A comprehensive, in-depth presentation of theoretical underpinnings and mathematical techniques
This is the first book of its kind to combine all the theories of molecular reaction dynamics and chemical kinetics in a single source. It provides a sophisticated treatment of the material that functions both as a professional reference and a high-level text for PhD and postdoctoral researchers.
Advanced Molecular Dynamics and Chemical Kinetics offers exceptional, in-depth coverage and includes a complete discussion of the theoretical as well as mathematical presentation of techniques. It features relevant exercises as well as comprehensive coverage of:
* Second Quantization
* Semiclassical Theory
* Quantum Theory of Reaction Rates
* Feynman Path Integrals
* Wavepacket Propagation and Grid Methods
* Photodissociation
* Molecular Properties of Solvated Molecules
* Quantum Model for Electron Transfer
* Electron Transfer Coupling Elements
* Proton Transfer Reactions in Solution
This is the ideal reference for seasoned professionals in molecular reaction dynamics as well as for younger researchers who may want to enter the field or simply wish to learn more about it.
Also available: Introduction to Molecular Dynamics and Chemical Kinetics
Gert D. Billing and Kurt V. Mikkelsen

A thorough exploration of the atomic structures and properties of the essential engineering interfaces—an invaluable resource for students, teachers, and professionals

The most up-to-date, accessible guide to solid-vapor, solid-liquid, and solid-solid phase transformations, this innovative book contains the only unified treatment of these three central engineering interfaces. Employing a simple nearest-neighbor broken-bond model, Interfaces in Materials focuses on metal alloys in a straightforward approach that can be easily extended to all types of interfaces and materials. Enhanced with nearly 300 illustrations, along with extensive references and suggestions for further reading, this book provides:

• A simple, cohesive approach to understanding the atomic structure and properties of interfaces formed between solid, liquid, and vapor phases
• Self-contained discussions of each interface—allowing separate study of each phase transformation
• A comparative look at the different interfaces, including atomic structure and crystallography; anisotropy, roughening, and melting; interfacial stability and segregation; continuous and ledge growth models; and atomistic modeling
• An analysis of nearest-neighbor broken-bond results against thermodynamic and kinetic descriptions of the interfaces
• Problem sets at the end of each chapter, emphasizing the key concepts detailed in the text

Spanning the fields of chemical, electrical and computer engineering, materials science, solid-state physics, and microscopy, Interfaces in Materials bridges a major gap in the literature of surface and interface science.

This book presents a comprehensive theoretical basis of symmetry representations of molecular vibrations, matrix representation of symmetries, and the elements of group theory that are relevant to other symmetry elements/operations, crystallographic and molecular point groups. The book helps understand the reducible and irreducible representations of symmetry matrices and then derive the normal modes of vibration of different molecules by using suitable techniques independently. Targeted to graduate students and researchers, this book aims not only to derive the normal modes of vibration of any given molecule themselves but also compares and verifies them with the experimentally found modes by using IR and Raman-related techniques. For the first time in the crystallographic history, this book presents the group multiplication tables of all 32 point groups in both international and Schoenflies notations.

This book provides the basis for understanding the elastic properties of nucleic acids (DNA, RNA), the methods used to manipulate them (e.g. optical, magnetic and acoustic tweezers and traps), and how to observe their interactions with proteins (e.g. fluorescence microscopy, FCS, FRET, etc.). It then exemplifies the use of these various methods in the study of three families of DNA enzymes: polymerases, helicases and topoisomerases. The book aims not to be exhaustive, but rather to stimulate the imagination of readers in the application of these single molecule approaches to the study of DNA/RNA and their interactions.

Topics covered in this text include: structural aspects of polymers; molecular mobility in amorphous solid polymers; non-elastic deformation of solid amorphous polymers; mechanical experiments; interpretation of results; physical ageing of amorphous polymers; and glass transition.

Introduction to Gauge Field Theory provides comprehensive coverage of modern relativistic quantum field theory, emphasizing the details of actual calculations rather than the phenomenology of the applications. Forming a foundation in the subject, the book assumes knowledge of relativistic quantum mechanics, but not of quantum field theory. The book is ideal for graduate students, advanced undergraduates, and researchers in the field of particle physics.

This historical survey of the discovery of the electron has been published to coincide with the centenary of the discovery. The text maps the life and achievements of J.J. Thomson, with particular focus on his ideas and experiments leading to the discovery. It describes Thomson's early years and education. It then considers his career at Cambridge, first as a fellow of Trinity, later as the head of the Cavendish Laboratory and finally as Master of Trinity and national spokesman for science. The core of the book is concerned with the work undertaken at the Cavendish, culminating in the discovery of "corpuscles," later named "electrons."; In the final two chapters, the immediate aftermath and implications of the work are described. These include the creation of the subject of atomic physics as well as the broader long term developments which can be traced from vacuum valves and the transistor through to the microelectronics revolution.

Using the quantum approach to the subject of atomic physics, this text keeps the mathematics to the minimum needed for a clear and comprehensive understanding of the material. Beginning with an introduction and treatment of atomic structure, the book goes on to deal with quantum mechanics, atomic spectra and the theory of interaction between atoms and radiation. Continuing to more complex atoms and atomic structure in general, the book concludes with a treatment of quantum optics. Appendices deal with Rutherford scattering, calculation of spin-orbit energy, derivation of the Einstein B coefficient, the Pauli Exclusion Principle and the derivation of eigenstates in helium. The book should be of interest to undergraduate physics students at intermediate and advanced level and also to those on materials science and chemistry courses.

The Advances in Chemical Physics series provides the chemical physics and physical chemistry fields with a forum for critical, authoritative evaluations of advances in every area of the discipline. Filled with cutting-edge research reported in a cohesive manner not found elsewhere in the literature, each volume of the Advances in Chemical Physics series serves as the perfect supplement to any advanced graduate class devoted to the study of chemical physics.

The electron is fundamental to almost all aspects of modern life, controlling the behavior of atoms and how they bind together to form gases, liquids, and solids. Flash of the Cathode Rays: A History of J.J. Thomson's Electron presents the compelling story of the discovery of the electron and its role as the first subatomic particle in nature. The book traces the evolution of the concept of electrical charge, from the earliest glow discharge studies to the final cathode ray and oil drop experiments of J.J. Thomson and Robert Millikan. It also provides an overview of the history of modern physics up to the advent of the old quantum theory around 1920. Consolidating scholarly material while incorporating new material discovered by the well-respected author, the book covers the continental and English race for the source of the cathode rays, culminating in Thomson's corpuscle in 1897. It explores the events leading to Millikan's unambiguous isolation of the electron and the simultaneous circumstances surrounding the birth of Ernest Rutherford's nuclear atom and the discovery of radioactivity in 1896. The author also focuses on the controversies over N-rays, Becquerel's positive electron, and the famous Ehrenhaft-Millikan dispute over subelectrons. Scholarly yet accessible to those with basic physics knowledge, this book should be of interest to historians of science, professional scientists and engineers, teachers and students of physics, and general readers interested in the development of modern physics.

The present volume covers the story of the history of CERN from the mid 1960s to the late 1970s.

The book is organized in three main parts. The first, containing contributions by historians of science, perceives the laboratory as being at the node of a complex of interconnected relationships between scientists and science managers on the staff, the users in the member states, and the governments which were called upon to finance the organization. Parts II and III include chapters by practising scientists. The former surveys the theoretical and experimental physics results obtained at CERN in this period, while the latter describes the development of the laboratory's accelerator complex and Charpak detection techniques.

Written by two leading experts in the field, this book explores the 'many-body' methods that have become the dominant approach in determining molecular structure, properties and interactions. With a tight focus on the highly popular Many-Body Perturbation Theory (MBPT) and Coupled-Cluster theories (CC), the authors present a simple, clear, unified approach to describe the mathematical tools and diagrammatic techniques employed. Using this book the reader will be able to understand, derive and confidently implement relevant algebraic equations for current and even new multi-reference CC methods. Hundreds of diagrams throughout the book enhance reader understanding through visualization of computational procedures and extensive referencing allows further exploration of this evolving area. With an extensive bibliography and detailed index, this book will be suitable for graduates and researchers within quantum chemistry, chemical physics and atomic, molecular and solid-state physics.

Integrating molecular physics and information theory, this work presents molecular electronics as a method for information storage and retrieval that incorporates nanometer-scaled systems, uses microscopic particles and exploits the laws of quantum mechanics. It furnishes application examples employing properties of distinct molecules joined together to a macroscopic ensemble of virtually identical units.

Acknowledged as the "founding father" of and world renowned expert on electron cyclotron resonance sources Richard Geller has produced a unique book devoted to the physics and technicalities of electron cyclotron resonance sources. Electron Cyclotron Resonance Ion Sources and ECR Plasmas provides a primer on electron cyclotron phenomena in ion sources as well as being a reference to the field of ion source developments. Coverage includes elements of plasma physics, specific electron cyclotron resonance physics, and the relevant technology directed at both scientists and engineers.

The Weak Interaction in Nuclear, Particle and Astrophysics presents concepts of the weak interaction and its integration into modern gauge theories of particle physics, such as grand unification and supersymmetry. The book explores the close connections between micro (nuclear and particle) physics and macro physics (astrophysics and cosmology) induced by the weak interaction. Special attention is given to neutrinos, which have a key role in the understanding of elementary particle theories. In addition to the theoretical aspects, the book covers the important research topics of solar and galactic neutrinos and double beta decay. Assuming knowledge of elementary electrodynamics and quantum mechanics, this resource provides an insight into the diversity of the problem areas associated with the weak interaction and will encourage intensive study of particular themes.

This book is intended for senior undergraduate and beginning graduate students in physics, nuclear engineering, health physics and nuclear medicine, and for specialized training courses for radiation protection personnel and environmental safety engineers.To keep the size of the book manageable, material has been selected to stress those detectors that are in widespread use. Attempts have also been made to emphasize alternatives available in approaching various measurement problems and to present the criteria by which a choice among these alternatives may be made.

The search for the elementary constituents of the physical universe and the interactions between them has transformed over time and continues to evolve today, as we seek answers to questions about the existence of stars, galaxies, and humankind. Integrating both theoretical and experimental work, Exploring Fundamental Particles traces the development of this fascinating field, from the discoveries of Newton, Fermi, and Feynman to the detection of CP violation and neutrinos to the quest to observe the Higgs boson and beyond. An Accessible yet In-Depth Account of How Fundamental Particles Shape Our World The book first examines the experiments and theoretical ideas that gave rise to the standard model. It discusses special relativity, angular momentum, spin, the Dirac electron, quantum field theory, Feynman diagrams, Pauli's neutrino, Fermi's weak interaction, Yukawa's pion, the muon neutrino, quarks, leptons, and flavor symmetry. The authors then explain the violation of the symmetry between matter and antimatter, known as CP violation. They cover the discoveries of CP violation in the decays of kaons and B mesons as well as future experiments that could detect possible CP violation beyond the standard model. In the next part, the authors present experimental results involving the once-mysterious neutrino. They explore the evidence that neutrinos have mass, new neutrino experiments in various countries, and the potential of neutrino astronomy to offer a new perspective on stars and galaxies. The final section focuses on the one undetected particle of the standard model: the Higgs boson. The authors review the experiments that established important constraints on the mass of the Higgs particle. They also highlight recent experiments of the Tevatron particle accelerator at Fermilab, along with the near future impact of the Large Hadron Collider (LHC) at CERN and th

Supersymmetry (SUSY) is one of the most important ideas ever conceived in particle physics. It is a symmetry that relates known elementary particles of a certain spin to as yet undiscovered particles that differ by half a unit of that spin (known as Superparticles). Supersymmetric models now stand as the most promising candidates for a unified theory beyond the Standard Model (SM). SUSY is an elegant and simple theory, but its existence lacks direct proof. Instead of dismissing supersymmetry altogether, Supersymmetry Beyond Minimality: from Theory to Experiment suggests that SUSY may exist in more complex and subtle manifestation than the minimal model. The book explores in detail non-minimal SUSY models, in a bottom-up approach that interconnects experimental phenomena in the fermionic and bosonic sectors. The book considers with equal emphasis the Higgs and Superparticle sectors, and explains both collider and non-collider experiments. Uniquely, the book explores charge/parity and lepton flavour violation. Supersymmetry Beyond Minimality: from Theory to Experiment provides an introduction to well-motivated examples of such non-minimal SUSY models, including the ingredients for generating neutrino masses and/or relaxing the tension with the heavily constraining Large Hadron Collider (LHC) data. Examples of these scenarios are explored in depth, in particular the discussions on Next-to-Minimal Supersymmetric SM (NMSSM) and B-L Supersymmetric SM (BLSSM).

Atomic and molecular beams are employed in physics and chemistry experiments and, to a lesser extent, in the biological sciences. These beams enable atoms to be studied under collision-free conditions and allow the study of their interaction with other atoms, charged particles, radiation, and surfaces. Atomic and Molecular Beams: Production and Collimation explores the latest techniques for producing a beam from any substance as well as from the dissociation of hydrogen, oxygen, nitrogen, and the halogens. The book not only provides the basic expressions essential to beam design but also offers in-depth coverage of: Design of ovens and furnaces for atomic beam production Creation of atomic beams that require higher evaporation temperatures Theory of beam formation including the Clausing equation and the transmission probability Construction of collimating arrays in metals, plastics, glass, and other materials Optimization of the design of atomic beam collimators While many review articles and books discuss the application of atomic beams, few give technical details of their production. Focusing on practical application in the laboratory, the author critically reviews over 800 references to compare the atomic and molecular beam formation theories with actual experiments. Atomic and Molecular Beams: Production and Collimation is a comprehensive source of material for experimentalists facing the design of any atomic or molecular beam and theoreticians wishing to extend the theory.

* Devoted to discussing the interaction between hadrons with nuclei* Discusses experimental data and the methods and results of the calculation of probabilities of various processes initiated by intermediate-energy hadrons in nuclei* Analyzes the potential for obtaining information on the structure and properties of nuclei by comparing experimental data with theoretical results* Covers new issues, such as analytic methods for the solution of kinetic equations describing the cascade and nuclear absorption of hadrons from bound states of hadronic atoms

Recent research has brought the application of microwaves from the classical fields of heating, communication, and generation of plasma discharges into the generation of compact plasmas that can be used for applications such as FIB and small plasma thrusters. However, these new applications bring with them a new set of challenges. With coverage ranging from the basics to new and emerging applications, Compact Plasma and Focused Ion Beams discusses how compact high-density microwave plasmas with dimensions smaller than the geometrical cutoff dimension can be generated and utilized for providing focused ion beams of various elements. Starting with the fundamentals of the cutoff problem for wave propagation in waveguides and plasma diagnostics, the author goes on to explain in detail the plasma production by microwaves in a compact geometry and narrow tubes. He then thoroughly discusses wave interaction with bounded plasmas and provides a deeper understanding of the physics. The book concludes with an up-to-date account of recent research on pulsed microwaves and the application of compact microwave plasmas for multi-element FIB. It provides a consolidated and unified description of the emerging areas in plasma science and technology utilizing wave-based plasma sources based on the author's own work and experience. The book will be useful not only to established researchers in this area but will also serve as an excellent introduction to those interested in applying these ideas to various current and new applications.

With the constant emergence of new research and application possibilities, gaseous electronics is more important than ever in disciplines including engineering (electrical, power, mechanical, electronics, and environmental), physics, and electronics. The first resource of its kind, Gaseous Electronics: Tables, Atoms, and Molecules fulfills the author's vision of a stand-alone reference to condense 100 years of research on electron-neutral collision data into one easily searchable volume. It presents most-if not all-of the properly classified experimental results that scientists, researchers, and students require for a theoretical and practical understanding of collision properties and their impact. An unprecedented collection and analysis of electron neutral collision properties This book follows a new user-friendly format that enables readers to easily retrieve, analyze, and apply specific atomic/molecular information as needed. In his previous work, Gaseous Electronics: Theory and Practice, the author first explored electron-neutron interactions. To clarify the complex fundamental processes involved, he cited as much experimental data on atoms and molecules as limited space would allow. Completing that task, this handy reference more fully compiles essential revised data on more than 420 atoms and molecules, arranging it into easily digestible chapters, sections, and appendices. Analysis parameters include total scattering, ionization, excitation, attachment cross sections, ionization and attachment coefficients, attachment rates, and ion drift velocity. Some recent research areas in gaseous electronics include: Environmentally efficient and protective lighting devices Plasma research for power generation and space applications Medical applications (some involving skin treatment and healing) Written entirely in SI units, the book includes hundreds of tables, figures, and specially drawn charts, with data expressed in both tabular and graphical form. Each chapter stands independently and contains references for further research.

Relating the story of the transatlantic struggle for subnuclear domination, The Quark Machines: How Europe Fought the Particle Physics War, Second Edition covers the history, the politics, and the personalities of particle physics. Extensively illustrated with many original photographs of the key players in the field, the book sheds new light on the sovereignty issues of modern scientific research as well as the insights it has produced. Throughout the twentieth century, Europe and the United States have vied for supremacy of subnuclear physics. Initially, the advent of World War II and an enforced exodus of scientific talent from Europe boosted American efforts. Then, buoyed along by the need to develop the bomb and the ensuing distrust of the Cold War, the United States vaulted into a commanding role-a position it retained for almost fifty years. Throughout this period, each new particle accelerator was a major campaign, each new particle a battle won. With the end of the Cold War, U.S. preeminence evaporated and Europe retook the advantage. Now CERN, for four decades the spearhead of the European fightback, stands as the leading global particle physics center. Today, particle physics is at a turning point in its history-how well Europe retains its advantage remains to be seen.

Not since Newton s apple has there been a physics phenomenon as deliciously appealing to the masses as Frank Close s Cosmic Onion. Widely embraced by scientists and laypersons alike, the book quickly became an international bestseller. Translated into seven languages, it propelled the author to become a worldwide celebrity as well as an inspiration to a generation of scientists. The book s title itself has entered popular usage as a metaphor for the layers that can be peeled away to understand the foundations of the physical world, from dimensions and galaxies, to atoms and quarks. Close is a lucid, reliable, and enthusiastic guide to the strange and wonderful microcosmic world that dwells deep within reality Frank Wilczek, Herman Feshbach Professor of Physics, MIT, 2004 Nobel Prize in Physics NEW Material Explains the principles behind the Hadron Collider as well as the potential it presents Considers the recent development of the Electroweak Theory as a law of nature Explores the mysteries uncovered and the ones that may be in store with regard to top and bottom quarks Keeping still-pertinent contents from the original volume that caught the world s attention in 1983, this fresh edition of the Cosmic Onion includes extensive new material to reflect new views of the

Introduces Novel Applications for Solving Neutron Transport Equations While deemed nonessential in the past, fractional calculus is now gaining momentum in the science and engineering community. Various disciplines have discovered that realistic models of physical phenomenon can be achieved with fractional calculus and are using them in numerous ways. Since fractional calculus represents a reactor more closely than classical integer order calculus, Fractional Calculus with Applications for Nuclear Reactor Dynamics focuses on the application of fractional calculus to describe the physical behavior of nuclear reactors. It applies fractional calculus to incorporate the mathematical methods used to analyze the diffusion theory model of neutron transport and explains the role of neutron transport in reactor theory. The author discusses fractional calculus and the numerical solution for fractional neutron point kinetic equation (FNPKE), introduces the technique for efficient and accurate numerical computation for FNPKE with different values of reactivity, and analyzes the fractional neutron point kinetic (FNPK) model for the dynamic behavior of neutron motion. The book begins with an overview of nuclear reactors, explains how nuclear energy is extracted from reactors, and explores the behavior of neutron density using reactivity functions. It also demonstrates the applicability of the Haar wavelet method and introduces the neutron diffusion concept to aid readers in understanding the complex behavior of average neutron motion. This text: Applies the effective analytical and numerical methods to obtain the solution for the NDE Determines the numerical solution for one-group delayed neutron FNPKE by the explicit finite difference method Provides the numerical solution for classical as well as fractional neutron point kinetic equations Proposes the Haar wavelet operational method (HWOM) to obtain the numerical approximate solution of the neutron point kinetic equation, and more Fractional Calculus with Applications for Nuclear Reactor Dynamics thoroughly and systematically presents the concepts of fractional calculus and emphasizes the relevance of its application to the nuclear reactor.