This book discusses the latest investigations into the electronic structure of narrow-gap semiconductors in extreme conditions, and describes in detail magnetic field and pressure measurements using two high-quality single crystals: black phosphorus (BP) and lead telluride (PbTe). The book presents two significant findings for BP and PbTe. The first is the successful demonstration of the pressure-induced transition from semiconductor to semimetal in the electronic structure of BP using magnetoresistance measurements. The second is the quantitative estimation of how well the Dirac fermion description works for electronic properties in PbTe. The overviews on BP and PbTe from the point of view of material properties help readers quickly understand the typical electronic character of narrow-gap semiconductor materials, which has recently attracted interest in topological features in condensed matter physics. Additionally the introductory review of the principles and methodology allows readers to understand the high magnetic field and pressure experiments.

Polarization-division interferometers have greatly increased the applications of infrared spectroscopy in recent years. This first dedicated book on the topic includes a chapter on the principles of polarization-division interferometric spectrometry followed by four chapters highlighting the range of applications of this important technique. Applications as diverse as the verification of the Big Bang theory and material characterization are discussed by leading researchers in their respective fields, so the book as a whole serves as a state of the art reference on the subject. The editor, Professor Prasad Polavarapu, has carried out important research in this area including the development of a Martin-Puplett interferometer. He has gathered together an international group of contributors of world-wide renown.

This is the second volume of textbooks on atomic, molecular and optical physics, aiming at a comprehensive presentation of this highly productive branch of modern physics as an indispensable basis for many areas in physics and chemistry as well as in state of the art bio- and material-sciences. It primarily addresses advanced students (including PhD students), but in a number of selected subject areas the reader is lead up to the frontiers of present research. Thus even the active scientist is addressed. This volume 2 introduces lasers and quantum optics, while the main focus is on the structure of molecules and their spectroscopy, as well as on collision physics as the continuum counterpart to bound molecular states. The emphasis is always on the experiment and its interpretation, while the necessary theory is introduced from this perspective in a compact and occasionally somewhat heuristic manner, easy to follow even for beginners.

Whole Pattern Fitting, Rietveld Analysis, and Calculated Diffraction Patterns. Quantitative Phase Analysis by XRay Diffraction (XRD). Thin Film and Surface Characterization by XRD. Lattice Defects and XRay Topography. Texture Analysis by XRD. XRD Instrumentation, Techniques, and Reference Materials. Stress Determination by Diffraction Methods. XRD Profile Fitting, Crystallite Size and Strain Determination. XRD Applications: Detection Limits, Superconductors, Organics, Minerals. Mathematical Methods in XRay Spectrometry (XRS). Thin Film and Surface Characterization by XRS and XPS. Total Reflection XRS. XRS Techniques and Instrumentation. XRS Applications. XRay Imaging and Tomography. 161 articles. Index.

Second Edition provides up-to-the-minute discussions on the application of mass spectrometry to the biological sciences. Shows how and why experiments are performed and furnishes details to facilitate duplication of results.

Ionization Methods in Organic Mass Spectrometry is a basic practical guide for scientists of all disciplines who wish to analyse samples by organic mass spectrometry. Concentrating on instrumental operation, this book gives step-by-step instructions on how to set up, and how to achieve the best results, using a range of ionization methods, including atmospheric pressure chemical ionization, electrospray ionization and matrix assisted laser desorption ionization. Ionization Methods in Organic Mass Spectrometry will enable a beginner, or practitioner with limited experience, to choose the most appropriate ionization technique in application areas such as biomolecules, drugs and metabolites, pesticides, polymers and many other organic compounds. It will be a valuable practical guide for technicians, graduates, students or researchers - or indeed anyone new to practical organic mass spectrometry.

From Hiroshima to the Iceman: The Development and Applications of Accelerator Mass Spectrometry presents a fascinating account of a breakthrough in science and the insights it has brought that would not have been possible without it. Involved since its invention, Harry Gove recounts the story of the development of accelerator mass spectrometry and its use as an ultrasensitive detection technique in many fields of science and the arts. A key advantage of the technique is that it requires only very small samples of material. The book explores the areas where the technique has increased understanding and provided solutions to problems, including the clean-up and storage of nuclear waste, the effects of the atomic bombing of Hiroshima, biomedical research, the settling of the Americas, and carbon dating of many precious artifacts. Objects dated include the Turin Shroud, the Iceman, the elephant bird egg, and the Dead Sea scrolls.

Industrial Analysis with Vibrational Spectroscopy is an integrated work which emphasises the synergy and complementary nature of the techniques of infrared and Raman spectroscopy in industrial laboratories. The book is written in a pragmatic and straight-forward manner and is illustrated throughout with examples of real-world, everyday problems and applications. It provides a developed, realistic insight into industrial analysis with vibrational spectroscopy for both undergraduate and academic researcher, while additionally providing a straight-forward working tool of value to the industrial laboratory worker.

This volume dedicated to the memory of Marcel Sergent who was a leader in this field for many years, addresses past achievements and recent developments in this vibrant area of research. Large classes of ligated transition metal clusters are produced either exclusively or most reliably by means of high-temperature solid-state reactions. Among them, the Chevrel-Sergent phases and related materials have generated enormous interest since their discovery in 1971. Today, these materials and their numerous derivatives still constitute a vivid area of research finding some applications not only in superconductivity, but also in catalysis, optics or thermoelectricity to mention a few.

This book offers a comprehensive overview of recent advances in the area of laser-induced breakdown spectroscopy (LIBS), focusing on its application to biological, forensic and materials sciences. LIBS, which was previously mainly used by physicists, chemists and in the industry, has now become a very useful tool with great potential in these other fields as well. LIBS has a unique set of characteristics including minimal destructiveness, remote sensing capabilities, potential portability, extremely high information content, trace analytical sensitivity and high throughput. With its content divided into two main parts, this book provides not only an introduction to the analytical capabilities and methodology, but also an overview of the results of recent applications in the above fields. The application-oriented, multidisciplinary approach of this work is also reflected in the diversity of the expert contributors. Given its breadth, this book will appeal to students, researchers and professionals interested in solving analytical/diagnostic/material characterization tasks with the application of LIBS.

In this authoritative review, leading international researchers explore the growing range of applications of stable isotope techniques for probing and integrating biological processes and palaeoclimatic cycles. The interdisciplinary approach covers a wide range of issues, opportunities and developments, setting interactions with plants in the context of water and nutrient cycles, exchanges with the atmosphere and modelling past and present climate change.
This important book will appeal to those requiring an overview of the use of stable isotopes in aquatic, terrestrial and climatic processes and is in tune with current global concerns. In addition postgraduates and research scientists will find an extensive guide to more specialist disciplines, including developing mass spectrometer technologies, compound-specific and cellular-discrimination processes or whole organism and ecosystem responses.

This book addresses Furnace Atomic Absorption Spectroscopy (FAAS), which has gained worldwide acceptance as an analytical technique. FAAS offers 100-1000 times better determination and detection limits than other techniques for a majority of the elements. This technique requires a small sample size, and demands less sample-preparation time than others. The handbook is a collection of thousands of references for detection and determination of various elements in agricultural products, biological and clinical samples, and metallurgical and electronic materials. Each chapter is devoted to an element or a similar group of elements. Included are instrumental setup parameters, references, and author and subject indexes. Also presented are detailed appendixes covering glossary, list of manufacturers of spectrophotometers and its accessories, list of chemical suppliers, and list of reviews and abstracts. The handbook covers topics such as heavy metals, clinical products, and trace metal analysis. This desk-top reference is meant for chemists who handle day-to-day analysis problems in laboratories in government, clinical, industrial and academic settings. It is invaluable for those involved in research in environmental science, analytical chemistry, clinical chemistry and forensic science.

Many books and reviews about scanning probe microscopies (SPM) cover the basics of their performance, novel developments, and state-of-the-art applications. Taking a different approach, Hybridizing Surface Probe Microscopies: Towards a Full Description of the Meso- and Nanoworlds encompasses the technical efforts in combining SPM with spectroscopic and optical complementary techniques that, altogether, provide a complete description of nanoscale and mesoscale systems and processes from corrosion to enzymatic reactions. The book is organized into eight chapters, following a general scheme that revolves around the two main capabilities of SPM: imaging and measuring interactions. Each chapter introduces key theoretical concepts and basic equations of the particular stand-alone technique with which the scanning probe microscopies are combined. Chapters end with the SPM-technique combination and some real-world examples in which the combination has been devised or used. Most chapters include a historical review of the techniques and numerous illustrations to support key ideas and provide the reader with intuitive understanding. To understand the limitations of any technique also means to understand how this technique works. This book has devoted a considerable amount of space in explaining the basics of each technique as they are being introduced. At the same time, it avoids explaining the particularities of each SPM-based technique and opts for a rather generalized approach. In short, the book's focus is not on what SPM can do, but rather on what SPM cannot do and, most specifically, on presenting the experimental approaches that circumvent these limitations.

This book embraces all physiochemical aspects of the structure and molecular dynamics of water, focusing on its role in biological objects, e.g. living cells and tissue, and in the formation of functionally active structures of biological molecules and their ensembles. Water is the single most abundant chemical found in all living things. It offers a detailed look into the latest modern physical methods for studying the molecular structure and dynamics of the water and provides a critical analysis of the existing literature data on the properties of water in biological objects. Water as a chemical reagent and as a medium for the formation of conditions for enzymatic catalysis is a core focus of this book. Although well suited for active researchers, the book as a whole, as well as each chapter on its own, can be used as fundamental reference material for graduate and undergraduate students throughout chemistry, physics, biophysics and biomedicine.

This book presents a selection of advanced lectures from leading researchers, providing recent theoretical results on strongly coupled quantum field theories. It also analyzes their use for describing new quantum states, which are physically realizable in condensed matter, cold-atomic systems, as well as artificial materials. It particularly focuses on the engineering of these states in quantum devices and novel materials useful for quantum information processing. The book offers graduate students and young researchers in the field of modern condensed matter theory an updated review of the most relevant theoretical methods used in strongly coupled field theory and string theory. It also provides the tools for understanding their relevance in describing the emergence of new quantum states in a variety of physical settings. Specifically, this proceedings book summarizes new and previously unrelated developments in modern condensed matter physics, in particular: the interface of condensed matter theory and quantum information theory; the interface of condensed matter physics and the mathematics emerging from the classification of the topological phases of matter, such as topological insulators and topological superconductors; and the simulation of condensed matter systems with cold atoms in optical lattices.

By delivering concentrated information in three different volumes, the editors of the Practical Aspects of Ion Trap Mass Spectrometry mini-series present in-depth reviews on mainstream developments in each active and popular area. Contributing authors provide concise reports illustrating successful approaches to difficult analytical problems across the basic scientific disciplines.
Ion Trap Instrumentation, the second volume in the series, conveys an appreciation of the ion trap as a versatile instrument which is used successfully in research and in applications, often in tandem with other instruments or components, such as external ion sources and lasers.
The book begins with a discussion of high resolution mass spectrometry and mass measurement accuracy. It then demonstrates that trajectories of high kinetic energy ions can be controlled so that such ions are confined. It provides applications of lasers to the study of trapped ions the laser photodissociation of gaseous ions confined within the ion trap. The book concludes with physics applications of the ion trap, in particular, the Penning trap and the Paul trap.

Fundamentals of Ion Trap Mass Spectrometry presents an account of the development and theory of the quadrupole ion trap and its utilization as an ion storage device, a reactor for ion/molecular reactions, and a mass spectrometer. It also expands the appreciation of ion traps from that of a unique arrangement of electrodes of hyperbolic form (and having a pure quadrupole field) to a series of ion traps having fields with hexapole and octopole components and introduces the practical ion trapping device in which electrode spacing has been increased.
The fundamentals of ion trap are covered in four chapters, beginning with the origin of the ion trap, its development and operating principles, and improvements in performance. The second part focuses on the environment within the ion trap -- the movement of ions within the trap -- and how this movement is modified by repeated collisions of the ions with buffer gas atoms of helium, and on the collisions of ions with molecules that lead to chemical change. The critical role of collisions in focusing the ion cloud for subsequent operations is emphasized.
This important reference presents a coherent picture of the present status of research in the ion trapping field to facilitate the entree of potential ion trappers and provide a backdrop for ion trap research and development in the future.

This work covers important aspects of X-ray spectrometry, from basic principles to the selection of instrument parameters and sample preparation. This edition explicates the use of combined X-ray fluorescence and X-ray diffraction data, and features new applications in environmental studies, forensic science, archeometry and the analysis of metals and alloys, minerals and ore, ceramic materials, catalysts and trace metals.;This work is intended for spectroscopists, analytical chemists, materials scientists, experimental physicists, mineralogists, biologists, geologists and graduate-level students in these disciplines.

Flame Spectrometry in Environmental Chemical Analysis is a simple, user-friendly guide to safe flame spectrometric methods for environmental samples. It explains key processes involved in achieving accurate and reliable results in atomic absorption spectrometry, atomic fluorescence spectrometry and flame emission spectrometry, showing the inter-relationship of the three techniques, and their relative importance. Flame Spectrometry in Environmental Chemical Analysis presents the important information with thoroughness and clarity, and in a style that makes it valuable to students and researchers using these techniques. It also offers straightforward reading for environmentalists with interests in such areas as pollution research, agriculture, ecology, soil science, geology and forestry; informing researchers of exactly what they can expect to be able to determine by flame spectrometric methods. Newcomers to flame spectrometry will gain increased confidence, job skills and many handy tips and ideas from this book. It will impart a strong working knowledge that can be translated into sound data in the laboratory.

A concise introduction, Optical Astronomical Spectroscopy appeals to the newcomer of astronomical spectroscopy and assumes no previous specialist knowledge. Beginning from the physical background of spectroscopy with a clear explanation of energy levels and spectroscopic notation, the book proceeds to introduce the main techniques of optical spectroscopy and the range of instrumentation that is available. With clarity and directness, it then describes the applications of spectroscopy in modern astronomy, such as the solar system, stars, nebulae, the interstellar medium, and galaxies, giving an immediate appeal to beginners.

Provides a self-teaching reference text for forensic chemistry laboratories and law enforcement agencies world-wide. The text includes sections on the importance of physical examinations of drugs and their wrappings; and the use of gas and high-performance chromatography.

About this book— In recent years, a number of different spectroscopic techniques have been applied to the study of a wide range of biomedical topics. Biomedical investigations in fields as diverse as eye lens research, the study of cardiovascular and inflammatory diseases, and the study of oxidative stress in disease can now be carried out by spectroscopic means. The nine chapters in Biomedical Applications of Spectroscopy present an authoritative overview of the current status of the field, with each chapter written by acknowledged experts. A wide range of techniques is considered, including optical microspectroscopy, Raman spectroscopy, FTIR spectroscopy, NMR and EPR spectroscopy and mass spectrometry. This highly topical volume will stimulate interest in this expanding field, and point the way towards future directions in research. The major objectives of this established series are to integrate theory and practice and to bring together different branches of both academic and industrial research through the presentation of critical review articles in fundamental and applied spectroscopy. The policy of the editors is to commission authoritative reviews by acknowledged leaders in the various fields of spectroscopy. Thus each volume presents a carefully composed picture of the ‘state of the art’ for a particular area. For each volume the subject matter is presented in a manner which is Comprehensible to the non-expert, for whom the series will continue to provide a valuable introduction, and a timely overview of topics in spectroscopy which are of current interest and importance. At the same time the involved expert will find much to engage his or her attention. The series is of interest to research scientists and technologists, to teachers and both graduate and undergraduate students.

Modern ESCA: The Principles and Practice of X-Ray Photoelectron Spectroscopy is a unique text/reference that focuses on the branch of electron spectroscopy generally labeled as either Electron Spectroscopy for Chemical Analysis (ESCA) or X-ray Photoelectron Spectroscopy (XPS). The book emphasizes the use of core level and valence band binding energies, their shifts, and line widths. It describes the background, present status, and possible future uses of a number of recently developed branches of ESCA, including:

Applications of Numerical Methods in Molecular Spectroscopy provides a mathematical background, theoretical perspective, and review of spectral data processing methods. The book discusses methods of complex spectral profile separation into bands, factor analysis methods, methods of quantitative analysis in molecular spectroscopy and reflectance spectroscopy, and new data processing methods. Mathematical methods in special areas of molecular spectroscopy, such as color science, electron spin resonance, and nuclear magnetic resonance spectroscopies are also covered. The book will benefit researchers and postgraduate students in fields of chemistry, physics, and biology.

The First Book on CRS Microscopy Compared to conventional Raman microscopy, coherent Raman scattering (CRS) allows label-free imaging of living cells and tissues at video rate by enhancing the weak Raman signal through nonlinear excitation. Edited by pioneers in the field and with contributions from a distinguished team of experts, Coherent Raman Scattering Microscopy explains how CRS can be used to obtain a point-by-point chemical map of live cells and tissues. In color throughout, the book starts by establishing the foundation of CRS microscopy. It discusses the principles of nonlinear optical spectroscopy, particularly coherent Raman spectroscopy, and presents the theories of contrast mechanisms pertinent to CRS microscopy. The text then provides important technical aspects of CRS microscopy, including microscope construction, detection schemes, and data analyses. It concludes with a survey of applications that demonstrate how CRS microscopy has become a valuable tool in biomedicine. Due to its label-free, noninvasive examinations of living cells and organisms, CRS microscopy has opened up exciting prospects in biology and medicine-from the mapping of 3D distributions of small drug molecules to identifying tumors in tissues. An in-depth exploration of the theories, technology, and applications, this book shows how CRS microscopy has impacted human health and will deepen our understanding of life processes in the future.