the network's sheet resistance. The resulting networks may be promising candidates for transparent electrodes with a variety of optoelectronic applications.

This is a text designed to provide a frim grounding in mathematical methods for chemical engineering students and researchers in academia and industry. Mathematical Methods in Chemical Engineering builds on the reader's previous knowledge of calculus, differential equations, and linear algebra. Varma and Morbidelli offer an integrated treatment of linear operator theory from determinants through partial differential equations, and feature extensive chapters on both ordinary differential equations and perturbation methods. Numerous high-quality diagrams and examples from chemical engineering illustrate the textual material and enhance the reader's understanding of complex mathematical systems.

This book treats the theoretical fundamentals of adsorption technology for water treatment from a practical perspective. It presents all the basics needed for experimental adsorption studies as well as for process modeling and adsorber design. According to the increasing importance of micropollutants in the water cycle, particular attention is paid to their competitive adsorption in the presence of background organic matter. The current edition considers recent developments in adsorption theory and practice.

At last, a book that covers safety procedures and standards with information that is rarely available outside of proprietary materials. A comprehensive source for basic and essential operations and procedures in use in any facility, the book offers chemical operators and first line supervisors guidance in applying appropriate practices to prevent accidents, and suggests which practices to avoid.

Contents - Preface to the English edition - Preface to the German edition - Introduction - CHAPTER I. - The basic materials of concrete - A) Cements and their resistance to corrosion - 1. The composition of cements - 2. The hydration of cement - 3. The resistance of various cements to chemical attack - B) Aggregates - 1. Sand - 2. Gravel - 3. Crushed stone - 4. Blast-furnace slag - 5. Coal slag - 6. Other aggregates - 7. Conclusion - C) Mixing water - CHAPTER II. - Groundwater - A) Engineering hydrology - 1. Determination of the highest groundwater table - 2. Determination of variations in the highest groundwater table - 3. Groundwater flow - 4. Hydrochemical groundwater maps - B) Groundwater sampling - C) Soil sampling - D) The reliability of analytical data of groundwater and soil samples - E) Investigation of groundwater and soil properties - CHAPTER III. - The corrosion and protection of concrete - A) The investigation of concrete corrosion - 1. Corrosion research 2. Rapid methods of corrosion testing - 3. The performance of corrosion tests - 4. Summary - B) General aspects of corrosion - C) Leaching corrosion of concrete due to soft water - 1. The hardness of water and its effect - 2. The effects of soft river water and groundwater in motion - 3. Effects of soft water seeping under pressure - 4. The effect of warm soft water - 5. The effect of cement type - 6. The effect of concrete density - 7. Effect of the concrete surface - 8. Dimensions and age of concrete - 9. Protective measures against the leaching action of water - D) Concrete corrosion due to attacking compounds - CHAPTER IV. Factors increasing or reducing corrosion - A) Corrosion of concrete due to flowing groundwater - B) The corrosive effect of warm groundwater - C) Corrosion due to fluctuations of the groundwater table - D) Corrosion in the range of evaporation - E) Thin-walled concrete objects, concrete canals, piles etc - 1. Cases of corrosion - 2. Protective measures - F) The effect of air oxidation - G) Microbiological corrosion (caused by sulphur bacteria) - 1. Sulphate-forming bacteria - 2. Sulphate-reducing bacteria - 3. Attempt at bacterial protection of concrete - 4. Iron organisms - CHAPTER V. Detailed discussion of protective measures against corrosive effects - A) Passive protective measures - 1. Selection of the suitable concrete mix and method of placement - 2. Surface treatments - 3. Other methods of protection - 4. Perfect sealing (waterproofing) - B) Active protective measures - 1. Exclusion of aggressive water - 2. Neutralization of aggressive water by chemical and biological methods - C) Repair of damaged concrete - Conclusion - Bibliography - Index -

Here is a classic in the field, an enormously successful handbook on the art of making fireworks. In non-technical language, it gives formulas and detailed instructions for all the time-honored favorites, exhibition and display pieces. An indispensable book for both the beginner and the professional pyrotechnist. PARTIAL CONTENTS: Ingredients; Manipulation; Tools and Appliances Used; Articles of Manufacture and Formulas; Exhibition Fireworks; Miscellaneous; Appendix; Glossary; Bibliography.

In Flame Structure and Processes, renowned physical chemist Robert M. Fristrom comprehensively documents the numerous experimental techniques used to study flame microstructure, and provides an interdisciplinary overview of how such research is revealing exciting new information about combustion and high temperature processes. Using premixed laminar flames as models for studying individual high temperature chemistries, physical processes, and their interactions, Fristrom expertly details experimental and mathematical methods for analyzing overall flame structure or any other high temperature reacting flow system. Specialized techniques required to obtain high spatial resolution under extreme temperature conditions are also described. Fristrom goes on to discuss what is currently known about flame chemistry, physical processes common to all flames, and combustion. An extensive bibliography and many useful tables round out the book. The only up-to-date book solely devoted to flame structure and processes, this book will be welcomed by students and professionals in chemical/mechanical engineering and physical chemistry.

Polymer Coatings: Technologies and Applications provides a comprehensive account of the recent developments in polymer coatings encompassing novel methods, techniques, and a broad spectrum of applications. The chapters explore the key aspects of polymer coatings while highlighting fundamental research, different types of polymer coatings, and technology advances. This book also integrates the various aspects of these materials from synthesis to application. Current status, trends, future directions, and opportunities are also discussed. FEATURES Examines the basics to the most recent advances in all areas of polymer coatings Serves as a one-stop reference Discusses polymer-coated nanocrystals and coatings based on nanocomposites Describes morphology, spectroscopic analysis, adhesion, and rheology of polymer coatings Explores conducting, stimuli-responsive, self-healing, hydrophobic and hydrophilic, antifouling, and antibacterial polymer coatings Covers modeling and simulation With contributions from the top international researchers from industry, academia, government, and private research institutions, both new and experienced readers will benefit from this applications-oriented book. Sanjay Mavinkere Rangappa is a research scientist at the Natural Composites Research Group Lab, Academic Enhancement Department, King Mongkut's University of Technology North Bangkok, Thailand. Jyotishkumar Parameswaranpillai is a research professor at the Center of Innovation in Design and Engineering for Manufacturing, King Mongkut's University of Technology North Bangkok, Thailand. Suchart Siengchin is a professor at and president of King Mongkut's University of Technology North Bangkok, Thailand.

Liquid-Liquid and Solid-Liquid Extractors, part of the Industrial Equipment for Chemical Engineering set, presents a concise and easy-to-use book on the calculation of differential liquid-liquid extraction, an investigation of equilibrium and material transfer between a fluid and a divided solid, and the fundamentals of liquid-solid extraction, among other strategies. The author also provides methods needed for the understanding the machinery used in applied thermodynamics in the hopes of encouraging students and engineers to construct the programs they need. Chapters are complemented with appendices which provide additional information and associated references.

High-pressure Molecular Spectroscopy describes examples of the applications of several spectroscopic methods to investigate the behavior of various chemical systems under high pressures, including guest-host interactions, chemical reactions, molecule-based multiferroics, lanthanide ion-doped glasses, and organic, inorganic and organometallic materials. The techniques involved include: Luminescence studies Inelastic neutron scattering Infrared and Raman studies Synchrotron X-ray diffraction

This timely text offers coverage of pollution prevention fundamentals, featuring examples and case studies drawn from the chemical process industries. Topics are presented on three different levels-macro, meso, and micro. The book's multifaceted approach provides a complete picture of current waste minimization theory and practice.
Macroscale
* Comprehensive analysis of the flow of materials in the United States, from natural resource extraction to consumer product disposal
* Overview of waste generation and management for different pollutant types
* Assessment of pollution prevention opportunities using industrial ecology and product life cycle frameworks
Mesoscale
* Detailed coverage of pollution prevention in chemical manufacturing processes
* Waste audits, emission inventories, flow sheet analysis, and many other important tools
* Waste reduction for unit operations, techniques for measuring economic benefits of pollution prevention, and more
Microscale
* Case studies of reaction pathway analysis and material design methods
Complete with case studies that give the material a real-world edge, plus worked examples to reinforce learning, this text is valuable to both advanced students and practitioners of chemical and civil engineering.

Multiscale Modeling for Process Safety Applications is a new reference demonstrating the implementation of multiscale modeling techniques on process safety applications. It is a valuable resource for readers interested in theoretical simulations and/or computer simulations of hazardous scenarios. As multi-scale modeling is a computational technique for solving problems involving multiple scales, such as how a flammable vapor cloud might behave if ignited, this book provides information on the fundamental topics of toxic, fire, and air explosion modeling, as well as modeling jet and pool fires using computational fluid dynamics. The book goes on to cover nanomaterial toxicity, QPSR analysis on relation of chemical structure to flash point, molecular structure and burning velocity, first principle studies of reactive chemicals, water and air reactive chemicals, and dust explosions. Chemical and process safety professionals, as well as faculty and graduate researchers, will benefit from the detailed coverage provided in this book.

"The Handbook of Nonwoven Filter Media" provides the reader with a fundamental understanding of nonwoven filter media. It is one of the few books dealing exclusively with the subject of nonwoven filter media, and is primarily intended as a reference for people in the nonwovens industry (industry and academic researchers, technical and quality control personnel) and universities offering courses in filtration theory and practice and nonwovens technology.

Coverage includes gas, liquid, and engine filtration, which are covered in such a way as to identify the types of filter media used in these applications.

Theoretical presentation is based on flow through porous media, and is developed around a nonwovens or engineered fabrics orientation. In addition, for aerosol filtration, the book presents single fiber theory, developed for the filtration of particles from an air stream.

New sections on developing filter media technologies, including: Nanofiber technology, saline water treatment, new filter media structures, turbine air filtration, membrane filter technology, and new materials for filter media.New chapter on sustainability issues in the nonwovens field, covering recycling/recyclability, energy consumption, and carbon footprint, in addition to other environmental indicators and effectsA comprehensive discussionof Computaional Flow Dynamics (CFD) by Dr George Chase, University of Akron, USA."

Heat transfer phenomena involving boiling and condensation are an important aspect of engineering in the power and process industries. This book, aimed at final year undergraduates and graduate students in mechanical or chemical engineering, deals with these phenomena in detail. The first part of the book describes gas-liquid two-phase flow, as a necessary preliminary to the later discussion of heat transfer and changes of phase. A detailed section on calculation methods shows how theory can be put to practical use, and there are also descriptions of some of the equipment and plant used in the process and power industries.

The plan of this book is to present the relevant thermodynamic features of fluid mixtures in contact with semipermeable barriers, then to apply this information in deriving the design requirements of individual membrane separation processes. The membranes, by this approach, are introduced by way of the mass transport and selectivity demands which they are to meet. This book gives a survey, in systematic order, of the terms and concepts by which barrier separations operate.

- Presents A rational holistic approach to use terrestrial biomass as a raw material - Comprises New techniques for converting waste biomass in added value materials - Describes The Methanol/ sulphuric acid system in cellulose saccharification - Reviews Fusion biomass straw in carbon fiber by acid impregnation techniques

Removal of Pollutants from Saline Water: Treatment Technologies provides a comprehensive understanding of technologies that are currently adopted in the treatment of pollutants present in saline water systems. It provides information on the treatment technologies for saline water systems, including seawater, brackish water, oil-produced water, and other industrial saline wastewaters. FEATURES Presents information exclusively for saline water pollutant removal Introduces current treatment technologies and addresses why and how the techniques differ between fresh and salt water Offers an inclusive overview of physicochemical, biological, membrane, and advanced oxidation treatment technologies Features various perspectives and case studies from relevant global experts Provides a comprehensive one-stop source for the treatment of pollutants in all saline water systems Aimed at students, academicians, researchers, and practicing engineers in the fields of chemical, civil, marine, and environmental engineering who wish to be acquainted with the most recent developments in the treatment of pollutants present in saline water systems. Prof. Dr. Shaik Feroz works at Prince Mohammad Bin Fahd University, Kingdom of Saudi Arabia. He has 30 years of experience in teaching, research, and industry. He has more than 190 publications to his credit in journals and conferences of international repute. He was awarded "Best Researcher" by Caledonian College of Engineering for the year 2014. Prof. Dr. Detlef W. Bahnemann is Head of the Research Unit, Photocatalysis and Nanotechnology at Leibniz University Hannover (Germany), Director of the Research Institute "Nanocomposite Materials for Photonic Applications" at Saint Petersburg State University (Russian Federation), and Distinguished Professor at Shaanxi University of Science and Technology in Xi'an (People's Republic of China). His research topics include photocatalysis, photoelectrochemistry, solar chemistry, and photochemistry focused on synthesis and physical-chemical properties of semiconductor and metal nanoparticles. His 500-plus publications have been cited more than 65,000 times (h-index: 100).

This volume reviews numerous reaction mechanisms and applications of nucleic acids with catalytic activity. Written by an interdisciplinary team of authors, it provides an essential overview of these acids' fundamental aspects, while also addressing associated methodologies such as nucleic acid enzyme engineering, peroxidase-mimicking DNAzymes and Aptazymes. After the discovery of natural ribozymes - RNA molecules that mediate the cleavage and formation of phosphodiester bonds and the formation of peptide bonds - numerous artificial ribozymes with altered catalytic activities were produced by in vitro and in vivo selection. Unlike ribozymes, DNAzymes do not occur in nature. Although the catalytic activity of nucleic acid enzymes is usually much slower than that of proteins, nucleic acid enzymes with comparable catalytic activity have been obtained using stringent selection processes. The key advantages of these enzymes: they are e.g. smaller, easier to produce and purify than proteins, and can withstand denaturation, e.g. by heat. Over the last few years, the number of publications on the applications of enzymatic nucleic acids has grown steadily. Summarizing the fundamentals and applications of these acids, this book will not only be an excellent resource for experts in the field but will also guide young researchers just starting out in this significant area.

Mineral Scales and Deposits: Scientific and Technological Approaches presents, in an integrated way, the problem of scale deposits (precipitation/crystallization of sparingly-soluble salts) in aqueous systems, both industrial and biological. It covers several fundamental aspects, also offering an applications' perspective, with the ultimate goal of helping the reader better understand the underlying mechanisms of scale formation, while also assisting the user/reader to solve scale-related challenges. It is ideal for scientists/experts working in academia, offering a number of crystal growth topics with an emphasis on mechanistic details, prediction modules, and inhibition/dispersion chemistry, amongst others. In addition, technologists, consultants, plant managers, engineers, and designers working in industry will find a field-friendly overview of scale-related challenges and technological options for their mitigation.

The timely volume describes recent discoveries and method developments that have revolutionized Structural Biology with the advent of X-ray Free Electron Lasers. It provides, for the first time, a comprehensive examination of this cutting-edge technology. It discusses of-the-moment topics such as growth and detection of nanocrystals, Sample Delivery Techniques for serial femtosecond crystallography, data collection methods at XFELs, and more. This book aims to provide the readers with an overview of the new methods that have been recently developed as well as a prospective on new methods under development. It highlights the most important and novel Structural Discoveries made recently with XFELS, contextualized with a big-picture discussion of future developments.

Practical Guides in Chemical Engineering are a cluster of short texts that each provides a focused introductory view on a single subject. The full library spans the main topics in the chemical process industries that engineering professionals require a basic understanding of. They are 'pocket publications' that the professional engineer can easily carry with them or access electronically while working. Each text is highly practical and applied, and presents first principles for engineers who need to get up to speed in a new area fast. The focused facts provided in each guide will help you converse with experts in the field, attempt your own initial troubleshooting, check calculations, and solve rudimentary problems. Solid-Liquid Filtration covers the basic principles and mechanisms of filtration, filtration testing including filter aids and filter media, types of filtration systems, selection of filtration systems and typical operating and troubleshooting approaches. This guide also discusses general applications and tips for process filtration and can be utilized by process engineers as a framework for "idea-generation" when analyzing filtration for an operating bottleneck issue or a new process development problem.

For the power industry, biomass is just a modern name for the ancient material of plant origin that was converted into energy in the simple technology of burning. This book discusses biomass as a raw material for the production of liquid or gaseous biofuels and valuable chemicals. Such biomass processing should be beneficial from both economic and environmental points of view. Classic technologies of biogas production are still being improved, but they always generate waste that differs in terms of chemical parameters, depending on the feedstock digested. These parameters dictate the manner of their final managing. Various biotechnologies allow the use of the biomass of hydrobionts, such as cyanobacteria as a raw substance for obtaining different products, e.g. hyaluronic acid, biopolymers, fertilizers, or even drugs. Animal fats or algae can be used to produce biodiesel which in turn is used in environmentally friendly urban transport. Even municipal solid waste can be a source of useful biomass. The authors show how its volume and composition can be predicted, by which form of processing it can be converted into valuable products, as well as in which ways its negative environmental impact can be limited.

CONTENTS - Introduction, L. A. Underkofler and R. J. Hickey - PART I -ALCOHOLIC FERMENTATION AND ITS MODIFICATIONS - 2. Alcoholic Fermentation of Grain, W. H. Stark - 3. Alcoholic Fermentation of Molasses, H. M. Hodge and F. M. Hildebrandt - 4. Alcoholic Fermentation of Sulfite Waste Liquor, J. L. McCarthy 955. Production of Alcohol from Wood Waste, J. F. Saeman and A. A. Andreasen - 6. The Brewing Industry, R. I. Tenney - 7. Commercial Production of Table and Dessert Wines, M. A. Joslyn and M. W. Turbovsky - 8. Glycerol, L. A. Underkofler - PART II. THE PRODUCTION OF YEAST - 9. Commercial Yeast Manufacture, R. Irvin - 10. Food and Feed Yeast, A. J. Wiley - PART III. THE BUTANOL ACETONE FERMENTATIONS - 11. The Butanol-Acetone Fermentations, W.N. McCutchan and R. J. Hickey - PART IV. FERMENTATIVE PRODUCTION OF ORGANIC ACIDS - 12. Lactic Acid, H. H. Schopmeyer - 13. The Citric Acid Fermentation, M. J. Johnson - 14. Gluconic Acid, L. A. Underkofler - 15. Fumaric Acid, J. W. Foster - 16. Itaconic Acid, L. B. Lockwood - 17. Acetic Acid-Vinegar, R. H. Vaughn - INDEX -

This book provides a comprehensive description of theories and applications of high-solid and multi-phase bioprocess engineering, which is considered as an important way to address the challenges of "high energy consumption, high pollution and high emissions" in bio-industry. It starts from specifying the solid-phase matrix properties that contribute to a series of "solid effects" on bioprocess, including mass transfer restrictions in porous media, water binding effects, rheological changes. Then it proposes the new principles of periodic intensification which combines the normal force and physiologic characteristics of microorganism for the bioprocess optimization and scale-up. Further breakthroughs in key periodic intensification techniques such as periodic peristalsis and gas pressure pulsation are described in detail which provide an industrialization platform and lay the foundation for high-solid and multi-phase bioprocess engineering. This book offers an excellent reference and guide for scientists and engineers engaged in the research on both the theoretical and practical aspects of high-solid and multi-phase bioprocess.

This book explores the potential of multi-functional carbon nanotubes for biomedical applications. It combines contributions from chemistry, physics, biology, engineering, and medicine. The complete overview of the state-of-the-art addresses different synthesis and biofunctionalisation routes and shows the structural and magnetic properties of nanotubes relevant to biomedical applications. Particular emphasis is put on the interaction of carbon nanotubes with biological environments, i.e. toxicity, biocompatibility, cellular uptake, intracellular distribution, interaction with the immune system and environmental impact. The insertion of NMR-active substances allows diagnostic usage as markers and sensors, e.g. for imaging and contactless local temperature sensing. The potential of nanotubes for therapeutic applications is highlighted by studies on chemotherapeutic drug filling and release, targeting and magnetic hyperthermia studies for anti-cancer treatment at the cellular level.