Sean Ashton's doctoral thesis, which he finished at the Technical University in Munich, describes the challenge of constructing a Differential Electrochemical Mass Spectrometer instrument (DEMS). DEMS combines an electrochemical cell with mass spectrometry via a membrane interface, allowing gaseous and volatile electrochemical reaction species to be monitored online. The thesis carefully introduces the fuel cell electrocatalyst development concerns before reviewing the pertinent literature on DEMS. This is followed by the presentation and discussion of the new extended design, including a thorough characterization of the instrument. The capabilities of the new setup are demonstrated in two research studies: The methanol oxidation reaction on Pt and PtRu catalysts, and the electrochemical corrosion of fuel cell catalyst supports. Despite both topics having long since been studied, new insights can be obtained through careful investigations with the new DEMS instrument that are of great, general interest. The thesis and the instrument thus show the way for future investigations in the field.

This book presents the current knowledge about superconductivity in high Tc cuprate superconductors. There is a large scientific interest and great potential for technological applications. The book discusses all the aspects related to all families of cuprate superconductors discovered so far. Beginning with the phenomenon of superconductivity, the book covers: the structure of cuprate HTSCs, critical currents, flux pinning, synthesis of HTSCs, proximity effect and SQUIDs, possible applications of high Tc superconductors and theories of superconductivity. Though a high Tc theory is still awaited, this book describes the present scenario and BCS and RVB theories. The second edition was significantly extended by including film-substrate lattice matching and buffer layer considerations in thin film HTSCs, brick-wall microstructure in the epitaxial films, electronic structure of the CuO2 layer in cuprates, s-wave and d-wave coupling in HTSCs and possible scenarios of theories of high Tc superconductivity.

"Solid-State Theory - An Introduction" is a textbook for graduate students of physics and material sciences. Whilst covering the traditional topics of older textbooks, it also takes up new developments in theoretical concepts and materials that are connected with such breakthroughs as the quantum-Hall effects, the high-Tc superconductors, and the low-dimensional systems realized in solids. Thus besides providing the fundamental concepts to describe the physics of the electrons and ions comprising the solid, including their interactions, the book casts a bridge to the experimental facts and gives the reader an excellent insight into current research fields. A compilation of problems makes the book especially valuable to both students and teachers.

Atomic Spectroscopy provides a comprehensive discussion on the general approach to the theory of atomic spectra, based on the use of the Lagrangian canonical formalism. This approach is developed and applied to explain the hydrogenic hyperfine structure associated with the nucleus motion, its finite mass, and spin. The non-relativistic or relativistic, spin or spin-free particle approximations can be used as a starting point of general approach. The special attention is paid to the theory of Lamb shift formation. The formulae for hydrogenic spectrum including the account of Lamb shift are written in simple analytical form. The book is of interest to specialists, graduate and postgraduate students, who are involved into the experimental and theoretical research in the field of modern atomic spectroscopy.

Common methods of local magnetic imaging display either a high spatial resolution and relatively poor field sensitivity (MFM, Lorentz microscopy), or a relatively high field sensitivity but limited spatial resolution (scanning SQUID microscopy). Since the magnetic field of a nanoparticle or nanostructure decays rapidly with distance from the structure, the achievable spatial resolution is ultimately limited by the probe-sample separation. This thesis presents a novel method for fabricating the smallest superconducting quantum interference device (SQUID) that resides on the apex of a very sharp tip. The nanoSQUID-on-tip displays a characteristic size down to 100 nm and a field sensitivity of 10^-3 Gauss/Hz^(1/2). A scanning SQUID microsope was constructed by gluing the nanoSQUID-on-tip to a quartz tuning-fork. This enabled the nanoSQUID to be scanned within nanometers of the sample surface, providing simultaneous images of sample topography and the magnetic field distribution. This microscope represents a significant improvement over the existing scanning SQUID techniques and is expected to be able to image the spin of a single electron.

The idea for this book arose out of the realization that, although excellent surveys and a phosphor handbook are available, there is no single source covering the area of phosphate based phosphors especially for lamp industry. Moreover, as this field gets only limited attention in most general books on luminescence, there is a clear need for a book in which attention is specifically directed toward this rapidly growing field of solid state lighting and its many applications. This book is aimed at providing a sound introduction to the synthesis and optical characterization of phosphate phosphor for undergraduate and graduate students as well as teachers and researchers. The book provides guidance through the multidisciplinary field of solid state lighting specially phosphate phosphors for beginners, scientists and engineers from universities, research organizations, and especially industry. In order to make it useful for a wide audience, both fundamentals and applications are discussed, together.

The International Workshop on "Intersubband Transitions in Quantum Wells:: Physics and Applications," was held at National Cheng Kung University, in Tainan, Taiwan, December 15-18, 1997. The objective of the Workshop is to facilitate the presentation and discussion of the recent results in theoretical, experimental, and applied aspects of intersubband transitions in quantum wells and dots. The program followed the tradition initiated at the 1991 conference in Cargese-France, the 1993 conference in Whistler, B. C. Canada, and the 1995 conference in Kibbutz Ginosar, Israel. Intersubband transitions in quantum wells and quantum dots have attracted considerable attention in recent years, mainly due to the promise of various applications in the mid- and far-infrared regions (2-30 J. lm). Over 40 invited and contributed papers were presented in this four-day workshop, with topics covered most aspects of the intersubband transition phenomena including: the basic intersubband transition processes, multiquantum well infrared photodetector (QWIP) physics, large format (640x480) GaAs QWIP (with 9. 0 J. lffi cutoff) focal plane arrays (FPAs) for IR imaging camera applications, infrared modulation, intersubband emission including mid- and long- wavelength quantum cascade (QC) lasers such as short (A. "" 3. 4 J. lm) and long (A. "" 11. 5 J. lm) wavelength room temperature QC lasers, quantum fountain intersubband laser at 15. 5 J. lm wavelength in GaAs/AIGaAs quantum well, harmonic generation and nonlinear effects, ultra-fast phenomena such as terahertz (THz) intersubband emission and detection. The book divides into five Chapters.

This volume contains the proceedings of the 5th International Symposium on Symmetries in Subatomic Physics (SSP2012), that was held in Groningen, The Netherlands from 18 till 22 June 2012. This sequence of symposia is now firmly connected with one of the main branches in fundamental nuclear and particle physics, i.e. in searches for physics beyond the Standard Model, focused on the (violation of) the discrete symmetries of Parity, Charge conjugation and Time reversal invariance. This field comes in various disguises: With large experimental facilities and large collaborations, as in LHC physics or in neutrino experiments, but also as table top experiments by small groups in the field of nuclear, atomic and molecular physics, such as in searches for a permanent electric dipole moments and atomic parity violation.

Bringing the practitioners of these divergent fields together gives a coherent overview and see the complementarities of the various approaches to the same question: why is the Standard Model what it is and what lies beyond it.

NMR Spectroscopy for Chemical Analysis at Low Magnetic Fields, by Stefan Gloeggler, Bernhard Blumich, Stephan Appelt Dynamic Nuclear Hyperpolarization in Liquids, by Ulrich L. Gunther NMR with Multiple Receivers, by Eriks Kupce TROSY NMR Spectroscopy of Large Soluble Proteins, by Yingqi Xu, Stephen Matthews Solid-State NMR Spectroscopy of Proteins, by Henrik Muller, Manuel Etzkorn, Henrike Heise Paramagnetic Solid-State Magic-Angle Spinning NMR Spectroscopy, by Guido Pintacuda, Gwendal Kervern

In his thesis, Matthias Junk takes an innovative approach to assess the local structure and dynamics of biological and synthetic amphiphilic macromolecules capable of transporting small molecules. Replacing the latter with stable radicals, he uses state-of-the-art electron paramagnetic resonance (EPR) spectroscopy to describe the highly relevant transport function from the viewpoint of the guest molecules. Such, he demonstrates that the functional structure of human serum albumin in solution significantly differs from its crystal structure - a consequence of the protein's adaptability to host various endogenous compounds and drug molecules. Further, he shows that the thermal collapse of thermoresponsive hydrogels and dendronized polymers leads to static and dynamic heterogeneities on the nanoscale. These heterogeneities bear consequences for the material's hosting properties and enable unforeseen complex catalytic functionalities.

The "Rudolf Moessbauer Story" recounts the history of the discovery of the "Moessbauer Effect" in 1958 by Rudolf Moessbauer as a graduate student of Heinz Maier-Leibnitz for which he received the Nobel Prize in 1961 when he was 32 years old. The development of numerous applications of the Moessbauer Effect in many fields of sciences , such as physics, chemistry, biology and medicine is reviewed by experts who contributed to this wide spread research. In 1978 Moessbauer focused his research interest on a new field "Neutrino Oscillations" and later on the study of the properties of the neutrinos emitted by the sun.

At present, there is an increasing interest in the prediction of properties of classical and new materials such as substitutional alloys, their surfaces, and metallic or semiconductor multilayers. A detailed understanding based on a thus of the utmost importance for fu microscopic, parameter-free approach is ture developments in solid state physics and materials science. The interrela tion between electronic and structural properties at surfaces plays a key role for a microscopic understanding of phenomena as diverse as catalysis, corrosion, chemisorption and crystal growth. Remarkable progress has been made in the past 10-15 years in the understand ing of behavior of ideal crystals and their surfaces by relating their properties to the underlying electronic structure as determined from the first principles. Similar studies of complex systems like imperfect surfaces, interfaces, and mul tilayered structures seem to be accessible by now. Conventional band-structure methods, however, are of limited use because they require an excessive number of atoms per elementary cell, and are not able to account fully for e.g. substitu tional disorder and the true semiinfinite geometry of surfaces. Such problems can be solved more appropriately by Green function techniques and multiple scattering formalism.

Diffusion in solids at moderate temperatures is a well-known phenomenon. However, direct experimental evidence about the responsible atomic-scale mechanisms has been scarce, due to difficulties in probing the relevant length- and time-scales. The present thesis deals with the application of X-ray Photon Correlation Spectroscopy (XPCS) for answering such questions. This is an established method for the study of slow dynamics on length-scales of a few nanometres. The scattered intensity in the diffuse regime, i.e. corresponding to atomic distances, is very low, however, and so it has so far been considered impossible to use XPCS for this problem. Threefold progress is reported in this work: It proposes a number of systems selected for high diffuse intensity, it optimizes the photon detection and data evaluation procedures, and it establishes theoretical models for interpretating the results. Together these advances allowed the first successful atomic-scale XPCS experiment, which elucidated the role of preferred configurations for atomic jumps in a copper-gold alloy. The growth in available coherent X-ray intensity together with next-generation X-ray sources will open up a wide field of application for this new method.

The properties and nature of water clusters studied with novel spectroscopic approaches are presented in this thesis. Following a general introduction on the chemistry of water and water clusters, detailed descriptions of the experiments and analyses are given. All the experimental results, including first size-selective spectra of large clusters consisting of 200 water molecules, are presented with corresponding analyses. Hitherto unidentified hydrogen bond network structures, dynamics, and reactivity of various water clusters have been characterized at the molecular level. The main targets of this book are physical chemists and chemical physicists who are interested in water chemistry or cluster chemistry.

Photoelectrochemical Hydrogen Production describes the principles and materials challenges for the conversion of sunlight into hydrogen through water splitting at a semiconducting electrode. Readers will find an analysis of the solid state properties and materials requirements for semiconducting photo-electrodes, a detailed description of the semiconductor/electrolyte interface, in addition to the photo-electrochemical (PEC) cell. Experimental techniques to investigate both materials and PEC device performance are outlined, followed by an overview of the current state-of-the-art in PEC materials and devices, and combinatorial approaches towards the development of new materials. Finally, the economic and business perspectives of PEC devices are discussed, and promising future directions indicated. Photoelectrochemical Hydrogen Production is a one-stop resource for scientists, students and R&D practitioners starting in this field, providing both the theoretical background as well as useful practical information on photoelectrochemical measurement techniques. Experts in the field benefit from the chapters on current state-of-the-art materials/devices and future directions.

Power consumption becomes the most important design goal in a wide range of electronic systems. There are two driving forces towards this trend: continuing device scaling and ever increasing demand of higher computing power. First, device scaling continues to satisfy Moore's law via a conventional way of scaling (More Moore) and a new way of exploiting the vertical integration (More than Moore). Second, mobile and IT convergence requires more computing power on the silicon chip than ever. Cell phones are now evolving towards mobile PC. PCs and data centers are becoming commodities in house and a must in industry. Both supply enabled by device scaling and demand triggered by the convergence trend realize more computation on chip (via multi-core, integration of diverse functionalities on mobile SoCs, etc.) and finally more power consumption incurring power-related issues and constraints. Energy-Aware System Design: Algorithms and Architectures provides state-of-the-art ideas for low power design methods from circuit, architecture to software level and offers design case studies in three fast growing areas of mobile storage, biomedical and security. Important topics and features: - Describes very recent advanced issues and methods for energy-aware design at each design level from circuit and architecture to algorithm level, and also covering important blocks including low power main memory subsystem and on-chip network at architecture level - Explains efficient power conversion and delivery which is becoming important as heterogeneous power sources are adopted for digital and non-digital parts - Investigates 3D die stacking emphasizing temperature awareness for better perspective on energy efficiency - Presents three practical energy-aware design case studies; novel storage device (e.g., solid state disk), biomedical electronics (e.g., cochlear and retina implants), and wireless surveillance camera systems. Researchers and engineers in the field of hardware and software design will find this book an excellent starting point to catch up with the state-of-the-art ideas of low power design.

In this book, Yoshimura provides a review of the UHV related development during the last decades. His very broad experience in the design enables him to present us this detailed reference. After a general description how to design UHV systems, he covers all important issue in detail, like pumps, outgasing, Gauges, and Electrodes for high voltages. Thus, this book serves as reference for everybody using UVH in scientific equipment.

Monomolecular assemblies on substrates, now termed Langmuir-Blodgett (LB) films, have been studied for over half a century. Their development can be viewed in three stages. Following the pioneering work of Irving Langmuir and Katharine Blodgett in the late 1930s there was a brief flurry of activity just before and just after the Second World War. Many years later Hans Kuhn published his stimulating work on energy transfer. This German contribution to the field, made in the mid-1960s, can be regarded as laying the foundation for studies of artificial systems of cooperat ing molecules on solid substrates. However, the resurgence of activity in academic and industrial laboratories, which has resulted in four large international con ferences, would not have occurred but for British and French groups highlighting the possible applications of LB films in thefield of electronics. Many academic and industrial establishments involved in high technology are now active in or maintaining a watching brief on the field. Nevertheless this impor tant area of solid state science is still perhaps largely unfamiliar to many involved in materials or electronic device research. The richness of the variety of organic molecular materials suitable for LB film deposition offers enormous scope for those interested in their basic properties or their practical applications. LB films are now an integral part of the field of molecular electronics. It seems inevitable that they will play some role in replacing inorganic materials in certain areas of application."

The effects of electromagnetic radiation and high-energy par ticles on semiconductors can be divided into two main processes: (a) the excitation of electrons (the special case is internal ioniza tion, i. e. , the generation of excess charge carriers); and(b) dis turbance of the periodic structure of the crystal, i. e. , the forma tion of "structural radiation defects. " Naturally, investigations of the effects of radiation on semiconductors cannot be considered in isolation. Thus, for example, the problern of "radiation de fects" is part of the generalproblern of crystal lattice defects and the influence of such defects on the processes occurring in semi conductors. The same is true of photoelectric and similar phe nomena where the action of the radiation is only the start of a complex chain of nonequilibrium electronprocesses. Nevertheless, particularly from the point of view of the experimental physicist, the radiation effects discussed in the present book have inter esting features: several types of radiation may produce the same resul t (for example, ionization by photons and by charged particles) or one type of radiation may produce several effects (ionization and radiation -defect formation). The aim of the author was to consider the most typical prob lems. The subjects discussed differ widely from one another in the extent to which they have been investigated.

Proceedings of a NATO ASI held in Les Arcs, France, April 2--13, 1990