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Books > Science & Mathematics > Chemistry > Analytical chemistry > Qualitative analytical chemistry > Chemical spectroscopy, spectrochemistry > General
This book provides a multidisciplinary overview to the application
of high order derivative spectrophotometry and Electron Spin
Resonance (ESR) spectroscopy in biology and ecology. The
characteristics of the principle methods as well as the generation
of reliable spectra are discussed in general terms allowing the
reader to gain an idea of these methods' potentials. Furthermore
the authors give an extended overview to the spectroscopic and
spectro-photometric analysis of specific biological materials. This
volume is a well condensed description of an analytical method and
a clear review to its application in biology and related fields and
an essential tool for researchers who are new in the field of
spectroscopic methods and their applications in the life sciences.
This book presents the state-of-the-art of Terahertz spectroscopy.
It is a modern source for a beginners and researcher interested in
THz spectroscopy. The basics and physical background of THz
spectroscopy and technology are explained, and important
applications are described. The book presents the highlights of
scientific research in the field of THz science and provides an
excellent overview of the field and future directions of research.
Over the last decade the field of terahertz spectroscopy has
developed into one of the most rapidly growing fields of
spectroscopy with large impact across a wide range of scientific
disciplines. Due to substantial advances in femtosecond laser
technology, terahertz time-domain spectroscopy (THz-TDS) has
established itself as the dominant spectroscopic technique for
experimental scientists interested in measurements in this
frequency range. In solids and liquids terahertz radiation is at
resonance with both phonon modes and hydrogen bonding modes which
makes it an ideal tool to study the interaction between molecules
in a unique way, thus opening a wealth of opportunities for
research in physics, chemistry, biology, materials science and
pharmaceuticals. This book provides an easy access to scientists,
engineers and students alike who want to understand the theory and
applications of modern terahertz spectroscopy.
The RF front-end - antenna combination is a vital part of a mobile
phone because its performance is very relevant to the link quality
between hand-set and cellular network base-stations. The RF
front-end performance suffers from changes in operating
environment, like hand-effects, that are often unpredictable.
Adaptive RF Front-Ends for Hand-Held Applications presents an
analysis on the impact of fluctuating environmental parameters. In
order to overcome undesired behavior two different adaptive control
methods are treated that make RF frond-ends more resilient:
adaptive impedance control, and adaptive power control. Several
adaptive impedance control techniques are discussed, using a priori
knowledge on matching network properties, in order to simplify
robust 2-dimensional control. A generic protection concept is
presented, based on adaptive power control, which improves the
ruggedness of a power amplifier or preserves its linearity under
extremes. It comprises over-voltage, over-temperature, and
under-voltage protection.
Progress continues in the theoretical treatment of surfaces and
processes on surfaces based on first-principles methods, i.e.
without invoking any empirical parameters. In this book, the
theoretical concepts and computational tools necessary and relevant
for a microscopic approach to the theoretical description of
surface science is presented, together with a detailed discussion
of surface phenomena. This makes the book suitable for both
graduate students and for experimentalists seeking an overview of
the theoretical concepts in surface science. This second enlarged
edition has been carefully revised and updated, a new chapter on
surface magnetism is included, and novel developments in
theoretical surface science are addressed.
Abstract This chapter lays the foundation for the work presented in
latter chapters. The potential of 60 GHz frequency bands for high
data rate wireless transfer is discussed and promising applications
are enlisted. Furthermore, the challenges related to 60 GHz IC
design are presented and the chapter concludes with an outline of
the book. Keywords Wireless communication 60 GHz Millimeter wave
integrated circuit design Phase-locked loop CMOS Communication
technology has revolutionized our way of living over the last
century. Since Marconi's transatlantic wireless experiment in 1901,
there has been tremendous growth in wireless communication evolving
from spark-gap telegraphy to today's mobile phones equipped with
Internet access and multimedia capabilities. The omnipresence of
wireless communication can be observed in widespread use of
cellular telephony, short-range communication through wireless
local area networks and personal area networks, wireless sensors
and many others. The frequency spectrum from 1 to 6 GHz
accommodates the vast majority of current wireless standards and
applications. Coupled with the availability of low cost radio
frequency (RF) components and mature integrated circuit (IC) techn-
ogies, rapid expansion and implementation of these systems is
witnessed. The downside of this expansion is the resulting scarcity
of available bandwidth and allowable transmit powers. In addition,
stringent limitations on spectrum and energy emissions have been
enforced by regulatory bodies to avoid interference between
different wireless systems.
This book is loosely based on a Multidisciplinary University
Research Initiative (MURI) project and a few supplemental projects
sponsored by the Of?ce of Naval Research (ONR) during the time
frame of 2004-2009. The initial technical scope and vision of the
MURI project was formulated by Drs. Larry Cooper and Joel Davis,
both program of?cers at ONR at the time. The unifying theme of this
MURI project and its companionefforts is the concept of cellular
nonlinear/neuralnetwork (CNN) technology and its various extensions
and chip implementations, including nanoscale sensors and the
broadening ?eld of cellular wave computing. In recent years,
CNN-based vision system drew much attention from vision scientists
to device technologists and computer architects. Due to its early -
plementation in a two-dimensional (2D) topography, it found success
in early vision technologyapplications, such as focal-plane arrays,
locally adaptable sensor/ processor integration, resulting in
extremely high frame rates of 10,000 frames per second. More
recently it drew increasing attention from computer architects, due
to its intrinsic local interconnect architecture and parallel
processing paradigm. As a result, a few spin-off companies have
already been successful in bringing cel- lar wave computing and CNN
technology to the market. This book aims to capture some of the
recent advances in the ?eld of CNN research and a few select areas
of applications.
The third volume of this book addresses central aspects of
spin-dynamic phenomena on a tutorial level. This volume
concentrates on new experimental techniques such as
ferromagnetic-resonance-force microscopy and two-photon
photoemission. There is a chapter devoted to the hot subject of
spin-transfer torque. The comprehensive presentation makes this a
timely and valuable resource for every researcher working in the
field of magnetism.
The field of Atomic and Molecular Physics (AMP) has reached
significant advances in high-precision experimental measurement
techniques. The area covers a wide spectrum ranging from
conventional to new emerging multi-disciplinary areas like physics
of highly charged ions (HCI), molecular physics, optical science,
ultrafast laser technology etc. This book includes the important
topics of atomic structure, physics of atomic collision,
photoexcitation, photoionization processes, Laser cooling and
trapping, Bose Einstein condensation and advanced technology
applications of AMP in the fields of astronomy, astrophysics,
fusion, biology and nanotechnology. This book is useful for
researchers, professors, graduate, postgraduate and PhD students
dealing with atomic and molecular physics. The book has a wide
scope with applications in neighboring fields like plasma physics,
astrophysics, cold collisions, nanotechnology and future fusion
energy sources like ITER (international Thermonuclear Experimental
Reactor) Tokomak plasma machine, which need accurate AMP data.
Device Architecture and Materials for Organic Light-Emitting
Devices focuses on the design of new device and material concepts
for organic light-emitting devices, thereby targeting high current
densities and an improved control of the triplet concentration. A
new light-emitting device architecture, the OLED with field-effect
electron transport, is demonstrated. This device is a hybrid
between a diode and a field-effect transistor. Compared to
conventional OLEDs, the metallic cathode is displaced by one to
several micrometers from the light-emitting zone, reducing optical
absorption losses. The electrons injected by the cathode accumulate
at an organic heterojunction and are transported to the
light-emission zone by field-effect. High mobilities for charge
carriers are achieved in this way, enabling a high current density
and a reduced number of charge carriers in the device. Pulsed
excitation experiments show that pulses down to 1 s can be applied
to this structure without affecting the light intensity, suggesting
that pulsed excitation might be useful to reduce the accumulation
of triplets in the device. The combination of all these properties
makes the OLED with field-effect electron transport particularly
interesting for waveguide devices and future electrically pumped
lasers. In addition, triplet-emitter doped organic materials, as
well as the use of triplet scavengers in conjugated polymers are
investigated.
This thesis presents the theory of three key elements of optical
spectroscopy of the electronic excitations in bilayer graphene:
angle-resolved photoemission spectroscopy (ARPES), visible range
Raman spectroscopy, and far-infrared (FIR) magneto-spectroscopy.
Bilayer graphene (BLG) is an atomic two-dimensional crystal
consisting of two honeycomb monolayers of carbon, arranged
according to Bernal stacking. The unperturbed BLG has a unique band
structure, which features chiral states of electrons with a
characteristic Berry phase of 2$\pi$, and it has versatile
properties which can be controlled by an externally applied
transverse electric field and strain. It is shown in this work how
ARPES of BLG can be used to obtain direct information about the
chirality of electron states in the crystal. The author goes on to
describe the influence of the interlayer asymmetry, which opens a
gap in BLG, on ARPES and on FIR spectra in a strong magnetic field.
Finally, he presents a comprehensive theory of inelastic Raman
scattering resulting in the electron-hole excitations in bilayer
graphene, at zero and quantizing magnetic fields. This predicts
their polarization properties and peculiar selection rules in terms
of the inter-Landau-level transitions.
The reader is provided with information about methods of
calibration of light sources and photodetectors as well as
responsiveness of spectral instruments ranging from near infrared
to vacuum UV spectral, 1200 - 100 nm, and radiation intensities of
up to several quanta per second in absolute and arbitrary units.
The author describes for the first time original methods of
measurements they created and draws upon over 40 years of
experience in working with light sources and detectors to provide
accurate and precise measurements. This book is the first to cover
these aspects of radiometry and is divided into seven chapters that
examine information about terminology, units, light sources and
detectors, methods, including author's original ones, of absolute
calibration of detectors, spectral instruments responsiveness,
absolute measurements of radiation intensity of photoprocesses, and
original methods of their study. Of interest to researchers
measuring; luminescence spectra, light intensities from IR to
vacuum UV, spectral range in wide-light intensity ranges, calibrate
light sources and detectors, absolute or relative quantum yields of
photoprocess determination.
The book is based on lectures presented on the International Summer
School on Biophysics held in Croatia in September 2009. The
advantage of the School is that it provides advanced training in
very broad scope of areas related to biophysics contrary to other
similar schools or workshops that are centered mainly on one topic
or technique. In this volume, tenth in the row, the papers in the
field of biophysics are presented. The topics are biological
phenomena from single protein to macromolecular aggregations
structure by using variant physical methods (NMR, EPR, FTIR, Mass
Spectrometry, etc.). The interrelationship of supramolecular
structures and their functions is enlightened by applications of
principals of these physical methods in the biophysical and
molecular biology context.
This thesis describes a new approach for cell analysis by the rapid
developing microfluidic technology. The nominee has made great
contributions to develop a new analysis platform which combined
microfluidic devices with mass spectrometry to determine the trace
compounds secreted by cells. Based on this analysis platform, she
studied the specific cell secreting behaviors under controlled
microenvironment, of which the secretion compounds were qualified
and semi-quantified by mass spectrometry. A novel cell sorting
device integrated homogenous porous PDMS membrane was invented to
classify cells from real samples based on the size difference. The
nominee further studied the signal transmission between different
cells, and the signal chemicals were qualitative and quantitative
monitored by the analysis platform. This indicates the potential
significant application of the new cell analysis platform in
medicine screening and early diagnosis.
This NATO-ASIinstallment is designed to provide an advanced
overview for doctoral and post-doctoral candidates of the
state-of-the-art technologies for bio-detection. The main objective
of the work aims at providingreaders with the latest developments
necessary to successfully understand the CBRN Agents and their
associated biotechnologies.
The core methods focused on aremass spectrometry (including
chromatographic and electrophoretic separation) and comparisons to
spectroscopic, immunological and molecular analysis of chemical,
biological and nuclear agents."
Simple carbohydrates, complex oligosaccharides and polysaccharides
all belong to a class of ubiquitous (macro)molecules that exhibit a
wide range of biological functions, and the recent advent of
enhanced enzymatic, chemical and analytical tools used to study
these sugars has inaugurated a genuine explosion in the field of
glycomics. Specifically, it has led to a deeper understanding of
how specific sugar structures modulate cellular phenotypes, and
that breakthrough has led to the discovery of new pharmaceuticals
for the treatment of many serious diseases, such as cancer. The
subsequent rapid expansion of this research holds high promise for
future therapeutic regimens, and capillary electrophoresis (CE)
refers to the range of related separation techniques that are
integral to this vital research. CE uses narrow-bore fused-silica
capillaries to separate a complex array of large and small
molecules, and Capillary Electrophoresis of Carbohydrates offers a
comprehensive look at the latest breakthroughs and improvements in
CE and CE techniques applied to monosaccharides up to complex
oligosaccharides and polysaccharides. It begins with an overview of
the application of CE and CE- mass spectrometric in the analysis of
simple carbohydrates without any previous derivatization step
before discussing various detection techniques such as
spectrophotometric detection, electrochemical detection and other
less common techniques. It then covers in detail an array of
related topics and numerous applications. It is an essential text
for anyone exploring the myriad possibilities of this rapidly
expanding field.
To anyone who is interested in surface chemical analysis of
materials on the nanometer scale, this book is prepared to give
appropriate information. Based on typical application examples in
materials science, a concise approach to all aspects of
quantitative analysis of surfaces and thin films with AES and XPS
is provided. Starting from basic principles which are step by step
developed into practically useful equations, extensive guidance is
given to graduate students as well as to experienced researchers.
Key chapters are those on quantitative surface analysis and on
quantitative depth profiling, including recent developments in
topics such as surface excitation parameter and backscattering
correction factor. Basic relations are derived for emission and
excitation angle dependencies in the analysis of bulk material and
of fractional nano-layer structures, and for both smooth and rough
surfaces. It is shown how to optimize the analytical strategy,
signal-to-noise ratio, certainty and detection limit. Worked
examples for quantification of alloys and of layer structures in
practical cases (e.g. contamination, evaporation, segregation and
oxidation) are used to critically review different approaches to
quantification with respect to average matrix correction factors
and matrix relative sensitivity factors. State-of-the-art issues in
quantitative, destructive and non-destructive depth profiling are
discussed with emphasis on sputter depth profiling and on angle
resolved XPS and AES. Taking into account preferential sputtering
and electron backscattering corrections, an introduction to the
mixing-roughness-information depth (MRI) model and its extensions
is presented.
This book outlines, with the help of several specific examples, the
important role played by absorption spectroscopy in the
investigation of deep-level centers introduced in semiconductors
and insulators like diamond, silicon, germanium and gallium
arsenide by high-energy irradiation, residual impurities, and
defects produced during crystal growth. It also describes the
crucial role played by vibrational spectroscopy to determine the
atomic structure and symmetry of complexes associated with light
impurities like hydrogen, carbon, nitrogen and oxygen, and as a
tool for quantitative analysis of these elements in the materials.
Proceedings of the 9th Latin American Conference on the
Applications of the Moessbauer Effect, LACAME 2004, held in Mexico
City, Mexico, 19-24 September 2004. This volume demonstrates the
way in which researchers, on a wide range of topics, many
interdisciplinary, find the applications of the Moessbauer Effect
an outstanding method whose results, sometimes unique, complements
and improves the information obtained by other techniques to deepen
the understanding of the matter under research. This volume
comprises research papers, reviews, and short communications
recording original investigations on applications to diverse areas
like archaeology, metallurgy, soil science, geology, industrial
applications, new instrumentation, corrosion, and chemical
applications. The papers present the latest scientific work of
various regional investigators and of the invited speakers from
abroad that have brought their perspectives to the meeting.
arranged. Among them the following types are met: nanotubes, nanop-
ticles, nanopowders, nano?bers, nanowires, nanocomposites, etc. *
At the microscale - Microcomposites, such as metal matrix
composites (MMCs), ceramic matrix composites (CMCs), alloys or
superalloys, s- tered powders, ceramic materials,
magnetorheological ?uids (MRFs), etc. * At the macroscale -
Macrocomposites, such as functionally graded ma- rials (FGMs), thin
layers or ?lms, thermal or oxidation or wear resistant coatings,
multilayered structures, long ?ber composites, etc. At each level
of analysis a response of the material to any physical excitation
may be observed, measured and analyzed. In the sense of innovation
of a material, the changes or new ideas can be introduced on the
same scale of control (say, atomic or nano) in order to achieve
fundamentally new behavior on the other scale of observation (say,
micro or macro). For instance, by replacing some similar atoms in
the metal crystal str- ture (e. g. Ti-Ti or Al-Al), by unlike atoms
in the crystal (e. g. Ti-Al), wi- out the lattice symmetry of the
original material changing, new improved properties and
characteristics may be observed in intermetallics at the - cro or
macroscale (higher speci?c strength, better creep resistance at
elevated temperatures, better corrosion resistance, to mention only
some properties observed at the macroscale). Similarly, changing
material characteristics at the nanoscale, enables creation of
completely new material functionality at micro or macroscales (e.
g.
1989 was by any standards an extraordinary year: the year in which
the Cold War ended. However, although much has changed, much
remains unresolved or not changed at all. Even though the rationale
for the huge military forces has been removed from the East-West
relationship, these forces still retain a tremendous potential to
do harm. Moreover, threats to peace may grow along North-South and
South-South axes. An example of such a threat is the rapid growth
in size and sophistication of military arsenals in the South. The
contributions to this volume make it clear that the problems of
East and West, North and South are inter- twined. Security can be
gained only through cooperation. The contributors, who come from
widely differing geographical, cultural and political backgrounds,
all share the Pugwash tradition of scientific objectivity.
This volume originated in a happy event honoring Arthur Schawlow on
his 65th birthday. As a research physicist, Schawlow has been a
major infiuence on the present nature of physics and of high
technology. He has also had a role, through the American Physical
Society and other organizations, in shaping policy for the world of
physicists. Important as these professional activities have been,
the contributions to this volume were not prepared just for these
reasons, but more for Art Schawlow the friend, colleague, and
teacher. I am one who has had the privilege of knowing and
collaborating with Art, probably over a longer period of time than
others participating in this volume, and in a number of different
enterprises; his friendship and stimulating scientific abilities
are a very significant part of my own life. It is hence a pleasure
to take part in this volume celebrating his contributions to
science and to scientists. Schawlow's career has been
geographically centered at the University of Toronto, Columbia
University, the Bell Telephone Laboratories, and Stan ford
University. But, as is illustrated by the papers of this volume,
its effects and his personal infiuence have diffused widely. In his
own work, Art Schawlow is noted for thoughtful imagination, keen
physical intuition, and what might be thought an interest in
gadgets - not just any gadgets, but beautiful and innovative
mechanisms or new techniques in which he charac teristically
recognizes important potentials.
This volume contains a series of six lecture courses presented by
some of the leading exponents in the field of low-temperature
physics. Special emphasis is given to theoretical and experimental
advances in our understanding of 3He, heavy fermion systems and
high-Tc superconductivity. The book provide an ideal basis for
graduate courses in low-temperature physics.
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