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Books > Science & Mathematics > Chemistry > Analytical chemistry > Qualitative analytical chemistry > Chemical spectroscopy, spectrochemistry > General
arranged. Among them the following types are met: nanotubes, nanop- ticles, nanopowders, nano?bers, nanowires, nanocomposites, etc. * At the microscale - Microcomposites, such as metal matrix composites (MMCs), ceramic matrix composites (CMCs), alloys or superalloys, s- tered powders, ceramic materials, magnetorheological ?uids (MRFs), etc. * At the macroscale - Macrocomposites, such as functionally graded ma- rials (FGMs), thin layers or ?lms, thermal or oxidation or wear resistant coatings, multilayered structures, long ?ber composites, etc. At each level of analysis a response of the material to any physical excitation may be observed, measured and analyzed. In the sense of innovation of a material, the changes or new ideas can be introduced on the same scale of control (say, atomic or nano) in order to achieve fundamentally new behavior on the other scale of observation (say, micro or macro). For instance, by replacing some similar atoms in the metal crystal str- ture (e. g. Ti-Ti or Al-Al), by unlike atoms in the crystal (e. g. Ti-Al), wi- out the lattice symmetry of the original material changing, new improved properties and characteristics may be observed in intermetallics at the - cro or macroscale (higher speci?c strength, better creep resistance at elevated temperatures, better corrosion resistance, to mention only some properties observed at the macroscale). Similarly, changing material characteristics at the nanoscale, enables creation of completely new material functionality at micro or macroscales (e. g.
This volume originated in a happy event honoring Arthur Schawlow on his 65th birthday. As a research physicist, Schawlow has been a major infiuence on the present nature of physics and of high technology. He has also had a role, through the American Physical Society and other organizations, in shaping policy for the world of physicists. Important as these professional activities have been, the contributions to this volume were not prepared just for these reasons, but more for Art Schawlow the friend, colleague, and teacher. I am one who has had the privilege of knowing and collaborating with Art, probably over a longer period of time than others participating in this volume, and in a number of different enterprises; his friendship and stimulating scientific abilities are a very significant part of my own life. It is hence a pleasure to take part in this volume celebrating his contributions to science and to scientists. Schawlow's career has been geographically centered at the University of Toronto, Columbia University, the Bell Telephone Laboratories, and Stan ford University. But, as is illustrated by the papers of this volume, its effects and his personal infiuence have diffused widely. In his own work, Art Schawlow is noted for thoughtful imagination, keen physical intuition, and what might be thought an interest in gadgets - not just any gadgets, but beautiful and innovative mechanisms or new techniques in which he charac teristically recognizes important potentials.
The aim of this book is to provide both an introduction and a state-of-the-art report on research into magnetism and magnetic materials. Particular emphasis has been put on the contribution of synchrotron radiation in relevant experimental investigations. Graduate students and nonspecialists will benefit from the tutorial approach while specialists will find the latest results that round off the material presented in the lectures.
1989 was by any standards an extraordinary year: the year in which the Cold War ended. However, although much has changed, much remains unresolved or not changed at all. Even though the rationale for the huge military forces has been removed from the East-West relationship, these forces still retain a tremendous potential to do harm. Moreover, threats to peace may grow along North-South and South-South axes. An example of such a threat is the rapid growth in size and sophistication of military arsenals in the South. The contributions to this volume make it clear that the problems of East and West, North and South are inter- twined. Security can be gained only through cooperation. The contributors, who come from widely differing geographical, cultural and political backgrounds, all share the Pugwash tradition of scientific objectivity.
Since the previous Symposium, several exciting new developments and advances have occurred in the field of frequency standards and metrology. These include the first results on the long-tenn stability of a millisecond Pulsar, for which data 14 integrated over several years now show a stability of around 10- . Improvements in the understanding of various biases in Cesium beam standards promise accuracies in the low 14s for primary standards and in the low 13s for short commercial tubes, for which long tenn stabilities in low 14s have already been shown to be obtainable by accuracy improvement. Beams using optical pumping for state selection and for detection have been operated with excellent results, and more are being realized. Other new frequency standards which have appeared include a macroscopic rf trap with Mercury ions, which perfonns in the low 15s in one day, the sub millimeter metastable Magnesium beam, which has shown a short tenn stability 19 in the low 12s in one second and promises an accuracy of 10- , and the cold Hydrogen masers, which have such high stabilities that they cannot be measured with existing local oscillators. Prospects for future developments include laser manipulation of neutrals and spectroscopy of single ions at rest in a trap. Both these groups of techniques have great potential for unprecedented accuracy and short-and long-tenn stability, and new superior frequency standards are expected to be realizable in this way in the not too distant future.
This volume contains a series of six lecture courses presented by some of the leading exponents in the field of low-temperature physics. Special emphasis is given to theoretical and experimental advances in our understanding of 3He, heavy fermion systems and high-Tc superconductivity. The book provide an ideal basis for graduate courses in low-temperature physics.
The book is devoted to the modern theory and experimental manifestation of Polarization Bremsstrahlung (PB) which arises due to scattering of charged particles from various targets: atoms, nanostructures (including atomic clusters, nanoparticle in dielectric matrix, fullerens, graphene-like two-dimensional atomic structure) and in condensed matter (monocrystals, polycrystals, partially ordered crystals and amorphous matter) The present book addresses mainly researchers interested in the radiative processes during the interaction between fast particles and matter. It also will be useful for post-graduate students specializing in radiation physics and related fields.
The 2002 Spring Meeting of the "Deutsche Physikalische Gesellschaft" was held in Regensburg from March 25th to 29th, 2002. The number of conference attendees has remained remarkably stable at about 2800, despite the decreas ing number of German PhD students. This can be taken as an indication that the program of the meeting was very attractive. The present volume of the "Advances in Solid State Physics" contains the written versions of most of the invited talks, also those presented as part of the Symposia. Most of these Symposia were organized by several divisions in collaboration and they covered fascinating selection of topics of current interest. I trust that the book reflects this year's status of the field in Germany. In particular, one notes a slight change in paradigms: from quantum dots and wires to spin transport and soft matter systems in the broadest sense. This seems to reflect the present general trend in physics. Nevertheless, a large portion of the invited papers as well as the discussions at the meeting concentrated on nanostrnctured matter.
Mulilayer Integrated Film Bulk Acoustic Resonators mainly introduces the theory, design, fabrication technology and application of a recently developed new type of device, multilayer integrated film bulk acoustic resonators, at the micro and nano scale involving microelectronic devices, integrated circuits, optical devices, sensors and actuators, acoustic resonators, micro-nano manufacturing, multilayer integration, device theory and design principles, etc. These devices can work at very high frequencies by using the newly developed theory, design, and fabrication technology of nano and micro devices. Readers in fields of IC, electronic devices, sensors, materials, and films etc. will benefit from this book by learning the detailed fundamentals and potential applications of these advanced devices. Prof. Yafei Zhang is the director of the Ministry of Education's Key Laboratory for Thin Films and Microfabrication Technology, PRC; Dr. Da Chen was a PhD student in Prof. Yafei Zhang's research group.
Principles and Applications of ESR Spectroscopy fills the gap between the detailed monographs in ESR spectroscopy and the general textbooks in molecular physics, physical chemistry, biochemistry or spectroscopy. The latter only briefly explain the underlying theory and do not provide details about applications, while the currently available ESR textbooks are primarily focused on the technique as such. This text is based upon the authors' long experience of teaching the subject to a mixed audience, in the extreme case ranging from physics to biology. The potential of the method is illustrated with applications in fields such as molecular science, catalysis and environmental sciences, polymer and materials sciences, biochemistry and radiation chemistry/physics. Theoretical derivations have in general been omitted, as they have been presented repeatedly in previous works. The necessary theory is instead illustrated by practical examples from the literature.
The reflection of and neutrons from surfaces has existed as an x-rays exp- imental for almost it is in the last technique fifty Nevertheless, only years. decade that these methods have become as of enormously popular probes This the surfaces and interfaces. to be due to of several appears convergence of intense different circumstances. These include the more n- availability be measured orders tron and sources that can over (so reflectivity x-ray many of and the much weaker surface diffuse can now also be magnitude scattering of thin films and studied in some the detail); growing importance multil- basic the realization of the ers in both and technology research; important which in the of surfaces and and role roughness plays properties interfaces; the of statistical models to characterize the of finally development topology its and its characterization from on roughness, dependence growth processes The of and to surface scattering experiments. ability x-rays neutro4s study four five orders of in scale of surfaces over to magnitude length regardless their and also their to ability probe environment, temperature, pressure, etc. , makes these the choice for buried interfaces often probes preferred obtaining information about the microstructure of often in statistical a global surfaces, the local This is manner to complementary imaging microscopy techniques, of such studies in the literature witnessed the veritable by explosion published the last few Thus these lectures will useful for over a resource years.
Millimeter and Submillimeter Wave Spectroscopy of Solids focuses on the experimental methods and recent experimental results which are currently employed in the millimeter wave spectral range. Time dome, Fourier transform, coherent source and resonant techniques are discussed by leading authorities in the field. The usefulness of the methods is discussed by reviewing experimental results on metals and semiconductors. Recent experiment covering modern topics such as correlation on metals, superconductors and confined quantum systems are also discussed. The volume is aimed at physicists, engineers and materials scientists interested in the dynamics of solid matter.
This book presents the current knowledge about superconductivity in high Tc cuprate superconductors. There is a large scientific interest and great potential for technological applications. The book discusses all the aspects related to all families of cuprate superconductors discovered so far. Beginning with the phenomenon of superconductivity, the book covers: the structure of cuprate HTSCs, critical currents, flux pinning, synthesis of HTSCs, proximity effect and SQUIDs, possible applications of high Tc superconductors and theories of superconductivity. Though a high Tc theory is still awaited, this book describes the present scenario and BCS and RVB theories. The second edition was significantly extended by including film-substrate lattice matching and buffer layer considerations in thin film HTSCs, brick-wall microstructure in the epitaxial films, electronic structure of the CuO2 layer in cuprates, s-wave and d-wave coupling in HTSCs and possible scenarios of theories of high Tc superconductivity.
Sean Ashton's doctoral thesis, which he finished at the Technical University in Munich, describes the challenge of constructing a Differential Electrochemical Mass Spectrometer instrument (DEMS). DEMS combines an electrochemical cell with mass spectrometry via a membrane interface, allowing gaseous and volatile electrochemical reaction species to be monitored online. The thesis carefully introduces the fuel cell electrocatalyst development concerns before reviewing the pertinent literature on DEMS. This is followed by the presentation and discussion of the new extended design, including a thorough characterization of the instrument. The capabilities of the new setup are demonstrated in two research studies: The methanol oxidation reaction on Pt and PtRu catalysts, and the electrochemical corrosion of fuel cell catalyst supports. Despite both topics having long since been studied, new insights can be obtained through careful investigations with the new DEMS instrument that are of great, general interest. The thesis and the instrument thus show the way for future investigations in the field.
A concise textbook bridging quantum theory and spectroscopy! Designed as a practical text, Quantum Mechanical Foundations of Molecular Spectroscopy covers the quantum mechanical fundamentals of molecular spectroscopy from the view of a professional spectroscopist, rather than a theoretician. Written by a noted expert on the topic, the book puts the emphasis on the relationship between spectroscopy and quantum mechanics, and provides the background information and derivations of the subjects needed to understand spectroscopy including: stationary energy states, transitions between these states, selection rules, and symmetry. The phenomenal growth of all forms of spectroscopy over the past eight decades has contributed enormously to our understanding of molecular structure and properties. Today spectroscopy covers a broad field including the modern magnetic resonance techniques, non-linear, laser and fiber-based spectroscopy, surface and surface-enhanced spectroscopy, pico- and femtosecond time resolved spectroscopy, and many more. This up-to-date resource discusses several forms of spectroscopy that are used in many fields of science, such as fluorescence, surface spectroscopies, linear and non-linear Raman spectroscopy and spin spectroscopy. This important text: Contains the physics and mathematics needed to understand spectroscopy Explores spectroscopic methods the are widely used in chemistry, biophysics, biology, and materials science Offers a text written by an experienced lecturer and practitioner of spectroscopic methods Includes detailed explanations and worked examples Written for chemistry, biochemistry, material sciences, and physics students, Quantum Mechanical Foundations of Molecular Spectroscopy provides an accessible text for understanding molecular spectroscopy.
Clinical pharmacology plays an important role in today's medicine. Due to the high sensitivity, selectivity, and affordability of a mass spectrometer (MS), the high performance liquid chromatography - mass spectrometry (LC-MS) analytical technique is widely used in the determination of drugs in human biological matrixes for clinical pharmacology. Specifically, LC-MS is used to analyze: anticancer drugs antidementia drugs antidepressant drugs antiepileptic drugs antifundal drug antimicrobial drugs antipsychotic drugs antiretroviral drugs anxiolytic/hypnotic drugs cardiac drugs drugs for addiction immunosuppressant drugs mood stabilizer drugs This book will primarily cover the various methods of validation for LC-MS techniques and applications used in modern clinical pharmacology.
"Solid-State Theory - An Introduction" is a textbook for graduate students of physics and material sciences. Whilst covering the traditional topics of older textbooks, it also takes up new developments in theoretical concepts and materials that are connected with such breakthroughs as the quantum-Hall effects, the high-Tc superconductors, and the low-dimensional systems realized in solids. Thus besides providing the fundamental concepts to describe the physics of the electrons and ions comprising the solid, including their interactions, the book casts a bridge to the experimental facts and gives the reader an excellent insight into current research fields. A compilation of problems makes the book especially valuable to both students and teachers.
Common methods of local magnetic imaging display either a high spatial resolution and relatively poor field sensitivity (MFM, Lorentz microscopy), or a relatively high field sensitivity but limited spatial resolution (scanning SQUID microscopy). Since the magnetic field of a nanoparticle or nanostructure decays rapidly with distance from the structure, the achievable spatial resolution is ultimately limited by the probe-sample separation. This thesis presents a novel method for fabricating the smallest superconducting quantum interference device (SQUID) that resides on the apex of a very sharp tip. The nanoSQUID-on-tip displays a characteristic size down to 100 nm and a field sensitivity of 10^-3 Gauss/Hz^(1/2). A scanning SQUID microsope was constructed by gluing the nanoSQUID-on-tip to a quartz tuning-fork. This enabled the nanoSQUID to be scanned within nanometers of the sample surface, providing simultaneous images of sample topography and the magnetic field distribution. This microscope represents a significant improvement over the existing scanning SQUID techniques and is expected to be able to image the spin of a single electron.
Atomic Spectroscopy provides a comprehensive discussion on the general approach to the theory of atomic spectra, based on the use of the Lagrangian canonical formalism. This approach is developed and applied to explain the hydrogenic hyperfine structure associated with the nucleus motion, its finite mass, and spin. The non-relativistic or relativistic, spin or spin-free particle approximations can be used as a starting point of general approach. The special attention is paid to the theory of Lamb shift formation. The formulae for hydrogenic spectrum including the account of Lamb shift are written in simple analytical form. The book is of interest to specialists, graduate and postgraduate students, who are involved into the experimental and theoretical research in the field of modern atomic spectroscopy.
MALDI-ToF Mass Spectrometry for Studying Noncovalent Complexes of Biomolecules, by Stefanie Madler, Elisabetta Boeri Erba, Renato Zenobi Application of MALDI-TOF-Mass Spectrometry to Proteome Analysis Using Stain-Free Gel Electrophoresis, by Iuliana Susnea, Bogdan Bernevic, Michael Wicke, Li Ma, Shuying Liu, Karl Schellander, Michael Przybylski MALDI Mass Spectrometry for Nucleic Acid Analysis, by Xiang Gao, Boon-Huan Tan, Richard J. Sugrue, Kai Tang Determination of Peptide and Protein Disulfide Linkages by MALDI Mass Spectrometry, by Hongmei Yang, Ning Liu, Shuying Liu MALDI In-Source Decay, from Sequencing to Imaging, by Delphine Debois, Nicolas Smargiasso, Kevin Demeure, Daiki Asakawa, Tyler A. Zimmerman, Loic Quinton, Edwin De Pauw Advances of MALDI-TOF MS in the Analysis of Traditional Chinese Medicines, by Minghua Lu, Zongwei Cai Chemical and Biochemical Applications of MALDI TOF-MS Based on Analyzing the Small Organic Compounds, by Haoyang Wang, Zhixiong Zhao, Yinlong Guo Bioinformatic Analysis of Data Generated from MALDI Mass Spectrometry for Biomarker Discovery, by Zengyou He, Robert Z. Qi, Weichuan Yu
Optics and Lasers is an introduction to engineering and applied optics, including not only elementary ray and wave optics, but also lasers, holography, copherence, fibers, and optical waveguides. It stresses physicalprinciples, applications, and instrumentation. It will be most usefull to the practicing engineer or experimental scientist, graduate student, or advanced undergraduate. It contains more than enough material from which to selelct the core of an introctory optics course and sufficientto form the bulk of a more advanced course.
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