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Books > Science & Mathematics > Chemistry > Crystallography
Semiconducting and Insulating Crystals details how absorption spectroscopy provides information on the nature, concentration, charge state and configuration of impurities in crystals and also on their kinetics and transformations under annealing. After an introduction of the bulk optical properties of semiconductors and insulators and of impurities in crystals, this book presents the physical bases necessary for the understanding of impurity spectra. The description of various set-ups and accessories used in absorption spectroscopy is followed by a presentation of experimental results on specific impurities and classes of impurities and their relation with those obtained by various computation and by other experimental techniques.
The molecular mechanisms underlying the fact that a crystal can
take a variety of external forms is something we have come to
understand only in the last few decades. This is due to recent
developments in theoretical and experimental investigations of
crystal growth mechanisms.
This contributed volume comprises research articles and reviews on topics connected to the mathematical modeling of cellular systems. These contributions cover signaling pathways, stochastic effects, cell motility and mechanics, pattern formation processes, as well as multi-scale approaches. All authors attended the workshop on "Modeling Cellular Systems" which took place in Heidelberg in October 2014. The target audience primarily comprises researchers and experts in the field, but the book may also be beneficial for graduate students.
The author applies methods of nonlinear elasticity to investigate the defects in the crystal structure of solids such as dislocations and disclinations that characterize the plastic and strength properties of many materials. Contrary to the geometrically motivated nonlinear theory of dislocations continuously distributed over the body, nonlinear analysis of isolated dislocations and disclinations is less developed; it is given for the first time in this book, and in a form accessible to both students and researchers. The general theory of Volterra's dislocations in elastic media under large deformations is developed. A number of exact solutions are found. The nonlinear approach to investigating the isolated defects produces results that often differ qualitatively from those of the linear theory.
Ferroelectric thin films continue to attract much attention due to their developing applications in memory devices, FeRAM, infrared sensors, piezoelectric sensors and actuators. This book, aimed at students, researchers and developers, gives detailed information about the basic properties of these materials and the associated device physics. The contributing authors are acknowledged experts in the field.
Structure of Crystals describes the ideal and real atomic structure of crystals as well as the electronic structures. The fundamentals of chemical bonding between atoms are given, and the geometric representations in the theory of crystal structure and crystal chemistry, as well as the lattice energy, are considered. The important classes of crystal structures in inorganic compounds as well as the structures of polymers, liquid crystals, biological crystals, and macromolecules are treated. This edition is complemented with recent data on many types of crystal structures - e.g., the structure of fullerenes, high-temperature superconductors, minerals, and liquid crystals.
An introduction to structure determination by x-ray crystallography, primarily for final-year undergraduate studies in crystallography, chemistry, and chemical physics, and introductory postgraduate work in this area of crystallography. This substantially revised edition (2nd, 1985) adds a chapter o
"This book contains overviews on technologically important classes of glasses, their treatment to achieve desired properties, theoretical approaches for the description of structure-property relationships, and new concepts in the theoretical treatment of crystallization in glass-forming systems. It contains overviews about the state of the art and about specific features for the analysis and application of important classes of glass-forming systems, and describes new developments in theoretical interpretation by well-known glass scientists. Thus, the book offers comprehensive and abundant information that is difficult to come by or has not yet been made public." Edgar Dutra Zanotto (Center for Research, Technology and Education in Vitreous Materials, Brazil) Glass, written by a team of renowned researchers and experienced book authors in the field, presents general features of glasses and glass transitions. Different classes of glassforming systems, such as silicate glasses, metallic glasses, and polymers, are exemplified. In addition, the wide field of phase formation processes and their effect on glasses and their properties is studied both from a theoretical and experimental point of view.
Crystals are the unacknowledged pillars of the world of modern technology. Today's technological developments depend critically on the availability of suitable single crystals, whether for lasers, semiconductors, magnetic devices, optical devices, superconductors or telecommunication. In spite of great technological advances in recent years, we are still at an early stage with respect to the growth of several important crystals such as diamond, silicon carbide, PZT and gallium nitride. This book covers all important aspects of crystal growth and growth techniques, together with relevant case studies. Particular emphasis is placed on new approaches designed to overcome the present limitations on crystal growth. The book will be essential reading for all scientists working on crystal growth.
Photonic Crystals are the newest types of optical material being
developed for commercial applications in industry. They are likely
to provide an exciting new tool for the manipulations of photons
and have received the attention of both academia and industry.
Roadmap on Photonic Crystals gives a detailed explanation of the
background of photonic crystals, the theories behind them,
numerical simulations, crystal structures, fabrication processes,
evaluation methods and proposed applications. This also includes a
roadmap addressing future development and applications.
The re-emergent field of quantitative electron crystallography is described by some of its most eminent practitioners. They describe the theoretical framework for electron scattering, specimen preparation, experimental techniques for optimum data collection, the methodology of structure analysis and refinement, and a range of applications to inorganic materials (including minerals), linear polymers, small organic molecules (including those used in nonlinear optical devices), incommensurately modulated structures (including superconductors), alloys, and integral membrane proteins. The connection between electron crystallography and X-ray crystallography is clearly defined, especially in the utilisation of the latest methods for direct determination of crystallographic phases, as well as the unique role of image analysis of high-resolution electron micrographs for phase determination. Even the aspect of multiple beam dynamic diffraction (once dreaded because it was thought to preclude ab initio analysis) is considered as a beneficial aid for symmetry determination as well as the elucidation of crystallographic phases, and as a criterion for monitoring the progress of structure refinement. Whereas other texts have hitherto preferentially dealt with the analysis of electron diffraction and image data from thin organic materials, this work discusses - with considerable optimism - the prospects of looking at harder' materials, composed of heavier atoms. Audience: Could be used with profit as a graduate-level course on electron crystallography. Researchers in the area will find a statement of current progress in the field.
The 9th edition of the World Directory of Crystallographers and of Other Scientists Employing Crystallographic Methods, which contains 7907 entries embracing 72 countries, differs considerably from the 8th edition, published in 1990. The content has been updated, and the methods used to acquire the information presented and to produce this new edition of the Directory have involved the latest advances in technology. The Directory is now also available as a regularly updated electronic database, accessible via e-mail, Telnet, Gopher, World-Wide Web, and Mosaic. Full details are given in an Appendix to the printed edition.
Low molar mass organic materials and polymers exhibit a range of physical properties that are dependent on their ability to undergo self organisation. The degree and extent of the molecular organisation depends on a complex interplay of inter and intra molecular interactions. Polymer Structure Characterization: From Nano to Macro Organization discusses in a systematic fashion the way in which molecular interactions influence observed morphologies. Topics include: organic crystals, liquid crystals, plastic crystals, polymer morphology, polymer crystallization, amorphous glassy materials, polymer surfaces, polymer phase separation and structure, and a brief introduction to organisation in naturally occurring materials. This textbook is primarily aimed at polymer and material scientists but would also be of interest to chemists and physicists studying the properties of organic materials. It provides complimentary material for a range of courses in materials science, molecular chemistry and chemical physics.
Liquid crystals, widely used in displays for electronic equipment and other applications, have highly unusual properties arising from the anisotropy of their molecules. It appears that some aspects of the fluid dynamics of liquid crystals, such as their viscosity, can be understood only by considering the role played by thermal fluctuations. In order to provide a theoretical framework for understanding the experimental results, the authors devote a large part of the book to a derivation of the nonlinear dynamic equations and to a discussion of linearized equations for the various types of liquid crystals. The diagrammatic and other techniques they use are of general use in condensed matter physics, and this exposition should thus be of interest to all condensed-matter theorists.
Volume 43 of Group III deals with crystallographic data of both intermetallic and classical inorganic compounds, updating the former Landolt-Bornstein volumes III/6 (Structure Data of Elements and Intermetallic Phases) and III/7 (Crystal Structure Data of Inorganic Compounds). It does not include compounds that contain C-H bonds. In contrast to the earlier edition, this volume presents the data in an improved, more modern arrangement, grouping known crystals by structure.
Market: Research scientists and students in materials science, physical metallurgy, and solid state physics. This detailed monograph presents the theory of reversible plasticity as a new direction of development in crystal physics. It features a unique integration of traditional concepts and new studies of high- temperature superconductors, plus in-depth analyses of various related phenomena. Among the topics discussed are elastic twinning (discovered by Dr. Garber), thermoelastic martensite transformation, superelasticity, shape memory effects, the domain structure of ferroelastics, and elastic aftereffect. Partial Contents: 1. Transformation of Dislocations. Dislocation Description of a Phase Transformation Front. 2. Dislocation Theory of Elastic Twinning. Twinning of Crystals: Principal Definitions. 3. Statics and Dynamics of Elastic Twinning. Discovery of Elastic Twinning. Verification of the Validity of the Static Theory in a Description of the Macroscopic Behavior of an Elastic Twin. 4. Thermoelastic Martensitic Transformation. Martensitic Transformation: a Diffusionless Process of Rebuilding the Crystal Lattice. 5. Superelasticity and the Shape Memory Effect. Main Characteristics of Superelasticity and Shape Memory Effects. 6. Reversible Plasticity of Ferroelastics. Ferroelastics: Main Definitions. 7. Investigation of Reversible Plasticity of Crystals by the Acoustic Emission Method. Emission of Sound by Moving Dislocations andTheir Pileups. Methods Used in Experimental Investigations of the Acoustic Emission Generated by a SingleTwin. Acoustic Emission Associated with Elastic Twinning. 8. Influence of Reversible Plasticity of Superconductors on Their Physical Properties. Reversible Changes in the Parameters of Traditional Superconductors under the Action of Elastic Stresses. Influence of Magnetic Fields on Reversible Changes in the Parameters
"Nature performs not hing vainly, and makes nothing unnecessary" Aristotle Interest in the passage of charged particles through crystals first appeared at the beginning of this century following experiments on x-ray diffraction in crystallattices, which provided the proof of an ordered distribution of atoms in a crystal. Stark [1] put forward the hypothesis that certain directions in a crystal should be relatively transparent to charged particles. These first ideas on the channeling of charged particles in crystals were forgotten but became topical again in the early 1960s when the channeling effect was rediscovered by computer simulation [2] and in experiments [3] that revealed anomalously long ion ranges in crystals. The orientational ef fects during the passage of charged particles through crystals have been found for a whole range of processes characterized by small impact parameters for collisions between particles and atoms: nuclear reactions, large-angle scatter ing, energy losses. Lindhard explained the channeling of charged particles in crystals [4]. The results of the numerous investigations into the channeling of low-energy (amounting to several MeV) charged particles in crystals have been summarized in several monographs and reviews [5~8l.
Solitons are a well-known and intriguing aspect of nonlinear behavior in a continuous system such as a fluid: a wave propagates through the medium without distortion. Liquid crystals are highly ordered systems without a rigid, long-range structure. Solitons in liquid crystals (sometimes referred to as "walls") have a wide variety of remarkable properties that are becoming important for practical applications such as electroluminescent display. This book, the first review of the subject to be published, contains not only surveys of the existing literature, but presents new results as well.
Just like the periodical crystalline potential in solid-state crystals determines their properties for the conduction of electrons, the periodical structuring of photonic crystals leads to envisioning the possibility of achieving a control of the photon flux in dielectric and metallic materials. The use of photonic crystals as a cage for storing, filtering or guiding light at the wavelength scale thus paves the way to the realisation of optical and optoelectronic devices with ultimate properties and dimensions. This should contribute toward meeting the demands for a greater miniaturisation that the processing of an ever increasing number of data requires. Photonic Crystals intends to provide students and researchers from different fields with the theoretical background needed for modelling photonic crystals and their optical properties, while at the same time presenting the large variety of devices, from optics to microwaves, where photonic crystals have found applications. As such, it aims at building bridges between optics, electromagnetism and solid-state physics. This book was written by six specialists of nanophotonics, and was coordinated by Jean-Michel Lourtioz, head of the Institut d'Electronique Fondamentale in Orsay and coordinator of the French Research Network in Nanophotonics."
Structural crystallographic studies can determine not only the full stereochemistry of chemical species but also their details of arrangement in the crystal. Such geometrical data provide an essential basis for the interpretation of chemical, physical, and biological properties of chemical species. This volume contains key papers presented at the seventh symposium on organic crystal chemistry at Poznan in Poland. Among the themes discussed were factors influencing molecular conformation and polymorphism, chemical and biological activity, intermolecular interactions, crystal chemistry of polymers and molecular modelling.
Despite the tremendous advances in the techniques and equipment for
carrying out high-pressure crystallography, the application or
exploration of the high-pressure variable in detailed structural
studies remains rare. The chapters in this book provide a set of
lecture notes and supplementary material for a course on high
pressure crystallography. The material comprises state-of-the-art
reviews of high-pressure experiments using X-ray and neutron
diffraction techniques at synchrotron and neutron facilities and in
the laboratory, as well as complementary experimental high-pressure
techniques and theoretical methods for investigating matter at
elevated pressures. The materials studies range from elemental
solids and liquids to inorganic compounds, minerals, organic
compounds, clathrates and pharmaceutical compounds, to large
biological molecules such as proteins and viruses.
There have been many advances in x-ray crystallography since the
production of the third edition of this book, and the authors have
endeavoured to introduce a number of them into this new edition.
The overall plan of the book has been maintained because we believe
that it has been well received in the academic community, but
substantial revisions have been carried out and new material and
chapters added. In particular, we have extended the discussion of
the theory of x-ray diffraction and added new chapters on structure
determination from powder data, on macromolecular crystallography,
and on computational procedures in x-ray crystallography. We
consider that x-ray crystallography is a universal tool for
studying molecular structure, a view upheld by the pioneers in the
subject, notably W.H. & W.L. Bragg, J. D. Bernal, Dorothy
Hodgkin (nA(c)e Crowfoot), Kathleen Lonsdale (nA(c)e Yardley), and
Linus Pauling, so that the broadening of the scope of the text in
this way is fully justified. This edition is accompanied by a suite of computer programs on a compact disc. The programs enable the reader to participate fully in many of the aspects of x-ray crystallography discussed in the book. In particular, the program system XRAY* is interactive, and enables the reader to follow through, at the monitor screen, the computational techniques involved in single-crystal structure determination, albeit in two dimensions. Several sets of x-ray data areprovided for practice with this system.
Diese Arbeit enthiilt zwei grof3ere Fallstudien zur Beziehung zwischen theo- retischer Mathematik und Anwendungen im 19. Jahrhundert. Sie ist das Ergebnis eines mathematikhistorischen Forschungsprojekts am Mathemati- schen Fachbereich der Universitiit-Gesamthochschule Wuppertal und wurde dort als Habilitationsschrift vorgelegt. Ohne das wohlwollende Interesse von Herrn H. Scheid und den Kollegen der Abteilung fUr Didaktik der Mathema- tik ware das nicht moglich gewesen: Inhaltlich verdankt sie - direkt oder indirekt - vielen Beteiligten et- was. So wurde mein Interesse an den kristallographischen Symmetriekon- zepten, dem Thema der ersten Fallstudie, durch Anregungen und Hinweise von Herrn E. Brieskorn geweckt. Sowohl von seiner Seite als auch von Herrn J. J. Burckhardt stammen uberdies viele wert volle Hinweise zum Manuskript von Kapitel I. Herrn C. J. Scriba mochte ich fur seine die gesamte Arbeit betreffenden priizisen Anmerkungen danken und Herrn W. Borho ebenso fUr seine ubergreifenden Kommentare und Vorschlage. Beziiglich der in Kapitel II behandelten projektiven Methoden in der Baustatik des 19. Jahrhunderts gilt mein besonderer Dank den Herren K. -E. Kurrer und T. Hiinseroth fUr ihre zum Teil sehr detaillierten Anmerkungen aus dem Blickwinkel der Geschichte der Bauwissenschaften. Schliefilich geht mein Dank an alle nicht namentlich Erwiihnten, die in Gesprachen, technisch oder auch anderweitig zur Fertig- stellung dieser Arbeit beigetragen haben. Fur die vorliegende Publikation habe ich einen Anhang mit einer Skizze von in unserem Zusammenhang besonders wichtig erscheinenden Aspekten der Theorie der kristallographischen Raumgruppen hinzugefUgt. Ich hoffe, daB er zum Verstiindnis des mathematischen Hintergrunds der historischen Arbeiten des ersten Kapitels beitragt. |
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