Providing the chemical physics field with a forum for critical, authoritative evaluations in every area of the discipline, the latest volume of Advances in Chemical Physics continues to provide significant, up-to-date chapters written by internationally recognized researchers.
This volume is essentially devoted to helping the reader obtain general information about a wide variety of topics in chemical physics. Advances in Chemical Physics, Volume 114 includes chapters addressing vibrational energy flow, discrete variable representations and their utilization, the unified theory of photochemical charge separation, and the association, dissociation, acceleration, and suppression of reactions by laser pulses.

This book presents investigations on the Earth's seismic structure using both active-source and natural earthquake records. It discusses the ground-truth data obtained from the TAiwan Integrated GEodynamics Research (TAIGER) active-source experiments that provides excellent and unique insights into the shallow crustal structures beneath Taiwan. It also explores the full-wave sensitivity kernels, which account for the effects of all possible wave interferences involved in shear-wave splitting and therefore loosen the restrictions on source-receiver geometry amenable to shear-wave splitting analysis. Moreover, it describes the 3D Frechet kernels, which enable us to resolve the vertical and lateral variations in seismic anisotropy and obtain 3D images of the Earth's anisotropic structure, as well as the practice in Southern California that enables us to infer the state of the stress and strain in the lithosphere and the dynamics of the asthenospheric mantle flow for a better understanding of the strength and deformation in the upper mantle beneath the San Andreas Fault system.

Nominated as an outstanding thesis by Professor Robert Crittenden of the Institute of Cosmology and Gravitation in Portsmouth, and winner of the Michael Penston Prize for 2014 given by the Royal Astronomical Society for the best doctoral thesis in Astronomy or Astrophysics, this work aims to shed light on one of the most important probes of the early Universe: the bispectrum of the cosmic microwave background. The CMB bispectrum is a potential window on exciting new physics, as it is sensitive to the non-Gaussian features in the primordial fluctuations, the same fluctuations that evolved into today's planets, stars and galaxies. However, this invaluable information is potentially screened, as not all of the observed non-Gaussianity is of primordial origin. Indeed, a bispectrum arises even for perfectly Gaussian initial conditions due to non-linear dynamics, such as CMB photons scattering off free electrons and propagating in an inhomogeneous Universe. Dr. Pettinari introduces the reader to this intrinsic bispectrum in a pedagogic way, building up from the standard model of cosmology and from cosmological perturbation theory, the tool cosmologists use to unravel the history of the cosmos. In doing so, he introduces SONG, a new and efficient code for solving the second-order Einstein and Boltzmann equations. Next, he moves on to answer the crucial question: is the intrinsic bispectrum going to screen the primordial signal in the CMB? Using SONG, he computes the intrinsic bispectrum and shows how its contamination leads to a small bias in the estimates of primordial non-Gaussianity, a great news for the prospect of using CMB data to probe primordial non-Gaussianity.

This book provides a concise overview of the photophysics and spectroscopy of bio chromophore ions. The book "Photophysics of Ionic Biochromophores" summarizes important recent advances in the spectroscopy of isolated biomolecular ions in vacuo, which has within the last decade become a highly active research field. Advanced instrumental apparatus and the steady increase in more and more powerful computers have made this development possible, both for experimentalists and theoreticians. Applied techniques described here include absorption and fluorescence spectroscopy, which are excellent indicators of environmental effects and can thus shed light on the intrinsic electronic structures of ions without perturbations from e.g. water molecules, counter ions, nearby charges, and polar amino acid residues. When compared with spectra of the chromophores in their natural environment, such spectra allow to identify possible perturbations. At the same time gas-phase spectra provide important benchmarks for quantum chemistry calculations of electronically excited states. This volume focuses on biological systems from protein biochromophores, e.g. the protonated Schiff-base retinal responsible for vision, and individual aromatic amino acids to peptides and whole proteins, studied using visible, ultraviolet and vacuum ultraviolet light. Work on DNA nucleotides and strands that are amenable to mass spectrometric studies because of the negatively charged sugarphosphate backbone are also presented. DNA strands represent an example of the interplay between multiple chromophores, which is even harder to model correctly than just single chromophores due to spatially extended excited states and weak coupling terms. The experimental techniques used to measure spectra and commonly used theoretical methods are described with a discussion on limitations and advantages. The volume includes an updated status of the field and interesting future directions such as cold ion spectroscopy.

Metamaterials, artificial electromagnetic media achieved by structuring on the subwave-length-scale were initially suggested for the negative index and superlensing. They became a paradigm for engineering electromagnetic space and controlling propagation of waves. The research agenda is now shifting on achieving tuneable, switchable, nonlinear and sensing functionalities. The time has come to talk about the emerging research field of metadevices employing active and tunable metamaterials with unique functionalities achieved by structuring of functional matter on the subwave-length scale. This book presents the first systematic and comprehensive summary of the reviews written by the pioneers and top-class experts in the field of metamaterials. It addresses many grand challenges of the cutting edge research for creating smaller and more efficient photonic structures and devices.

The second edition of Solar System Astrophysics: Planetary Atmospheres and the Outer Solar System provides a timely update of our knowledge of planetary atmospheres and of the bodies of the outer solar system and their analogs in other planetary systems. This volume begins with an expanded treatment of the physics, chemistry, and meteorology of the atmospheres of the Earth, Venus, and Mars, moving on to their magnetospheres and then to a full discussion of the gas and ice giants and their properties. From here, attention switches to the small bodies of the solar system, beginning with the natural satellites. The comets, meteors, meteorites, and asteroids are discussed in order, and the volume concludes with the origin and evolution of our solar system. Finally, a fully revised section on extrasolar planetary systems puts the development of our system in a wider and increasingly well understood galactic context. All of the material is presented within a framework of historical importance. This book and its sister volume, Solar System Astrophysics: Background Science and the Inner Solar system, are pedagogically well written, providing clearly illustrated explanations, for example, of such topics as the numerical integration of the Adams-Williamson equation, the equations of state in planetary interiors and atmospheres, Maxwell's equations as applied to planetary ionospheres and magnetospheres, and the physics and chemistry of the Habitable Zone in planetary systems. Together, the volumes form a comprehensive text for any university course that aims to deal with all aspects of solar and extra-solar planetary systems. They will appeal separately to the intellectually curious who would like to know how just how far our knowledge of the solar system has progressed in recent years.

This thesis describes the essential features of Moon-plasma interactions with a particular emphasis on the Earth's magnetotail plasma regime from both observational and theoretical standpoints. The Moon lacks a dense atmosphere as well as a strong intrinsic magnetic field. As a result, its interactions with the ambient plasma are drastically different from solar-wind interactions with magnetized planets such as Earth. The Moon encounters a wide range of plasma regime from the relatively dense, cold, supersonic solar-wind plasma to the low-density, hot, subsonic plasma in the geomagnetic tail. In this book, the author presents a series of new observations from recent lunar missions (i.e., Kaguya, ARTEMIS, and Chandrayaan-1), demonstrating the importance of the electron gyro-scale dynamics, plasma of lunar origin, and hot plasma interactions with lunar magnetic anomalies. The similarity and difference between the Moon-plasma interactions in the geomagnetic tail and those in the solar wind are discussed throughout the thesis. The basic knowledge presented in this book can be applied to plasma interactions with airless bodies throughout the solar system and beyond.

This book provides an excellent overview on the most recent results on the industrial applications of Mossbauer spectroscopy attained on the fields of nanotechnology, metallurgy, biotechnology and pharmaceutical industry, applied mineralogy, energy production industry (coal, oil, nuclear, solar, etc.), computer industry, space technology, electronic and magnetic devices technology, ion implantation technology, including topics like characterization of novel construction materials, electronic components and magnetic materials, composite materials, colloids, amorphous and nanophase materials, small particles, coatings, interfaces, thin films and multilayers, catalysis, corrosion, tribology, surface modification, hydrogen storage, ball milling, radiation effects, electrochemistry, batteries, etc. From the various reports a broad overview emerges illustrating that the method can successfully be applied in a wide variety of topics.
Previously published in the journal Hyperfine Interactions."

This is the first book to systematically consider the modern aspects of chaotic dynamics of magnetic field lines and charged particles in magnetically confined fusion plasmas. The analytical models describing the generic features of equilibrium magnetic fields and magnetic perturbations in modern fusion devices are presented. It describes mathematical and physical aspects of onset of chaos, generic properties of the structure of stochastic magnetic fields, transport of charged particles in tokamaks induced by magnetic perturbations, new aspects of particle turbulent transport, etc. The presentation is based on the classical and new unique mathematical tools of Hamiltonian dynamics, like the action--angle formalism, classical perturbation theory, canonical transformations of variables, symplectic mappings, the Poincare-Melnikov integrals. They are extensively used for analytical studies as well as for numerical simulations of magnetic field lines, particle dynamics, their spatial structures and statistical properties. The numerous references to articles on the latest development in the area are provided. The book is intended for graduate students and researchers who interested in the modern problems of magnetic stochasticity in magnetically confined fusion plasmas. It is also useful for physicists and mathematicians interested in new methods of Hamiltonian dynamics and their applications.

The present book provides a contemporary systematic treatment of shock waves in high-temperature collisionless plasmas as are encountered in near Earth space and in Astrophysics. It consists of two parts. Part I develops the complete theory of shocks in dilute hot plasmas under the assumption of absence of collisions among the charged particles when the interaction is mediated solely by the self-consistent electromagnetic fields. Such shocks are naturally magnetised implying that the magnetic field plays an important role in their evolution and dynamics. This part treats subcritical shocks which dissipate flow energy by generating anomalous resistance or viscosity. The main emphasis is, however, on super-critical shocks where the anomalous dissipation is insufficient to retard the upstream flow. These shocks, depending on the direction of the upstream magnetic field, are distinguished as quasi-perpendicular and quasi-parallel shocks which exhibit different behaviours, reflecting particles back upstream and generating high electromagnetic wave intensities. Particle acceleration and turbulence at such shocks become possible and important. Part II treats planetary bow shocks and the famous Heliospheric Termination shock as examples of two applications of the theory developed in part I.

This book addresses the peculiarities of nonlinear wave propagation in waveguides and explains how the stratification depends on the waveguide and confinement. An example of this is an optical fibre that does not allow light to pass through a density jump. The book also discusses propagation in the nonlinear regime, which is characterized by a specific waveform and amplitude, to demonstrate so-called solitonic behaviour. In this case, a wave may be strongly localized, and propagates with a weak change in shape. In the waveguide case there are additional contributions of dispersion originating from boundary or asymptotic conditions. Offering concrete guidance on solving application problems, this essentially (more than twice) expanded second edition includes various aspects of guided propagation of nonlinear waves as well as new topics like solitonic behaviour of one-mode and multi-mode excitation and propagation and plasma waveguides, propagation peculiarities of electromagnetic waves in metamaterials, new types of dispersion, dissipation, electromagnetic waveguides, planetary waves and plasma waves interaction.The key feature of the solitonic behaviour is based on Coupled KdV and Coupled NS systems. The systems are derived in this book and solved numerically with the proof of stability and convergence. The domain wall dynamics of ferromagnetic microwaveguides and Bloch waves in nano-waveguides are also included with some problems of magnetic momentum and charge transport.

The series of texts composing this book is based on the lectures presented during the II Jose Plinio Baptista School of Cosmology, held in Pedra Azul (Espirito Santo, Brazil) between 9 and 14 March 2014. This II JBPCosmo has been entirely devoted to the problem of understanding theoretical and observational aspects of Cosmic Background Radiation (CMB).The CMB is one of the most important phenomena in Physics and a fundamental probe of our Universe when it was only 400,000 years old. It is an extraordinary laboratory where we can learn from particle physics to cosmology; its discovery in 1965 has been a landmark event in the history of physics.The observations of the anisotropy of the cosmic microwave background radiation through the satellites COBE, WMAP and Planck provided a huge amount of data which are being analyzed in order to discover important informations regarding the composition of our universe and the process of structure formation.

The book explores the phenomenon of surface-enhanced Raman scattering (SERS), the huge amplification of Raman signal from molecules in the proximity of a metallic nanostructured surface, allowing readers to gain an in-depth understanding of the mechanisms affecting the spectroscopic response of SERS-active systems for effective applications. SERS spectroscopy is an ultrasensitive analytical technique with great potential for applications in the field of biophysics and nanomedicine. As examples, the author presents the design of nanocolloid-based SERS-active substrates for molecular sensing and of a folate-based SERS-active nanosensor capable of selectively interacting with cancer cells, enabling cancer diagnostics and therapy at the single-cell level. The author also suggests novel paths for the systematization of the SERS nanosystem design and experimental protocols to maximize sensitivity and reproducibility, which is essential when real-world biomedical applications are the goal of the study. With a combined approach, both fundamental and applied, and a detailed analysis of the state of the art, this book provides a valuable overview both for students new to SERS spectroscopy and for experts in the field.

The main focus of this book is on the interconnection of two unorthodox scientific ideas, the varying-gravity hypothesis and the expanding-earth hypothesis. As such, it provides a fascinating insight into a nearly forgotten chapter in both the history of cosmology and the history of the earth sciences. The hypothesis that the force of gravity decreases over cosmic time was first proposed by Paul Dirac in 1937. In this book the author examines in detail the historical development of Dirac's hypothesis and its consequences for the structure and history of the earth, the most important of which was that the earth must have been smaller in the past.

This book is aimed at advanced undergraduates, graduate students and other researchers who possess an introductory background in materials physics and/or chemistry, and an interest in the physical and chemical properties of novel materials, especially transition metal oxides. New materials often exhibit novel phenomena of great fundamental and technological importance. Contributing authors review the structural, physical and chemical properties of notable 4d- and 5d-transition metal oxides discovered over the last 10 years. These materials exhibit extraordinary physical properties that differ significantly from those of the heavily studied 3d-transition metal oxides, mainly due to the relatively strong influence of the spin- orbit interaction and orbital order in 4d- and 5d materials. The immense growth in publications addressing the physical properties of these novel materials underlines the need to document recent advances and the current state of this field. This book includes overviews of the current experimental situation concerning these materials.

"Principles of Environmental Physics: Plants, Animals, and the Atmosphere, 4e, "provides a basis for understanding the complex physical interactions of plants and animals with their natural environment. It is the essential reference to provide environmental and ecological scientists and researchers with the physical principles, analytic tools, and data analysis methods they need to solve problems. This book describes the principles by which radiative energy reaches the earth s surface and reviews the latest knowledge concerning the surface radiation budget. The processes of radiation, convection, conduction, evaporation, and carbon dioxide exchange are analyzed. Many applications of environmental physics principles are reviewed, including the roles of surface albedo and atmospheric aerosols in modifying microclimate and climate, remote sensing of vegetation properties, wind forces on trees and crops, dispersion of pathogens and aerosols, controls of evaporation from vegetation and soil (including implications of changing weather and climate), and interpretation of micrometeorological measurements of carbon dioxide and other trace gas fluxes.
Presents a unique synthesis of micrometeorology and ecology in its widest senseDeals quantitatively with the impact of weather on living systems but also with the interactions between organisms and the atmosphere that are a central feature of life on earthOffers numerous worked examples and problems with solutionsProvides many examples of laboratory and field measurements and their interpretationIncludes an up-to-date bibliography and review of recent micrometeorological applications in forestry, ecology, hydrology, and agriculture"

This book deals with fractals in understanding problems encountered in earth science, and their solutions. It starts with an analysis of two classes of methods (homogeneous fractals random models, and homogeneous source distributions or "one point" distributions) widely diffused in the geophysical community, especially for studying potential fields and their related source distributions. Subsequently, the use of fractals in potential fields is described by scaling spectral methods for estimation of curie depth. The book also presents an update of the use of the fractal concepts in geological understanding of faults and their significance in geological modelling of hydrocarbon reservoirs. Geophysical well log data provide a unique description of the subsurface lithology; here, the Detrended Fluctuation Analysis technique is presented in case studies located off the west-coast of India. Another important topic is the fractal model of continuum percolation which quantitatively reproduce the flow path geometry by applying the Poiseuille's equation. The pattern of fracture heterogeneity in reservoir scale of natural geological formations can be viewed as spatially distributed self-similar tree structures; here, the authors present simple analytical models based on the medium structural characteristics to explain the flow in natural fractures. The Fractal Differential Adjacent Segregation (F-DAS) is an unconventional approach for fractal dimension estimation using a box count method. The present analysis provides a better understanding of variability of the system (adsorbents - adsorbate interactions). Towards the end of book, the authors discuss multi-fractal scaling properties of seismograms in order to quantify the complexity associated with high-frequency seismic signals. Finally, the book presents a review on fractal methods applied to fire point processes and satellite time-continuous signals that are sensitive to fire occurrences.

This thesis develops new and powerful methods for identifying planetary signals in the presence of "noise" generated by stellar activity, and explores the physical origin of stellar intrinsic variability, using unique observations of the Sun seen as a star. In particular, it establishes that the intrinsic stellar radial-velocity variations mainly arise from suppression of photospheric convection by magnetic fields. With the advent of powerful telescopes and instruments we are now on the verge of discovering real Earth twins in orbit around other stars. The intrinsic variability of the host stars themselves, however, currently remains the main obstacle to determining the masses of such small planets. The methods developed here combine Gaussian-process regression for modeling the correlated signals arising from evolving active regions on a rotating star, and Bayesian model selection methods for distinguishing genuine planetary signals from false positives produced by stellar magnetic activity. The findings of this thesis represent a significant step towards determining the masses of potentially habitable planets orbiting Sun-like stars.

This book provides new structural, biochemical, and clinical information on ABC transporters. The authors explore and describe the state of the art of research, knowledge, and prospects for the future for this important family of proteins. The first ABC transporter was discovered in 1973 and was named P-glycoprotein. It elicits resistance to cytotoxic drugs, chiefly in human tumours, within which chemotherapy failure is observed in about 50% of cases. Together with its complex pharmacology, and even a suspected role in Alzheimer's disease, this ABC transporter still eludes a clinical solution to its multidrug resistance property. ABC transporters are integral membrane active proteins and they belong to one of the largest protein families across all species. Their myriad roles encompass the import or export of a diverse range of allocrites, including ion, nutrients, peptides, polysaccharides, lipids, and xenobiotics. They are of major medical importance with many members elaborating multidrug resistance in bacteria, fungi, yeast, parasites, and humans. Other ABC transporters are involved in a number of inherited diseases, including cystic fibrosis, macular degeneration, gout, and several other metabolic disorders

Winner of the 2021 Donald E. Osterbrock Book Prize for Historical Astronomy In Decoding the Stars, Ileana Chinnici offers an account of the life of the Jesuit scientist Angelo Secchi (1818-1878). In addition to providing an invaluable account of Secchi's life and work-something that has been sorely lacking in the English-language scholarship-this biography will be especially stimulating for those interested in the evolution of astrophysics as a discipline from the nineteenth century onward. Despite his eclecticism, reminiscent of the natural philosophers of the seventeenth and eighteenth centuries, Secchi was in many ways a very modern scientist: open to innovation and cooperation, and a promoter of popularization and citizen science. Secchi also appears fully inserted in the cultural context of his time: he participated in philosophical and scientific debates, spread new theories and ideas, but also suffered the consequences of political events that marked those years and impacted on his life and activities.

Tackling galactic evolution in a truly novel way, this outstanding thesis statistically explores the long-term evolution of galaxies, using recent theoretical breakthroughs that explicitly account for their self-gravity. While treating processes statistically, the astrophysical differences on each scale are also captured. As the archetype of self-amplified diffusion, the implications of the thesis go far beyond astrophysics. Gravity is the driving force in galaxies, from their far outskirts to their innermost cores. These "extended kinetic theories" offer unique physical insights into the competing dynamical processes at play, complementing N-body approaches. The thesis successfully gauges the role of nature and nurture in establishing the galaxies' observed properties, using kinetic equations to capture both sources of fluctuations. Further, it shows how secular diffusion shapes the phase space structure of cold stellar disks. The thesis subsequently determines the characteristic timescales and examines the signatures of secular evolution in this framework on two scales: from the kinetic evolution in galactic disks and their thickening via giant molecular clouds; all the way down to the stellar resonant relaxation of the central cluster and its black hole.