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Books > Science & Mathematics > Chemistry > Analytical chemistry > Qualitative analytical chemistry > Chemical spectroscopy, spectrochemistry > General
This book is loosely based on a Multidisciplinary University Research Initiative (MURI) project and a few supplemental projects sponsored by the Of?ce of Naval Research (ONR) during the time frame of 2004-2009. The initial technical scope and vision of the MURI project was formulated by Drs. Larry Cooper and Joel Davis, both program of?cers at ONR at the time. The unifying theme of this MURI project and its companionefforts is the concept of cellular nonlinear/neuralnetwork (CNN) technology and its various extensions and chip implementations, including nanoscale sensors and the broadening ?eld of cellular wave computing. In recent years, CNN-based vision system drew much attention from vision scientists to device technologists and computer architects. Due to its early - plementation in a two-dimensional (2D) topography, it found success in early vision technologyapplications, such as focal-plane arrays, locally adaptable sensor/ processor integration, resulting in extremely high frame rates of 10,000 frames per second. More recently it drew increasing attention from computer architects, due to its intrinsic local interconnect architecture and parallel processing paradigm. As a result, a few spin-off companies have already been successful in bringing cel- lar wave computing and CNN technology to the market. This book aims to capture some of the recent advances in the ?eld of CNN research and a few select areas of applications.
Power consumption becomes the most important design goal in a wide range of electronic systems. There are two driving forces towards this trend: continuing device scaling and ever increasing demand of higher computing power. First, device scaling continues to satisfy Moore's law via a conventional way of scaling (More Moore) and a new way of exploiting the vertical integration (More than Moore). Second, mobile and IT convergence requires more computing power on the silicon chip than ever. Cell phones are now evolving towards mobile PC. PCs and data centers are becoming commodities in house and a must in industry. Both supply enabled by device scaling and demand triggered by the convergence trend realize more computation on chip (via multi-core, integration of diverse functionalities on mobile SoCs, etc.) and finally more power consumption incurring power-related issues and constraints. Energy-Aware System Design: Algorithms and Architectures provides state-of-the-art ideas for low power design methods from circuit, architecture to software level and offers design case studies in three fast growing areas of mobile storage, biomedical and security. Important topics and features: - Describes very recent advanced issues and methods for energy-aware design at each design level from circuit and architecture to algorithm level, and also covering important blocks including low power main memory subsystem and on-chip network at architecture level - Explains efficient power conversion and delivery which is becoming important as heterogeneous power sources are adopted for digital and non-digital parts - Investigates 3D die stacking emphasizing temperature awareness for better perspective on energy efficiency - Presents three practical energy-aware design case studies; novel storage device (e.g., solid state disk), biomedical electronics (e.g., cochlear and retina implants), and wireless surveillance camera systems. Researchers and engineers in the field of hardware and software design will find this book an excellent starting point to catch up with the state-of-the-art ideas of low power design.
Atomistic simulations of metals under irradiation are indispensable for understanding damage processes at time- and length-scales beyond the reach of experiment. Previously, such simulations have largely ignored the effect of electronic excitations on the atomic dynamics, even though energy exchange between atoms and electrons can have significant effects on the extent and nature of radiation damage. This thesis presents the results of time-dependent tight-binding simulations of radiation damage, in which the evolution of a coupled system of energetic classical ions and quantum mechanical electrons is correctly described. The effects of electronic excitations in collision cascades and ion channeling are explored and a new model is presented, which makes possible the accurate reproduction of non-adiabatic electronic forces in large-scale classical molecular dynamics simulations of metals.
This NATO-ASIinstallment is designed to provide an advanced overview for doctoral and post-doctoral candidates of the state-of-the-art technologies for bio-detection. The main objective of the work aims at providingreaders with the latest developments necessary to successfully understand the CBRN Agents and their associated biotechnologies. The core methods focused on aremass spectrometry (including chromatographic and electrophoretic separation) and comparisons to spectroscopic, immunological and molecular analysis of chemical, biological and nuclear agents."
Strain Effect in Semiconductors: Theory and Device Applications presents the fundamentals and applications of strain in semiconductors and semiconductor devices that is relevant for strain-enhanced advanced CMOS technology and strain-based piezoresistive MEMS transducers. Discusses relevant applications of strain while also focusing on the fundamental physics pertaining to bulk, planar, and scaled nano-devices. Hence, this book is relevant for current strained Si logic technology as well as for understanding the physics and scaling for future strained nano-scale devices.
This thesis describes a new approach for cell analysis by the rapid developing microfluidic technology. The nominee has made great contributions to develop a new analysis platform which combined microfluidic devices with mass spectrometry to determine the trace compounds secreted by cells. Based on this analysis platform, she studied the specific cell secreting behaviors under controlled microenvironment, of which the secretion compounds were qualified and semi-quantified by mass spectrometry. A novel cell sorting device integrated homogenous porous PDMS membrane was invented to classify cells from real samples based on the size difference. The nominee further studied the signal transmission between different cells, and the signal chemicals were qualitative and quantitative monitored by the analysis platform. This indicates the potential significant application of the new cell analysis platform in medicine screening and early diagnosis.
This book presents the state-of-the-art of Terahertz spectroscopy. It is a modern source for a beginners and researcher interested in THz spectroscopy. The basics and physical background of THz spectroscopy and technology are explained, and important applications are described. The book presents the highlights of scientific research in the field of THz science and provides an excellent overview of the field and future directions of research. Over the last decade the field of terahertz spectroscopy has developed into one of the most rapidly growing fields of spectroscopy with large impact across a wide range of scientific disciplines. Due to substantial advances in femtosecond laser technology, terahertz time-domain spectroscopy (THz-TDS) has established itself as the dominant spectroscopic technique for experimental scientists interested in measurements in this frequency range. In solids and liquids terahertz radiation is at resonance with both phonon modes and hydrogen bonding modes which makes it an ideal tool to study the interaction between molecules in a unique way, thus opening a wealth of opportunities for research in physics, chemistry, biology, materials science and pharmaceuticals. This book provides an easy access to scientists, engineers and students alike who want to understand the theory and applications of modern terahertz spectroscopy.
The RF front-end - antenna combination is a vital part of a mobile phone because its performance is very relevant to the link quality between hand-set and cellular network base-stations. The RF front-end performance suffers from changes in operating environment, like hand-effects, that are often unpredictable. Adaptive RF Front-Ends for Hand-Held Applications presents an analysis on the impact of fluctuating environmental parameters. In order to overcome undesired behavior two different adaptive control methods are treated that make RF frond-ends more resilient: adaptive impedance control, and adaptive power control. Several adaptive impedance control techniques are discussed, using a priori knowledge on matching network properties, in order to simplify robust 2-dimensional control. A generic protection concept is presented, based on adaptive power control, which improves the ruggedness of a power amplifier or preserves its linearity under extremes. It comprises over-voltage, over-temperature, and under-voltage protection.
This book provides a multidisciplinary overview to the application of high order derivative spectrophotometry and Electron Spin Resonance (ESR) spectroscopy in biology and ecology. The characteristics of the principle methods as well as the generation of reliable spectra are discussed in general terms allowing the reader to gain an idea of these methods' potentials. Furthermore the authors give an extended overview to the spectroscopic and spectro-photometric analysis of specific biological materials. This volume is a well condensed description of an analytical method and a clear review to its application in biology and related fields and an essential tool for researchers who are new in the field of spectroscopic methods and their applications in the life sciences.
In this book, Yoshimura provides a review of the UHV related development during the last decades. His very broad experience in the design enables him to present us this detailed reference. After a general description how to design UHV systems, he covers all important issue in detail, like pumps, outgasing, Gauges, and Electrodes for high voltages. Thus, this book serves as reference for everybody using UVH in scientific equipment.
Proceedings of the 9th Latin American Conference on the Applications of the Moessbauer Effect, LACAME 2004, held in Mexico City, Mexico, 19-24 September 2004. This volume demonstrates the way in which researchers, on a wide range of topics, many interdisciplinary, find the applications of the Moessbauer Effect an outstanding method whose results, sometimes unique, complements and improves the information obtained by other techniques to deepen the understanding of the matter under research. This volume comprises research papers, reviews, and short communications recording original investigations on applications to diverse areas like archaeology, metallurgy, soil science, geology, industrial applications, new instrumentation, corrosion, and chemical applications. The papers present the latest scientific work of various regional investigators and of the invited speakers from abroad that have brought their perspectives to the meeting.
Atomic Spectroscopy provides a comprehensive discussion on the general approach to the theory of atomic spectra, based on the use of the Lagrangian canonical formalism. This approach is developed and applied to explain the hydrogenic hyperfine structure associated with the nucleus motion, its finite mass, and spin. The non-relativistic or relativistic, spin or spin-free particle approximations can be used as a starting point of general approach. The special attention is paid to the theory of Lamb shift formation. The formulae for hydrogenic spectrum including the account of Lamb shift are written in simple analytical form. The book is of interest to specialists, graduate and postgraduate students, who are involved into the experimental and theoretical research in the field of modern atomic spectroscopy.
The third volume of this book addresses central aspects of spin-dynamic phenomena on a tutorial level. This volume concentrates on new experimental techniques such as ferromagnetic-resonance-force microscopy and two-photon photoemission. There is a chapter devoted to the hot subject of spin-transfer torque. The comprehensive presentation makes this a timely and valuable resource for every researcher working in the field of magnetism.
This text on the electrical, optical, magnetic, and thermal properties of materials stresses concepts rather than mathematical formalism. Suitable for advanced undergraduates, it is intended for materials and electrical engineers who want to gain a fundamental understanding of alloys, semiconductor devices, lasers, magnetic materials, and so forth. The book is organized to be used in a one-semester course; to that end each section of applications, after the introduction to the fundamentals of electron theory, can be read independently of the others. Many examples from engineering practice serve to provide an understanding of common devices and methods. Among the modern applications covered are: high-temperature superconductors, optoelectronic materials, semiconductor device fabrication, xerography, magneto-optic memories, and amorphous ferromagnetics. The fourth edition has been revised and updated with an emphasis on the applications sections, which now cover devices of the next generation of electronics.
This thesis presents the theory of three key elements of optical spectroscopy of the electronic excitations in bilayer graphene: angle-resolved photoemission spectroscopy (ARPES), visible range Raman spectroscopy, and far-infrared (FIR) magneto-spectroscopy. Bilayer graphene (BLG) is an atomic two-dimensional crystal consisting of two honeycomb monolayers of carbon, arranged according to Bernal stacking. The unperturbed BLG has a unique band structure, which features chiral states of electrons with a characteristic Berry phase of 2$\pi$, and it has versatile properties which can be controlled by an externally applied transverse electric field and strain. It is shown in this work how ARPES of BLG can be used to obtain direct information about the chirality of electron states in the crystal. The author goes on to describe the influence of the interlayer asymmetry, which opens a gap in BLG, on ARPES and on FIR spectra in a strong magnetic field. Finally, he presents a comprehensive theory of inelastic Raman scattering resulting in the electron-hole excitations in bilayer graphene, at zero and quantizing magnetic fields. This predicts their polarization properties and peculiar selection rules in terms of the inter-Landau-level transitions.
The book is based on lectures presented on the International Summer School on Biophysics held in Croatia in September 2009. The advantage of the School is that it provides advanced training in very broad scope of areas related to biophysics contrary to other similar schools or workshops that are centered mainly on one topic or technique. In this volume, tenth in the row, the papers in the field of biophysics are presented. The topics are biological phenomena from single protein to macromolecular aggregations structure by using variant physical methods (NMR, EPR, FTIR, Mass Spectrometry, etc.). The interrelationship of supramolecular structures and their functions is enlightened by applications of principals of these physical methods in the biophysical and molecular biology context.
The reader is provided with information about methods of calibration of light sources and photodetectors as well as responsiveness of spectral instruments ranging from near infrared to vacuum UV spectral, 1200 - 100 nm, and radiation intensities of up to several quanta per second in absolute and arbitrary units. The author describes for the first time original methods of measurements they created and draws upon over 40 years of experience in working with light sources and detectors to provide accurate and precise measurements. This book is the first to cover these aspects of radiometry and is divided into seven chapters that examine information about terminology, units, light sources and detectors, methods, including author's original ones, of absolute calibration of detectors, spectral instruments responsiveness, absolute measurements of radiation intensity of photoprocesses, and original methods of their study. Of interest to researchers measuring; luminescence spectra, light intensities from IR to vacuum UV, spectral range in wide-light intensity ranges, calibrate light sources and detectors, absolute or relative quantum yields of photoprocess determination.
This brief presents numerical methods for describing and calculating invariant phase space structures, as well as solving the classical and quantum equations of motion for polyatomic molecules. Examples covered include simple model systems to realistic cases of molecules spectroscopically studied. Vibrationally excited and reacting molecules are nonlinear dynamical systems, and thus, nonlinear mechanics is the proper theory to elucidate molecular dynamics by investigating invariant structures in phase space. Intramolecular energy transfer, and the breaking and forming of a chemical bond have now found a rigorous explanation by studying phase space structures.
This book explains concepts of transmission electron microscopy (TEM) and x-ray diffractometry (XRD) that are important for the characterization of materials. The fourth edition adds important new techniques of TEM such as electron tomography, nanobeam diffraction, and geometric phase analysis. A new chapter on neutron scattering completes the trio of x-ray, electron and neutron diffraction. All chapters were updated and revised for clarity. The book explains the fundamentals of how waves and wavefunctions interact with atoms in solids, and the similarities and differences of using x-rays, electrons, or neutrons for diffraction measurements. Diffraction effects of crystalline order, defects, and disorder in materials are explained in detail. Both practical and theoretical issues are covered. The book can be used in an introductory-level or advanced-level course, since sections are identified by difficulty. Each chapter includes a set of problems to illustrate principles, and the extensive Appendix includes laboratory exercises.
To anyone who is interested in surface chemical analysis of materials on the nanometer scale, this book is prepared to give appropriate information. Based on typical application examples in materials science, a concise approach to all aspects of quantitative analysis of surfaces and thin films with AES and XPS is provided. Starting from basic principles which are step by step developed into practically useful equations, extensive guidance is given to graduate students as well as to experienced researchers. Key chapters are those on quantitative surface analysis and on quantitative depth profiling, including recent developments in topics such as surface excitation parameter and backscattering correction factor. Basic relations are derived for emission and excitation angle dependencies in the analysis of bulk material and of fractional nano-layer structures, and for both smooth and rough surfaces. It is shown how to optimize the analytical strategy, signal-to-noise ratio, certainty and detection limit. Worked examples for quantification of alloys and of layer structures in practical cases (e.g. contamination, evaporation, segregation and oxidation) are used to critically review different approaches to quantification with respect to average matrix correction factors and matrix relative sensitivity factors. State-of-the-art issues in quantitative, destructive and non-destructive depth profiling are discussed with emphasis on sputter depth profiling and on angle resolved XPS and AES. Taking into account preferential sputtering and electron backscattering corrections, an introduction to the mixing-roughness-information depth (MRI) model and its extensions is presented.
Proceedings of the Eleventh Latin American Conference on the Applications of the Moessbauer Effect, La Plata, Argentina, 9-14 November 2008. The broad scope of the Applications of the Moessbauer Effect to interdisciplinary subjects makes this volume an outstanding source of information to researchers and graduate students, who will find the unique results of Moessbauer spectroscopy a valuable aid and complement to their research in conjunction with other techniques. In this volume, applications to mineralogy, catalysis, soil science, amorphous materials, nanoparticles, magnetic materials, nanotechnology, metallurgy, corrosion, and magnetism, have been put together in original works produced by invited speakers and different research teams across the continent.
Simple carbohydrates, complex oligosaccharides and polysaccharides all belong to a class of ubiquitous (macro)molecules that exhibit a wide range of biological functions, and the recent advent of enhanced enzymatic, chemical and analytical tools used to study these sugars has inaugurated a genuine explosion in the field of glycomics. Specifically, it has led to a deeper understanding of how specific sugar structures modulate cellular phenotypes, and that breakthrough has led to the discovery of new pharmaceuticals for the treatment of many serious diseases, such as cancer. The subsequent rapid expansion of this research holds high promise for future therapeutic regimens, and capillary electrophoresis (CE) refers to the range of related separation techniques that are integral to this vital research. CE uses narrow-bore fused-silica capillaries to separate a complex array of large and small molecules, and Capillary Electrophoresis of Carbohydrates offers a comprehensive look at the latest breakthroughs and improvements in CE and CE techniques applied to monosaccharides up to complex oligosaccharides and polysaccharides. It begins with an overview of the application of CE and CE- mass spectrometric in the analysis of simple carbohydrates without any previous derivatization step before discussing various detection techniques such as spectrophotometric detection, electrochemical detection and other less common techniques. It then covers in detail an array of related topics and numerous applications. It is an essential text for anyone exploring the myriad possibilities of this rapidly expanding field.
This book offers a balanced mixture of practice-oriented information and theoretical background as well as numerous references, clear illustrations, and useful data tables. Problems and solutions are accessible via a special website. This new edition has been completely revised and extended; it now includes three new chapters on tandem mass spectrometry, interfaces for sampling at atmospheric pressure, and inorganic mass spectrometry.
Within the last 30 years, electron energy-loss spectroscopy (EELS) has become a standard analytical technique used in the transmission electron microscope to extract chemical and structural information down to the atomic level. In two previous editions, Electron Energy-Loss Spectroscopy in the Electron Microscope has become the standard reference guide to the instrumentation, physics and procedures involved, and the kind of results obtainable. Within the last few years, the commercial availability of lens-aberration correctors and electron-beam monochromators has further increased the spatial and energy resolution of EELS. This thoroughly updated and revised Third Edition incorporates these new developments, as well as advances in electron-scattering theory, spectral and image processing, and recent applications in fields such as nanotechnology. The appendices now contain a listing of inelastic mean free paths and a description of more than 20 MATLAB programs for calculating EELS data.
Abstract This chapter lays the foundation for the work presented in latter chapters. The potential of 60 GHz frequency bands for high data rate wireless transfer is discussed and promising applications are enlisted. Furthermore, the challenges related to 60 GHz IC design are presented and the chapter concludes with an outline of the book. Keywords Wireless communication 60 GHz Millimeter wave integrated circuit design Phase-locked loop CMOS Communication technology has revolutionized our way of living over the last century. Since Marconi's transatlantic wireless experiment in 1901, there has been tremendous growth in wireless communication evolving from spark-gap telegraphy to today's mobile phones equipped with Internet access and multimedia capabilities. The omnipresence of wireless communication can be observed in widespread use of cellular telephony, short-range communication through wireless local area networks and personal area networks, wireless sensors and many others. The frequency spectrum from 1 to 6 GHz accommodates the vast majority of current wireless standards and applications. Coupled with the availability of low cost radio frequency (RF) components and mature integrated circuit (IC) techn- ogies, rapid expansion and implementation of these systems is witnessed. The downside of this expansion is the resulting scarcity of available bandwidth and allowable transmit powers. In addition, stringent limitations on spectrum and energy emissions have been enforced by regulatory bodies to avoid interference between different wireless systems. |
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