Traditionally, process design and control system design are performed sequentially. It is only recently displayed that a simultaneous approach to the design and control leads to significant economic benefits and improved dynamic performance during plant operation.

Extensive research in issues such as 'interactions of design and control', 'analysis and design of plant wide control systems', 'integrated methods for design and control' has resulted in impressive advances and significant new technologies that have enriched the variety of instruments available for the design engineer in her endeavour to design and operate new processes. The field of integrated process design and control has reached a maturity level that mingles the best from process knowledge and understanding and control theory on one side, with the best from numerical analysis and optimisation on the other. Direct implementation of integrated methods should soon become the mainstream design procedure.

Within this context 'The Integration of Process Design and Control', bringing together the developments in a variety of topics related to the integrated design and control, will be a real asset for design engineers, practitioners and researchers. Although the individual chapters reach a depth of analysis close to the frontier of current research status, the structure of the book and the autonomous nature of the chapters make the book suitable for a newcomer in the area.

The book comprises four distinct parts:
Part A: Process characterization and controllability analysis
Part B: Integrated process design and control ⊣ Methods
Part C: Plant wide interactions of design and control
Part D: Integrated process design and control ⊣ Extensions

By the end of the book, the reader will have developed a commanding comprehension of the main aspects of integrated design and control, the ability to critically assess the key characteristics and elements related to the interactions between design and control and the capacity to implement the new technology in practice.
* This book brings together the latest developments in a variety of topics related to integrated design and control.
* It is a valuable asset for design engineers, practitioners and researchers.
* The structure of the book and the nature of its chapters also make it suitable for a newcomer to the field.

Contents - 1. The Free Atom- The contribution of spectroscopy - The Rutherford-Bohr model of the atom - Modern quantum theory - The Pauli exclusion principle - The periodic system - Isotopes - 2. The Bound Atom - Band structure - The attractive and repulsive forces in binding - Stable electron configurations - Ionic bonding - Covalent bonding - Van der Waals' forces - The metallic bond - Implications of the type of bond on the structure of elements - Implications on conductivity - 3. Constitution - Crystallographic principles - The unit cell - The face centred cubic lattice - The close-packed hexagonal lattice. The body-centred cubic lattice - Twin crystals - The rhombohedral lattice - The tetragonal lattice - The structure of compounds - The silicate structure - Glasses - Carbon compounds - 4. Imperfections in Crystals - The surface - Vacant lattice sites - Interstitial atoms - Line and plane defects - Dislocations - Dislocation climb - Dislocation jogs - Imperfect dislocations - Sessile dislocations - Frank-Read sources - 5. The Vibration of Atoms and their Thermal Properties - The lattice vibration - Specific heat - Thermal expansion - Melting - Anisotropy - Thermal conductivity of insulators - Thermal shock - Thermal conductivity of good conductors - 6. Electrical, Magnetic, and Optical Properties - Electrical conductivity - Ionic conductivity - Semiconductors - Thermoelectric effects - Magnetic properties - Ferromagnetism - Antiferromagnetism and ferrimagnetism - Dielectrics - Optical properties - Other electromagnetic radiations - 7. Mechanical Properties - General aspects - Electricity - Plasticity - Resolved shear stress - The role of dislocations in plastic flow - The effect of temperature - Fracture - Creep - Fatigue - Thermal cycling - 8. Metals and Alloys - Properties of pure metals - Compatibility - Interstitial solid solution - Substitutional solid solution - Intermetallic compounds - Equilibrium and non-equilibrium - The properties of alloys - Precipitation in alloys - Complex alloys - 9. Non-metallic Materials - General - Timber - Stone, concrete, and asphalt - Plastics - Ceramics and glasses - Cermets - 10. Service Factors - General - Heterogeneity - Residual stresses - Corrosion - Radiation damage - Conclusion - Further Reading - Author Index - Subject Index - Preface - This book attempts to provide the broad background, to illustrate the basic reasons for the properties of elements, and to explain the consequences of chemical combination, alloying, and mixing. Most previous books have touched only lightly on the atom itself, but my experience in teaching engineers in the University of Manchester suggests that a greater depth of approach is welcome, perhaps because it can account for so much of the subsequent behaviour of metals.

Although many papers have been published describing methods for the inorganic analysis of petroleum no book has previously appeared devoted exclusively to this subject. The purpose of this work is to provide a laboratory handbook for industrial analysts of various degrees of professional training covering the determination of those elements commonly occurring in various types of petroleum products. The procedures represent, from the author's point of view, a reasonable compromise among the usual conflicting interests of speed, accuracy, and cost, and emphasize manufacturing rather than research applications. CONTENTS: Introduction 1. The Inorganic Components of Petroleum 2. Preparation of Samples for Inorganic Analysis: Direct Ashing, Soft Ashing and Wet Oxidation, Direct Wet Oxidation, Fusion with Pyrosulfate, The Oxygen Bomb, The Peroxide Bomb, Sodium Dehalogenation, Extraction Methods, Combustion Methods, Alkaline Sulfide Treatment, Direct Methods, Combustion Tube, Emission Spectrograph, X-rays 3. Aluminum: Colorimetric Determination, Gravimetric Determination 4. Arsenic 5. Barium: Determination in New Lubricating Oils, Determination in Used Lubricating Oils 6. Boron: Colorimetric Determination, Alkalimetric Determination 7. Calcium: Determination in New Lubricating Oils and Additives, Determination in Used Lubricating Oils, Estimation of Smaller Concentrations 8. Chromium 9. Cobalt: Electrolytic Determination, Volumetric Determination 10. Copper: Determination in Gasoline, Determination in Naphthenate Driers, Determination in Distillates, Determination in Used Lubricating Oils 11. The Halogens: Peroxide Bomb Combustion, Sodium Dehalogenation, Extraction Procedures, Wickbold Oxyhydrogen Combustion, Potentiometric Determination of Bromide and Chloride, Colorimetric Determination of Chloride, Volumetric Determination of Fluoride 12. Iron: Determination in Distillates, Determination in Used Lubricating Oils, Determination in Naphthenate Driers, Colorimetric Determination, Volumetric Determination 13. Lead: Determination in Naphthenate Driers, Determination in Light Distillates, Determination in Lubricating Oils 14. Manganese 15. Molybdenum: Determination in New Lubricating Oils, Determination in Used Lubricating Oils 16. Nickel: Determination in Distillates, Gravimetric Determination 17. Nitrogen: Determination of Total Nitrogen by Kjeldahl Method, Determination of Basic Nitrogen, Determination of Quaternary Ammonium Compounds 18. Phosphorus: Decomposition by Ashing in Presence of Zinc Oxide, Colorimetric Methods, Alkalimetric Determination of Phosphorus 19. Selenium: Colorimetric Determination, Volumetric Determination 20. Silicon: Determination in Synthetic Oils, Determination of Silica in Used Lubricating Oils 21. Sodium: Decomposition of Sample by Direct Ashing, Gravimetric Determination, Determination by Flame Photometer 22. Sulfur: Determination by Peroxide Fusion Bomb, Determination by Wickbold Oxyhydrogen Combustion 23. Vanadium: Determination in Distillates, Determination in Fuel Oils, Volumetric Determination 24. Zinc: Determination in Additives and Naphthenate Driers, Determination in New and Used Lubricating Oils, Potentiometric Determination, Gravimetric Determination; Appendix; Wickbold Apparatus for Oxyhydrogen Combustion; Index

There is hardly a technical library in the world in which the volumes of the Chemical Formulary (Volumes 1-34) do not occupy a prominent place. Chemists both experienced and beginner, continually refer to them. It does not duplicate any of the formulas included in previous volumes, but lists a wide array of modern and salable products from all branches of the chemical industries. An excellent reference for formulation problems. - CONTENTS - I. Introduction - II. Adhesives - III. Beverages and Foods - IV. Cosmetics - V. Coatings - VI. Detergents and Disinfectants - VII. Drug Products - VIII. Metal Treatments - IX. Polishes - X. Textile Specialties - XI. Miscellaneous - Appendix - Index - Preface - Chemistry, as taught in our schools and colleges, concerns chiefly synthesis, analysis, and engineering-and properly so. It is part of the right foundation for the education of the chemist. Many a chemist entering an Industry soon finds that most of the products manufactured by his concern are not synthetic or definite complex compounds, but are mixtures, blends, or highly complex compounds of which he knows little or nothing. The literature in this field, if any, may be meager, scattered, or obsolete. Even chemists with years of experience In one or more Industries spend considerable time and effort in acquainting themselves with any new field which they may enter. Consulting chemists similarly have to solve problems brought to them from industries foreign to them. There was a definite need for an up-to-date compilation of formulae for chemical compounding and treatment. Since the fields to be covered are many and varied, an editorial board of chemists and engineers engaged in many industries was formed. Many publications, laboratories, manufacturing firms, and Individuals have been consulted to obtain the latest and best information. It is felt that the formulas given in this volume will save chemists and allied workers much time and effort. Manufacturers and sellers of chemicals will find, In these formulae, new uses for their products. Non-chemical executives, professional men, and Interested laymen will make through this volume a "speaking acquaintance" with products which they may be using, trying or selling. It often happens that two Individuals using the same Ingredients in the same formula get different results. This may be due to slight deviations in the raw materials or unfamiliarity with the intricacies of a new technique. Accordingly, repeated experiments may be necessary to get the best results. Although many of the formulas given are being used commercially, many have been taken from the literature and may be subject to various errors and omissions. This should be taken into consideration. Wherever possible, it is advisable to consult with other chemists or technical workers regarding commercial production.

This book provides a hybrid methodology for engineering of trickle bed reactors by integrating conventional reaction engineering models with state-of-the-art computational flow models. The content may be used in several ways and at various stages in the engineering process: it may be used as a basic resource for making appropriate reactor engineering decisions in practice; as study material for a course on reactor design, operation, or optimization of trickle bed reactors; or in solving practical reactor engineering problems. The authors assume some background knowledge of reactor engineering and numerical techniques.

Quantitative structure-activity relationships (QSARs) represent predictive models derived from the application of statistical tools correlating biological activity or other properties of chemicals with descriptors representative of molecular structure and/or property. Quantitative Structure-Activity Relationships in Drug Design, Predictive Toxicology, and Risk Assessment discusses recent advancements in the field of QSARs with special reference to their application in drug development, predictive toxicology, and chemical risk analysis. Focusing on emerging research in the field, this book is an ideal reference source for industry professionals, students, and academicians in the fields of medicinal chemistry and toxicology.

Ion Exchange Materials: Properties and Applications fills a "two-dimensional" gap in books currently available on the subject. Firstly, there is a lack of modern comprehensive publications on the chemistry of ion exchange materials and on the relationships between their properties and practical applications. Secondly, there are few books on ion exchange chemistry that are targeted to industrial R&D specialists and research students who (i) do not work with ion exchange on a daily basis, (ii) need to develop competence in this area, and (iii) find it difficult to start studying the subject from primary scientific publications.
The book bridges these gaps by describing classical and modern theoretical concepts, as well as practical approaches for using ion exchange materials. Ion exchange materials combine properties of homogeneous and heterogeneous materials. Besides being an interesting subject for investigation, they are essential in a wide variety of industrial technologies: in the chemical and biochemical industries, pharmacy, medicine, microelectronics, the nuclear industry, food production, waste treatment, and many other areas. Ion exchange is a powerful tool in chemical analysis and scientific research. The main focus in this book is on ion exchange polymers: ion exchange resins, chelating resins, imprinted (templated), and other functional polymers. It provides an in-depth study of ion exchange materials, suitable for postgraduate students and R&D industrial specialists in chemistry, chemical and biochemical technology.
* Comprehensively covers the subject.
* Provides links between theoretical concepts, material properties, practical applications, and technical solutions.
* Easy to understand - requires only ground knowledge of university-level chemistry and can be read without an in-depth knowledge of mathematics.
* Supported with an interactive web-site.

Consolidating a collection of papers that Professor Eli Ruckenstein and his co-workers have published over the past four decades, Heterogeneous Catalysis Contributions to Experimental and Theoretical Studies addresses catalysts involved in reactions such as methane CO2 reforming, methane partial oxidation, and catalytic combustion. Each chapter opens with an introduction summarizing the papers included in the chapter and highlights the relevance of the chemistry to todays R&D. This valuable resource for catalytic and material scientists and graduate students paves the way to help develop new chemicals and materials.

This new edition of the Phosphor Handbook comprises three volumes and provides a comprehensive source of knowledge for researchers interested in synthesis, characterization, properties, and applications of phosphor materials. The first volume covers the theoretical background and fundamental properties of luminescence as applied to solid-state phosphor materials. New sections include the rapid developments in principal phosphors in nitrides, perovskite, and silicon carbide. The second volume provides the descriptions of synthesis and optical properties of phosphors used in different applications, including the novel phosphors for some newly developed applications. New sections on smart phosphors, quantum dots for display applications, up-conversion nanophosphors for photonic application, phosphors for solar cells. The third volume addresses the experimental methods for phosphor evaluation and characterization and the contents are widely expanded from the Second Edition, including the theoretical and experimental designs for new phosphors as well as the phosphor analysis through high pressure and synchrotron studies.

The Chemical Batch Reactor is aimed at tackling the above problems from a blending of academic and industrial perspectives. Advanced solutions (i.e., those based on recent research results) to the four fundamental problems of modeling, identification, control and fault diagnosis for batch processes are developed in detail in four distinct chapters. In each chapter, a general overview of foundational concepts is also given, together with a review of recent and classical literature on the various subjects.

To provide a unitary treatment of the different topics and give a firm link to the underlying practical applications, a single case study is developed as the book progresses; a batch process of industrial interest, i.e., the phenol-formaldehyde reaction for the production of phenolic resins, is adopted to test the various techniques developed. In this way, a roadmap of the solutions to fundamental problems, ranging from the early stages of the production process to the complete design of control and diagnosis systems, is provided for both industrial practitioners and academic researchers.

MICROBIAL INTERACTIONS AT NANOBIOTECHNOLOGY INTERFACES This book covers a wide range of topics including synthesis of nanomaterials with specific size, shape, and properties, structure-function relationships, tailoring the surface of nanomaterials for improving the properties, interaction of nanomaterials with proteins/microorganism/eukaryotic cells, and applications in different sectors. This book also provides a strong foundation for researchers who are interested to venture into developing functionalized nanomaterials for any biological applications in their research. Practical concepts such as modelling nanomaterials, and simulating the molecular interactions with biomolecules, transcriptomic or genomic approaches, advanced imaging techniques to investigate the functionalization of nanomaterials/interaction of nanomaterials with biomolecules and microorganisms are some of the chapters that offer significant benefits to the researchers.

Acknowledgements - Introduction - Contents - Part One- Natural Rubber - 1. THE STORY OF NATURAL RUBBER - The early history - The beginnings of the rubber industry - Goodyear and vulcanization - Plantation rubber - 2. THE NATURE OF NATURAL RUBBER - The physical properties of natural rubber- Tensile properties - Dynamic properties - Hardness - Abrasion - Electrical properties - The chemistry of natural rubber - Atoms and molecules - The formula of natural rubber - The elasticity of natural rubber - Part Two-Synthetic Rubber - 3. HISTORICAL INTRODUCTION TO SYNTHETIC RUBBER - The beginnings of synthetic rubber production - Synthetic rubber in the First World War - Progress between the wars - The American contribution - Developments after the Second World War - 4. THE MANUFACTURE OF GENERAL PURPOSE SYNTHETIC RUBBER - Butadiene: Petroleum - Butadiene and cracking - Styrene Production of the polymer: Emulsion polymerization - The polymerization formula - The synthetic rubber plant - 5. THE PROCESSING OF GENERAL PURPOSE SYNTHETIC RUBBER - Processing machinery: The bale-cutting machine - The mill - The internal mixer - The calendar - The spreading machine - The extruder Compounding: Plasticizers and softeners - Tack - Extenders - Reclaimed rubber - Fillers - Colouring materials - The ageing of rubber - Antioxidants - Vulcanization Accelerators - Vulcanization activators - Summary of compounding 6. SPECIAL PURPOSE RUBBERS - Nitrile rubber - Butyl rubber - Neoprene - Thiokol - Silicone rubbers - Polyurethanes - Hard rubber - 7. THE MANUFACTURE OF RUBBER ARTICLES - Mechanicals: Soles and heels - Bathing caps - Hot water bottles - Extruded articles - Wires and cables - Hose: Plain hose - Wrapped hose - Moulded hose - Armouring - Belting: Conveyor belts - Transmission belting - Rubber balls: Gold balls - Tyres: The cover - The bead - The casing - The tread and sidewalls - Cover building - Vulcanizing the cover - Inner tubes - Goods from latex: Compounding latex - Dipped goods - Latex thread - Latex foam - Part Three-The Future of Rubber - 8. MODERN DEVELOPMENTS - Polymerization: Condensation polymerization - Addition polymerization - Initiators - The arrangement of atoms in a chain - Synthetic natural rubber - cis Polybutadiene - Radiation and rubber: Polymerization - Cross-linking - Looking ahead - Bibliography - Glossary - Index - Plates - The object of this book is to explain what these various rubbers are, how they behave, and why they behave as they do. As synthetic rubbers are now being made in this country and will play an important part in the future of the rubber industry, most of this book is devoted to them. How they are made and how they compare with natural rubber is discussed in the appropriate place.- To enable a reasonable comparison to be made between natural rubber and the various synthetic rubbers the subject has been treated from a scientific standpoint, and to keep the size of the book between reasonable limits much technological information has been omitted. Because of the comparison between natural and synthetic rubbers the first section of this book is devoted to natural rubber. In this section the fundamentals of rubber science are introduced, to be developed later in connection with the synthetic rubbers. This book is intended as an introduction to a complex subject, and as a surveyor report for non-technical readers who wish to know something about rubber. The reader who requires further information on a particular point or topic should consult the bibliography at the end of the book.-

The capability to generate potable water from polluted sources is growing in importance as pharmaceuticals, microplastics and waste permeate our soil. Nanotechnology allows for improvements in water remediation technologies by taking advantage of the unique properties of materials at this small scale.

There is hardly a technical library in the world in which the volumes of the Chemical Formulary (Volumes 1-34) do not occupy a prominent place. Chemists both experienced and beginner, continually refer to them. It does not duplicate any of the formulas included in previous volumes, but lists a wide array of modern and salable products from all branches of the chemical industries. An excellent reference for formulation problems. -CONTENTS - I. Introduction - II. Adhesives - III. Coatings - IV. Cosmetics - V. Detergents and Disinfectants - VI. Drug Products - VII. Elastomers, Plastics and Resins - VIII. Foods and Beverages - IX. Polishes - X. Textile Specialties - XI. Miscellaneous - Appendix - Index - PREFACE - Chemistry, as taught in our schools and colleges, concerns chiefly synthesis, analysis, and engineering-and properly so. It is part of the right foundation for the education of the chemist. Many a chemist entering an Industry soon finds that most of the products manufactured by his concern are not synthetic or definite complex compounds, but are mixtures, blends, or highly complex compounds of which he knows little or nothing. The literature in this field, if any, may be meager, scattered, or obsolete. Even chemists with years of experience In one or more Industries spend considerable time and effort in acquainting themselves with any new field which they may enter. Consulting chemists similarly have to solve problems brought to them from industries foreign to them. There was a definite need for an up-to-date compilation of formulae for chemical compounding and treatment. Since the fields to be covered are many and varied, an editorial board of chemists and engineers engaged in many industries was formed. Many publications, laboratories, manufacturing firms, and Individuals have been consulted to obtain the latest and best information. It is felt that the formulas given in this volume will save chemists and allied workers much time and effort. Manufacturers and sellers of chemicals will find, In these formulae, new uses for their products. Non-chemical executives, professional men, and Interested laymen will make through this volume a "speaking acquaintance" with products which they may be using, trying or selling. It often happens that two Individuals using the same Ingredients in the same formula get different results. This may be due to slight deviations in the raw materials or unfamiliarity with the intricacies of a new technique. Accordingly, repeated experiments may be necessary to get the best results. Although many of the formulas given are being used commercially, many have been taken from the literature and may be subject to various errors and omissions. This should be taken into consideration. Wherever possible, it is advisable to consult with other chemists or technical workers regarding commercial production.

These meetings, held every four years, bring together researchers from academia and industry and offer a forum for discussions on the chemistry involved in the preparation of industrial heterogeneous catalysts. Contributions focus on the aspects of catalyst preparation. Reports on physico-chemical characteristics of catalysts and catalytic performances are limited to correlations with the preparation parameters.

Contains a collection of the papers presented at the workshop

Properties of chemical compounds and their mixtures are needed in almost every aspect of process and product design. When the use of experimental data is not possible, one of the most widely used options in the use of property estimation models.
Computer Aided Property Estimation for Process and Product Design provides a presentation of the most suitable property estimation models available today as well as guidelines on how to select an appropriate model. Problems that users are faced with, such as: which models to use and what their accuracy is, are addressed using a systematical approach to property estimation.
The volume includes contributions from leading experts from academia and industry. A wide spectrum of properties and phase equilibria types is covered, making it indispensable for research, development and educational purposes.
* This book presents the latest developments in computational modelling for thermodynamic property estimation.
* It combines theory with practice and includes illustrative examples of software applications.
* The questions users of property models are faced with are addressed comprehensively.

There is hardly a technical library in the world in which the volumes of the Chemical Formulary (Volumes 1-34) do not occupy a prominent place. It does not duplicate any of the formulas included in previous volumes, but lists a wide array of modern and salable products from all branches of the chemical industries. An excellent reference for formulation problems. - CONTENTS - I. Introduction - II. Adhesives - III. Coatings - IV. Cosmetics - V. Detergents and Disinfectants - VI. Drug Products - VII. Suspensions and Emulsions - VIII. Food Products - IX. Metals and Their Treatment - X. Polish - XI. Textile Chemical Specialties - XII. Miscellaneous - Appendix - Index - PREFACE - Chemistry, as taught in our schools and colleges, concerns chiefly synthesis, analysis, and engineering-and properly so. It is part of the right foundation for the education of the chemist. Many a chemist entering an Industry soon finds that most of the products manufactured by his concern are not synthetic or definite complex compounds, but are mixtures, blends, or highly complex compounds of which he knows little or nothing. The literature in this field, if any, may be meager, scattered, or obsolete. Even chemists with years of experience In one or more Industries spend conslderable time and effort in acquainting themselves with any new field which they may enter. Consulting chemists similarly have to solve problems brought to them from industries foreign to them. There was a definite need for an up-to-date compilation of formulae for chemical compounding and treatment. Since the fields to be covered are many and varied, an editorial board of chemists and engineers engaged in many industries was formed. Many publications, laboratories, manufacturing firms, and Individuals have been consulted to obtain the latest and best information. It is felt that the formulas given in this volume will save chemists and allied workers much time and effort.

Much has been written about fundamental aspects of catalysis, yet despite their universal applications details concerning commercial catalysts and information about actual operating conditions are not readily available. This book provides up-to-date reviews and references to guide those working on industrial catalysts. It will be an invaluable guide for catalysis researchers in industry and academia, and for students.

Handbook of Methods and Instrumentation in Separation Science, Volume 1 provides concise overviews and summaries of the main methods used for separation. It is based on the Encyclopedia of Separation Science. The handbook focuses on the principles of methods and instrumentation. It provides general concepts concerning the subject matter; it does not present specific procedures. This volume discusses the separation processes including affinity methods, analytical ultracentrifugation, centrifugation, chromatography, and use of decanter centrifuge and dye. Each methodology is defined and compared with other separation processes. It also provides specific techniques, principles, and theories concerning each process. Furthermore, the handbook presents the applications, benefits, and validation of the processes described in this book. This handbook is an excellent reference for biomedical researchers, environmental and production chemists, flavor and fragrance technologists, food and beverage technologists, academic and industrial librarians, and nuclear researchers. Students and novices will also find this handbook useful for practice and learning.

This user friendly introduction highlights the importance of electrochemistry and its applications to the modern world and the future. In contrast to other texts currently available, it emphasises understanding and avoids using many pages of complex equations. It also describes the diverse applications of electrochemistry rather than focusing on analytical chemistry alone. Although the book follows a similar structure to the first edition, the earlier chapters have been extensively up-dated and the later chapters are entirely new. The text is supported by a large number of figures which illustrate key points. The book starts by describing the essential electrochemical techniques before moving on to cover experimental problems and applications. To reflect the present interest in fuel cells and the environment, these have become the focus of the final chapters. A useful appendix contains problems with fully worked answers to test the reader's understanding.