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Books > Science & Mathematics > Chemistry > Analytical chemistry > Qualitative analytical chemistry > Chemical spectroscopy, spectrochemistry > General
Soon after the discovery of quantum mechanics, group theoretical
methods were used extensively in order to exploit rotational
symmetry and classify atomic spectra. And until recently it was
thought that symmetries in quantum mechanics should be groups. But
it is not so. There are more general algebras, equipped with
suitable structure, which admit a perfectly conventional
interpretation as a symmetry of a quantum mechanical system. In any
case, a "trivial representation" of the algebra is defined, and a
tensor product of representations. But in contrast with groups,
this tensor product needs to be neither commutative nor
associative. Quantum groups are special cases, in which
associativity is preserved. The exploitation of such "Quantum
Symmetries" was a central theme at the Ad vanced Study Institute.
Introductory lectures were presented to familiarize the
participants with the al gebras which can appear as symmetries and
with their properties. Some models of local field theories were
discussed in detail which have some such symmetries, in par ticular
conformal field theories and their perturbations. Lattice models
provide many examples of quantum theories with quantum symmetries.
They were also covered at the school. Finally, the symmetries which
are the cause of the solubility of inte grable models are also
quantum symmetries of this kind. Some such models and their
nonlocal conserved currents were discussed.
Distinct scientific communities are usually involved in the three
fields of quasi-crystals, of liquid crystals, and of systems having
modulated crystalline structures. However, in recent years, there
has been a growing feeling that a number of common problems were
encountered in the three fields. These comprise the need to recur
to "exotic" spaces for describing the type of order of the atomic
or molecular configurations of these systems (Euclidian
"superspaces" of dimensions greater than 3, or 4-dimensional curved
spaces); the recognition that one has to deal with geometrically
frustrated systems, and also the occurence of specific excitations
(static or dynamic) resulting from the continuous degeneracies of
the stable structures considered. In the view of discussing these
problems, aNA TO-Advance Research Workshop has assembled in Preveza
(Greece), in september 1989,50 experts of the three considered
fields (with an equal proportion of theorists and
experimentalists). 35 hours of conferences and discussions have led
to a more detailed evaluation of the similarities and of the
differences in the approaches implemented in the studies of the
three types of systems. The papers contained in this NATO-series
book provide the substance of this workshop. The reader will find
three types of papers. Some very short papers giving the main ideas
stated on a subject. Papers comprising 8-10 pages which stick
closely to the contents of the talks presented. Longer papers
providing more extensively the background and results relative to a
given topic. It is worth summarizing the principal outputs of the
workshop.
The past three decades have been a period where useful current and
voltage instabilities in solids have progressed from exciting
research problems to a wide variety of commercially available
devices. Materials and electronics research has led to devices such
as the tunnel (Esaki) diode, transferred electron (Gunn) diode,
avalanche diodes, real-space transfer devices, and the like. These
structures have proven to be very important in the generation,
amplification, switching, and processing of microwave signals up to
frequencies exceeding 100 GHz. In this treatise we focus on a
detailed theoretical understanding of devices of the kind that can
be made unstable against circuit oscillations, large amplitude
switching events, and in some cases, internal rearrangement of the
electric field or current density distribution. The book is aimed
at the semiconductor device physicist, engineer, and graduate
student. A knowledge of solid state physics on an elementary or
introductory level is assumed. Furthermore, we have geared the book
to device engineers and physicists desirous of obtaining an
understanding substantially deeper than that associated with a
small signal equivalent circuit approach. We focus on both
analytical and numerical treatment of specific device problems,
concerning ourselves with the mechanism that determines the
constitutive relation governing the device, the boundary conditions
(contact effects), and the effect of the local circuit environment.
The interest in the problem of surface diffusion has been steadily
growing over the last fifteen years. This is clearly evident from
the increase in the number of papers dealing with the problem, the
development of new experimental techniques, and the specialized
sessions focusing on diffusion in national and international
meetings. Part of the driving force behind this increasing activity
is our recently acquired ability to observe and possibly control
atomic scale phenomena. It is now possible to look selectively at
individual atomistic processes and to determine their relative
importance during growth and reactions at surfaces. The number of
researchers interested in this problem also has been growing
steadily which generates the need for a good reference source to
farniliarize newcomers to the problem. While the recent emphasis is
on the role of diffusion during growth, there is also continuing
progress on the more traditional aspects of the problem describing
mass transport in an ensemble of particles. Such a description is
based on the statistical mechanical analysis of a collection of
particles that mutually interact and develop correlations. An
average over the multitude of atomistic processes that operate
under these conditions is necessary to fully describe the dynamics
in the system.
Since the early days of modem physics spectroscopic techniques have
been employed as a powerful tool to assess existing theoretical
models and to uncover novel phenomena that promote the development
of new concepts. Conventionally, the system to be probed is
prepared in a well-defined state. Upon a controlled perturbation
one measures then the spectrum of a single particle (electron,
photon, etc.) emitted from the probe. The analysis of this single
particle spectrum yields a wealth of important information on the
properties of the system, such as optical and magnetic behaviour.
Therefore, such analysis is nowadays a standard tool to investigate
and characterize a variety of materials. However, it was clear at a
very early stage that real physical compounds consist of many
coupled particles that may be excited simultaneously in response to
an external perturbation. Yet, the simultaneous (coincident)
detection of two or more excited species proved to be a serious
technical obstacle, in particular for extended electronic systems
such as surfaces. In recent years, however, coincidence techniques
have progressed so far as to image the multi-particle excitation
spectrum in an impressive detail. Correspondingly, many-body
theoretical concepts have been put forward to interpret the
experimental findings and to direct future experimental research.
This book gives a snapshot of the present status of multi-particle
coincidence studies both from a theoretical and an experimental
point of view. It also includes selected topical review articles
that highlight the achievements and the power of coincident
techniques.
This volume represents the primary lectures of the NATO Advanced
Study Institute (ASI) on "Nuclear Magnetic Resonance in Modern
Technology," which was held at Sarigerme Park (near the Dalaman
Airport) on the southern Aegean shore of Turkey from August 23 to
September 4, 1992. As indicated in the title, this ASI was aimed at
examining, displaying, and perhaps influencing, the role of nuclear
magnetic resonance (NMR) in modern technological activity. The
lectures summarized in this volume and the numerous short
contributed talks and posters were primarily aimed at the question,
"What is NMR doing in support of modern technology?" During the
main discussion periods and the numerous small scheduled meetings
of specific interest groups this same topic was also addressed,
along with questions like, "What could or should NMR be doing in
support of modern technology?" With this kind of subject
orientation, the organizers attempted to include a large
participation at the ASI from scientists and engineers from diverse
private industries in which NMR does, or perhaps should, play a
substantial role in supporting or optimizing technology. Perhaps
because of a combination of worldwide industrial contractions and
residual corporate nervousness regarding the then recent Gulf War
(which caused a one-year postponement of this ASI), the
participation from private industry was numerically disappointing.
We hope that this book will serve to bring the role of NMR in
modern industry to the attention of numerous industrial scientists
and engineers who were unable to attend the AS .
The present volume contains the text of the invited talks delivered
at the Eighth International Conference on Recent Progress in
Many-Body Theories held at SchloB Seggau, Province of Styria,
Austria, during the period August 22-26, 1994. The pro ceedings of
the Fifth Conference (Oulu, Finland 1987), the Sixth Conference
(Arad, Israel 1989) and the Seventh Conference (Minneapolis, USA
1991) have been published. by Plenum as the first three volumes of
this series. Papers from the First Conference (Trieste, Italy 1978)
comprise Nuclear Physics volume A328, Nos. 1 and 2, the Second
Conference (Oaxtepec, Mexico 1979) was published by Springer-Verlag
as volume 142 of "Lecture Notes in Physics," entitled "Recent
Progress in Many Body Theories." Vol ume 198 of the same series
contains the papers from the Third Conference (Altenberg, 1983).
These volumes intend to cover a broad spectrum of current research
topics in physics that benefit from the application of many-body
theories for their elucidation. At the same time there is a focus
on the development and refinement of many-body methods. One of the
major aims of the conference series has been to foster the exchange
of ideas among physicists working in such diverse areas as nuclear
physics, quantum chemistry, complex systems, lattice Hamiltonians,
quantum fluids and condensed matter physics. The present volume
contains contributions from all these areas. th The conference was
dedicated on the occasion of Ludwig Boltzmann's 150 birthday."
Semiconducting and Insulating Crystals details how absorption
spectroscopy provides information on the nature, concentration,
charge state and configuration of impurities in crystals and also
on their kinetics and transformations under annealing. After an
introduction of the bulk optical properties of semiconductors and
insulators and of impurities in crystals, this book presents the
physical bases necessary for the understanding of impurity spectra.
The description of various set-ups and accessories used in
absorption spectroscopy is followed by a presentation of
experimental results on specific impurities and classes of
impurities and their relation with those obtained by various
computation and by other experimental techniques.
Nanometer CMOS RFICs for Mobile TV Applications focuses on how
to break the trade-off between power consumption and performance
(linearity and noise figure) by optimizing the mobile TV front-end
dynamic range in three hierarchical levels: the intrinsic MOSFET
level, the circuit level, and the architectural level. It begins by
discussing the fundamental concepts of MOSFET dynamic range,
including nonlinearity and noise. It then moves to the circuit
level introducing the challenges associated with designing
wide-dynamic range, variable-gain, broadband low-noise amplifiers
(LNAs). The book gives a detailed analysis of a new noise-canceling
technique that helps CMOS LNAs achieve a sub - 2 dB wideband noise
figure. Lastly, the book deals with the front-end dynamic range
optimization process from the systems perspective by introducing
the active and passive automatic gain control (AGC) mechanism.
The individual papers that comprise this monograph are derived from
two American Chemical Society (ACS) Fall National Meetings that
focused on the current uses of synchrotron radiation (SR) research
techniques. The first Symposium was held in Washington, DC, in
August 1994, and the second convened in Chicago, IL, in August
1995. The intent of these symposia was to present a broad overview
of several current topics in industrial, chemical, and
materials-based SR research to a chemically inclined audience. The
SR techniques covered were divided roughly into the three general
fields of industrial, chemical, and materials science for this
purpose. Included within these four categories are environmental,
geologic, atomic/molecular, analytical, solid state physics,
surface science, and biological applications of SR. There is little
doubt that structural biology and environmental science are the
largest growth areas in SR research as this monograph goes to
press. The spirit of these symposia was to bring together the
expert synchrotron radiation user with new and potential users of
SR techniques. There are now a preponderance of particle storage
rings, located throughout the world, devoted exclusively to the
production of SR. There have been great improvements in the
particle accelerators and storage rings from which SR emanates.
These newest third generation SR sources are the result of the
successful collaboration between SR users and accelerator
physicists which has made a reality out of experiments never before
possible.
Just over 25 years ago the first laser-excited Raman spectrum of
any crystal was obtained. In November 1964, Hobden and Russell
reported the Raman spectrum of GaP and later, in June 1965, Russell
published the Si spectrum. Then, in July 1965, the forerunner of a
series of meetings on light scattering in solids was held in Paris.
Laser Raman spectroscopy of semiconductors was at the forefront in
new developments at this meeting. Similar meetings were held in
1968 (New York), 1971 (Paris) and 1975 (Campinas). Since then, and
apart from the multidisciplinary biennial International Conference
on Raman Spectroscopy there has been no special forum for experts
in light scattering spectroscopy of semiconductors to meet and
discuss latest developments. Meanwhile, technological advances in
semiconductor growth have given rise to a veritable renaissance in
the field of semiconductor physics. Light scattering spectroscopy
has played a crucial role in the advancement of this field,
providing valuable information about the electronic, vibrational
and structural properties both of the host materials, and of
heterogeneous composite structures. On entering a new decade, one
in which technological advances in lithography promise to open even
broader horirons for semiconductor physics, it seemed to us to be
an ideal time to reflect on the achievements of the past decade, to
be brought up to date on the current state-of-the-art, and to catch
some glimpses of where the field might be headed in the 1990s.
Proceedings of a NATO ASI/18th Course of the International School
of Crystallography, held in Erice, Sicily, Italy, April 18--29, 199
Rapid thermal processing has contributed to the development of
single wafer cluster processing tools and other innovations in
integrated circuit manufacturing environments. Borisenko and
Hesketh review theoretical and experimental progress in the field,
discussing a wide range of materials, processes, and conditions.
They thoroughly cover the work of international investigators in
the field.
The workshop entitled Magnetic Susceptibility of Superconductors
and other Spin Systems (S4) was held at Coolfont Resort and Health
Spa. located near Berkley Springs West Virginia on May 20-23. 1991.
There were over sixty attendees. approximately half from the United
States. the remainder representing over twelve different countries.
The international character of the workshop may be gleaned form the
attendee list, included in this volume. The intent of the workshop
was to bring together those experimentalists and theoreticians
whose efforts have resulted in significant recent contributions to
the development and use of the ac susceptibility technique as well
as to the interpretation of data obtained from these measurements.
Many spirited discussions occurred during and after the
presentations. These are reflected in the manuscripts contained in
these proceedings. Although camera ready manuscripts were required
from all participants at registration, all manuscripts were revised
and reflect the lively exchanges that followed each presentation.
The small size of the workshop allowed the participants a high
degree of flexibility. Consequently when a controversial topic such
as "the irreversibility line" emerged, a special session was
organized on the spot. At the suggestion of Ron Goldfarb,
participants were invited to contribute a one page summary
containing their thoughts on the topic. These stand alone
contributions were retyped and included as submitted, with only
minor editorial changes. These proceedings are intended for those
experienced scientists new to the field and graduate students just
beginning their research.
This conference is the second on the Science and Technology of Thin
Film Superconductors. It proved to be an excellent forum for these
specialists in thin film superconductivity. The conference, held
April 30-May 4, 1990, in Denver, Colorado, hosted 170 researchers
from 17 countries. The response to the conference again emphasized
the need for a meeting devoted to the science and technology of
thin film superconductors. The breadth of artic1es and advances
made in this technology since the first conference in November
1988, reflect on the maturity of the topic. These proceedings
contain artic1es on deposition methods by sputtering, e1ectron beam
evaporation, resistive evaporation, laser ablation, chemical vapor
deposition and electrodeposition, and on other studies related to
substrates, thermodynamics of formation, grain boundaries and weak
links, characterization, and some practical applications. The
program committee was pleased with the quality of the publications
and contributed articles. This conference was highlighted by a fuU
day dedicated to presentations from the federallaboratories,
discussing a wide range of topics on the fabrication,
characterization, and theory of high-temperature superconductor
thin films. Other highlights at the conference dealt with (1)
critical parameters or problems in measuring critical current
density and other important parameters, and (2) problems of
scale-up, reproducibility, and amenability to device fabrication.
It became evident from the presentations that three issues were
developing into critical issues for the ultimate practical
application of high temperature superconductor thin films."
Leading practitioners describe in detail advanced methods of mass
spectrometry used in structural characterization of
biomacromolecules of both natural and recombinant origin. They
demonstrate by example how these methodologies can solve a wide
array of real-world problems in protein biochemistry, immunology,
and glycobiology, as well as for human bacterial pathogens, lipids,
and nucleic acids. The book offers a unique opportunity to learn
these techniques that are revolutionizing the field. Its
authoritative assessment in the context of how to solve important
and challenging problems in bioscience and medicine ensures a
competitive advantage for today's researchers.
The NATO Advanced Research Workshop on Fundamental Aspects of Inert
Gases in Solids, held at Bonas, France from 16-22 September 1990,
was the fifth in a series of meetings that have been held in this
topic area since 1979. The Consultants' Meeting in that year at
Harwell on Rare Gas Behaviour in Metals and Ionic Solids was
followed in 1982 by the Jiilich Inter national Symposium on
Fundamental Aspects of Helium in Metals. Two smaller meetings have
followed-a CECAM organised workshop on Helium Bubbles in Metals was
held at Orsay, France in 1986 while in February 1989, a Topical
Symposium on Noble Gases in Metals was held in Las Vegas as part of
the large TMS/AIME Spring Meeting. As is well known, the dominating
feature of inert gas atoms in most solids is their high heat of
solution, leading in most situations to an essentially zero
solubility and gas-atom precipita tion. In organising the workshop,
one particular aim was to target the researchers in the field of
inert-gas/solid interactions from three different areas--namely
metals, tritides and nuclear fuels-in order to encourage and foster
the cross-fertilisation of approaches and ideas. In these three
material classes, the behaviour of inert gases in metals has
probably been most studied, partly from technological
considerations-the effects of helium production via (n, a) reac
tions during neutron irradiation are of importance, particularly in
a fusion reactor environ ment-and partly from a more fundamental
viewpoint."
Provides a rigorous derivation of surface properties such as
temperature and deformation using continuum mechanics; Discussion
is animated by the authors' decades of experience in experimental
mechanics; Includes many techniologically motivated problems,
solutions and computer solutions
This monograph introduces the students and specialists of
agricultural and food science to the fundamentals of optical
spectroscopy, main principles of modern spectroscopic
instrumentation, advantages and practical applications of
spectroscopic methods to investigation of agricultural objects such
as milk and dairy products, eggs, honey, animal hair, and agronomic
plants.
Since the publication in 1950 of Vol. I, Spectra of Diatomic
Molecules of Molecular Spectra and Molecular Structure, much
progress has been made in the field. While there have been some
important refinements in the theory of diatomic molecular spectra,
most of the advances have been in the further exploration of
individual spectra. Not only has the number of molecules about
which some spectroscopic data are available been increased by a
factor of 2 to 3, but also the spectroscopic information about the
molecules known in 1950 has been vastly extended. This is due to
the observation of new elec tronic states (about three times as
many as known before), the enormous improvements in the accuracy of
the constants of the states known in 1950, and the determination of
higher order constants. In view of the increasing use of
spectroscopic information on diatomic molecules in other fields of
physics, in chemistry, and in astrophysics, it appeared desirable
to prepare an up-to-date version of the table of molecular
constants in the appendix of Vol. I. This updating proved to be far
more time-consuming than originally anticipated, and it is only
now, 10 years that we are able to present such a table, which,
instead after its initiation, of the original 80 pages (plus 30
pages of bibliography), now fills a volume of 700 pages. In the
interest of economy, and unlike the original version, the new table
has been produced by photo-offset from the final manuscript."
In recent years, III-V devices, integrated circuits, and
superconducting integrated circuits have emerged as leading
contenders for high-frequency and ultrahigh speed applications.
GaAs MESFETs have been applied in microwave systems as low-noise
and high-power amplifiers since the early 1970s, replacing silicon
devices. The heterojunction high-electron-mobility transistor
(HEMT), invented in 1980, has become a key component for satellite
broadcasting receiver systems, serving as the ultra-low-noise
device at 12 GHz. Furthermore, the heterojunction bipolar
transistor (HBT) has been considered as having the highest
switching speed and cutoff frequency in the semiconductor device
field. Initially most of these devices were used for analog
high-frequency applications, but there is also a strong need to
develop high-speed III-V digital devices for computer, telecom
munication, and instrumentation systems, to replace silicon
high-speed devices, because of the switching-speed and
power-dissipation limitations of silicon. The potential high speed
and low power dissipation of digital integrated circuits using GaAs
MESFET, HEMT, HBT, and superconducting Josephson junction devices
has evoked tremendous competition in the race to develop such
technology. A technology review shows that Japanese research
institutes and companies have taken the lead in the development of
these devices, and some integrated circuits have already been
applied to supercomputers in Japan. The activities of Japanese
research institutes and companies in the III-V and superconducting
device fields have been superior for three reasons. First, bulk
crystal growth, epitaxial growth, process, and design technology
were developed at the same time.
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