Recent research on superconductors with high critical temperature has led to results that were not available when the original German edition was prepared but could be included in the present English edition. This concerns materials based on bismuth and thallium, as well as measurements of low microwave loss. The author would like to thank Mr. A. H. Armstrong for translating the book from German to English in a very dedicated and competent manner. Thanks are also due once again to Springer-Verlag for their generous support and cordial cooperation. Bad Salzdetfurth September 1989 Johann H. Rinken Preface to the German Edition The development of materials which lose their electrical resistance when cooled, even before reaching the boiling point of liquid nitrogen, has considerably in creased the interest in superconductor technology, and with it superconductor electronics. This development had not been foreseen when work on the present book started, just over a year ago. Nevertheless, recent results of research on materials with high critical temperature are included to the extent that they seem to be confirmed and to be of interest to superconductor electronics. The present book deals with the physical and technological foundations of superconductor electronics so far as they must be known in order to under stand the principal modes of operation of superconductor electronics components.

The sixth Taniguchi Symposium on the Theory of Condensed Matter was held between 14-18 November 1983 at Kashikojima. Japan. During the Symposium, about twenty participants lived together and discussed the magnetic super conductors and related problems in an active and friendly atmosphere. This volume contains the papers presented at this Symposium. A strong impetus for organizing a Symposium of this subject is afforded by recent intense interest and accumulated information on magnetic and other novel superconductors newly discovered, and indeed the Symposium has pro duced many excellent contributions to this very exciting field of condensed matter theory, as reported in this volume. In order to give the readers a general outline of the subject, a brief sketch of the problem is made in the Introduction. Then the remainder of this volume is divided into four Parts and an Appendix. Part I is devoted to di scuss ions on several aspects of ferromagnetic superconductors includ ing superconductivity in heavy fermion systems. Part II treats problems on anti ferromagnetic superconductors. In Part III three papers on organic supercon ductors are presented. Part IV includes discussions on the exotic supercon ductors. The Appendix is concerned with the new research project towards high Tc superconductors in Japan. The last but not least remark is to mention the activity of the Taniguchi Foundation whose support makes this Symposium possible. For many years Mr."

This Topics in Current Physics (TCP) Volume 34 is concerned primarily with super- conductivity and magnetism, and the mutual interaction of these two phenomena in ternary rare earth compounds. It is the companion of TCP Volume 32 - Superconduc- tivity in Ternary Compounds: Structural, Electronic and Lattice Properties. The interplay between superconductivity and magnetism has intrigued theoreticians and experimentalists alike for more than two decades. V. L. Ginzburg first addressed the question of whether or not superconductivity and ferromagnetism could coexist in 1957, and B. T. Matthias and coworkers carried out the first experimental inves- tigations on this problem in 1959. The early experiments were made on systems that consisted of a superconducting element or compound into which small concentrations of rare earth impurities with partially-filled 4f electron shells had been intro- duced. These dilute impurity systems were chosen because the scattering of conduc- tion electrons by parama9. netic rare earth impurity ions usually has a strong de- structive "pa i r breaking" effect on superconducti vity, typi ca lly drivi ng the super- conducting transition temperature to zero at impurity concentrations of only a few atomic percent. Unfortunately, analysis of these early experiments was complicated by clustering and/or the formation of short range or "glassy" types of magnetic order so that definitive conclusions regarding the coexistence of superconductivity and magnetism could not be reached.

The recent discovery of high-temperature superconductivity in copper based oxides is an event of major importance not only with respect to the physical phenomenon itself but also because it definitely shows that solid state chemistry, and especially the crystal chemistry of oxides, has a crucial place in the synthesis and understanding of new materials for future appli cations. The numerous papers published in the field of high Tc supercon ductors in the last five years demonstrate that the great complexity of these materials necessitates a close collaboration between physicists and solid state chemists. This book is based to a large extent on our experience of the crystal chemistry of copper oxides, which we have been studying in the laboratory for more than twelve years, but it also summarizes the main results which have been obtained for these compounds in the last five years relating to their spectacular superconducting properties. We have focused on the struc ture, chemical bonding and nonstoichiometry of these materials, bearing in mind that redox reactions are the key to the optimization of their supercon ducting properties, owing to the importance of the mixed valence of copper and its Jahn-Teller effect. We have also drawn on studies of extended defects by high-resolution electron microscopy and on their creation by ir radiation effects."

The book provides an in-depth understanding of the fundamentals of superconducting electronics and the practical considerations for the fabrication of superconducting electronic structures. Additionally, it covers in detail the opportunities afforded by superconductivity for uniquely sensitive electronic devices and illustrates how these devices (in some cases employing high-temperature, ceramic superconductors) can be applied in analog and digital signal processing, laboratory instruments, biomagnetism, geophysics, nondestructive evaluation and radioastronomy. Improvements in cryocooler technology for application to cryoelectronics are also covered. This is the first book in several years to treat the fundamentals and applications of superconducting electronics in a comprehensive manner, and it is the very first book to consider the implications of high-temperature, ceramic superconductors for superconducting electronic devices. Not only does this new class of superconductors create new opportunities, but recently impressive milestones have been reached in superconducting analog and digital signal processing which promise to lead to a new generation of sensing, processing and computational systems. The 15 chapters are authored by acknowledged leaders in the fundamental science and in the applications of this increasingly active field, and many of the authors provide a timely assessment of the potential for devices and applications based upon ceramic-oxide superconductors or hybrid structures incorporating these new superconductors with other materials. The book takes the reader from a basic discussion of applicable (BCS and Ginzburg-Landau) theories and tunneling phenomena, through the structure and characteristics of Josephson devices and circuits, to applications that utilize the world's most sensitive magnetometer, most sensitive microwave detector, and fastest arithmetic logic unit.

For the last few years astrophysicists and elementary particle physicists have been working jointly on the following fascinating phenomena: 1. The solar neutrino puzzle and the question: What happens to the neutrinos on their way from the sun to the earth? 2. The growing evidence that our universe is filled with about 10 times more matter than is visible and the question: What is dark matter made of? 3. The supernovae explosions and the question: What do neutrinos tell us about such explosions and vice versa? The experimental investigation of these phenomena is difficult and involves unconventional techniques. These are presently under development, and bring together such seemingly disparate disciplines as astrophysics and elementary particle physics on the one hand and superconductivity and solid-state physics on the other. This book contains the proceedings of a workshop held in March 1987 at which the above subjects and their experimental investigation were discussed. The proposed experimental methods are very new. They involve frontier developments in low temperature and solid-state physics. The book should be useful to researchers and students who actively work on these subjects or plan to enter the field. It also offers the non-expert reader with some physics background a good survey of the activities in this field.

The structural. electronic and lattice properties of superconducting ternary com pounds are the subject of this Topics volume. Its companion volume (Topics in Cur rent Physics. Volume 34) deals primarily with the mutual interaction of supercon ductivity and magnetism in ternary compounds. These two volumes are the culmination of a project. started nearly two years ago. that was inspired by the intense re search effort. both experimental and theoretical. then being expended to explore and develop an understanding of the remarkable physical properties of ternary super conductors. Research activity on this subject has increased in the meantime. The interest in ternary superconductors originated in 1972. when B.T. Matthias and his co-workers first discovered superconductivity in several ternary molybdenum sulfide compounds that had been synthesized in 1971 by R. Chevrel. M. Sergent. and J. Prigent. The superconducting critical temperature Tc of one of the compounds. PbMo S * was reported to be ~ 15 K. This value is sufficiently high that there was g 6 (and still is) reason to expect that other ternary compounds would be found with superconducting transition temperatures rivaling those of the A15 compounds. of which Nb Ge has the record high Tc of 23 K. The interest in ternary superconductors 3 received further impetus when several of the ternary molybdenum sulfides were found to have exceptionally high upper critical magnetic fields. some of them in the neighborhood of 50 Tesla or more. An immense amount of research on ternary molybdenum chalcogenides then followed.

This volume deals with physical properties of electrically one-dimensional conductors. It includes both a description of basic concepts and a review of recent progress in research. One-dimensional conductors are those materials in which an electric current flows easily in one specific crystal direction while the resistivity is very high in transverse directions. It was about 1973 when much attention began to be focussed on them and investigations started in earnest. The research was stimulated by the successful growth of crystals of the organic conductor TTF-TCNQ and of the inorganic conductor KCP. New concepts, characteristic of one dimension, were established in the in vestigations of their properties. Many new one-dimensional conductors were also found and synthesized. This field of research is attractive because of the discovery of new ma terials, phenomena and concepts which have only recently found a place in the framework of traditional solid-state physics and materials science. The relation of this topic to the wider field of solid-state sciences is therefore still uncertain. This situation is clearly reflected in the wide distribution of the fields of specialization of researchers. Due to this, and also to the rapid progress of research, no introductory book has been available which covers most of the important fields of research on one-dimensional conductors."

During the past thirty years considerable efforts have been made to design the synthesis and the study of molecular semiconductors. Molecular semiconductors - and more generally molecular materials - involve interactions between individual subunits which can be separately synthesized. Organic and metallo-organic derivatives are the basis of most of the molecular materials. A survey of the literature on molecular semiconductors leaves one rather confused. It does seem to be very difficult to correlate the molecular structure of these semiconductors with their experimental electrical properties. For inorganic materials a simple definition delimits a fairly homogeneous family. If an inorganic material has a conductivity intermediate between that of an 12 1 1 3 1 1 insulator " 10- n- cm- ) and that of a metal (> 10 n- cm- ), then it is a semiconductor and will exhibit the characteristic properties of this family, such as junction formation, photoconductivity, and the photovoltaic effect. For molecular compounds, such simplicity is certainly not the case. A huge number of molecular and macromolecular systems have been described which possess an intermediate conductivity. However, the various attempts which have been made to rationalize their properties have, more often than not, failed. Even very basic electrical properties such as the mechanism of the charge carrier formation or the nature and the density ofthe dopants are not known in detail. The study of molecular semiconductor junctions is very probably the most powerful approach to shed light on these problems.

Process Technology for Semiconductor Lasers describes the design principles of semiconductor lasers, mainly from the fabrication point of view. A review is given of the history of semiconductor-laser development and applications and of the materials used in lasing at short to long wavelengths. The basic design principles for semiconductor-laser devices and the epitaxy for laser production are discussed. An entire chapter is devoted to the technology of liquid-phase epitaxy, and another one to vapor-phase and beam epitaxies. The characterizations of laser materials and the fabrication and characteristics of semiconductor lasers are treated. Mode-control techniques are presented, and surface-emitting lasers are introduced in the final chapter.

In this text experts review experimental studies that directly reveal the relationship between the atomic structure and physical behavior of high-Tc superconductors. The thorough discussion centers on twins, twin boundaries, the vortex lattice, and magnetic and mechanical properties in connection with structural imperfections. Particular attention is paid to the role of the oxygen atom in the Y-Ba-Cu-O and La-Cu-O species. The experimental methods evaluated include electron and X-ray diffraction, electron microscopy, and M-ssbauer spectroscopy. This book makes extraordinarily valuable data obtained at the Institute of Solid State Physics at Chernogolovka accessible to the wider international community of researchers in superconductivity.

In less than two decades the concept of supercon In every field of science there are one or two ductivity has been transformed from a laboratory individuals whose dedication, combined with an innate curiosity to usable large-scale applications. In the understanding, permits them to be able to grasp, late 1960's the concept of filamentary stabilization condense, and explain to the rest of us what that released the usefulness of zero resistance into the field is all about. For the field of titanium alloy marketplace, and the economic forces that drive tech superconductivity, such an individual is Ted Collings. nology soon focused on niobium-titanium alloys. They His background as a metallurgist has perhaps given him are ductile and thus fabricable into practical super a distinct advantage in understanding superconduc conducting wires that have the critical currents and tivity in titanium alloys because the optimization of fields necessary for large-scale devices. More than superconducting parameters in these alloys has been 90% of all present-day applications of superconductors almost exclusively metallurgical. Advantages in use titanium alloys. The drive to optimize these training and innate abilities notwithstanding, it is alloys resulted in a flood of research that has been the author's dedication that is the essential com collected, condensed, and analyzed in this volume."

High temperature superconductivity is still one of the most discussed topicsin physics. "The Physics and Chemistry of Oxide Superconductors " collects together more than one hundred original contributions presented during the 2nd International Symposium of the Institute for Solid State Physics of the University of Tokyo. The main topics cover new insights into the basic mechanism of high temperature superconductivity, recent developments of new superconducting materials, the state of the art of thin film production, theoretical understanding of the electronic structures in this kind of material, theories for strongly correlated electron systems, and many physical and chemical effects.

Single-electron tunneling (SET) and related phenomena have recently come to be considered as "hot topics." This also became apparent when we organized the 4th International Conference on Superconducting and Quantum Effect Devices and Their Applications, SQUID'91, which was held June 18-21, 1991, in Berlin, Germany. Impressed by the number of contributions dedicated to the new physics of ultrasmall devices, we deemed it appropriate to devote this volume of the Springer Series in Electronics and Photonics to these specialized proceedings. The other contributions presented at SQUID'91, which are more conventional in character but nevertheless contain excitingly innovative results, are published separately as Volume 64 of the series Springer Proceedings in Physics. At first glance it seems strange that a conference abbreviated SQUID'91 should attract so many papers on non-superconducting devices, and in fact the first SQUID'XX conferences dealt exclusively with the physics and technology of Josephson junctions, SQUIDs and other superconducting devices and their ap plications. However, many concepts developed for superconducting devices, like tunneling, flux quantization, and flux-charge conjugation, appeared to be suitable for ultrasmall non-superconducting structures as well, and many researchers in the field of superconducting devices extended their activities accordingly. Thus the extension of the conference programme evolved quite informally. Meanwhile, the meetings established themselves as well-known conference series tradition ally appreciated by the SQUID community for its balanced mixture of physics and technology, review and preview. SQUID'XX became a kind of a trademark."

Compound semiconductor devices form the foundation of solid-state microwave and optoelectronic technologies used in many modern communication systems. In common with their low frequency counterparts, these devices are often represented using equivalent circuit models, but it is often necessary to resort to physical models in order to gain insight into the detailed operation of compound semiconductor devices. Many of the earliest physical models were indeed developed to understand the 'unusual' phenomena which occur at high frequencies. Such was the case with the Gunn and IMPATI diodes, which led to an increased interest in using numerical simulation methods. Contemporary devices often have feature sizes so small that they no longer operate within the familiar traditional framework, and hot electron or even quantum mechanical models are required. The need for accurate and efficient models suitable for computer aided design has increased with the demand for a wider range of integrated devices for operation at microwave, millimetre and optical frequencies. The apparent complexity of equivalent circuit and physics-based models distinguishes high frequency devices from their low frequency counterparts . . Over the past twenty years a wide range of modelling techniques have emerged suitable for describing the operation of compound semiconductor devices. This book brings together for the first time the most popular techniques in everyday use by engineers and scientists. The book specifically addresses the requirements and techniques suitable for modelling GaAs, InP. ternary and quaternary semiconductor devices found in modern technology."

Springer-Verlag, Berlin Heidelberg, in conjunction with Springer-Verlag New York, is pleased to announce a new series: CRYSTALS Growth, Properties, and Applications The series presents critical reviews of recent developments in the field of crystal growth, properties, and applications. A substantial portion of the new series will be devoted to the theory, mechanisms, and techniques of crystal growth. Occasionally, clear, concise, complete, and tested instructions for growing crystals will be published, particularly in the case of methods and procedures that promise to have general applicability. Responding to the ever-increasing need for crystal substances in research and industry, appropriate space will be devoted to methods of crystal characterization and analysis in the broadest sense, even though reproducible results may be expected only when structures, microstructures, and composition are really known. Relations among procedures, properties, and the morphology of crystals will also be treated with reference to specific aspects of their practical application. In this way the series will bridge the gaps between the needs of research and industry, the pos sibilities and limitations of crystal growth, and the properties of crystals. Reports on the broad spectrum of new applications - in electronics, laser tech nology, and nonlinear optics, to name only a few - will be of interest not only to industry and technology, but to wider areas of applied physics as well and to solid state physics in particular. In response to the growing interest in and importance of organic crystals and polymers, they will also be treated."

Physics and Chemistry of Transition-Metal Oxides includes both theoretical and experimental approaches to the variety of phenomena found in the transition-metal oxides, including high-temperature superconductivity, colossal magnetoresistance, and metal-insulator transition. These are the central issues in materials science and condensed matter physics/chemistry, and readers can obtain up-to-date information on what is happening in this field of research.

The expansion of the application of ferroelectric crystals in engineering as well as of a number of fundamental problems of solid-state physics, which have not yet been solved and which bear a direct relation to ferro electricity, has lately stimulated much interest in the problem of ferroelectricity. In courses of solid-state physics ferroelectricity is studied today along with traditional disciplines, such as magnetism, superconductivity, and 'semiconducting phe nomena. Moreover, new specialities have been born concerned directly with the development and utilization of ferroelectric material in optics, acous tics, computer technology, and capacitor engineering. Special courses in the physics of ferroelectrics are read in a number of colleges and universities. The study of the nature of ferro electricity has currently reached such a level of development that we may speak of having gained a rather deep insight into the physical essence of a number of phenomena, which contribute to the generation of a spontaneous electric polarization in crystals. It is exactly at this level that it has become possible to single out that part of the problem, the physical picture of which can be depicted in a rather unsophisticated manner and which is the foundation for the construction of a building of "complete understanding.""

Recent experimental and theoretical progress has elucidated the tunable crossover, in ultracold Fermi gases, from BCS-type superconductors to BEC-type superfluids.

"The BCS-BEC Crossover and the Unitary Fermi Gas" is a collaborative effort by leading international experts to provide an up-to-date introduction and a comprehensive overview of current research in this fast-moving field.

It is now understood that the unitary regime that lies right in the middle of the crossover has remarkable universal properties, arising from scale invariance, and has connections with fields as diverse as nuclear physics and string theory.

This volume will serve as a first point of reference for active researchers in the field, and will benefit the many non-specialists and graduate students who require a self-contained, approachable exposition of the subject matter.

"

One of the most exciting developments in modern physics has been the discovery of the new class of oxide materials with high superconducting transition temperature. Systems with Tc well above liquid nitrogen temperature are already a reality and higher Tc's are anticipated. Indeed, the idea of a room-temperature superconductor, which just a short time ago was considered science fiction, appears to be a distinctly possible outcome of materials research. To address the need to train students and scientists for research in this exciting field, Jeffrey W. Lynn and colleagues at the University of Maryland, College Park, as well as other superconductivity experts from around the U.S., taught a graduate-level course in the fall of 1987, from which the chapters in this book were drawn. Subjects included are: Survey of superconductivity (J. Lynn).- The theory of type-II superconductivity (D. Belitz).- The Josephson effect (P. Ferrell).- Crystallography (A. Santoro).- Electronic structure (C.P. Wang).- Magnetic properties and interactions (J. Lynn).- Synthesis and diamagnetic properties (R. Shelton).- Electron pairing (P. Allen).- Superconducting devices (F. Bedard).- Superconducting properties (J. Crow, N.-P. Ong).

This book should fill a gap which has existed in the literature on supercon ductivity. There have been a number of excellent textbooks available on the phenomenon of superconductivity, which describe in detail the variety of ef fects connected with it and the mathematical techniques to deal with them properly. However, until now there has not been a textbook available in English which concentrates on the mate ial aspects of superconductivity. This is a major shortcoming since most physicists working in the field of superconduc tivity are mainly concerned with specific materials and subsequently often need to know more about the interplay of superconductivity and material prop erties. On the other hand, people working in the field know that a competent and well-written book by S. V. Vonsovsky, V. A. Izyumov, and E. Z. Kurmaev has been available in Russian. It presents a thorough discussion of superconducting transition-metal alloys and compounds. This volume is a translation of an updated version of the Russian edition. The translation was done by A. P. Zavarnitsyn of the authors' institution and by Dr. E. H. Brandt of the Max-Planck-Institut fur Metallforschung in Stuttgart. The master manuscript was ably typed by Mrs. C. Pendl. I would like to take this opportunity to thank each of them. I sincerely hope that the book will turn out to be useful to physicists working in the field of superconductivity as well as to nonspecialists and interested graduate students."

Various experimental techniques for point contact production are described. Examples of point-contact spectra are presented for pure metals, alloys and compounds, as well as for semimetals and semiconductors, heavy fermion systems, Kond-lattices, mixed valence compounds and more. Superconducting point contacts are considered in respect to Andreev reflection and Josephson effects. Special attention is paid to contact conductance fluctuation, and new trends of research are outlined.

Since its inception in 1966, the series of numbered volumes known as "Semiconductors and Semimetals" has distinguished itself through the careful selection of well-known authors, editors, and contributors. The "Willardson and Beer" Series, as it is widely known, has succeeded in publishing numerous landmark volumes and chapters. Not only did many of these volumes make an impact at the time of their publication, but they continue to be well-cited years after their original release. Recently, Professor Eicke R. Weber of the University of California at Berkeley joined as a co-editor of the series. Professor Weber, a well-known expert in the field of semiconductor materials, will further contribute to continuing the series' tradition of publishing timely, highly relevant, and long-impacting volumes. Some of the recent volumes, such as "Hydrogen in Semiconductors, Imperfections in III/V Materials, Epitaxial Microstructures, High-Speed Heterostructure Devices, Oxygen in Silicon, " and others promise that this tradition will be maintained and even expanded. Reflecting the truly interdisciplinary nature of the field that the series covers, the volumes in "Semiconductors and Semimetals" have been and will continue to be of great interest to physicists, chemists, materials scientists, and device engineers in modern industry.
Written and edited by internationally renowned expertsRelevant to a wide readership: physicists, chemists, materials scientists, and device engineers in academia, scientific laboratories and modern industry

An invaluable introduction to nanomaterials and their applications

Offering the unique approach of applying traditional physics concepts to explain new phenomena, Introduction to Nanomaterials and Devices provides readers with a solid foundation on the subject of quantum mechanics and introduces the basic concepts of nanomaterials and the devices fabricated from them. Discussion begins with the basis for understanding the basic properties of semiconductors and gradually evolves to cover quantum structures--including single, multiple, and quantum wells--and the properties of nanomaterial systems, such as quantum wires and dots.

Written by a renowned specialist in the field, this book features:

An introduction to the growth of bulk semiconductors, semiconductor thin films, and semiconductor nanomaterials

Information on the application of quantum mechanics to nanomaterial structures and quantum transport

Extensive coverage of Maxwell-Boltzmann, Fermi-Dirac, and Bose-Einstein stastistics

An in-depth look at optical, electrical, and transport properties

Coverage of electronic devices and optoelectronic devices

Calculations of the energy levels in periodic potentials, quantum wells, and quantum dots

Introduction to Nanomaterials and Devices provides essential groundwork for understanding the behavior and growth of nanomaterials and is a valuable resource for students and practitioners in a field full of possibilities for innovation and invention.

A graduate textbook presenting the underlying physics behind devices that drive today's technologies. The book covers important details of structural properties, bandstructure, transport, optical and magnetic properties of semiconductor structures. Effects of low-dimensional physics and strain - two important driving forces in modern device technology - are also discussed. In addition to conventional semiconductor physics the book discusses self-assembled structures, mesoscopic structures and the developing field of spintronics. The book utilizes carefully chosen solved examples to convey important concepts and has over 250 figures and 200 homework exercises. Real-world applications are highlighted throughout the book, stressing the links between physical principles and actual devices. Electronic and Optoelectronic Properties of Semiconductor Structures provides engineering and physics students and practitioners with complete and coherent coverage of key modern semiconductor concepts. A solutions manual and set of viewgraphs for use in lectures are available for instructors, from [email protected].