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Books > Science & Mathematics > Physics > Atomic & molecular physics
Prominent progress in science is inevitably associated with
controversies. Thus, young researchers, in particular, have to
learn how to persevere during the period of controversy and
struggle for acceptance. Unfortunately, the skills needed are not
taught in textbooks or monographs, which mostly describe the
consensus of contemporary experts.
Photothermal science continues to be an area of rapid development and active investigation, as is demonstrated by this volume. The various contributions present fundamental research in materials science, physics, chemistry, biology, and medicine, as well as important applications of photothermal techniques in nondestructive evaluation, aeronomy and pollution control, and other areas. The topics treated include measurements of spectral properties of gases, the theory of thermally generated elastic waves, a method of monitoring local surface displacements, materials characterization and nondestructive evaluation of materials, studies of the dynamics of primary photophysical processes, fast energy exchange at surfaces and at interfaces (e.g. in medicine and photobiology), thermal EXAFS and XANES applied to metals and semiconductors, and imaging of magnetic materials using microwave sources.
dissociation, E, of a dimer into two monomers and that, E', of a trimer into a dimer and a monomer. The observed velocity distribution for a beam of sodium iodide is shown in Fig. 23. The monomer and dimer distributions, which are each of the form of Eq. (9. 2), are separately shown. The sum of the two assumed distributions is seen to agree with the experimental data. The data for lithium bromide are shown in Fig. 24. The separate distributions for the monomer, dimer, and trimer required to fit the data are shown as is the sum of these distributions. An attempt to describe the observed distribution in terms of a monomer and a dimer only is shown by the dotted line, where the relative amounts of these species have been adjusted to give a fit on the low velocity side of the spectrum. Table 2. Summary oj data on the degree of association oj diatomic molecules. The data on the fluorides are from unpublished results of M. EISENSTADT, G. ROTHBERG and P. KUSCH. Uncertainties in E and E' are given in parentheses. E E' Temperature OK I ----- ----" Species at which a2 a, kcaljmole p 10-2mmHg RbCl 866 0. 063 48. 0 (0. 5) I KCI 0. 083 897 45.8 (0. 7) I KI 823 0. 046, 45.3 (0.9) NaC] 920 0. 259 44. 6 (0.9) i NaI 817 0. 235 38. 6 (3-4) LiC] 2."
A variety of novel applications for the investigation of disordered surfaces by beams of thermal energy atoms are discussed and illustrated by numerous examples. A straightforward semiclassical approach is introduced to yield a remarkably detailed insight into the lateral distributions of diffuse scatterers such as adsorbates, vacancies and atomic steps. The recent discovery that the long range Van der Waals force is the cause of the unusually large cross-sections for diffuse He-scattering on individual defects and impurities led the authors to propose a new methods of surface analysis. They introduce a semiclassical method, the overlap approach, to give a simple and detailed description of He-scattering from disordered surfaces. The method yields subtle, otherwise hardly obtainable information on the nature of interactions between diffuse scatterers. The authors address such questions as the lateral distribution of adsorbates, two-dimensional phase transitions, surface diffusions, and the morphology of growing or sputtered layers.
photoacoustic and Photothermal Phenomena contains reviews and a large numberof selected contributed papers reporting progress in the application of new photoacoustic and photo- thermal techniques in physics, chemistry, biology, medicine and materials science. Theoretical and experimental work is presented on spectroscopy, kinetics and relaxation, trace analysis, mass and heat transport, surfaces and thin films, nondestructive evaluation, ultrasonics and semiconductors.
The broad field of conformational motion disorder in crystals is described with particular attention to the separation from the well known mesophases of liquid crystals and plastic crystals. Structure, thermodynamics and motion of a larger number of small and large molecules are discussed. Of special interest are the borderlines between smectic and high viscosity liquid crystals and condis crystals and between plastic crystals and condis crystals as complicated by pseudorotation, jumping between symmetry-related states and hindered rotation. This paper illustrates the wide distribution of conformational disorder in nature. Condis crystals and glasses ("Con"formational "Dis"order) can be found in small and large molecule systems made of organic, inorganic and biological compounds. The condis state was newly discovered only four years ago. In this article over 100 examples are discussed as example of the condis state. In many cases the condis state was suggested for the first time. Motion in the Condensed State, Condis Crystals and their Relation to Plastic Crystals, Condis Crystals of Flexible Macromolecules, Condis Crystals and their Relation to Liquid Crystals, Condis Crystals of Stiff Macromolecules.
At the time when increasing numbers of chemists are being attracted by the fascination of supposedly easy computing and associated colourful imaging, this book appears as a counterpoint. The first part focuses on fundamental concepts of quantum chemistry, covering MCSCF theory, perturbation treatments, basis set developments, density matrices, wave function instabilities to correlation effects, and momentum space theory. The second part is devoted to more practical studies, ranging from the characterisation of exotic interstellar molecules, the accurate determination of spectroscopic constants, excited states structures and EPR parameters through photochemical and charge-transfer processes, cluster chemistry and fullerenes, muonium chemistry, to the possible prediction of the response of materials to electric fields in view of nonlinear optical applications. Audience: Graduate students and researchers whose work involves quantum chemistry, molecular physics, and materials modelling.
Nuclear magnetic resonance spectroscopy, which has evolved only within the last 20 years, has become one of the very important tools in chemistry and physics. The literature on its theory and application has grown immensely and a comprehensive and adequate treatment of all branches by one author, or even by several, becomes increasingly difficult. This series is planned to present articles written by experts working in various fields of nuclear magnetic resonance spectroscopy, and will contain review articles as well as progress reports and original work, its main aim, however, is to fill a gap, existing in literature, by publishing articles written by specialists, which take the reader from the introductory stage to the latest development in the field. The editors are grateful to the authors for the time and effort spent in writing the articles, and for their invaluable cooperation. The Editors Contents P. Diehl and C. L. Khetrapal NMR Studies of Molecules Oriented in the Nematic Phase of Liquid Crystais......................................................... 1 R. G. Jones The Use of Symmetry in Nuclear Magnetic Resonance................. 97 NMR Studies of Molecules Oriented in the Nematic Phase of Liquid Crystals P. DIEHL and C. L. KHETRAPAL * Department of Physics, University of Basel, Switzerland Contents 1. Introduction . . . . . . . . . . . . . . . . . . . .. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 3 2. Liquid Crystals . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 4 . . . . . . . . . . . . . . 2.1. Classification of Liquid Crystal Phases . . . . . . . . . . . . . . . . . . . . . . . 4 2.2. Theories of the Liquid Crystalline State . . . . . . . . . . . . . . . . . . . . . . 5 2.3. Nematic Phases . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 6 3. Experimental . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 7 1 4. Basic Theory (for I = I ). . . . . . . . . . . . . * . . . . . . . . . . . . . . . . . . . . . . . 7 . .
Il capitano generale lagrimo per allegrezza e nomino quel capo: Deseado, perehe l'avevamo gia gran tempo desiderato. Antonio Pigafetta Il Primo Viaggo in torno al Mondo I would like to take some poetic license in introducing this volume in a way that seems appropriate for a country, like Chile, that Iooks to the ocean. I believe it was Heisenberg who compared different times in physics with sailing a ship. He said that most of the time we keep our ships in port, or in the protection of a bay. But on a few occasions we go into the open sea, and those occasions are really the great times in theoretical physics, when everything can change. It does not seem totally unwarranted to hope that we are now entering one of those times. In that spirit, I would like to mention a wonderful book, which in English would be called something like Chile, Or a Crazy Geography.
This textbook is intended as an introduction to the physics of solar and stellar coronae, emphasizing kinetic plasma processes. It is addressed to observational astronomers, graduate students, and advanced undergraduates without a ba- ground in plasma physics. Coronal physics is today a vast field with many different aims and goals. So- ing out the really important aspects of an observed phenomenon and using the physics best suited for the case is a formidable problem. There are already several excellent books, oriented toward the interests of astrophysicists, that deal with the magnetohydrodynamics of stellar atmospheres, radiation transport, and radiation theory. In kinetic processes, the different particle velocities play an important role. This is the case when particle collisions can be neglected, for example in very brief phenomena - such as one period of a high-frequency wave - or in effects produced by energetic particles with very long collision times. Some of the most persistent problems of solar physics, like coronal heating, shock waves, flare energy release, and particle acceleration, are likely to be at least partially related to such p- cesses. Study of the Sun is not regarded here as an end in itself, but as the source of information for more general stellar applications. Our understanding of stellar processes relies heavily, in turn, on our understanding of solar processes. Thus an introduction to what is happening in hot, dilute coronae necessarily starts with the plasma physics of our nearest star.
Neutron radiography has in recent years emerged as a useful and complementary technology for radiation diagnosis. It is now routinely used in industrial quality assurance and in support of selected research and developmental activities. Conferences are held on the subject, pertinent handbooks exist, and technical papers appear regularly reporting on new developments. While neutron radiography has indeed passed through the transition from a scientific curiosity to technological relevance, it is a sign of its continuing dynamic evolution that little material has appeared which provides an integrated mathematical and physical analysis of the subject possessing both an instructional as well as reference function. It is our hope that this monograph will fill this need. The distinctiveness of neutron radiography rests on the unique interactions between neutrons and nuclei. This leads to some special relationships between the material and geometrical properties of an object and the neutron radiographic image. The evolution of a technical discipline demands that specific conceptual constructs be developed and their mathematical representations examined and compared with controlled experiments. Experience has convinced us that a particular and substantial body of knowledge has accumulated endowing neutron radiography with the essential foundations of a unique mathematical and physical science. Our scientific and professional involvement in neutron radiography began some 15 years ago when the senior author (A.A.H.) found himself with convenient access to the McMaster University Nuclear Reactor and research support from the Government of Canada.
This book is intended to give an introduction to intermolecular forces from an experimental point of view. Within the last 10 years the interest has turned more and more into an understanding of the weak, but important, int- molecular forces. New experimental techniques have been developed which have helped to gain more insight into this interesting topic. This book is intended as an introduction for graduate students who are familiar with the main concepts of n olecular spectroscopy. Special emphasis will be laid on the theoretical concepts. After a detailed description of experimental techniques, the results for two prototype systems which have been the subject of several studies in the literature within recent years will be presented. Ar-CO is becoming the most extensively studied van der Waals complex, theoretically and experimentally. Nevertheless, this example shows that even though the theory has greatly improved and has helped us to improve our knowledge of intermolecular forces, even for relatively simple cases the theory car1 still fall short of an accurate description. For a long time (NH3)2 was considered as a prototype for hydrogen bo- ing. However, subsequent experimental and theoretical studies have revealed the mysteries of the obtained spectra and proved that our previous concept of hydrogen bonds was just too naive.
The optical trapping of colloidal matter is an unequalled field of technology for enabling precise handling of particles on microscopic scales, solely by the force of light. Although the basic concept of optical tweezers, which are based on a single laser beam, has matured and found a vast number of exciting applications, in particular in the life sciences, there are strong demands for more sophisticated approaches. This thesis gives an introductory overview of existing optical micromanipulation techniques and reviews the state-of-the-art of the emerging field of structured light fields and their applications in optical trapping, micromanipulation, and organisation. The author presents established, and introduces novel concepts for the holographic and non-holographic shaping of a light field. A special emphasis of the work is the demonstration of advanced applications of the thus created structured light fields in optical micromanipulation, utilising various geometries and unconventional light propagation properties. While most of the concepts developed are demonstrated with artificial microscopic reference particles, the work concludes with a comprehensive demonstration of optical control and alignment of bacterial cells, and hierarchical supramolecular organisation utilising dedicated nanocontainer particles.
Powerful new techniques, including heavy ion and exotic beams, are pushing the frontiers of nuclear physics and opening up a wealth of new fields of research. After introductory chapters on theoretical and experimental aspects of nuclear collisions and beams, Exotic Nuclear Physics'' offers articles by experienced lecturers on forefront topics in nuclear physics, such as the conquest of the neutron and the proton drip-lines, nuclear astrophysics, the equation of state of hypernuclear matter, nuclear supersymmetry and chaotic motion in nuclei. This volume continues the successful tradition of published lecture notes from the Hispalensis International Summer School. It will benefit graduate students and lecturers in search of advanced material for self-study and courses as will as researchers in search of a modern and comprehensive source of reference.
The papers collected in this volume have been presented during a workshop on "Electron-Atom and Molecule Collisions" held at the Centre for Interdisciplinary Studies of the University of Bielefeld in May 1980. This workshop, part of a larger program concerned with the "Properties and Reactions of Isolated Molecules and Atoms," focused on the theory and computational techniques for the quanti tative description of electron scattering phenomena. With the advances which have been made in the accurate quantum mechanical characterisation of bound states of atoms and molecules, the more complicated description of the unbound systems and resonances important in electron collision processes has matured too. As expli cated in detail in the articles of this volume, the theory for the quantitative explanation of elastic and inelastic electron molecule collisions, of photo- and multiple photon ionization and even for electron impact ionization is well developed in a form which lends itself to a complete quantitative ab initio interpretation and pre diction of the observable effects. Many of the experiences gained and the techniques which have evolved over the years in the com putational characterization of bound states have become an essential basis for this development. To be sure, much needs to be done before we have a complete and detailed theoretical understanding of the known collisional processes and of the phenomena and effects, which may still be un covered with the continuing refinement of the experimental tech niques.
This volume is published in honor of Friedrich Hund's 100th birthday. It is a modern review on matter at high densities and pressures in astrophysics from Hund's early contribution to present-day ideas. The relation between the equation of state and the structure of compact cosmic objects is discussed, and two main contributions deal with the equation of state of baryonic matter at nuclear densities and with the numerical solution of the general relativistic field equations for non-rotating and rapidly rotating neutron stars. In a final chapter the present state of asteroseismology is presented as a tool to explore the interior of cosmic objects by analyzing the observed free oscillations of the Earth, the Sun, and white dwarf stars.
EPR of Free Radicals in Solids: Trends in Methods and Applications, 2nd ed. presents a critical two volume review of the methods and applications of EPR (ESR) for the study of free radical processes in solids. Emphasis is on the progress made in the developments in EPR technology, in the application of sophisticated matrix isolation techniques and in the advancement in quantitative EPR that have occurred since the 1st edition was published. Improvements have been made also at theoretical level, with the development of methods based on first principles and their application to the calculation of magnetic properties as well as in spectral simulations. EPR of Free Radicals in Solids I focuses on the trends in experimental and theoretical methods to extract structural and dynamical properties of radicals and spin probes in solid matrices by continuous wave (CW) and pulsed techniques. It presents simulation techniques and software for CW and pulsed EPR as well as studies of quantum effects at low temperature. The chapters dealing with quantum chemistry methods for the theoretical interpretation of hyperfine coupling tensors and g-tensors have been much extended in this edition and a new chapter on the calculation of zero-field splitting tensors has been added. This new edition is a valuable resource to experimentalists and theoreticians in research involving free radicals, as well as for students of advanced courses in physical chemistry, chemical physics, materials science, biophysics, biochemistry and related fields. This new edition is a valuable resource to experimentalists and theoreticians in research involving free radicals, as well as for students of advanced courses in physical chemistry, chemical physics, materials science, biophysics, biochemistry and related fields.
This volume is the outcome of a community-wide review of the field of dynamics and thermodynamics with nuclear degrees of freedom. It presents the achievements and the outstanding open questions in 26 articles collected in six topical sections and written by more than 60 authors. All authors are internationally recognized experts in their fields.
In response to the explosion of theories and experiments since the appearance of the first edition, the author has revised and expanded his basic text. New sections include up-to-date discussions of multiphoton ionization, and electron-atom and atom-atom scattering in laser fields, reaffirming the work's position as the standard introduction to the field. |
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