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Books > Science & Mathematics > Chemistry > Crystallography
Physics of laser crystals has been constantly developing since the invention of the laser in 1960. Nowadays, more than 1500 wide-band-gap and semiconductors crystals are suitable for the production of the laser effect. Different laser devices are widely used in science, medicine and communication systems according to the progress achieved in the development of laser crystal physics. Scintillators for radiation detection also gained benefit from these developments. Most of the optically active materials offer laser radiations within the 500 to 3000 nm region with various quantum efficiency which fit the usual applications. However, new crystals for laser emissions are needed either in the blue, UV and VUV - region or far IR- region, especially for medicine, computer microchip production and for undiscovered practical uses. Scientific problems of the growth and properties of laser crystals are discussed in numerous books and scientific journals by many scientists working in the field. Therefore, we thought that joint discussions of the scientific and technical problems in laser physics will be useful for further developments in this area. We have proposed to held a Workshop on Physics of Laser Crystals for attempting to induce additional advances especially in solid state spectroscopy. This NATO Advanced Research Workshop (ARW) was hold in Kharkiv * Stary Saltov th nd (Ukraine) on august 26 - September 2 , 2002, and was mainly devoted to the consideration 0 f modem approaches and Iast results in physics of laser crystals.
This is the first comprehensive book on the dynamical diffraction of X-rays since the development of synchrotron radiation. Up-to-date, with extensive references, it is required knowledge for x-ray optics and x-ray characterization of materials. An excellent reference book for graduate students and researchers.
The accurate determination of the structure of molecular systems provides information about the consequences of weak interactions both within and between molecules. These consequences impact the properties of the materials and the behaviour in interactions with other substances. The book presents modern experimental and computational techniques for the determination of molecular structure. It also highlights applications ranging from the simplest molecules to DNA and industrially significant materials. Readership Graduate students and researchers in structural chemistry, computational chemistry, molecular spectroscopy, crystallography, supramolecular chemistry, solid state chemistry and physics, and materials science.
The electron density of a non-degenerate ground state system determines essentially all physical properties of the system. This statement of the Hohenberg-Kohn theorem of Density Functional Theory plays an exceptionally important role among all the fundamental relations of Molecular Physics. In particular, the electron density distribution and the dynamic properties of this density determine both the local and global reactivities of molecules. High resolution experimental electron densities are increasingly becoming available for more and more molecules, including macromolecules such as proteins. Furthermore, many of the early difficulties with the determination of electron densities in the vicinity of light nuclei have been overcome. These electron densities provide detailed information that gives important insight into the fundamentals of molecular structure and a better understanding of chemical reactions. The results of electron density analysis are used in a variety of applied fields, such as pharmaceutical drug discovery and biotechnology. If the functional form of a molecular electron density is known, then various molecular properties affecting reactivity can be determined by quantum chemical computational techniques or alternative approximate methods.
This volume contains papers presented at the NATO Advanced Study Institute (ASI) Photonic Crystals and Light Localization held at the Creta Maris Hotel in Limin Hersonissou, Crete, June 18-30, 2000. Photonic crystals offer unique ways to tailor light and the propagation of electromagnetic waves (EM). In analogy to electrons in a crystal, EM waves propagating in a structure with a periodically modulated dielectric constant are organized into photonic bands, separated by gaps where propagating states are forbidden. There have been proposals for novel applications ofthese photonic band gap (PBG) crystals, with operating frequencies ranging from microwave to the optical regime, that include zero threshold lasers, low-loss resonators and cavities, and efficient microwave antennas. Spontaneous emission, suppressed for photons in the photonic band gap, offers novel approaches to manipulate the EM field and create high-efficiency light-emitting structures. Innovative ways to manipulate light can have a profound iofluence on science and technology."
The prime objective of the collection of lectures contained in this book is to formulate our current understanding of aperiodic solids with long range order, quasicrystals in particular. At the same time it provides a comprehensive insight into the most recent concepts and tools of condensed matter physics and gives a detailed discussion and interpretation of relevant experimental data. The deliberate pedagogical approach of the authors makes this book particularly useful for graduate students and experimentalists wishing to acquaint themselves with the fundamental concepts.
Crystal engineering is an interdisciplinary area that cuts across the traditional subdivisions of chemistry. Fuelled by our increasingly precise understanding of the chemistry and properties of supramolecular systems, interest in the potential of the field has increased rapidly. The topics discussed in the 28 contributions in this book provide a state-of-the-art description of the field and offer new research ideas that, if pursued, will serve to strengthen the field at the interface between supramolecular chemistry and materials science.
At the time of its original publication this reissued 'classic' text, co-written by the Nobel Laureate of 1954, Max Born, represented the final account of the subject and in many ways it still does. The book is divided into four sections. The first of these is very general in nature and deals with the general statistical mechanics of ideal lattices, leading to the electric polarizability and to the scattering of light. The second part deals with the properties of long lattice waves; the third with thermal properties and the fourth with optical properties.
The 10th edition of the World Directory of Crystallographers and of Other Scientists Employing Crystallographic Methods is a revised and up-to-date edition of the World Directory and contains the current addresses, academic status and research interests of over 8000 scientists in 74 countries. It is produced directly from the regularly updated electronic World Directory database, which is accessible via the World-Wide Web. Full details of the database are given in an Annex to the printed edition.
Site Symmetry in Crystals is the first comprehensive account of the group-theoretical aspects of the site (local) symmetry approach to the study of crystalline solids. The efficiency of this approach, which is based on the concepts of simple induced and band representations of space groups, is demonstrated by considering newly developed applications to electron surface states, point defects, symmetry analysis in lattice dynamics, the theory of second-order phase transitions, and magnetically ordered and non-rigid crystals. Tables of simple induced respresentations are given for the 24 most common space groups, allowing the rapid analysis of electron and phonon states in complex crystals with many atoms in the unit cell.
A number of general-purpose, reasonably accurate and well-tested ab-initio codes for crystals are discussed in this book. The aim is to expand competence of their application in material sciences and solid-state physics. The book addresses particularly readers with a general knowledge in quantum chemistry and intends to give a deeper insight into the special algorithms and computational techniques in ab-initio computer codes for crystals. Three different programs which are available to all interested potential users on request are presented.
The application of neutron scattering to polymers has been extremely successful during the last two decades. This book presents, for the first time, both the theories and experimental examples which are needed to understand how these techniques can be applied. Now available in paperback for the first time this book is specifically written to introduce the newcomer and non-expert to the experimental techniques and the basic theory necessary to understand the results.
Electrooptic effects provide the basis for much liquid-crystal display technology. This book, by two of the leaders in liquid-crystal research in Russia, presents a complete and accessible treatment of virtually all known phenomena occurring in liquid crystals under the influence of electric fields.
This book is the collection of most of the written versions of the Courses given at the Winter School "Beyond Quasicrystals" in Les Houches (March 7-18, 1994). The School gathered lecturers and participants from all over the world and was prepared in the spirit of a general effort to promote theoretical and experimental interdisciplinary communication between mathematicians, theoretical and experimental physicists on the topic of the nature of geometric order in solids beyond standard periodicity and quasi periodicity. The overall structure of the book reflects the wish of the editors to pose this fundamental question of geometric order in solids from both the experimental and theoretical point of view. The first part is devoted more specifically to quasicrystals. These materials were the common starting point of most of the audience and present a first concrete example of a non-trivial geometric order. We chose to focus on a few fundamental aspects of quasicrystals related to hidden symmetries in solids which are not easily found in standard textbooks on the topic, not to reach an exhaustive survey which is already available elsewhere.
Despite the fact that crystals make up an estimated 80% of chemical and pharmaceutical products, few resources exist that provide practical guidance on achieving precision control of their size and size distribution. Based on a model developed by the author and his colleagues, Precision Crystallization: Theory and Practice of Controlling Crystal Size presents scientists and product engineers with the tools to control crystal nucleation, enabling them to ultimately control crystal size and size distribution for batch and continuous crystallizations. At the cutting edge of crystallization science and technology, this volume presents information never before available. Introducing the Balanced Nucleation and Growth (BNG) model, the book demonstrates how the results of the nucleation process are quantitatively related to practical experimental control values such as: reaction addition rate crystal solubility temperature residence time (continuous crystallizations) the effect of ripening agents (crystal supersizing) during nucleation the effect of crystal growth restrainers (crystal nanosizing) during nucleation control of renucleation The author shows how the BNG theory predicts previously unknown phenomena and also how it corrects erroneous perceptions of the importance of reaction volume on the outcome of crystal nucleation. Going above and beyond classical nucleation theories which rely to a large extent on guesswork, the BNG model gives precise guidance to scientists working in a range of critical areas, leading to promising implications for research, quality control, product development, production processes, pilot plant operations, and manufacturing.
This text describes the theory and practice of optical mineralogy in terms useful to all practitioners from the beginning student to the professional in field and laboratory geology and industrial and environmental mineralogy. The author's aim is to provide the simplest possible access to the most powerful techniques of optical crystal identification. The book emphasizes useful practical theoretical material and methods for studying both thin sections of rocks and immersion of mineral grains in refractive index liquids. It contains original research results found in no other text. A major goal of the text is to allow precise determination of refractive index and the essential composition of crystals belonging to important mineral groups such as olivine, feldspar, and pyroxene. New methods for achieving this are developed for both white light and colored light of variable wavelength. Among the book's unique features is the color fringe chart developed by Prof. Morse for estimating both the direction and degree of mismatch between the refraction index of a crystal and that of the surrounding liquid medium in the immersion method. Further, a new algebraic treatment of the dispersion method allows a high precision of match between crystal and liquid. An original classification of interference figures aids crystal identification. Worked examples of refractive index determination and crystal identification are given for each optical class of crystals. The optic orientation of optically biaxial crystals is illustrated with examples from each crystal system portrayed in stereographic projection. Principles and applications of crystal identification with the dispersion method are developed in aseparate chapter. The final chapter is a practical, step-by-step guide to crystal identification in thin section or immersion. An identification table for the most common asbestos minerals, including the dispersion staining method used by most environmental laboratories.
There has been an explosion of interest in the study of molecular crystals, and their applications in optics and electronics. This advanced 1994 textbook describes their chemical and physical structure, their optical and electronic properties and the reactions between neighbouring molecules in crystals. The author has taken into account research areas which have undergone extremely rapid development since the first edition was published in 1987. For instance, this edition features the applications of molecular materials in high-technology devices. There is also an additional chapter on C60 and organic non-linear optic materials. The level of treatment is aimed at first-year postgraduates or workers in industrial research laboratories wishing to gain insights into organic solid state materials. Molecular Crystals is also suitable for special topics in final year undergraduate courses in chemistry, physics and electronic engineering.
Hydrogen bonds are weak attractions, with a binding strength less
than one-tenth that of a normal covalent bond. However, hydrogen
bonds are of extraordinary importance; without them all wooden
structures would collapse, cement would crumble, oceans would
vaporize, and all living things would disintegrate into random
dispersions of inert matter.
Cellular growth, especially its pattern formation, has been studied both experimentally and numerically. In situ observations of faceted cellular growth have clearly revealed cellular interactions in the array of cells. For the first time, the true time-dependent faceted cellular array growth has been modelled properly. It has been found that pattern formation is determined by cellular interactions in the array. Readers of the book will obtain a general view of the field of pattern formation in crystal growth, and in-depth and up-to-date knowledge of faceted cellular array growth, which occurs in semiconductor crystals.
This book presents a computational scheme for calculating the electronic properties of crystalline systems at an ab-ini tio Hartree-Fock level of approximation. The first chapter is devoted to discussing in general terms the limits and capabilities of this approximation in solid state studies, and to examining the various options that are open for its implementation. The second chapter illustrates in detail the algorithms adopted in one specific computer program, CRYSTAL, to be submitted to QCPE. Special care is given to illustrating the role and in: fluence of computational parameters, because a delicate compromise must always be reached between accuracy and costs. The third chapter describes a number of applications, in order to clarify the possible use of this kind of programs in solid state physics and chemistry. Appendices A, B, and C contain various standard expressions, formulae, and definitions that may be useful for reference purposes; appendix D is intended to facilitate the interpretations of symbols, conventions, and acronyms that occur in the book. Thanks are due to all those who have contributed to the implementation and test of the CRYSTAL program, especially to V.R. Saunders and M. Causal, and to F. Ricca, E. Ferrero, R. Or lando, E. Ermondi, G. Angonoa, P. Dellarole, G. Baracco
In the last decade mathematical crystallography has found increasing interest. Siginificant results have been obtained by algebraic, geometric, and group theoretic methods. Also classical crystallography in three-dimen sional Euclidean space has been extended to higher dimen sions in order to understand better the dimension independent crystallographic properties. The aim of this note is to introduce the reader to the fascinating and rich world of geometric crystallography. The prerequisites for reading it are elementary geometry and topological notations, and basic knowledge of group theory and linear algebra. Crystallography is geometric by its nature. In many cases, geometric arguments are the most appropriate and can thus best be understood. Thus the geometric point of view is emphasized here. The approach is axiomatic start ing from discrete point sets in Euclidean space. Symmetry comes in very soon and plays a central role. Each chapter starts with the necessary definitions and then the subject is treated in two- and three-dimensional space. Subsequent sections give an extension to higher dimensions. Short historical remarks added at the end of the chapters will show the development of the theory. The chapters are main ly self-contained. Frequent cross references, as well as an extended subject index, will help the reader who is only interested in a particular subject."
A brief historical account of the background leading to the publication of the first four editions of the World Directory of Crystallographers was presented by G. Boom in his preface to the Fourth Edition, published late in 1971. That edition was produced by traditional typesetting methods from compilations of biographical data prepared by national Sub-Editors. The major effort required to produce a directory by manual methods provided the impetus to use computer techniques for the Fifth Edition. The account of the production of the first computer assisted Directory was described by S.C. Abrahams in the preface of the Fifth Edition. Computer composition, which required a machine readable data base, offered several major advantages. The choice of typeface and range of characters was flexible. Corrections and additions to the data base were rapid and, once established, it was hoped updating for future editions would be simple and inexpensive. The data base was put to other Union uses, such as preparation of mailing labels and formulation of lists of crystallographers with specified common fields of interest. The Fifth Edition of the World Directory of Crystallographers was published in June of 1977, the Sixth in May of 1981. The Subject Indexes for the Fifth and Sixth Editions were printed in 1978 and 1981 respectively, both having a limited distribution. |
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