This book presents a detailed look at experimental and computational techniques for accurate structure determination of free molecules. The most fundamental property of a molecule is its structure - it is a prerequisite for determining and understanding most other important properties of molecules. The determination of accurate structures is hampered by a myriad of factors, subjecting the collected data to non-negligible systematic errors. This book explains the origin of these errors and how to mitigate and even avoid them altogether. It features a detailed comparison of the different experimental and computation methods, explaining their interplay and the advantages of their combined use. Armed with this information, the reader will be able to choose the appropriate methods to determine - to a great degree of accuracy - the relevant molecular structure.

This book presents proton-3He elastic scattering experiments conducted at intermediate energies, with the aim of identifying three-nucleon force (3NF) effects in a four-nucleon scattering system. The 3NF plays an essential part in understanding various nuclear phenomena, and few-nucleon scatterings further offers a good opportunity to study the dynamical aspects of 3NFs. In particular, proton-3He scattering is one of the most promising approaches to an iso-spin dependence of 3NFs. The book in-depth explains the achieved development of polarized 3He target system for the proton-3He scattering experiments, and describes successful precise evaluation of the target polarization. The experiments yielded the first precise data for this system and offer a valuable resource for the study of 3NFs.

The development of nuclear weapons during the Manhattan Project is one of the most significant scientific events of the twentieth century. This revised and updated 4th edition explores the challenges that faced the scientists and engineers of the Manhattan Project. It gives a clear introduction to fission weapons at the level of an upper-year undergraduate physics student by examining the details of nuclear reactions, their energy release, analytic and numerical models of the fission process, how critical masses can be estimated, how fissile materials are produced, and what factors complicate bomb design. An extensive list of references and a number of exercises for self-study are included. Revisions to this fourth edition include many upgrades and new sections. Improvements are made to, among other things, the analysis of the physics of the fission barrier, the time-dependent simulation of the explosion of a nuclear weapon, and the discussion of tamped bomb cores. New sections cover, for example, composite bomb cores, approximate methods for various of the calculations presented, and the physics of the polonium-beryllium "neutron initiators" used to trigger the bombs. The author delivers in this book an unparalleled, clear and comprehensive treatment of the physics behind the Manhattan project.

This book presents mechanics miniaturization trends explored step by step, starting with the example of the miniaturization of a mechanical calculator. The ultra-miniaturization of mechanical machinery is now approaching the atomic scale. In this book, molecule-gears, trains of molecule-gears, and molecule motors are studied -one molecule at a time- on a solid surface, using scanning probe manipulation protocols and in solution as demonstrated in the European project "MEMO". All scales of mechanical machinery are presented using the various lithography techniques currently available, from the submillimeter to the nanoscale. Researchers and nanomechanical engineers will find new inspirations for the construction of minute mechanical devices which can be used in diverse hostile environments, for example under radiation constraints, on the surface membrane of a living cell or immersed in liquid. The book is presented in a format accessible for university students, in particular for those at the Master and PhD levels.

Part 1: A Dostoeyevskijan Hero.- An Archimedes from Sicily studies in Rome.- A Certain Interest in Pure Science.- Ten short papers.- Part 2: Power for the Italian School.- The 1937 Chance.- Landing in Naples.- Part 3: A Legacy from the Grand Inquisitor.- The Mystery of the Missing Papers.- Fortunes and Misfortunes of a Famous Director.- Part 4: Investigation of a Disappearance.- Before March 26.- In Search for a Missing Professor.- The Last Chapter.- Epilogue.

This book discusses the spectral properties of solid-state laser materials, including emission and absorption of light, the law of radiative and nonradiative transitions, the selection rule for optical transitions, and different calculation methods of the spectral parameters. The book includes a systematic presentation of the authors' own research works in this field, specifically addressing the stimulated nonradiative transition theory and the apparent crystal field model. This volume is helpful resource for researchers and graduate students in the fields of solid spectroscopy and solid-state laser material physics, while also serving as a valuable reference guide for instructors and advanced students of physics.

This text gives an introduction to particle physics at a level accessible to advanced undergraduate students. It is based on lectures given to 4th year physics students over a number of years, and reflects the feedback from the students. The aim is to explain the theoretical and experimental basis of the Standard Model (SM) of Particle Physics with the simplest mathematical treatment possible. All the experimental discoveries that led to the understanding of the SM relied on particle detectors and most of them required advanced particle accelerators. A unique feature of this book is that it gives a serious introduction to the fundamental accelerator and detector physics, which is currently only available in advanced graduate textbooks. The mathematical tools that are required such as group theory are covered in one chapter. A modern treatment of the Dirac equation is given in which the free particle Dirac equation is seen as being equivalent to the Lorentz transformation. The idea of generating the SM interactions from fundamental gauge symmetries is explained. The core of the book covers the SM. The tools developed are used to explain its theoretical basis and a clear discussion is given of the critical experimental evidence which underpins it. A thorough account is given of quark flavour and neutrino oscillations based on published experimental results, including some from running experiments. A simple introduction to the Higgs sector of the SM is given. This explains the key idea of how spontaneous symmetry breaking can generate particle masses without violating the underlying gauge symmetry. A key feature of this book is that it gives an accessible explanation of the discovery of the Higgs boson, including the advanced statistical techniques required. The final chapter gives an introduction to LHC physics beyond the standard model and the techniques used in searches for new physics. There is an outline of the shortcomings of the SM and a discussion of possible solutions and future experiments to resolve these outstanding questions. For updates, new results, useful links as well as corrections to errata in this book, please see the book website maintained by the authors: https://pplhcera.physics.ox.ac.uk/

Describing the processes in stars which produce the chemical elements for planets and life, this book shows how similar processes may be reproduced in laboratories using exotic beams, and how these results can be analyzed. Beginning with one-channel scattering theory, the book builds up to multi-channel reactions. Emphasis is placed on using transfer and breakup reactions to probe structure and predict capture processes, as well as R-matrix methods for modeling compound nucleus dynamics described by Hauser-Feshbach methods. Practical applications are prominent in this book, confronting theory predictions with data throughout. The associated reaction program Fresco is described, allowing readers to apply the methods to practical cases. Each chapter ends with exercises so readers can test their understanding of the materials covered. Supplementary materials at www.cambridge.org/9780521856355 include the Fresco program, input and output files for the examples given in the book, and hints and graphs related to the exercises.

This book introduces vibronic coupling density and vibronic coupling constant analyses as a way to understand molecular structure and chemical reactions. After quantum study, the behavior of electrons circulating around nuclei led to the principal concept that underlies all explanations in chemistry. Many textbooks have given plausible explanations to clarify molecular structure-for example, the bond elongation of ethylene under anionization and the nonplanar structure of ammonia. Frontier molecular orbital concepts were proposed to visualize the path of chemical reactions, and conventional explanations gave students a familiarity with molecular structures in terms of the electronic state. By contrast, this book offers a more rational and more convincing path to understanding. It starts from the ab initio molecular Hamiltonian and provides systematic, rational approaches to comprehend chemical phenomena. In this way, the book leads the reader to a grasp of the quantitative evaluation of the force applied under the molecular deformation process. As well, guidelines are offered for integrating the traditional "hand-waving" approach of chemistry with more rational and general VCD and VCC alternatives along with the outlook for newly functionalized chemical systems.

This book presents the latest advances and future trends in electron and phonon spectrometrics, focusing on combined techniques using electron emissions, electron diffraction, and phonon absorption and reflection spectrometrics from a substance under various perturbations to obtain new information on bond-electron-phonon dynamics. Discussing the principles of the bond order-length-strength (BOLS) correlation, nonbonding electron polarization (NEP), local bond average (LBA), and multi-field lattice oscillation dynamics for systems under perturbation, the book covers topics like differential photoelectron/phonon spectrometrics (DPS), which distils transition of the length, energy, stiffness and the fraction of bonds upon chemical or physical conditioning; and the derived performance of electrons in various bands in terms of quantum entrapment and polarization. This book appeals to researchers, scientists and engineers in the fields of chemistry, physics, surface and interface science, and materials science and engineering who are interested in electron and phonon spectrometrics.

This edited, multi-author book gathers selected, peer-reviewed contributions based on papers presented at the 23rd International Workshop on Quantum Systems in Chemistry, Physics, and Biology (QSCP-XXIII), held in Mopani Camp, The Kruger National Park, South Africa, in September 2018. The content is primarily intended for scholars, researchers, and graduate students working at universities and scientific institutes who are interested in the structure, properties, dynamics, and spectroscopy of atoms, molecules, biological systems, and condensed matter.

This book presents 140 problems with solutions in introductory nuclear and particle physics. Rather than being only partially provided or simply outlined, as is typically the case in textbooks on nuclear and particle physics, all solutions are explained in detail. Furthermore, different possible approaches are compared. Some of the problems concern the estimation of quantities in realistic experimental situations. In general, solving the problems does not require a substantial mathematics background, and the focus is instead on developing the reader's sense of physics in order to work out the problem in question. Consequently, sections on experimental methods and detection methods constitute a major part of the book. Given its format and content, it offers a valuable resource, not only for undergraduate classes but also for self-assessment in preparation for graduate school entrance and other examinations.

Management systems play an important role in the success of a nuclear power programme. Recognizing that their development poses a number of questions, this publication aims to share experiences of regulatory bodies and owner operator organizations in developing management systems consistent with the main activities planned from inception of these organizations to construction of a nuclear power plant, whilst prioritizing safety.

This is the second edition of a well-received book. It provides an up-to-date, concise review of essential topics in the physics of matter, from atoms and molecules to solids, including elements of statistical mechanics. It features over 160 completely revised and enhanced figures illustrating the main physical concepts and the fundamental experimental facts, and discusses selected experiments, mainly in spectroscopy and thermodynamics, within the general framework of the adiabatic separation of the motions of electrons and nuclei. The book focuses on what can be described in terms of independent-particle models, providing the mathematical derivations in sufficient detail for readers to grasp the relevant physics involved. The final section offers a glimpse of more advanced topics, including magnetism and superconductivity, sparking readers' curiosity to further explore the latest developments in the physics of matter.

X ray, neutron and gamma radiography have been widely used by industry as non-destructive testing methods for quality control and to assess the safety and integrity of structures. Such techniques use intense, human-made radiation sources in the laboratory and at industrial sites. Muons are relatively massive elementary particles produced naturally by cosmic rays, and which may be used as a highly penetrating, non-destructive probe. Muon imaging is therefore an attractive alternative for certain applications. This publication describes some of the main muon imaging techniques, the detector types involved, and a wide variety of applications that have been identified from examination of modern and ancient built environments, volcanology, industry to nuclear security and safeguards. This publication is expected to be of use to all those individuals working in industry and academia with an interest in muon imaging.

The interactions of DNA with force are central to manifold fields of inquiry, including the de novo design of DNA nanostructures, the use of DNA to probe the principles of biological self-assembly, and the operation of cellular nanomachines. This work presents a survey of three distinct ways coarse-grained simulations can help characterize these interactions. A non-equilibrium energy landscape reconstruction technique is validated for use with the oxDNA model and a practical framework to guide future applications is established. A novel method for calculating entropic forces in DNA molecules is outlined and contrasted with existing, flawed approaches. Finally, a joint experimental-simulation study of large DNA origami nanostructures under force sheds light on design principles and, through vivid illustrations, their unfolding process. This text provides an accessible and exciting launching point for any student interested in the computational study of DNA mechanics and force interactions.

This book describes the state of the art across the broad range of spectroscopic techniques used in the study of biological systems. It reviews some of the latest advances achieved in the application of these techniques in the analysis and characterization of small and large biological compounds, covering topics such as VUV/UV and UV-visible spectroscopies, fluorescence spectroscopy, IR and Raman techniques, dynamic light scattering (DLS), circular dichroism (CD/SR-CD), pulsed electron paramagnetic resonance techniques, Moessbauer spectroscopy, nuclear magnetic resonance, X-ray methods and electron and ion impact spectroscopies. The second part of the book focuses on modelling methods and illustrates how these tools have been used and integrated with other experimental and theoretical techniques including also electron transfer processes and fast kinetics methods. The book will benefit students, researchers and professionals working with these techniques to understand the fundamental mechanisms of biological systems.

This Safety Guide, prepared jointly by the International Atomic Energy Agency (IAEA) and the International Labour Organization (ILO), provides guidance on fulfilling the requirements of the International Basic Safety Standards (IAEA Safety Standards Series No. GSR Part 3) with respect to occupational exposure. It provides general guidance on the development of occupational radiation protection programmes as appropriate for the sources of radiation likely to be encountered in the workplaces in question to fulfil the management's responsibility for protection and safety. Detailed guidance is also provided on the monitoring and assessment of workers' exposure due to external radiation sources and from intakes of radionuclides. The Safety Guide reflects the current internationally accepted principles and recommended good practices in occupational radiation protection, with account taken of the conceptual changes and technological enhancements that have occurred over the past decade.

Since the 1970s, the IAEA has been involved in the analysis of fuel failures in water cooled reactors in normal (nonaccident) operational conditions. This updated version of IAEA Nuclear Energy Series No. NFT2.1 provides information on all aspects of fuel failures in current nuclear power plant operations. It summarizes fuel failure occurrences and their mechanisms and root causes, as well as fuel failure prevention and management in plant operation for 97% of light and heavy water cooled nuclear power units operated worldwide during the period 2006-2015. Data on fuel failures from 1987 to 2006 extracted from three previous IAEA fuel failure reports are included and analysed in the present publication, together with the 2006-2015 fuel failure data, to reveal long term tendencies in fuel performance. In addition to fuel rod leakers, fuel structural damages and other fuel assembly issues are considered in the report.

This Open Access biography chronicles the life and achievements of the Norwegian engineer and physicist Rolf Wideroe. Readers who meet him in the pages of this book will wonder why he isn't better known. The first of Wideroe's many pioneering contributions in the field of accelerator physics was the betatron, the second, the linear accelerator, both summarized in a 27 page PhD. The betatron revolutionized the fields of cancer treatment through radiation therapy and also nondestructive testing; hospitals worldwide installed Wideroe's machine and today's modern radiation treatment equipment is based on his inventions. The most recent renaissance of the linac provides unprecedented x-ray intensities at Free Electron Laser (FEL) facilities in operation and construction worldwide. . Wideroe's story also includes a fair share of drama, particularly during World War II when both Germans and the Allies vied for his collaboration. Wideroe held leading positions in multinational industry groups and was one of the consultants for building the world's largest nuclear laboratory, CERN, in Switzerland. He gained over 200 patents, received several honorary doctorates and a number of international awards. The author, a professional writer and maker of TV documentaries, has gained access to hitherto restricted archives in several countries, which provided a wealth of new material and insights, in particular in relation to the war years. She tells here a gripping and illuminating story.

This book describes advanced research on the structures and photochemical properties of polyatomic molecules and molecular clusters having various functionalities under cold gas-phase conditions. Target molecules are crown ethers, polypeptides, large size protonated clusters, metal clusters, and other complex polyatomic molecules of special interest. A variety of advanced frequency and time-domain laser spectroscopic methods are applied. The book begins with the principle of an experimental setup for cold gas-phase molecules and various laser spectroscopic methods, followed by chapters on investigation of specific molecular systems. Through a molecular-level approach and analysis by quantum chemical calculation, it is possible to learn how atomic and molecular-level interactions (van der Waals, hydrogen-bonding, and others) control the specific properties of molecules and clusters. Those properties include molecular recognition, induced fitting, chirality, proton and hydrogen transfer, isomerization, and catalytic reaction. The information will be applicable to the design of new types of functional molecules and nanoparticles in the broad area that includes applied chemistry, drug delivery systems, and catalysts.

This book provides a systematic and comprehensive introduction to the neutronics of advanced nuclear systems, covering all key aspects, from the fundamental theories and methodologies to a wide range of advanced nuclear system designs and experiments. It is the first-ever book focusing on the neutronics of advanced nuclear systems in the world. Compared with traditional nuclear systems, advanced nuclear systems are characterized by more complex geometry and nuclear physics, and pose new challenges in terms of neutronics. Based on the achievements and experiences of the author and his team over the past few decades, the book focuses on the neutronics characteristics of advanced nuclear systems and introduces novel neutron transport methodologies for complex systems, high-fidelity calculation software for nuclear design and safety evaluation, and high-intensity neutron source and technologies for neutronics experiments. At the same time, it describes the development of various neutronics designs for advanced nuclear systems, including neutronics design for ITER, CLEAR and FDS series reactors. The book not only summarizes the progress and achievements of the author's research work, but also highlights the latest advances and investigates the forefront of the field and the road ahead.

The present research studies the fundamental physics occurring during the magnetic flux and magnetized plasma compression by plasma implosion. This subject is relevant to numerous studies in laboratory and space plasmas. Recently, it has attracted particular interest due to the advances in producing high-energy-density plasmas in fusion-oriented experiments, based on the approach of magnetized plasma compression. The studied configuration consists of a cylindrical gas-puff shell with pre-embedded axial magnetic field that pre-fills the anode-cathode gap. Subsequently, axial pulsed current is driven through the plasma generating an azimuthal magnetic field that compresses the plasma and the axial magnetic field embedded in it. A key parameter for the understanding of the physics occurring during the magnetized plasma compression is the evolution and distribution of the axial and azimuthal magnetic fields. Here, for the first time ever, both fields are measured simultaneously employing non-invasive spectroscopic methods that are based on the polarization properties of the Zeeman effect. These measurements reveal unexpected results of the current distribution and the nature of the equilibrium between the axial and azimuthal fields. These observations show that a large part of the current does not flow in the imploding plasma, rather it flows through a low-density plasma residing at large radii. The development of a force-free current configuration is suggested to explain this phenomenon. Previously unpredicted observations in higher-power imploding-magnetized-plasma experiments, including recent unexplained structures observed in the Magnetized Liner Inertial Fusion experiment, may be connected to the present discovery.

This book highlights the latest advances and outlines future trends in aqueous solvation studies from the perspective of hydrogen bond transition by charge injection, which reconciles the solvation dynamics, molecular nonbond interactions, and the extraordinary functionalities of various solutes on the solution bond network and properties. Focus is given on ionic and dipolar electrostatic polarization, O:H nonbond interaction, anti-HB and super-HB repulsion, and solute-solute interactions. Its target audience includes researchers, scientists, and engineers in chemistry, physics, surface and interface science, materials science and engineering.

This book focuses on the study of the interfacial water using molecular dynamics simulation and experimental sum frequency generation spectroscopy. It proposes a new definition of the free O-H groups at water-air interface and presents research on the structure and dynamics of these groups. Furthermore, it discusses the exponential decay nature of the orientation distribution of the free O-H groups of interfacial water and ascribes the origin of the down pointing free O-H groups to the presence of capillary waves on the surface. It also describes how, based on this new definition, a maximum surface H-bond density of around 200 K at ice surface was found, as the maximum results from two competing effects. Lastly, the book discusses the absorption of water molecules at the water-TiO2 interface. Providing insights into the combination of molecular dynamics simulation and experimental sum frequency generation spectroscopy, it is a valuable resource for researchers in the field.