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Books > Science & Mathematics > Chemistry > Crystallography
Dislocations are lines of irregularity in the structure of a solid
analogous to the bumps in a badly laid carpet. Like these bumps
they can be easily moved, and they provide the most important
mechanism by which the solid can be deformed. They also have a
strong influence on crystal growth and on the electronic properties
of semiconductors.
This book presents selected topics on processing and properties of ferroelectric materials that are currently the focus of attention in scientific and technical research. Ferro-piezoelectric ceramics are key materials in devices for many applications, such as automotive, healthcare and non-destructive testing. As they are polycrystalline, non-centrosymmetric materials, their piezoelectricity is induced by the so-called poling process. This is based on the principle of polarization reversal by the action of an electric field that characterizes the ferroelectric materials. This book was born with the aim of increasing the awareness of the multifunctionality of ferroelectric materials among different communities, such as researchers, electronic engineers, end-users and manufacturers, working on and with ferro-piezoelectric ceramic materials and devices which are based on them. The initiative to write this book comes from a well-established group of researchers at the Laboratories of Ferroelectric Materials, Materials Science Institute of Madrid (ICMM-CSIC). This group has been working in different areas concerning thin films and bulk ceramic materials since the mid-1980s. It is a partner of the Network of Excellence on Multifunctional and Integrated Piezoelectric Devices (MIND) of the EC, in which the European Institute of Piezoelectric Materials and Devices has its origin.
This book focuses on the development of liquid crystal displays (LCDs) and liquid crystal materials (LCs) in Japan. The Committee of Organic Materials Research for Information Sciences of the Japan Society for the Promotion of Science (JSPS) planned the book to document essential LCD innovations and developments since the beginnings of the field-effect LCD technology in 1970. The book illustrates the remarkable effort and progress behind those flat, lightweight, and high-information-content LCDs that have become the indispensable human-machine interface for virtually all electronic devices. In contrast to other publications on this topic, the book illustrates the interdisciplinary character of the LCD technology and its crucial importance for technological progress of the field far beyond displays. It also gives insights into breakthrough innovations not revealed in other publications. Moreover, prospects for the development of LC research toward new fields of applications are provided. In line with its interdisciplinary character, the book targets researchers in basic science as well as engineers and researchers in industry.
X-ray multiple-wave diffraction, sometimes called multiple diffraction or N-beam diffraction, results from the scattering of X-rays from periodic two or higher-dimensional structures, like 2-d and 3-d crystals and even quasi crystals. The interaction of the X-rays with the periodic arrangement of atoms usually provides structural information about the scatterer. Unlike the usual Bragg reflection, the so-called two-wave diffraction, the multiply diffracted intensities are sensitive to the phases of the structure factors in volved. This gives X-ray multiple-wave diffraction the chance to solve the X-ray phase problem. On the other hand, the condition for generating an X ray multiple-wave diffraction is much more strict than in two-wave cases. This makes X-ray multiple-wave diffraction a useful technique for precise measure ments of crystal lattice constants and the wavelength of radiation sources. Recent progress in the application of this particular diffraction technique to surfaces, thin films, and less ordered systems has demonstrated the diver sity and practicability of the technique for structural research in condensed matter physics, materials sciences, crystallography, and X-ray optics. The first book on this subject, Multiple Diffraction of X-Rays in Crystals, was published in 1984, and intended to give a contemporary review on the fundamental and application aspects of this diffraction."
Optically Anomalous Crystals begins with an historical introduction covering the contributions of Brewster, Biot, Mallard, Brauns, Tamman, and many other distinguished crystallographers. From this follows a tutorial in crystal optics. Further chapters discuss the two main mechanisms of optical dissymmetry: the piezo-optic effect, and the kinetic ordering of atoms. The text then tackles complex, inhomogeneous crystals, and the complex optical properties resulting from the superposition of anomalies having various etiologies. The book treats the literature comprehensively, but uses illustrations from the authors' laboratories as the subjects of detailed analyses. This is an invaluable text for crystallographers, mineralogists, and petrologists interested in the growth of minerals and synthetic crystals, and their optical properties. It is also ideally suited to students of optical mineralogy, professional scientists and engineers and historians of science.
Fiber Crystal Growth from the Melt reviews the growth, modelling, characterization and application of single crystal fibers are reviewed. Due to their very large length-to-diameter ratio together with perfect crystallographic structure and chemical homogeneity, such fibers have mechanical and physical properties that approach the theoretical values. Fukuda explains how their ultra-high strength enables their application as reinforcing agents in structural components. And he elucidates how and why fiber crystals are particularly well suited for wave guiding, tunable narrow-band filters and nonlinear optics and for the generation of green, blue and violet wavelenghts, and also as micro lasers and laser modulators. The book is suitable for specialists and students in the fields of materials science, crystal growth, physics, chemistry, crystallography, optics, mechanics and engineering.
The book contains 5 chapters with 19 contributions form internationally well acknowledged experts in various fields of crystal growth. The topics are ranging from fundamentals (thermodynamic of epitaxy growth, kinetics, morphology, modeling) to new crystal materials (carbon nanocrystals and nanotubes, biological crystals), to technology (Silicon Czochralski growth, oxide growth, III-IV epitaxy) and characterization (point defects, X-ray imaging, in-situ STM). It covers the treatment of bulk growth as well as epitaxy by anorganic and organic materials.
In this book, academic researchers and technologists will find important information on the interaction of polymeric and non-polymeric inhibitors with a variety of scale forming crystals such as calcium phosphates, calcium carbonate, calcium oxalates, barium sulfate, calcium pyrophosphates, and calcium phosphonates. Moreover, the book delivers information to plant managers and formulators who would like to broaden and deepen their knowledge about processes involved in precipitation of sparingly soluble salts and learn more about the inhibitory aspects of various commercially available materials. Furthermore, experienced researchers will obtain fruitful and inspiring ideas from the easily accessible information about overlapping research areas, which will promote discoveries of new inhibitors (synthetic and/or natural) for the currently unmet challenges.
Crystal growth and nucleation are treated in the specialized literature in different ways depending on the discipline in question (physics, physical chemistry, chemical engineering) and on the theoretical approaches (atomistic vs continuum approach as regards crystal growth, phase vs chemical concept as regards nucleation). This book relates the different approaches to one another, giving preference to atomistic treatments by the methods of statistical thermodynamics and chemical kinetics. This unified approach also facilitates an understanding of some related phenomena of surface physics, such as adsorption, wetting etc. The book allows research novices and graduate students to get an insight into the physics of the phenomena and to interpret some of the experimental results.
Crystal engineering is an interdisciplinary area that cuts across the traditional subdivisions of chemistry. Fuelled by our increasingly precise understanding of the chemistry and properties of supramolecular systems, interest in the potential of the field has increased rapidly. The topics discussed in the 28 contributions in this book provide a state-of-the-art description of the field and offer new research ideas that, if pursued, will serve to strengthen the field at the interface between supramolecular chemistry and materials science.
The book considers the main growth-related phenomena occurring
during epitaxial growth, such as thermal etching, doping,
segregation of the main elements and impurities, coexistence of
several phases at the crystal surface and segregation-enhanced
diffusion.
Since the invention of the first laser 30 years ago, the frequency conversion of laser radiation in nonlinear optical crystals has become an important technique widely used in quantum electronics and laser physics for solving various scientific and engineering problems. The fundamental physics of three-wave light interactions in nonlinear optical crystals is now well understood. This has enabled the production of various harmonic generators, sum-and difference frequency generators, and optical parametric oscillators based on nonlinear optical crystals that are now commercially available. At the same time, scientists continue an active search for novel, highly efficient nonlinear optical materials. Therefore, in our opinion, there is a great need for a handbook of nonlinear optical crystals, intended for specialists and practitioners with an engineering background. This book contains a complete description of the properties and applications of all nonliner optical crystals of practical importance reported in the literature up to the beginning of 1990. In addition, it contains the most important equations for calculating the main parameters (such as phase-matching direction, effective nonlinearity, and conversion efficiency) of nonlinear frequency converters. Dolgoprudnyi, Yerevan, Troitzk v. G. Dmitriev USSR G. G. Gurzadyan October 1990 D. N. Nikogosyan Contents 1 Introduction. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2 Optics of Nonlinear Crystals. . . . . . . . . . . . . . . . . . . . . . . . 3 . . . . . ."
This survey of the important types of inorganic and organic crystal
structures treats its subject thoroughly and in sufficient depth
for undergraduate modules in chemistry courses. Features of this
book are the instructions for 3D stereoviewing which is central to
a full appreciation of the presentation. Clear directions for
making your own stereo have been provided in the book, which
enables readers to examine the plentiful stereo of lattices and
crystal structures which are illustrated.
Designed for easy use by both beginning and experienced protein
crystallographers, the second edition of Practical Protein
Crystallography is an essential handbook for any scientist
interested in solving a protein structure. The book includes
examples of actual experiments and data, electron density maps, and
computer methods. This second edition has new material covering
CCP4, SHELX, cryocrystallography, MAD and automated fitting.
This book is by far the most comprehensive treatment of point and space groups, and their meaning and applications. Its completeness makes it especially useful as a text, since it gives the instructor the flexibility to best fit the class and goals. The instructor, not the author, decides what is in the course. And it is the prime book for reference, as material is much more likely to be found in it than in any other book; it also provides detailed guides to other sources.Much of what is taught is folklore, things everyone knows are true, but (almost?) no one knows why, or has seen proofs, justifications, rationales or explanations. (Why are there 14 Bravais lattices, and why these? Are the reasons geometrical, conventional or both? What determines the Wigner-Seitz cells? How do they affect the number of Bravais lattices? Why are symmetry groups relevant to molecules whose vibrations make them unsymmetrical? And so on). Here these analyses are given, interrelated, and in-depth. The understanding so obtained gives a strong foundation for application and extension. Assumptions and restrictions are not merely made explicit, but also emphasized.In order to provide so much information, details and examples, and ways of helping readers learn and understand, the book contains many topics found nowhere else, or only in obscure articles from the distant past. The treatment is (often completely) different from those elsewhere. At least in the explanations, and usually in many other ways, the book is completely new and fresh. It is designed to inform, educate and make the reader think. It strongly emphasizes understanding.The book can be used at many levels, by many different classes of readers - from those who merely want brief explanations (perhaps just of terminology), who just want to skim, to those who wish the most thorough understanding. remove remove
This proceedings volume contains research data on structural investigation of materials of high industrial value. In particular, the following issues are discussed: phase characterization by diffraction methods, application of direct methods for solving crystal structure from powder diffraction, electron crystallography, Rietveld method application, defects and substructure analysis in materials, new X-ray methods, small angle scattering studies of crystalline and amorphous solids, phase transformation studies including crystallography of the reversible martensitic transformation, structure of noncrystalline materials, structure and properties of new materials.
Quasicrystals are a new form of the solid state which differ from the other two known forms, crystalline and amorphous, by possesing a new type of long-range translational order, called quasiperiodicty, and a noncrystallographic orientational order. This book provides an up-to-date description of the unusual physical properties of these new materials. Emphasis is placed on the experimental results, which are compared with those of the corresponding crystalline and amorphous systems and discussed in terms of modern theoretical models. Written by leading authorities in the field, the book will be of great use both to experienced workers in the field and to uninitiated graduate students.
The electron density of a nondegenerate ground state system determines essentially all physical properties of the system. This statement of the Hohenberg-Kohn theorem of Density Functional Theory plays an exceptionally important role among all the fundamental relations of molecular physics. Electron densities provide detailed information that gives important insight into the fundamentals of molecular structure and a better understanding of chemical reactions. If the functional form of a molecular electron density is known, then various molecular properties affecting reactivity can be determined by quantum chemical computational techniques or alternative approximate methods. This book contains a selection of chapters based on papers given at the 12th conference of the Commission of Charge, Spin and Momentum Density of the International Union for Crystallography, held in Waskiesiu, Prince Albert National Park, Canada, on July 27 - August 1, 1997. The choice of topics represents some of the latest advances in the field of electron, spin, and momentum densities and the analysis of these densities with respect to their roles in determining chemical reactivity. This book provides an exciting collection of accounts of the latest advances, and also provides further motivation for new research to address some of the challenging, unsolved problems of the fascinating interrelations between electron, spin, and momentum densities, and the complex subject of chemical reactivity.
Computer simulation techniques are now having a major impact on
almost all areas of the physical and biological sciences. This book
concentrates on the application of these methods to inorganic
materials, including topical and industrially relevant systems
including zeolites and high Tc superconductors.
Physics of laser crystals has been constantly developing since the invention of the laser in 1960. Nowadays, more than 1500 wide-band-gap and semiconductors crystals are suitable for the production of the laser effect. Different laser devices are widely used in science, medicine and communication systems according to the progress achieved in the development of laser crystal physics. Scintillators for radiation detection also gained benefit from these developments. Most of the optically active materials offer laser radiations within the 500 to 3000 nm region with various quantum efficiency which fit the usual applications. However, new crystals for laser emissions are needed either in the blue, UV and VUV - region or far IR- region, especially for medicine, computer microchip production and for undiscovered practical uses. Scientific problems of the growth and properties of laser crystals are discussed in numerous books and scientific journals by many scientists working in the field. Therefore, we thought that joint discussions of the scientific and technical problems in laser physics will be useful for further developments in this area. We have proposed to held a Workshop on Physics of Laser Crystals for attempting to induce additional advances especially in solid state spectroscopy. This NATO Advanced Research Workshop (ARW) was hold in Kharkiv * Stary Saltov th nd (Ukraine) on august 26 - September 2 , 2002, and was mainly devoted to the consideration 0 f modem approaches and Iast results in physics of laser crystals.
This book is the most comprehensive compilation of data on the optical properties of diamond ever written. The handbook presents for the first time in English a multitude of data on the optics of diamond which were previously published only in Russian and which were never known to western researchers. The author presents his own views alongside the opinions of other researchers, even in cases where these are contradictory. The main benefit derived from this handbook is a quick access to the most comprehensive information on all aspects of the optical properties of diamond. |
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