This thesis presents a systematic discussion of experimental approaches to investigating the nonlinear interaction of ultrashort visible strong fields with dielectrics directly in the time domain. The key finding is the distinctly different peak-intensity dependence of the light-matter energy transfer dynamics on the one hand, and the observed transient optical and electronic modifications on the other. As the induced electron dynamics evolve on sub-femtosecond timescales, real-time spectroscopy requires attosecond temporal resolution. This allows a range of parameters to be identified where the optical properties of the samples exposed to ultrashort light fields suffer dramatic changes allowing signal metrology while real absorption leading to dissipation is essentially absent. These findings indicate the feasibility of efficient optical switching at frequencies several orders of magnitude faster than current state-of-the-art electronics and thus have far-reaching technological consequences.

This book provides insight into the underlying basic theories and concepts in X-ray, light, and neutron scattering. The three scattering principles are systematically presented, together with a unified description based on elastic scattering of electromagnetic waves and the Schroedinger wave from matter. These explanations are presented with an introduction of their common Born approximation using a consistent set of symbols and terminology and with step-by-step derivations of equations. This book emphasizes the combined applications of these three scattering methods, wherever and whenever possible, as a very powerful methodology for characterization of internal structures of soft matters in the length scale ranging from subnanometers to a few 10 micron meters. These applications include explorations for evolution of hierarchically self-organized internal structures of a variety of soft matters, including cells, under diverse environmental conditions. This book will not only be an excellent resource for graduate students and academic researchers who analyze structures of soft matters and polymers, but it will also be useful for researchers in industries.

Covering everything from the basic theoretical and practical knowledge to new exciting developments in the field with a focus on analytical and life science applications, this monograph shows how to apply surface-enhanced Raman scattering (SERS) for solving real world problems. From the contents: * Theory and practice of SERS * Analytical applications * SERS combined with other analytical techniques * Biophysical applications * Life science applications including various microscopies Aimed at analytical, surface and medicinal chemists, spectroscopists, biophysicists and materials scientists. Includes a Foreword by the renowned Raman spectroscopist Professor Wolfgang Kiefer, the former Editor-in-Chief of the Journal of Raman Spectroscopy.

This book provides an understandable review of SU(3) representations, SU(3) Wigner-Racah algebra and the SU(3) SO(3) integrity basis operators, which are often considered to be difficult and are avoided by most nuclear physicists. Explaining group algebras that apply to specific physical systems and discussing their physical applications, the book is a useful resource for researchers in nuclear physics. At the same time it helps experimentalists to interpret data on rotational nuclei by using SU(3) symmetry that appears in a variety of nuclear models, such as the shell model, pseudo-SU(3) model, proxy-SU(3) model, symplectic Sp(6, R) model, various interacting boson models, various interacting boson-fermion models, and cluster models. In addition to presenting the results from all these models, the book also describes a variety of statistical results that follow from the SU(3) symmetry.

In this thesis, the author outlines the development of new monolithic columns and isotope dimethyl labeling strategies and their applications in high-performance proteome analyses. Though different types of monolithic columns have been widely developed for chromatography and electrophoresis separation, their application in proteomics for complex peptide mixtures separation is still a challenge. The author discusses the preparation of new monolithic columns and optimization of chromatography separation capability to improve coverage and accuracy of proteome analysis. Further, the author describes a novel online multidimensional chromatography system combined with automated online isotope labeling, which significantly improves the throughput, sensitivity and accuracy of quantitative proteomics. In addition to the development of new technologies, the author investigates the proteome and phosphoproteome expression changes of clinical hepatocellular carcinoma tissues and the hippocampi of mice with Alzheimer s disease. The work in this thesis has led to several publications in high-profile journals in the fields of analytical chemistry and proteome research."

This book covers the fundamental aspects of fiber lasers and fiber amplifiers, and includes a wide range of material from laser physics fundamentals to state-of-the-art topics in this rapidly growing field of quantum electronics. This expanded and updated new edition includes substantial new material on nonlinear frequency conversion and Raman fiber lasers and amplifiers, as well as an expanded list of references inclusive of the recent literature in the field. Emphasis is placed on the nonlinear processes taking place in fiber lasers and amplifiers, their similarities, differences to, and their advantages over other solid-state lasers. The reader will learn the basic principles of solid-state physics and optical spectroscopy of laser active centers in fibers, the main operational laser regimes, and will receive practical recommendations and suggestions on fiber laser research, laser applications, and laser product development. The book will be useful for students, researchers, and professional physicists and engineers who work with lasers in the optical and telecommunications field, as well as those in the chemical and biological industries.

The latest edition of this highly acclaimed title introduces the reader to a wide range of spectroscopies, and includes both the background theory and applications to structure determination and chemical analysis. It covers rotational, vibrational, electronic, photoelectron and Auger spectroscopy, as well as EXAFs and the theory of lasers and laser spectroscopy. * A revised and updated edition of a successful, clearly written book* Includes the latest developments in modern laser techniques, such as cavity ring--down spectroscopy and femtosecond lasers* Provides numerous worked examples, calculations and questions at the end of chapters

Annual Reports on NMR Spectroscopy, Volume 108, highlights new advances in the field, with this new volume presenting interesting chapters written by an international board of authors.

Mass spectrometry (MS) along with its hyphenated techniques is capable of high throughput, sensitivity, accuracy and selectivity for the analysis of structure and composition of almost any product. Like in electrophoresis, MS separates mo- cules based on the mass-to-charge ratio. In case of gel electrophoresis (SDS- PAGE), a well-known and efficient bioanalytical technique, proteins bear negative charges but have the same charge density, so proteins are separated according to their size. Similarly, in case of MS analysis, proteins carry the same charge, and are separated by their molecular weight. Unlike SDS-PAGE, however, modern ultra high resolution MS discerns very small mass differences and can resolve and completely identify in a single experiment species of the same nominal mass in complex biological mixtures. Consequently, MS can be used for the structural characterization, identification and sensitive detection of mixtures of biomolecules or for assessing the quality of isolated proteins (purity, integrity, or post-translational modifications, for example), carbohydrates, nucleic acids, drugs, metabolites, pollutants etc. In the post-genome era, MS is continuously developing as one of the most re- able analytical method for elucidating the structure of molecules originating from various biological matrices. The potential of MS for high-sensitive structural a- lyses became unsurpassable after the introduction of electrospray (ESI) and matrix assisted laser/desorption ionization (MALDI) methods, on one hand, and the pos- bility to deduce in detail unknown biopolymer structures by highly accurate mo- cular mass measurement followed by sequencing using dissociation techniques based on multiple stage MS, on the other.

This book provides a multidisciplinary overview to the application of high order derivative spectrophotometry and Electron Spin Resonance (ESR) spectroscopy in biology and ecology. The characteristics of the principle methods as well as the generation of reliable spectra are discussed in general terms allowing the reader to gain an idea of these methods' potentials. Furthermore the authors give an extended overview to the spectroscopic and spectro-photometric analysis of specific biological materials. This volume is a well condensed description of an analytical method and a clear review to its application in biology and related fields and an essential tool for researchers who are new in the field of spectroscopic methods and their applications in the life sciences.

This thesis describes the results of angle resolved photoemission spectroscopy experiments on delafossite oxide metals, and theoretical work explaining these observations. The study was motivated by the extraordinarily high conductivity of the non-magnetic delafossites PdCoO2 and PtCoO2, the measurement of whose electronic structure is reported and discussed. Two unexpected effects were observed in the course of the investigation; each is described and analysed in detail. Firstly, a previously unrecognised type of spectroscopic signal, allowing the non-magnetic probe of photoemission to become sensitive to spin-spin correlations, was observed in the antiferromagnetic PdCrO2. Its origin was identified as the Kondo-like coupling of itinerant and Mott insulating electrons. Furthermore, surface states exhibiting an unusually large Rashba-like spin-splitting were observed on the transition metal terminated surfaces of delafossites. The large inversion symmetry breaking energy scale, a consequence of the unusual structure of the surface layer, is identified as the origin of the effect.

Fifth volume of a 40 volume series on nanoscience and nanotechnology, edited by the renowned scientist Challa S.S.R. Kumar. This handbook gives a comprehensive overview about X-ray and Neutron Techniques for Nanomaterials Characterization. Modern applications and state-of-the-art techniques are covered and make this volume an essential reading for research scientists in academia and industry.

Fabrication technologies for nanostructured devices have been developed recently, and the electrical and optical properties of such nanostructures are a subject of advanced research.This book describes the different approaches to spectroscopic microscopy, i.e., Electron Beam Probe Spectroscopy, Spectroscopic Photoelectron Microscopy, and Scanning Probe Spectroscopy. It will be useful as a compact source of reference for the experienced reseracher, taking into account at the same time the needs of postgraduate students and nonspecialist researchers by using a tutorial approach throughout.

This book describes the latest developments in the new research discipline of X-ray nanochemistry, which uses nanomaterials to enhance the effectiveness of X-ray irradiation. Nanomaterials now can be synthesized in such a way as to meet the demand for complex functions that enhance the X-ray effect. Innovative methods of delivering the X-rays, which can interact with those nanomaterials much more strongly than energetic electrons and gamma rays, also create new opportunities to enhance the X-ray effect. As a result, new concepts are conceived and new developments are made in the last decade, which are discussed and summarized in this book. This book will help define the discipline and encourage more students and scientists to work in this discipline. These efforts will eventually lead to formation of a full set of physical, chemical and materials principles for this new research field.

Molecular and Laser Spectroscopy, Advances and Applications: Volume 2 gives students and researchers an up-to-date understanding of the fast-developing area of molecular and laser spectroscopy. This book covers basic principles and advances in several conventional as well as new and upcoming areas of molecular and laser spectroscopy, such as a wide range of applications in medical science, material science, standoff detection, defence and security, chemicals and pharmaceuticals, and environmental science. It covers the latest advancements, both in terms of techniques and applications, and highlights future projections. Editors V.P. Gupta and Yukihiro Ozaki have brought together eminent scientists in different areas of spectroscopy to develop specialized topics in conventional molecular spectroscopy (Cavity ringdown, Matrix Isolation, Intense THz, Far- and Deep- UV, Optogalvanic ), linear and nonlinear laser spectroscopy (Rayleigh & Raman Scattering), Ultrafast Time-resolved spectroscopy, and medical applications of molecular spectroscopy. and advanced material found in research articles. This new volume expands upon the topics covered in the first volume for scientists to learn the latest techniques and put them to practical use in their work.

The past three decades have witnessed the great success of lithium-ion batteries, especially in the areas of 3C products, electrical vehicles, and smart grid applications. However, further optimization of the energy/power density, coulombic efficiency, cycle life, charge speed, and environmental adaptability are still needed. To address these issues, a thorough understanding of the reaction inside a battery or dynamic evolution of each component is required. Microscopy and Microanalysis for Lithium-Ion Batteries discusses advanced analytical techniques that offer the capability of resolving the structure and chemistry at an atomic resolution to further drive lithium-ion battery research and development. * Provides comprehensive techniques that probe the fundamentals of Li-ion batteries. * Covers the basic principles of the techniques involved as well as its application in battery research. * Describes details of experimental set-ups and procedure for successful experiments. This reference is aimed at researchers, engineers, and scientists studying lithium-ion batteries including chemical, materials, and electrical engineers, as well as chemists and physicists.

This book provides extensive and novel insights into transport phenomena in MnSi, paving the way for applying the topology and chirality of spin textures to the development of spintronics devices. In particular, it describes in detail the key measurements, e.g. magnetoresistance and nonlinear electronic transport, and multiple material-fabrication techniques based on molecular beam epitaxy, ion-beam microfabrication and micromagnetic simulation. The book also reviews key aspects of B20-type MnSi chiral magnets, which host magnetic skyrmions, nanoscale objects formed by helical spatial spin structures. Readers are then introduced to cutting-edge findings on the material. Furthermore, by reviewing the author's successful experiments, the book provides readers with a valuable update on the latest achievements in the measurement and fabrication of magnetic materials in spintronics.

When bombarded with X-rays, solid materials produce distinct scattering patterns similar to fingerprints. X-ray powder diffraction is a technique used to fingerprint solid samples, which are then identified and cataloged for future use—much the way the FBI keeps fingerprints on file. The current database of some 70,000 material prints has been put to a broad range of uses, from the analysis of moon rocks to testing drugs for purity.

Introduction to X-ray Powder Diffractometry fully updates the achievements in the field over the past fifteen years and provides a much-needed explanation of the state-of-the-art techniques involved in characterizing materials. It covers the latest instruments and methods, with an emphasis on the fundamentals of the diffractometer, its components, alignment, calibration, and automation.

The first three chapters outline diffraction theory in clear language, accessible to both students and professionals in chemistry, physics, geology, and materials science. The book's middle chapters describe the instrumentation and procedures used in X-ray diffraction, including X-ray sources, X-ray detection, and production of monochromatic radiation. The chapter devoted to instrument design and calibration is followed by an examination of specimen preparation methods, data collection, and reduction. The final two chapters provide in-depth discussions of qualitative and quantitative analysis.

While the material is presented in an orderly progression, beginning with basic concepts and moving on to more complex material, each chapter stands on its own and can be studied independently or used as a professional reference. More than 230 illustrations and tables demonstrate techniques and clarify complex material.

Self-contained, timely, and user-friendly, Introduction to X-ray Powder Diffractometry is an enormously useful text and professional reference for analytical chemists, physicists, geologists and materials scientists, and upper-level undergraduate and graduate students in materials science and analytical chemistry.

X-ray powder diffraction—a technique that has matured significantly in recent years—is used to identify solid samples and determine their composition by analyzing the so-called "fingerprints" they generate when X-rayed. This unique volume fulfills two major roles: it is the first textbook devoted solely to X-ray powder diffractometry, and the first up-to-date treatment of the subject in 20 years.

This timely, authoritative volume features:

• Clear, concise descriptions of both theory and practice—including fundamentals of diffraction theory and all aspects of the diffractometer
• A treatment that reflects current trends toward automation, covering the newest instrumentation and automation techniques
• Coverage of all the most common applications, with special emphasis on qualitative and quantitative analysis
• An accessible presentation appropriate for both students and professionals
• More than 230 tables and illustrations

Introduction to X-ray Powder Diffractometry, a collaboration between two internationally known and respected experts in the field, provides invaluable guidance to anyone using X-ray powder diffractometers and diffractometry in materials science, ceramics, the pharmaceutical industry, and elsewhere.

This thesis presents two significant results in the field of precision measurements in low-energy nuclear physics. Firstly, it presents a precise half-life determination of 11C, leading to the most precise ft-value for a beta decay transition between mirror nuclides, an important advance in the testing of the electroweak sector of the Standard Model. Secondly, it describes a high-precision mass measurement of 56Cu, a critical nucleus for determining the path of the astrophysical rapid-proton capture process, performed by the author using the LEBIT Penning trap at the National Superconducting Cyclotron Laboratory. This new measurement resolves discrepancies in previously-reported calculated mass excesses. In addition, the thesis also presents the construction and testing of a radio-frequency quadrupole cooler and buncher that will be part of the future N = 126 factory at Argonne National Laboratory aimed at producing nuclei of interest for the astrophysical rapid-neutron capture process for the first time.

SESSION 1- DESIGN ASPECTS - 1.1 Single Focusing Magnetic Deflection Mass Spectrometers - 1.2 The Design of Double Focusing Magnetic Deflection Instruments - 1.3 A New Cycloidal Mass Spectrometer - 1.4 A Time of Flight Mass Spectrometer - 1.5 Recent Developments in the Quadrupole Mass Filter - SESSION 2 - PHYSICAL AND CHROMATOGRAPHIC APPLICATIONS - 2.1 A Fast-scan Mass Spectrometer for Residual Gas Analysis and the Examination of Effluents from Gas Chromatography Columns - 2.2 Flavour Research with a Low Cost Fast-scan Mass Spectrometer - 2.3 A Gas Chromatograph-Mass Spectrometer Linkup Recent Developments - 2.4 A Small 1800 Deflection Partial Pressure-Total Pressure Gauge for Vacuum System Diagnosis - 2.5 A Cycloidal Mass Spectrometer Applied to the Measurement of the Speed of Sputter Ion Pumps - 2.6 The Sorption of Gases by Thin Films - SESSION 3 - CHEMICAL APPLICATIONS I - 3.1 The Use of a Quadrupole Mass Filter in the Study of a Reacting Surface - 3.2 Mass-spectrometric Investigation of the Formation of Di-imide by the Catalytic Decomposition of Hydrazine at Low Pressures on Platinum - 3.3 Rearrangement Processes in the Fragmentation of Organic Ions - 3.4 A Novel Ion in the Mass Spectra of Arylureas and Related Compounds - 3.5 Mass Spectra of Some Substituted Cyclotetrazenoboranes - 3.6 The Decomposition of 9,1O-Diphenylanthracene Under Electron Impact - SESSION 4 - CHEMICAL APPLICATIONS II - 4.1 Use of Multiplet Peaks in the Examination of High Molecular Weight Petroleum Fractions - 4.2 Inorganic Analysis of Spark Source Mass Spectrometry - 4.3 An Examination of Metal Chelates by Mass Spectrometry - 4.4 Data Handling and Instrumentation in the A.W.R.E. Mass Spectrometers - SYMPOSIUM IMPRESSIONS - INDEX

Sample Introduction Systems in ICPMS and ICPOES provides an in-depth analysis of sample introduction strategies, including flow injection analysis and less common techniques, such as arc/spark ablation and direct sample insertion. The book critically evaluates what has been accomplished so far, along with what can be done to extend the capabilities of the technique for analyses of any type of sample, such as aqueous, gaseous or solid. The latest progress made in fields, such as FIA, ETV, LC-ICP-MS and CE-ICP-MS is included and critically discussed. The book addresses problems related to the optimization of the system, peak dispersion and calibration and automatization.

This book presents a selection of advanced lectures from leading researchers, providing recent theoretical results on strongly coupled quantum field theories. It also analyzes their use for describing new quantum states, which are physically realizable in condensed matter, cold-atomic systems, as well as artificial materials. It particularly focuses on the engineering of these states in quantum devices and novel materials useful for quantum information processing. The book offers graduate students and young researchers in the field of modern condensed matter theory an updated review of the most relevant theoretical methods used in strongly coupled field theory and string theory. It also provides the tools for understanding their relevance in describing the emergence of new quantum states in a variety of physical settings. Specifically, this proceedings book summarizes new and previously unrelated developments in modern condensed matter physics, in particular: the interface of condensed matter theory and quantum information theory; the interface of condensed matter physics and the mathematics emerging from the classification of the topological phases of matter, such as topological insulators and topological superconductors; and the simulation of condensed matter systems with cold atoms in optical lattices.

This book is a collection of selected papers presented at the symposium titled "In situ Spectroscopy in Monomer and Polymer Synthesis," held at the April, 2001 ACS National Meeting in San Diego, California, USA. The co-organizers of this symposium were Timothy Long, Judit E. Puskas, Robson F. Storey, and J. Andrews. In situ spectroscopic monitoring is gaining popularity both in academia and industry. FfIR monitoring is used most frequently, but UV-visible, raman, and NMR spectroscopy are also important. This book concentrates mostly on FfIR monitoring, both in the near and mid-infrared ranges. The first chapter is a short general overview of FfIR spectroscopy, followed by the symposium contribu tions. We thought that this would be especially useful for student readers. We hope that the book will present a state-of-the-art overview of research related to in situ spectroscopic monitoring. -Judit E. Puskas ix Acknowledgments This book would not have been possible without the dedicated effort of the chapter contributors and the symposium committee: Professor Judit E. Puskas Professor Timothy Long Professor Robson F. Storey Professor J. Andrews The symposium was financially supported by: ACS-Petroleum Research Fund REMSPEC Co. Wyatt Technology Co."

This book describes the basic physical principles of techniques to generate and ultrashort pulse lasers and applications to ultrafast spectroscopy of various materials covering chemical molecular compounds, solid-state materials, exotic novel materials including topological materials, biological molecules and bio- and synthetic polymers. It introduces non-linear optics which provides the basics of generation and measurement of pulses and application examples of ultrafast spectroscopy to solid state physics. Also it provide not only material properties but also material processing procedures. The book describes also details of the world shortest visible laser and DUV lasers developed by the author's group. It is composed of the following 12 Sections: The special features of this book is that it is written by a single author with a few collaborators in a systematic way. Hence it provides a comprehensive and systematic description of the research field of ultrashort pulse lasers and ultrafast spectroscopy. Generation of ultrashort pulses in deep ultraviolet to near infrared Generation of ultrashort pulses in terahertz Carrier envelope phase (CEP) Simple NLO processes with a few colors Multi-color involved NLO processes Multi-color ultrashort pulse generation NLO materials NLO processes in time-resolved spectroscopy Low dimension materials Conductors and superconductors Chemical reactions and material processing Photobiological reactions