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Books > Science & Mathematics > Chemistry > Crystallography
'The book is well organized and is pedagogical. By discussing crystallization in pure systems, the author introduces and describes the important concepts, physical parameters and theoretical models pertaining to nucleation and growth of crystals ... If you are a young investigator or a graduate student whose research involves understanding the fundamentals of crystallization including nucleation and growth, this book will be a treat for you. Readers who have a strong background in physical chemistry or thermal physics may find the book easy to read. Nevertheless, this book should be a good reference to have on the bookshelf if you are an experienced researcher whose interest crosses the path with the general topics of crystal growth.'Acta Crystallographica Section BThe processes of new phase formation and growth are of fundamental importance in numerous rapidly developing scientific fields such as modern materials science, micro- and optoelectronics, and environmental science. Crystal Growth for Beginners combines the depth of information in monographs, with the thorough analysis of review papers, and presents the resulting content at a level understandable by beginners in science. The book covers, in practice, all fundamental questions and aspects of nucleation, crystal growth, and epitaxy.This book is a non-eclectic presentation of this interdisciplinary topic in materials science. The third edition brings existing chapters up to date, and includes new chapters on the growth of nanowires by the vapor-liquid-solid mechanism, as well as illustrated short biographical texts about the scientists who introduced the basic ideas and concepts into the fields of nucleation, crystal growth and epitaxy. All formulae and equations are illustrated by examples that are of technological importance. The book presents not only the fundamentals but also the state of the art in the subject.Crystal Growth for Beginners is a valuable reference for both graduate students and researchers in materials science. The reader is required to possess some basic knowledge of mathematics, physics and thermodynamics.
'This is a book for crystal chemistry lovers written by one of the pioneers of solid-state chemistry.'MRS BulletinDevoted to a diverse group of solid state scientists, the book has two objectives, both relating to structural chemistry: (i) a progressive analytic familiarization with the main parameters that govern the organization of crystallized matter and related crystal structures, (ii) a study of what are the various ways to 'read' a structure far beyond its representation in scientific articles. Hence, the reader will, from numerous examples illustrated in color, analyze what are the main characteristics of these structures, from their geometric characteristics, their coordination polyhedra, their connections with the resulting dimensionalities of these solids, including also the defects they exhibit, before looking at possibilities to classify structures, within which recurrence laws can emerge.Chemists are required to understand the potentials of a new structure for becoming future materials scientists. The first part of the book is by no means a database for known structures, but facilitates a progressive understanding of the organization of the solid state. With these tools in hand, the reader is invited in the later part of the book to analyze new structures, and to also use new concepts for viewing structures in a more synthetic way for the future. Such new vision is already leading to the creation of completely new solids with outstanding characteristics that find applications in societal problems concerning energy, energy savings, environment and health.The content is not exclusively academic but relates to the creation of innovative materials, through a more physical approach, that might condition the future of materials.
'This is a book for crystal chemistry lovers written by one of the pioneers of solid-state chemistry.'MRS BulletinDevoted to a diverse group of solid state scientists, the book has two objectives, both relating to structural chemistry: (i) a progressive analytic familiarization with the main parameters that govern the organization of crystallized matter and related crystal structures, (ii) a study of what are the various ways to 'read' a structure far beyond its representation in scientific articles. Hence, the reader will, from numerous examples illustrated in color, analyze what are the main characteristics of these structures, from their geometric characteristics, their coordination polyhedra, their connections with the resulting dimensionalities of these solids, including also the defects they exhibit, before looking at possibilities to classify structures, within which recurrence laws can emerge.Chemists are required to understand the potentials of a new structure for becoming future materials scientists. The first part of the book is by no means a database for known structures, but facilitates a progressive understanding of the organization of the solid state. With these tools in hand, the reader is invited in the later part of the book to analyze new structures, and to also use new concepts for viewing structures in a more synthetic way for the future. Such new vision is already leading to the creation of completely new solids with outstanding characteristics that find applications in societal problems concerning energy, energy savings, environment and health.The content is not exclusively academic but relates to the creation of innovative materials, through a more physical approach, that might condition the future of materials.
Provides a through and systematic discussion on the functionally graded adhesive and its joints Discusses analytical modelling and numerical analyses of the joints Details 3D stress and failure delamination analysis for composite analyses of functionally graded out-of-plane joints under various combinations of loading Illustrates FE Modeling and simulation of interfacial failure and damage propagation in out-of-plane joints Includes effect of various gradation function profiles on damage growth driving forces (SERR)
Covers radiation-assisted synthesis, processing, and modification of all kinds of materials Provides comparative studies, merits, demerits, and applications very systematically Transcends across polymers science and technology, radiation technology, advanced materials technology, biomaterials technology and so forth Includes a section on 3D printing by laser melting of CoCr alloys
The book presents a unified and self-sufficient and reader-friendly introduction to the anisotropic elasticity theory necessary to model a wide range of point, line, planar and volume type crystal defects (e.g., vacancies, dislocations, interfaces, inhomogeneities and inclusions).The necessary elasticity theory is first developed along with basic methods for obtaining solutions. This is followed by a detailed treatment of each defect type. Included are analyses of their elastic fields and energies, their interactions with imposed stresses and image stresses, and the interactions that occur between them, all employing the basic methods introduced earlier.All results are derived in full with intermediate steps shown, and 'it can be shown' is avoided. A particular effort is made to describe and compare different methods of solving important problems. Numerous exercises (with solutions) are provided to strengthen the reader's understanding and extend the immediate text.In the 2nd edition an additional chapter has been added which treats the important topic of the self-forces that are experienced by defects that are extended in more than one dimension. A considerable number of exercises have been added which expand the scope of the book and furnish further insights. Numerous sections of the book have been rewritten to provide additional clarity and scope.The major aim of the book is to provide, in one place, a unique and complete introduction to the anisotropic theory of elasticity for defects written in a manner suitable for both students and professionals.
The book presents a unified and self-sufficient and reader-friendly introduction to the anisotropic elasticity theory necessary to model a wide range of point, line, planar and volume type crystal defects (e.g., vacancies, dislocations, interfaces, inhomogeneities and inclusions).The necessary elasticity theory is first developed along with basic methods for obtaining solutions. This is followed by a detailed treatment of each defect type. Included are analyses of their elastic fields and energies, their interactions with imposed stresses and image stresses, and the interactions that occur between them, all employing the basic methods introduced earlier.All results are derived in full with intermediate steps shown, and 'it can be shown' is avoided. A particular effort is made to describe and compare different methods of solving important problems. Numerous exercises (with solutions) are provided to strengthen the reader's understanding and extend the immediate text.In the 2nd edition an additional chapter has been added which treats the important topic of the self-forces that are experienced by defects that are extended in more than one dimension. A considerable number of exercises have been added which expand the scope of the book and furnish further insights. Numerous sections of the book have been rewritten to provide additional clarity and scope.The major aim of the book is to provide, in one place, a unique and complete introduction to the anisotropic theory of elasticity for defects written in a manner suitable for both students and professionals.
Liquid crystal science underlies the technology of about half the current display technology by value, an industry now worth some $10 billion per annum worldwide. The fundamental science straddles the disciplines of chemistry, physics, engineering, mathematics and computer science. Among liquid crystal scientists today there is much interest in the historical process that has brought the subject to its present level. The historical roots lie in the years following 1888, again in the interwar years, and finally in the late 60s and 70s. This book has collected important papers in the development of liquid crystal science into one reference volume. The collection is divided into sections, each of which is prefaced by a brief commentary, referring to the historic-scientific context of the time. Some of these papers are available for the first time in English. More modern papers carry a short commentary from the original author, offering recollections of the context in which the work was carried out and what its impact has been. Crystals that Flow is aimed at liquid crystal scientists- from whatever background- physics, mathematics, chemistry, engineering or computer science. Historians of science will also find this a useful reference.
This work gives a comprehensive overview on materials, processes and technological challenges for electrochemical storage and conversion of energy. Optimization and development of electrochemical cells requires consideration of the cell as a whole, taking into account the complex interplay of all individual components. Considering the availability of resources, their environmental impact and requirements for recycling, the design of new concepts has to be based on the understanding of relevant processes at an atomic level.
Self-assembly monolayer (SAM) structures of lipids and macromolecules have been found to play an important role in many industrial and biological phenomena. This book describes two procedures, namely the STM and AFM, that are used to study SAMs at solid surfaces. K.S. Birdi examines the SAMs at both liquid and solid surfaces by using the Langmuir monolayer method. This book is intended for researchers, academics and professionals.
This work presents a snapshot of the state of the art of modern biomolecular crystallography, from crystallisation through structure determination and even interactive presentation on the web. Methods driving the latest automated structure determination pipelines are explained, as well as how to deal with problems such as crystal pathologies that still demand expert analysis. These methods are illustrated through their application to problems of great biological interest, such as the molecular machinery underlying the complement pathway, the mechanism of action of monoamine oxidase inhibitors, and the structure of the eukaryotic ribosome. Complementary approaches, such as neutron diffraction, small angle X-ray scattering, coherent diffraction and computational modelling, are also explored.
"Aperiodic Crystals" collects 37 selected papers from the scientific contributions presented at "Aperiodic" 2012 - theSeventh International Conference on Aperiodic Crystalsheld held in Cairns, Australia, 2-7 of September 2012. The volume discusses state-of-the-art discoveries, new trends and applications of aperiodic crystals - including incommensurately modulated crystals, composite crystals, and quasicrystals - from a wide range of different perspectives. Starting with a general historical introduction to aperiodic crystals, the book proceeds to examine the complex mathematics of aperiodic long-range order, as well as the theoretical approaches aimed at understanding some of the unique properties and mechanisms underlying the existence of aperiodic crystals. The book then explores in detail such topics as complex metallic alloys, modulated structures, quasicrystals and their approximants, dynamics, disorder and defects in quasicrystals. It concludes with an analysis of quasicrystal surfaces and their properties. By describing the latest research and the progress made on the structure determination of aperiodic crystals and the influence of this unique structure on their physical properties, this book represents a valuable resource to mathematicians, crystallographers, physicists, chemists, materials and surface scientists, and even architects and artists, interested in the fascinating nature of aperiodic crystals.
The Lectures: Conjugated Polymers in Layered Hosts; M.G. Kanatzidis, et al. Staging in Intercalated Graphites, Polymers, and Fullerenes; E.J. Mele. Seminars and Communications: Size-Mismatch Melting in Two Dimensions; N. Mousseau, M.F. Thorpe. Tight Binding Molecular Dynamics for Intercalation Chemistry; M. Menon, et al. Local Oscillator Model for Superconducting Fullerenes; Z. Gedik, S. Ciraci. Some Optical Properties of Fullerenes; B. Friedman. Photoluminescence of Solid State Fullerenes; H.J. Byrne, et al. Magnetic Properties of Alkali Metal Intercalated Fullerides; P. Byszewski, et al. Charge Transport and Percolation in Conducting Polymers; J. Voit. Overview on the Chemistry of Intercalation in Graphite of Binary Metallic Alloys; P. Lagrange. Mineralomimetic Inclusion Behavior of Cadmium Cyanide Systems; T. Iwamoto, et al. 36 additional articles. Index.
This book is published to celebrate the International Year of Crystallography 2014, as proclaimed by the United Nations. The year has been chosen as the International Year of Crystallography since it was 100 years ago that the first Nobel Prize was awarded for crystallographic observations to Max von Laue. Just a year later, Sir William Henry Bragg and William Lawrence Bragg, father and son, won their prize for showing the possibility of determining atomic positions in crystals. This book describes the lives and works of 33 Nobel Laureates starting with Wilhelm Conrad Roentgen (1901) and ending with Brian Kobilka (2012). It also reproduces the most important works of these scientists. The book gives a historical perspective of a scientific field that is important for our understanding of the atomic organization of the world around us, from inorganic materials to complex biological molecules, such as the ribosome.This book is a timely summary of the main developments in crystallography over the last 100 years. The central publications of 33 Nobel laureates are reproduced. There is no other book providing this selection of material.
Topics in Electron Diffraction and Microscopy of Materials
celebrates the retirement of Professor Michael Whelan from the
University of Oxford. Professor Whelan taught many of today's heads
of department and was a pioneer in the development and use of
electron microscopy. His collaborators and colleagues, each one of
whom has made important advances in the use of microscopy to study
materials, have contributed to this cohesive work.
Photoresponsive polymers that can be manipulated with specific frequency of light Designing of polymers for vibration damping Smart manipulations of hydrophic and superhydrophobic polymers Biopolymers including hydrogel for smart application, drug delivery etc. Smart paints Self-healing and shape memory polymers Holography for data storage Phase change polymers and solid polymer electrolyte for thermal and electrochemical energy Molecularly imprinting polymers for sub ppm sensing and removal of undesired materials Smart textile covering the concept of advanced textiles
The book intends to give a state-of-the-art overview of flexoelectricity, a linear physical coupling between mechanical (orientational) deformations and electric polarization, which is specific to systems with orientational order, such as liquid crystals.Chapters written by experts in the field shed light on theoretical as well as experimental aspects of research carried out since the discovery of flexoelectricity. Besides a common macroscopic (continuum) description the microscopic theory of flexoelectricity is also addressed. Electro-optic effects due to or modified by flexoelectricity as well as various (direct and indirect) measurement methods are discussed. Special emphasis is given to the role of flexoelectricity in pattern-forming instabilities.While the main focus of the book lies in flexoelectricity in nematic liquid crystals, peculiarities of other mesophases (bent-core systems, cholesterics, and smectics) are also reviewed. Flexoelectricity has relevance to biological (living) systems and can also offer possibilities for technical applications. The basics of these two interdisciplinary fields are also summarized.
Crystallographic groups are groups which act in a nice way and via isometries on some n-dimensional Euclidean space. They got their name, because in three dimensions they occur as the symmetry groups of a crystal (which we imagine to extend to infinity in all directions). The book is divided into two parts. In the first part, the basic theory of crystallographic groups is developed from the very beginning, while in the second part, more advanced and more recent topics are discussed. So the first part of the book should be usable as a textbook, while the second part is more interesting to researchers in the field. There are short introductions to the theme before every chapter. At the end of this book is a list of conjectures and open problems. Moreover there are three appendices. The last one gives an example of the torsion free crystallographic group with a trivial center and a trivial outer automorphism group.This volume omits topics about generalization of crystallographic groups to nilpotent or solvable world and classical crystallography. We want to emphasize that most theorems and facts presented in the second part are from the last two decades. This is after the book of L Charlap "Bieberbach groups and flat manifolds" was published.
This book walks you through the fundamental deformation and damage mechanisms. It lends the reader the key to open the doors into the maze of deformation/fracture phenomena under various loading conditions. Furthermore it provides the solution method to material engineering design and analysis problems, for those working in the aerospace, automotive or energy industries. The book introduces the integrated creep-fatigue theory (ICFT) that considers holistic damage evolution from surface/subsurface crack nucleation to propagation in coalescence with internally-distributed damage/discontinuities.
This book gives a comprehensive description of the physical properties of lyotropic liquid crystals. Structural features, phase transitions and phase diagrams are discussed in detail. The available experimental data on lyotropic mixtures is presented in the unifying context of the Landau theories. This phenomenological approach is used for establishing connections between structural properties and phase diagrams. The book is suitable for use as a pedagogical introduction to the subject.
The understanding, at the molecular level, of the interactions between innate and adaptive arms of the immune system is currently a hot topic, particularly to those interested in immunology - especially susceptibility to infectious diseases. This book provides a survey of topics, in the area of innate and adaptive immunity, which have been researched within the MRC Immunochemistry Unit, at Oxford University, over a period of forty years. The topics include: " antibody structure - for which the first Director of the Immunochemistry Unit, Professor RR Porter, was awarded a Nobel prize in 1972 " the characterization of membrane proteins on lymphoid cells - leading to the concept of these molecules belonging to an immunoglobulin super family " the proteins of the human serum complement system - one of the body's major defences against microbial infection " the human cell -surface integrins and the hyaluronan- binding proteins, which are involved in regulation of inflammation at cell surfaces and within the extracellular matrix " the family of collectin molecules - containing distinct globular carbohydrate -binding domains linked to collagen-like regions - which play important roles in innate immunity in the lungs and bloodstream by immediate recognition and clearance of microbial pathogens Each chapter in the book gives a brief historical background to a topic and then provides a survey of recent advances in the field and are written by internationally recognised renowned experts. The theme running through the chapters is that of protein structure-function relationships - including, amongst others, descriptions of quaternary structures of large oligomeric proteins, of Factor H and C1q binding to specific ligands, and of the chemistry of the mechanism of catalysis of covalent binding of activated C3 and C4 proteins to nucleophilic groups on microbial surfaces. In several chapters excellent descriptions are given with respect to how the immune system can be recruited to combat microbial infection - via proteins of both the innate and adaptive immune systems. The book also includes notable chapters which are excellent examples of the importance of how the isolation, characterisation, protein engineering and crystallisation has resulted in a full understanding of complex protein-protein interactions involved in the recognition and triggering events of important sections of the immune system: -Structure and Function of the C1 Complex - GUrard J. Arlaud -Chemical Engineering of Therapeutic Antibodies - George T Stevenson -Leukocyte surface proteins - purification and characterisation - A. Neil Barclay -Cell Surface Integrins - Suet-Mien Tan and S.K. Alex Law This book is aimed primarily at established senior research scientists, postdoctoral research scientists and PhD students who have an interest in proteins of the immune system. However, the wide range of immunity system topics, while staying broadly within innate/adaptive immunity will also appeal to a wider audience.
Focusing on the applied and basic aspects of confined liquid crystals, this book provides a current treatise of the subject matter and places it in the broader context of electrooptic applications. The book takes an interdisciplinary approach to the subject, combining basic principles of physics, chemistry, polymer science, materials science and engineering.
The structural biology of protein-nucleic acid interactions is in some ways a mature field and in others in its infancy. High-resolution structures of protein-DNA complexes have been studied since the mid 1980s and a vast array of such structures has now been determined, but surprising and novel structures still appear quite frequently. High-resolution structures of protein-RNA complexes were relatively rare until the last decade. Propelled by advances in technology as well as the realization of RNA's importance to biology, the number of example structures has ballooned in recent years. New insights are now being gained from comparative studies only recently made possible due to the size of the database, as well as from careful biochemical and biophysical studies. As a result of the explosion of research in this area, it is no longer possible to write a comprehensive review. Instead, current review articles tend to focus on particular subtopics of interest. This makes it difficult for newcomers to the field to attain a solid understanding of the basics. One goal of this book is therefore to provide in-depth discussions of the fundamental principles of protein-nucleic acid interactions as well as to illustrate those fundamentals with up-to-date and fascinating examples for those who already possess some familiarity with the field. The book also aims to bridge the gap between the DNA- and the RNA- views of nucleic acid - protein recognition, which are often treated as separate fields. However, this is a false dichotomy because protein - DNA and protein - RNA interactions share many general principles. This book therefore includes relevant examples from both sides, and frames discussions of the fundamentals in terms that are relevant to both. The monograph approaches the study of protein-nucleic acid interactions in two distinctive ways. First, DNA-protein and RNA-protein interactions are presented together. Second, the first half of the book develops the principles of protein-nucleic acid recognition, whereas the second half applies these to more specialized topics. Both halves are illustrated with important real life examples. The first half of the book develops fundamental principles necessary to understand function. An introductory chapter by the editors reviews the basics of nucleic acid structure. Jen-Jacobsen and Jacobsen discuss how solvent interactions play an important role in recognition, illustrated with extensive thermodynamic data on restriction enzymes. Marmorstein and Hong introduce the zoology of the DNA binding domains found in transcription factors, and describe the combinational recognition strategies used by many multiprotein eukaryotic complexes. Two chapters discuss indirect readout of DNA sequence in detail: Berman and Lawson explain the basic principles and illustrate them with in-depth studies of CAP, while in their chapter on DNA bending and compaction Johnson, Stella and Heiss highlight the intrinsic connections between DNA bending and indirect readout. Horvath lays out the fundamentals of protein recognition of single stranded DNA and single stranded RNA, and describes how they apply in a detailed analysis of telomere end binding proteins. Nucleic acids adopt more complex structures - Lilley describes the conformational properties of helical junctions, and how proteins recognize and cleave them. Because RNA readily folds due to the stabilizing role of its 2'-hydroxyl groups, Li discusses how proteins recognize different RNA folds, which include duplex RNA. With the fundamentals laid out, discussion turns to more specialized examples taken from important aspects of nucleic acid metabolism. Schroeder discusses how proteins chaperone RNA by rearranging its structure into a functional form. Berger and Dong discuss how topoisomerases alter the topology of DNA and relieve the superhelical tension introduced by other processes such as replication and transcription. Dyda and Hickman show how DNA transposes mediate genetic mobility and Van Duyne discusses how site-specific recombinases "cut" and "paste" DNA. Horton presents a comprehensive review of the structural families and chemical mechanisms of DNA nucleases, whereas Li in her discussion of RNA-protein recognition also covers RNA nucleases. Lastly, FerrU-D'AmarU shows how proteins recognize and modify RNA transcripts at specific sites. The book also emphasises the impact of structural biology on understanding how proteins interact with nucleic acids and it is intended for advanced students and established scientists wishing to broaden their horizons."
Powder diffraction is a widely used scientific technique in the characterization of materials with broad application in materials science, chemistry, physics, geology, pharmacology and archaeology. Powder Diffraction: Theory and Practice provides an advanced introductory text about modern methods and applications of powder diffraction in research and industry. The authors begin with a brief overview of the basic theory of diffraction from crystals and powders. Data collection strategies are described including x-ray, neutron and electron diffraction setups using modern day apparatus including synchrotron sources. Data corrections, essential for quantitative analysis are covered before the authors conclude with a discussion of the analysis methods themselves. The information is presented in a way that facilitates understanding the information content of the data, as well as best practices for collecting and analyzing data for quantitative analysis. This long awaited book condenses the knowledge of renowned experts in the field into a single, authoritative, overview of the application of powder diffraction in modern materials research. The book contains essential theory and introductory material for students and researchers wishing to learn how to apply the frontier methods of powder diffraction
International Tables for Crystallography Volume F is an expert guide to macromolecular crystallography for the structural biologist. It was commissioned by the International Union of Crystallography in recognition of the extraordinary contributions that knowledge of macromolecular structure has made, and will make, to the analysis of biological systems, from enzyme catalysis to the workings of a whole cell. The volume covers all stages of a crystallographic analysis from the preparation of recombinant proteins, through crystallization, diffraction data collection, phase determination, structure validation and structure analysis. Although the volume is written for experienced scientists, it is recognized that the reader is more likely to be a biologist interested in structure than a classical crystallographer interested in biology. Thus, there are chapters on the fundamentals, history and current perspectives of macromolecular crystallography, as well as on useful programs and databases such as the Protein Data Bank. Each chapter is written by one or more internationally recognized experts. This second edition features 19 new articles and many articles from the first edition have been revised. The new articles cover topics such as standard definitions for quality indicators, expression of membrane proteins, protein engineering, high-throughput crystallography, radiation damage, merohedral twinning, low-resolution ab initio phasing, robotic crystal loading, whole-cell X-ray diffraction imaging and halogen interactions in biological crystal structures. There are also new articles on relevant software, including software for electron microscopy. These enhancements will ensure that Volume F continues to be a key reference for macromolecular crystallographers and structural biologists. More information on the series can be found at: http://it.iucr.org |
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